CN109321174A - A kind of uncured water-based acrylic resin is fire-retardant embedding to meet glue and preparation method thereof - Google Patents
A kind of uncured water-based acrylic resin is fire-retardant embedding to meet glue and preparation method thereof Download PDFInfo
- Publication number
- CN109321174A CN109321174A CN201810824224.2A CN201810824224A CN109321174A CN 109321174 A CN109321174 A CN 109321174A CN 201810824224 A CN201810824224 A CN 201810824224A CN 109321174 A CN109321174 A CN 109321174A
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- fire
- acrylic resin
- retardant
- based acrylic
- water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Sealing Material Composition (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of uncured water-based acrylic resin it is fire-retardant it is embedding meet glue, including following components, and the weight percent of each component is respectively as follows: water-based acrylic resin: 40-50%；Epoxy resin: 30-40%；Fire retardant 8-12%；Dispersing aid 2-4%；Defoaming agent 0.5-2.5%；Chlorinated rubber powder 5-12%.The present invention discloses preparation methods.The filleting glue that the preparation method is prepared through the invention can construct at normal temperature, it is not only easy for construction, simple, and energy conservation and environmental protection, with excellent croop property, fire protecting performance and self-repairing capability, it is pollution-free, the percolating water that crack can effectively be blocked, can be widely applied to underground engineering expansion joint, deformation joint construction.
Description
Technical field
The present invention relates to a kind of waterproof material of the underground infrastructures seam crossing such as tunnel, pipe gallery, more particularly, to
A kind of uncured water-based acrylic resin it is fire-retardant it is embedding meet glue and preparation method thereof, belong to technical field of chemical products.
Background technique
The high speed development in city brings big city, megalopolis and is persistently transformed and expansion.The scale and structure in city are all
It is among big variation, a large amount of tunnel, pipe gallery etc. come into being with the expansion in city.Since tunnel, piping lane etc. bury
Set on underground, throughout the year in groundwater environment, waterproof effect quality directly affect tunnel using function and entire engineering
Success or failure.
Since construction factor, uneven settlement of foundation factor, temperature deformation factor, structural factor and vehicle pass-through are to knot
Structure has certain vibration disturbance, and the underground infrastructures seam crossing such as nearly most subways, subterranean tunnel, pipe gallery exists not
With the percolating water phenomenon of degree.Tunnel Water Leakage accelerates rail and fastener corrosion, damages railway roadbed and basis.Piping lane deformation joint exists
When local damage, external water source can be penetrated on the inside of structure by damaged deformation joint, cause deformation joint leak.Pipe gallery deformation
Stitching leakage phenomenon influences piping lane internal environment, is unfavorable for the safe operation of water supply, power supply, heat supply pipeline etc. in piping lane.
Currently, subterranean tunnel, pipe gallery seam waterproof are many kinds of, but market confusion, the good and bad jumbled together, and quality is irregular
It is uneven, cause waterproof effect bad so that at the tunnels such as deformation joint, construction joint seam waterproof become underground infrastructure control leakage,
Control the emphasis of infiltration.
Currently, common uncured rubber asphalt waterproof coating needs heating melting, heated by mating heating equipment, then
Blade coating or spraying application.It is generally necessary to which difficulty is larger, the requirement to equipment paint heating to being constructed after 120-150 DEG C again
Height, and energy consumption is high.In addition, the uncured water-repellent paint of solvent type is made decentralized medium with organic solvent, is adopted using asphalt as base-material
Make the modified material of pitch with polymer rubber and auxiliary agent, then is made with proper amount of adjuvant.But solvent usage is big, and material is solid
Content is low, pollutes the environment after solvent volatilization, and solvent volatilization and residual can all influence the performance of coating.Semi-enclosedly
The requirements such as temperature, fire prevention and environmental protection and worker's physical and mental health are hampered both by iron, subterranean tunnel, pipe gallery construction
The expansion of technology uses.
Summary of the invention
To solve the deficiencies in the prior art, the purpose of the present invention is to provide one kind to construct at normal temperature, easy for construction,
And the uncured water-based acrylic resin of energy conservation and environmental protection, simple process fire-retardant embedding meets glue and preparation method thereof.
In order to achieve the above objectives, the present invention adopts the following technical scheme that:
A kind of uncured water-based acrylic resin is fire-retardant embedding to meet glue, including following components, and the weight percent of each component
It is respectively as follows:
Water-based acrylic resin: 40-50%；
Epoxy resin: 30-40%；
Fire retardant 8-12%；
Dispersing aid 2-4%；
Defoaming agent 0.5-2.5%；
Chlorinated rubber powder 5-12%.
The epoxide number of above-mentioned epoxy resin is E44 (commercially available).
Above-mentioned fire retardant is at least one of antimony trichloride, antimony trioxide.
Above-mentioned dispersing aid is BYK191 (brand is Germany Bi Ke, commercially available).
Above-mentioned defoaming agent is BYK-012 or BYK-015 (brand is Germany Bi Ke, commercially available).
And the viscosity of above-mentioned chlorinated rubber powder is then 8-30mP.S.
Further, the fire-retardant embedding preparation method for meeting glue of above-mentioned uncured water-based acrylic resin, comprising the following steps:
Required raw material is weighed according to the weight ratio, first mixes water-based acrylic resin and epoxy resin, forms mixed solution, is being turned
Under conditions of fast 300-400r/min, after stirring 60-90min, revolving speed is adjusted to 400-600r/min, then remaining ingredient is former
Material is successively scattered in the mixed solution of water-based acrylic resin and epoxy resin, under room temperature, stirs 40-80min, is made each
After component is uniformly mixed, obtain that uncured water-based acrylic resin is fire-retardant embedding to meet glue.
The invention has the beneficial effects that: the present invention is enhanced by introducing epoxy resin in water-based acrylic resin
The fire-retardant embedding adhesion strength for meeting glue and basal plane, the fire-retardant embedding inside for meeting glue never solidify, and have excellent croop property, and obstruction is split
The percolating water of seam, and the uncured water-based acrylic resin that is prepared it is fire-retardant it is embedding meet glue that there is self-repairing capability, can from
I heals, and maintains complete waterproof layer, effectively prevention percolating water, and can construct on the basal plane of moist (basal plane is without bright water),
Particularly, underground engineering expansion joint, deformation joint construction be can be applied to, can greatly shorten the construction time, further, it is also possible to normal
Temperature lower construction, absolutely not smog pollution, energy conservation and environmental protection, are conducive to the health of industry security protection and operator, and
With excellent fire protecting performance, fire protecting performance reaches FY-0 grades of technical requirements, can reduce the safety accident as caused by fire
It is injured with life, and preparation method step is simple, construction technology is succinct, significantly reduces production energy consumption, has saved and has been produced into
This.
Specific embodiment
Below in conjunction with detailed description of the invention by specific embodiments.
Embodiment 1
Required raw material is weighed according to the weight ratio, first puts the epoxy resin of 40% water-based acrylic resin and 30%
Enter mixing in stirring container, form mixed solution, under conditions of revolving speed 400r/min, after stirring 80min, improving revolving speed is
600r/min, then by remaining ingredient raw material: 12% fire retardant antimony trichloride, 4% dispersing aid BYK191,2% defoaming
Agent BYK-012,12% chlorinated rubber powder be successively scattered in the mixed solution of water-based acrylic resin and epoxy resin, room temperature
Under the conditions of, 70min is stirred, after being uniformly mixed each component, obtains the uncured water that can be used for underground foundation buildings waterproof
Property acrylic resin is fire-retardant embedding to meet glue.
According to " flame retardant sealant for building " GB/T 24267-2009, the performance indexes of 1 products obtained therefrom of embodiment is surveyed
Test result is as follows:
1 embodiment of table, 1 products obtained therefrom the performance test results
2 embodiment of table, 1 products obtained therefrom the performance test results
As shown in Tables 1 and 2: the detection project of 1 products obtained therefrom of embodiment meets flame retardant sealant for building " GB/T
The performance requirement of 4267-2009, flame retardant property reach FY-0 grades in " flame retardant sealant for building " GB/T 4267-2009 of skill
Art requirement.
Embodiment 2
Required raw material is weighed according to the weight ratio, first puts the epoxy resin of 44% water-based acrylic resin and 33%
Enter mixing in stirring container, form mixed solution, under conditions of revolving speed 300r/min, after stirring 90min, improving revolving speed is
500r/min, then by remaining ingredient raw material: 9% fire retardant antimony trichloride, 2.5% dispersing aid BYK191,1.5% disappear
Infusion BYK-012,10% chlorinated rubber powder be successively scattered in the mixed solution of water-based acrylic resin and epoxy resin,
Under room temperature, 60min is stirred, after being uniformly mixed each component, obtains can be used for the non-solid of underground foundation buildings waterproof
Change that water-based acrylic resin is fire-retardant embedding to meet glue.
According to " flame retardant sealant for building " GB/T 24267-2009, the performance indexes of 2 products obtained therefrom of embodiment is surveyed
Test result is as follows:
3 embodiment of table, 2 products obtained therefrom the performance test results
4 embodiment of table, 2 products obtained therefrom the performance test results
As shown in table 3 and table 4: the detection project of 2 products obtained therefrom of embodiment meets flame retardant sealant for building " GB/T
The performance requirement of 4267-2009, flame retardant property reach FY-0 grades in " flame retardant sealant for building " GB/T 4267-2009 of skill
Art requirement.
Embodiment 3
Required raw material is weighed according to the weight ratio, first puts the epoxy resin of 45% water-based acrylic resin and 36%
Enter mixing in stirring container, form mixed solution, under conditions of revolving speed 300r/min, after stirring 60min, revolving speed is adjusted to
500r/min, then by remaining ingredient raw material: 8% fire retardant antimony trioxide, 2% dispersing aid BYK191,1% defoaming agent
BYK-015,8% chlorinated rubber powder be successively scattered in the mixed solution of water-based acrylic resin and epoxy resin, room temperature item
Under part, 80min is stirred, after being uniformly mixed each component, obtains can be used for the uncured aqueous of underground foundation buildings waterproof
Acrylic resin is fire-retardant embedding to meet glue.
According to " flame retardant sealant for building " GB/T 24267-2009, the performance indexes of 3 products obtained therefrom of embodiment is surveyed
Test result is as follows:
5 embodiment of table, 3 products obtained therefrom the performance test results
6 embodiment of table, 3 products obtained therefrom the performance test results
As shown in table 5 and table 6: the detection project of 3 products obtained therefrom of embodiment meets flame retardant sealant for building " GB/T
The performance requirement of 4267-2009, flame retardant property reach FY-0 grades in " flame retardant sealant for building " GB/T 4267-2009 of skill
Art requirement.
Embodiment 4
Required raw material is weighed according to the weight ratio, first puts the epoxy resin of 42% water-based acrylic resin and 40%
Enter mixing in stirring container, form mixed solution, under conditions of revolving speed 300r/min, after stirring 80min, revolving speed is adjusted to
600r/min, then by remaining ingredient raw material: 8% fire retardant antimony trioxide, 2% dispersing aid BYK191,1.5% defoaming
Agent BYK-015,6.5% chlorinated rubber powder be successively scattered in the mixed solution of water-based acrylic resin and epoxy resin, room
Under the conditions of temperature, 70min is stirred, after being uniformly mixed each component, obtains can be used for the uncured of underground foundation buildings waterproof
Water-based acrylic resin is fire-retardant embedding to meet glue.
According to " flame retardant sealant for building " GB/T 24267-2009, the performance indexes of 4 products obtained therefrom of embodiment is surveyed
Test result is as follows:
7 embodiment of table, 4 products obtained therefrom the performance test results
8 embodiment of table, 4 products obtained therefrom the performance test results
As shown in table 7 and table 8: the detection project of 4 products obtained therefrom of embodiment meets flame retardant sealant for building " GB/T
The performance requirement of 4267-2009, flame retardant property reach FY-0 grades in " flame retardant sealant for building " GB/T 4267-2009 of skill
Art requirement.
Although the preferred embodiment of the application has been described, it is created once a person skilled in the art knows basic
Property concept, then additional changes and modifications may be made to these embodiments.So it includes excellent that the following claims are intended to be interpreted as
It selects embodiment and falls into all change and modification of the application range.Obviously, those skilled in the art can be to the application
Various modification and variations are carried out without departing from spirit and scope.If in this way, these modifications and variations of the application
Belong within the scope of the claim of this application and its equivalent technologies, then the application is also intended to encompass these modification and variations and exists
It is interior.
Claims (6)
1. a kind of uncured water-based acrylic resin is fire-retardant embedding to meet glue, which is characterized in that including following components, and the weight of each component
Amount percentage is respectively as follows:
Water-based acrylic resin: 40-50%；
Epoxy resin: 30-40%；
Fire retardant 8-12%；
Dispersing aid 2-4%；
Defoaming agent 0.5-2.5%；
Chlorinated rubber powder 5-12%.
2. a kind of uncured water-based acrylic resin according to claim 1 is fire-retardant embedding to meet glue, which is characterized in that described
Fire retardant is at least one of antimony trichloride, antimony trioxide.
3. a kind of uncured water-based acrylic resin according to claim 1 is fire-retardant embedding to meet glue, which is characterized in that described
Dispersing aid is BYK191.
4. a kind of uncured water-based acrylic resin according to claim 1 is fire-retardant embedding to meet glue, which is characterized in that described
Defoaming agent is BYK-012 or BYK-015.
5. a kind of uncured water-based acrylic resin according to claim 1 is fire-retardant embedding to meet glue, which is characterized in that described
The viscosity of chlorinated rubber powder is 8-30mP.S.
6. a kind of uncured fire-retardant embedding preparation method for meeting glue of water-based acrylic resin described in claim 1, which is characterized in that
The following steps are included: weighing required raw material according to the weight ratio, water-based acrylic resin and epoxy resin are mixed first, formed
Revolving speed after stirring 60-90min, is adjusted to 400-600r/min under conditions of revolving speed 300-400r/min by mixed solution,
It again successively disperses remaining ingredient raw material in the mixed solution of water-based acrylic resin and epoxy resin, under room temperature, stirs
40-80min is mixed, after being uniformly mixed each component, obtains that uncured water-based acrylic resin is fire-retardant embedding to meet glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810824224.2A CN109321174B (en) | 2018-07-25 | 2018-07-25 | Non-cured water-based acrylic resin flame-retardant caulking glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810824224.2A CN109321174B (en) | 2018-07-25 | 2018-07-25 | Non-cured water-based acrylic resin flame-retardant caulking glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109321174A true CN109321174A (en) | 2019-02-12 |
| CN109321174B CN109321174B (en) | 2021-01-08 |
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|---|---|---|---|
| CN201810824224.2A Active CN109321174B (en) | 2018-07-25 | 2018-07-25 | Non-cured water-based acrylic resin flame-retardant caulking glue and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113716912A (en) * | 2021-07-12 | 2021-11-30 | 广东碧橙建材有限公司 | Negative ion ceramic tile glue |
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| KR100730984B1 (en) * | 2006-03-29 | 2007-06-22 | 도레이새한 주식회사 | Adhesive composition for flexible copper clad laminated film |
| KR20140008070A (en) * | 2012-07-10 | 2014-01-21 | 주식회사 정우인터내셔날 | The tile adhesive with improving water-repellent and water-resistance |
| CN105885582A (en) * | 2016-05-26 | 2016-08-24 | 杭州高思途实业有限公司 | Water-borne plastic paint and preparation method thereof |
| CN106543931A (en) * | 2016-10-28 | 2017-03-29 | 天长市永泰密封材料有限公司 | Anti-oxidant aqueous impervious container fluid sealant of a kind of antirust and preparation method thereof |
-
2018
- 2018-07-25 CN CN201810824224.2A patent/CN109321174B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100730984B1 (en) * | 2006-03-29 | 2007-06-22 | 도레이새한 주식회사 | Adhesive composition for flexible copper clad laminated film |
| KR20140008070A (en) * | 2012-07-10 | 2014-01-21 | 주식회사 정우인터내셔날 | The tile adhesive with improving water-repellent and water-resistance |
| CN105885582A (en) * | 2016-05-26 | 2016-08-24 | 杭州高思途实业有限公司 | Water-borne plastic paint and preparation method thereof |
| CN106543931A (en) * | 2016-10-28 | 2017-03-29 | 天长市永泰密封材料有限公司 | Anti-oxidant aqueous impervious container fluid sealant of a kind of antirust and preparation method thereof |
Non-Patent Citations (1)
| Title |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113716912A (en) * | 2021-07-12 | 2021-11-30 | 广东碧橙建材有限公司 | Negative ion ceramic tile glue |
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| CN109321174B (en) | 2021-01-08 |
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