CN109320822A - A kind of production method of vinyl toy mashing toning environment-friendly type PVC - Google Patents
A kind of production method of vinyl toy mashing toning environment-friendly type PVC Download PDFInfo
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- CN109320822A CN109320822A CN201811188127.5A CN201811188127A CN109320822A CN 109320822 A CN109320822 A CN 109320822A CN 201811188127 A CN201811188127 A CN 201811188127A CN 109320822 A CN109320822 A CN 109320822A
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- Prior art keywords
- parts
- environment
- mashing
- toning
- friendly type
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of production methods of vinyl toy mashing toning environment-friendly type PVC, it is made in parts by mass by following raw material: 80-100 parts of polyvinyl monomer, 1-2 parts of fatty alcohol, 70-110 parts of deionized water, 1-2 parts of oil-soluble composite initiator, 1-3 parts of emulsifier, 5-10 parts of mill base, 5-20 parts of polypropylene fibre, 1-3 parts of primary plasticizer, 1-2 parts of co-plasticizer, 2-4 parts of stabilizer, 1-5 parts of fire retardant, the present invention is simple, adhesive force, wear-resisting and compressive property greatly promote, and PVC obtained is environment friendly and pollution-free, safety greatly improves.
Description
Technical field
The present invention relates to vinyl toy mashing toning PVC manufacture technology field, specially a kind of vinyl toy mashing is adjusted
The production method of color environment-friendly type PVC.
Background technique
It is just vinyl toy with the toy that glue material is done is warded off, is to touch up very easypro by a kind of call of production material classification
Clothes, it is sliding sliding, have one is very soft, there are also one is hard, that be just divided into it is soft ward off glue and ward off glue firmly, and the inside is hollow
's.
PVC paste resin is that such resin is mainly applied so that paste forms are made as its name suggests, and people commonly use such
Paste is referred to as plasticized paste, is a kind of unique liquid form of the igelite under rough, paste resin often by lotion and
Microsuspending method is made.
PVC adhesive force, the wear-resisting property of the toning of vinyl toy mashing at present are poor, are easily deformed and fall off, color is not bright enough
It is bright, and material is not environmentally friendly enough mostly, it would therefore be highly desirable to a kind of improved technology come solve in the presence of the prior art this ask
Topic.
Summary of the invention
The purpose of the present invention is to provide a kind of vinyl toy mashing toning environment-friendly type PVC production method, adhesive force,
Wear-resisting and compressive property greatly promotes, and PVC obtained is environment friendly and pollution-free, and safety greatly improves, to solve above-mentioned background skill
The problem of being proposed in art.
To achieve the above object, the invention provides the following technical scheme: a kind of vinyl toy is beaten toning environment-friendly type PVC
Production method, be made in parts by mass by following raw material: 80-100 parts of polyvinyl monomer, 1-2 parts of fatty alcohol, deionized water
70-110 parts, 1-2 parts of oil-soluble composite initiator, 1-3 parts of emulsifier, 5-10 parts of mill base, 5-20 parts of polypropylene fibre, main plasticising
1-3 parts of agent, 1-2 parts of co-plasticizer, 2-4 parts of stabilizer, 1-5 parts of fire retardant.
Preferably, it is made in parts by mass by following raw material: 90 parts of polyvinyl monomer, 1 part of fatty alcohol, deionized water 90
Part, 1 part of oil-soluble composite initiator, 2 parts of emulsifier, 8 parts of mill base, 15 parts of polypropylene fibre, 2 parts of primary plasticizer, co-plasticizer 1
Part, 3 parts of stabilizer, 3 parts of fire retardant.
Preferably, the plasticizer is epoxidized soybean oil.
Preferably, the co-plasticizer is poly- decanedioic acid propylene glycol ester.
Preferably, the stabilizer is metal soap.
Preferably, the fire retardant be trimethylbenzene lipoprotein of phosphoric acid, have antimony oxide, zinc borate, chlorinated paraffin one such or
It is a variety of.
Preferably, the emulsifier is anionic surfactant.
Preferably, vinyl toy mashing toning environment-friendly type PVC preparation method the following steps are included:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 3000r/
Min persistently stirs 25min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 55 DEG C, continue 18 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 65 DEG C by temperature setting, revolving speed is set as 4500r/min, continues 2h, obtains environment-friendly type PVC.
Compared with prior art, the beneficial effects of the present invention are:
Adhesive force, wear-resisting and compressive property greatly promote, and PVC obtained is environment friendly and pollution-free, and safety greatly improves.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The present invention provides a kind of technical solution: a kind of production method of vinyl toy mashing toning environment-friendly type PVC, by with
Lower raw material is made in parts by mass: 80-100 parts of polyvinyl monomer, 1-2 parts of fatty alcohol, 70-110 parts of deionized water, oil-soluble are multiple
Close initiator 1-2 parts, 1-3 parts of emulsifier, 5-10 parts of mill base, 5-20 parts of polypropylene fibre, 1-3 parts of primary plasticizer, co-plasticizer
1-2 parts, 2-4 parts of stabilizer, 1-5 parts of fire retardant.
Embodiment one:
A kind of production method of vinyl toy mashing toning environment-friendly type PVC, is made: polyethylene in parts by mass by following raw material
80 parts of monomer, 1 part of fatty alcohol, 70 parts of deionized water, 1 part of oil-soluble composite initiator, 1 part of emulsifier, 5 parts of mill base, polypropylene
5 parts of fiber, 1 part of primary plasticizer, 1 part of co-plasticizer, 2 parts of stabilizer, 1 part of fire retardant.
The present embodiment preparation method includes the following steps:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 2500r/
Min persistently stirs 20min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 40 DEG C, continue 8 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 60 DEG C by temperature setting, revolving speed is set as 4000 r/min, continues 1h, obtains environment-friendly type PVC.
Embodiment two:
A kind of production method of vinyl toy mashing toning environment-friendly type PVC, is made: polyethylene in parts by mass by following raw material
85 parts of monomer, 1 part of fatty alcohol, 80 parts of deionized water, 1 part of oil-soluble composite initiator, 2 parts of emulsifier, 6 parts of mill base, polypropylene
8 parts of fiber, 2 parts of primary plasticizer, 1 part of co-plasticizer, 2 parts of stabilizer, 2 parts of fire retardant.
The present embodiment preparation method includes the following steps:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 3000r/
Min persistently stirs 25min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 50 DEG C, continue 12 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 65 DEG C by temperature setting, revolving speed is set as 3500 r/min, continues 2h, obtains environment-friendly type PVC.
By comparison, embodiment two is clearly more demarcated compared with PVC color made from embodiment one, adhesive force, pressure resistance, abrasion resistance
More preferably.
Embodiment three:
A kind of production method of vinyl toy mashing toning environment-friendly type PVC, is made: polyethylene in parts by mass by following raw material
90 parts of monomer, 2 parts of fatty alcohol, 85 parts of deionized water, 2 parts of oil-soluble composite initiator, 2 parts of emulsifier, 7 parts of mill base, polypropylene
10 parts of fiber, 2 parts of primary plasticizer, 1 part of co-plasticizer, 2 parts of stabilizer, 3 parts of fire retardant.
The present embodiment preparation method includes the following steps:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 3000r/
Min persistently stirs 25min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 50 DEG C, continue 14 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 65 DEG C by temperature setting, revolving speed is set as 4500 r/min, continues 2h, obtains environment-friendly type PVC.
By comparison, embodiment three is clearly more demarcated compared with PVC color made from embodiment two, adhesive force, pressure resistance, abrasion resistance
More preferably.
Example IV:
A kind of production method of vinyl toy mashing toning environment-friendly type PVC, is made: polyethylene in parts by mass by following raw material
90 parts of monomer, 1 part of fatty alcohol, 90 parts of deionized water, 1 part of oil-soluble composite initiator, 2 parts of emulsifier, 8 parts of mill base, polypropylene
15 parts of fiber, 2 parts of primary plasticizer, 1 part of co-plasticizer, 3 parts of stabilizer, 3 parts of fire retardant.
The present embodiment preparation method includes the following steps:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 3000r/
Min persistently stirs 25min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 55 DEG C, continue 18 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 65 DEG C by temperature setting, revolving speed is set as 4500r/min, continues 2h, obtains environment-friendly type PVC.
By comparison, example IV is clearly more demarcated compared with PVC color made from embodiment three, adhesive force, pressure resistance, abrasion resistance
More preferably.
Embodiment five:
A kind of production method of vinyl toy mashing toning environment-friendly type PVC, is made: polyethylene in parts by mass by following raw material
95 parts of monomer, 2 parts of fatty alcohol, 100 parts of deionized water, 2 parts of oil-soluble composite initiator, 3 parts of emulsifier, 8 parts of mill base, polypropylene
18 parts of fiber, 2 parts of primary plasticizer, 2 parts of co-plasticizer, 3 parts of stabilizer, 4 parts of fire retardant.
The present embodiment preparation method includes the following steps:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 3500r/
Min persistently stirs 30min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 60 DEG C, continue 18 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 70 DEG C by temperature setting, revolving speed is set as 5000 r/min, continues 2h, obtains environment-friendly type PVC.
By comparison, PVC color made from embodiment five do not have it is clearly demarcated made from example IV, it is adhesive force, pressure resistance, wear-resistant
Performance is also good without PVC made from example IV.
Embodiment six:
A kind of production method of vinyl toy mashing toning environment-friendly type PVC, is made: polyethylene in parts by mass by following raw material
100 parts of monomer, 2 parts of fatty alcohol, 110 parts of deionized water, 2 parts of oil-soluble composite initiator, 3 parts of emulsifier, 10 parts of mill base, poly- third
20 parts of alkene fiber, 3 parts of primary plasticizer, 2 parts of co-plasticizer, 4 parts of stabilizer, 5 parts of fire retardant.
The present embodiment preparation method includes the following steps:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 3500r/
Min persistently stirs 30min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 65 DEG C, continue 24 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 70 DEG C by temperature setting, revolving speed is set as 5000 r/min, continues 3h, obtains environment-friendly type PVC.
By comparison, PVC color made from embodiment six do not have it is clearly demarcated made from example IV, it is adhesive force, pressure resistance, wear-resistant
Performance is also good without PVC made from example IV.
Embodiment seven:
A kind of production method of vinyl toy mashing toning environment-friendly type PVC, is made: polyethylene in parts by mass by following raw material
90 parts of monomer, 1 part of fatty alcohol, 90 parts of deionized water, 1 part of oil-soluble composite initiator, 2 parts of emulsifier, 8 parts of mill base, polypropylene
15 parts of fiber, 2 parts of primary plasticizer, 1 part of co-plasticizer, 3 parts of stabilizer, 3 parts of fire retardant.
The present embodiment preparation method includes the following steps:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, revolving speed is set as 3500r/
Min persistently stirs 30min；
Step 2: being added oil-soluble composite initiator and polymerize under this condition by temperature setting in 65 DEG C, continue 24 hours, with
Afterwards after spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, be 70 DEG C by temperature setting, revolving speed is set as 5000 r/min, continues 3h, obtains environment-friendly type PVC.
By comparison, PVC color made from embodiment seven do not have it is clearly demarcated made from example IV, it is adhesive force, pressure resistance, wear-resistant
Performance is also good without PVC made from example IV, but good compared with PVC made from embodiment one, two, three, five, six.
In conclusion PVC made from various embodiments of the present invention is subjected to color, adhesive force, pressure resistance, abrasion resistance experiment,
It is obtained after comparison, PVC made from example IV can reach optimum performance.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (8)
1. a kind of production method of vinyl toy mashing toning environment-friendly type PVC, it is characterised in that: press mass parts by following raw material
Meter be made: 80-100 parts of polyvinyl monomer, 1-2 parts of fatty alcohol, 70-110 parts of deionized water, 1-2 parts of oil-soluble composite initiator,
1-3 parts of emulsifier, 5-10 parts of mill base, 5-20 parts of polypropylene fibre, 1-3 parts of primary plasticizer, 1-2 parts of co-plasticizer, stabilizer 2-4
Part, 1-5 parts of fire retardant.
2. a kind of production method of vinyl toy mashing toning environment-friendly type PVC according to claim 1, feature exist
In: be made in parts by mass by following raw material: 90 parts of polyvinyl monomer, 1 part of fatty alcohol, 90 parts of deionized water, oil-soluble are compound
1 part of initiator, 2 parts of emulsifier, 8 parts of mill base, 15 parts of polypropylene fibre, 2 parts of primary plasticizer, 1 part of co-plasticizer, 3 parts of stabilizer,
3 parts of fire retardant.
3. a kind of production method of vinyl toy mashing toning environment-friendly type PVC according to claim 1, feature exist
In: the plasticizer is epoxidized soybean oil.
4. a kind of production method of vinyl toy mashing toning environment-friendly type PVC according to claim 1, feature exist
In: the co-plasticizer is poly- decanedioic acid propylene glycol ester.
5. a kind of production method of vinyl toy mashing toning environment-friendly type PVC according to claim 1, feature exist
In: the stabilizer is metal soap.
6. a kind of production method of vinyl toy mashing toning environment-friendly type PVC according to claim 1, feature exist
In: the fire retardant is trimethylbenzene lipoprotein of phosphoric acid, has antimony oxide, zinc borate, chlorinated paraffin one such or a variety of.
7. a kind of production method of vinyl toy mashing toning environment-friendly type PVC according to claim 1, feature exist
In: the emulsifier is anionic surfactant.
8. a kind of production method of vinyl toy mashing toning environment-friendly type PVC according to claim 1, feature exist
In: vinyl toy mashing toning environment-friendly type PVC preparation method the following steps are included:
Step 1: polyvinyl monomer, fatty alcohol, deionized water, emulsifier are added in reaction kettle, and revolving speed is set as 2500 ~
3500r/min persistently stirs 20 ~ 30min；
Step 2: oil-soluble composite initiator is added and polymerize under this condition by temperature setting in 40 ~ 65 DEG C, it is small to continue 8 ~ 24
When, after then passing through spray drying grinding, hybrid particles are obtained, for use；
Step 3: hybrid particles and mill base, polypropylene fibre, primary plasticizer, co-plasticizer, stabilizer, fire retardant are put again
Enter into reaction kettle, is 60 ~ 70 DEG C by temperature setting, revolving speed is set as 4000 ~ 5000 r/min, continues 1 ~ 3h, obtains environmental protection
Type PVC.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811188127.5A CN109320822A (en) | 2018-10-12 | 2018-10-12 | A kind of production method of vinyl toy mashing toning environment-friendly type PVC |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811188127.5A CN109320822A (en) | 2018-10-12 | 2018-10-12 | A kind of production method of vinyl toy mashing toning environment-friendly type PVC |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01163244A (en) * | 1987-12-19 | 1989-06-27 | Tosoh Corp | High-density vibration damper |
| EP0991678A1 (en) * | 1998-04-27 | 2000-04-12 | Evc Technology Ag | Polyvinyl chloride, processes for its production, and compositions containing it |
| CN101744393A (en) * | 2009-12-01 | 2010-06-23 | 武岳 | Preparation method of fragrant simulation fruit and fragrant simulation fruit prepared by same |
| CN102875936A (en) * | 2012-10-29 | 2013-01-16 | 成都市新津事丰医疗器械有限公司 | DEHP (di-2-ethylhexyl phthalate)-free medical PVC (polyvinyl chloride) paste material |
| CN106915025A (en) * | 2017-02-21 | 2017-07-04 | 王端华 | It is a kind of to ward off the preparation method that glue or heat ward off colour mixture product |
-
2018
- 2018-10-12 CN CN201811188127.5A patent/CN109320822A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01163244A (en) * | 1987-12-19 | 1989-06-27 | Tosoh Corp | High-density vibration damper |
| EP0991678A1 (en) * | 1998-04-27 | 2000-04-12 | Evc Technology Ag | Polyvinyl chloride, processes for its production, and compositions containing it |
| CN101744393A (en) * | 2009-12-01 | 2010-06-23 | 武岳 | Preparation method of fragrant simulation fruit and fragrant simulation fruit prepared by same |
| CN102875936A (en) * | 2012-10-29 | 2013-01-16 | 成都市新津事丰医疗器械有限公司 | DEHP (di-2-ethylhexyl phthalate)-free medical PVC (polyvinyl chloride) paste material |
| CN106915025A (en) * | 2017-02-21 | 2017-07-04 | 王端华 | It is a kind of to ward off the preparation method that glue or heat ward off colour mixture product |
Non-Patent Citations (1)
| Title |
|---|
| 张倩: "《聚氯乙烯制备及生产工艺学》", 31 December 2014 * |
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