CN109306265A - Perovskite quantum dot of polymer overmold and preparation method thereof - Google Patents
Perovskite quantum dot of polymer overmold and preparation method thereof Download PDFInfo
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- CN109306265A CN109306265A CN201710631645.9A CN201710631645A CN109306265A CN 109306265 A CN109306265 A CN 109306265A CN 201710631645 A CN201710631645 A CN 201710631645A CN 109306265 A CN109306265 A CN 109306265A
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- quantum dot
- perovskite quantum
- polymer
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- polymer overmold
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- 239000002096 quantum dot Substances 0.000 title claims abstract description 136
- 229920000642 polymer Polymers 0.000 title claims abstract description 80
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000002253 acid Substances 0.000 claims abstract description 40
- 239000000178 monomer Substances 0.000 claims abstract description 30
- 239000003446 ligand Substances 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 19
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 4
- -1 4- aminostyryl Chemical group 0.000 claims description 22
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 17
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 11
- 239000012965 benzophenone Substances 0.000 claims description 9
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 7
- 150000003254 radicals Chemical class 0.000 claims description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical group C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 6
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 5
- JTCFNJXQEFODHE-UHFFFAOYSA-N [Ca].[Ti] Chemical compound [Ca].[Ti] JTCFNJXQEFODHE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 4
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 3
- 244000028419 Styrax benzoin Species 0.000 claims description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 3
- 229960002130 benzoin Drugs 0.000 claims description 3
- 235000019382 gum benzoic Nutrition 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 2
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 2
- GQWAOUOHRMHSHL-UHFFFAOYSA-N 4-ethenyl-n,n-dimethylaniline Chemical compound CN(C)C1=CC=C(C=C)C=C1 GQWAOUOHRMHSHL-UHFFFAOYSA-N 0.000 claims description 2
- UQBOJOOOTLPNST-UHFFFAOYSA-N Dehydroalanine Chemical compound NC(=C)C(O)=O UQBOJOOOTLPNST-UHFFFAOYSA-N 0.000 claims description 2
- GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical group CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 claims description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 19
- 150000001336 alkenes Chemical class 0.000 description 12
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 229910001507 metal halide Inorganic materials 0.000 description 7
- 150000005309 metal halides Chemical class 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 6
- 230000015271 coagulation Effects 0.000 description 6
- 238000005345 coagulation Methods 0.000 description 6
- 238000005253 cladding Methods 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 238000006862 quantum yield reaction Methods 0.000 description 4
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 3
- DTRIDVOOPAQEEL-UHFFFAOYSA-N 4-sulfanylbutanoic acid Chemical compound OC(=O)CCCS DTRIDVOOPAQEEL-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000013047 polymeric layer Substances 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- ACTRVOBWPAIOHC-UHFFFAOYSA-N succimer Chemical compound OC(=O)C(S)C(S)C(O)=O ACTRVOBWPAIOHC-UHFFFAOYSA-N 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000015511 Liquidambar orientalis Nutrition 0.000 description 2
- 241000736148 Styrax Species 0.000 description 2
- 239000004870 Styrax Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 210000003739 neck Anatomy 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012454 non-polar solvent Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 1
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical compound C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 description 1
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- YCHKKRJCPBFHAV-UHFFFAOYSA-N C(C)(=O)O.SNC(=N)N Chemical compound C(C)(=O)O.SNC(=N)N YCHKKRJCPBFHAV-UHFFFAOYSA-N 0.000 description 1
- HRNDFHCRWHCDNZ-UHFFFAOYSA-N C(C)O.C(C1=CC=CC=C1)(=O)C1=CC=CC=C1 Chemical compound C(C)O.C(C1=CC=CC=C1)(=O)C1=CC=CC=C1 HRNDFHCRWHCDNZ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- ZASWJUOMEGBQCQ-UHFFFAOYSA-L dibromolead Chemical compound Br[Pb]Br ZASWJUOMEGBQCQ-UHFFFAOYSA-L 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- KOUKXHPPRFNWPP-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;hydrate Chemical group O.OC(=O)C1=CN=C(C(O)=O)C=N1 KOUKXHPPRFNWPP-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
- C09K11/025—Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/52—Amides or imides
- C08F120/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F120/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/66—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing germanium, tin or lead
- C09K11/664—Halogenides
- C09K11/665—Halogenides with alkali or alkaline earth metals
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Luminescent Compositions (AREA)
Abstract
The present invention provides a kind of preparation methods of the perovskite quantum dot of polymer overmold, the following steps are included: providing perovskite quantum dot, perovskite quantum dot dispersion is formed into perovskite quantum dot solution in a solvent, wherein, the ligand of the perovskite quantum dot surface includes thionothiolic acid class ligand；Polymer monomer and photoinitiator are added in the perovskite quantum dot solution, under the conditions of water vapour content is lower than 30% ultraviolet irradiation, reaction generates the perovskite quantum dot of polymer overmold, wherein the polymer monomer is the unsaturated polymer monomer containing amino.
Description
Technical field
The invention belongs to perovskite technical field of quantum dot preparation more particularly to a kind of polymer overmolds and its perovskite amount
The preparation method of son point.
Background technique
Inorganic perovskite quantum dot became a newcomer for being concerned and studying in " quantum dot family " in recent years.
Inorganic perovskite quantum dot has narrow fluorescent emission half-peak breadth, high fluorescence quantum yield and is easy in the various function of surface modification
The advantage of energy group；And also have unrivaled characteristic on biological chemical performance, and such as good bio-compatibility, low cell toxicant
Property, it is extensive that these superior optical properties have inorganic perovskite quantum dot in the fields such as biochemical and optical analysis detection
Application prospect.
Currently, common perovskite quantum dot, generally using thionothiolic acid class ligand as stabilizer in synthesis process, such as 2- mercapto
Guanidine-acetic acid, 3- mercaptopropionic acid, dimercaptosuccinic acid, 4- mercaptobutyric acid etc..Thionothiolic acid class compound is used to coat as ligand
Perovskite quantum dot, the carboxylate radical anion that quantum dot surface ionizes out can form the effect that identical charges repel each other, so that quantum dot
Do not occur to reunite and precipitate.However, in acid condition, carboxylic acid is difficult to ionize, and therefore, perovskite quantum dot surface hardly band
Charge, perovskite quantum dot are still easy to happen coagulation.In addition, although the thionothiolic acid class stabilizer of small molecule can divide to a certain degree
It dissipates in quantum dot surface, but is difficult completely to coat perovskite quantum dot surface, the surface defect being consequently formed will lead to luminous
The decline of efficiency.
Summary of the invention
The purpose of the present invention is to provide perovskite quantum dots of a kind of polymer overmold and preparation method thereof, it is intended to solve
Coagulation occurs in acid condition for the perovskite quantum dot of thionothiolic acid class ligand and thionothiolic acid class ligand is difficult to perovskite quantum
The problem of point surface coats completely.
The invention is realized in this way a kind of preparation method of the perovskite quantum dot of polymer overmold, including following step
It is rapid:
Perovskite quantum dot is provided, it is molten that the perovskite quantum dot is dissolved in formation perovskite quantum dot in nonpolar solvent
Liquid, wherein the perovskite quantum dot surface ligand includes thionothiolic acid class ligand；
It is added polymer monomer and photoinitiator in the perovskite quantum dot solution, under the conditions of ultraviolet irradiation, reaction
Generate the perovskite quantum dot of polymer overmold, wherein the polymer monomer is the unsaturated polymer monomer containing amino.
And a kind of perovskite quantum dot of the polymer overmold by above method preparation, the perovskite quantum dot table
Face ligand includes thionothiolic acid class ligand, and the perovskite quantum dot is coated with polymeric outer layer, the polymerization of the polymeric outer layer
Object is amino-containing polymer.
The preparation method of the perovskite quantum dot of polymer overmold provided by the invention, in the calcium containing thionothiolic acid class ligand
Titanium ore quantum dot surface introduces the polymer with flexible branch winding, forms fine and close cladding by Photoinitiated reactions
Layer.On the one hand, contain amino in the polymer that Photoinitiated reactions generate, and in the carboxyl and polymer on script mercapto acids ligand
Substituted-amino exist simultaneously, improve perovskite quantum dot in acid, the dispersibility in alkali environment, so that the calcium titanium of polymer overmold
Under acid, alkaline condition coagulation does not occur for mine quantum dot, improves the quantum yield of perovskite quantum dot.On the other hand,
Fine and close clad is formed in the perovskite quantum dot surface by the polymer, can reduce emission defects, further
Improve luminous efficiency.
The perovskite quantum dot of polymer overmold provided by the invention does not occur coagulation under acid, alkaline condition, mentions
The high quantum yield of perovskite quantum dot.And since the perovskite quantum dot surface forms fine and close clad, reduce
Emission defects further increase luminous efficiency.
Specific embodiment
In order to which technical problems, technical solutions and advantageous effects to be solved by the present invention are more clearly understood, below in conjunction with
Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only used to explain
The present invention is not intended to limit the present invention.
The embodiment of the invention provides a kind of preparation methods of the perovskite quantum dot of polymer overmold, including following step
It is rapid:
S01. perovskite quantum dot is provided, it is molten that perovskite quantum dot dispersion is formed perovskite quantum dot in a solvent
Liquid, wherein the perovskite quantum dot includes thionothiolic acid class ligand；
S02. it is added polymer monomer and photoinitiator in the perovskite quantum dot solution, under the conditions of ultraviolet irradiation,
Reaction generates the perovskite quantum dot of polymer overmold, wherein the polymer monomer is the unsaturated polymer containing amino
Monomer.
Specifically, titanium ore quantum dot of the invention includes inorganic perovskite quantum and organic-inorganic calcium in above-mentioned steps S01
Titanium ore quantum, such as CsPbX3Quantum dot, wherein X is Cl, Br or I, CH3NH3PbX3, wherein X is Cl, Br or I.The calcium titanium
Mine quantum dot surface ligand includes thionothiolic acid class ligand.Wherein, the thionothiolic acid class ligand include but is not limited to 2- thioacetic acid,
At least one of 3- mercaptopropionic acid, dimercaptosuccinic acid, 4- mercaptobutyric acid.The solvent should have the perovskite quantum dot
Preferable solubility property, such as can be conventional nonpolar solvent, it preferably include benzene, carbon tetrachloride, n-hexane, isooctane, first
At least one of benzene, methylene chloride, diphenyl ether, chloroform, dichloroethanes, carbon disulfide, hexamethylene, hexane, petroleum ether.This hair
In bright embodiment, it is molten that quantum dot is obtained described in 0.1-0.2g/1L configuration by the amount ratio of the perovskite quantum dot and solvent
Liquid.
In the embodiment of the present invention, the perovskite quantum dot can use ready-made perovskite quanta point material, can also be with
Voluntarily prepare.As a preferred embodiment, the perovskite quantum dot the preparation method is as follows:
S011., IA race metal halide, alkene solvent and thionothiolic acid are provided, are heated to 130 after dissolution under an inert atmosphere
DEG C~160 DEG C, after reacting 0.1-24 hours, it is cooled to 80-100 DEG C, constant temperature 4-6 hours, prepares the first presoma；
S012. lead halide is dissolved in alkene solvent, is reacted 0.5-1 hours under vacuum conditions, thionothiolic acid and oil is added
Amine is heated to 140-220 DEG C of reaction and prepares the second presoma；
S013. first presoma and the second presoma are mixed under 140-220 DEG C of constant temperature, after reaction
Cooling treatment is handled using organic solvent crystallization, obtains perovskite quantum dot.
In above-mentioned steps S011, IA race metal in IA race metal halide be lithium, sodium, potassium, rubidium, in caesium at least
One kind, halogen therein are at least one of chlorine, bromine, iodine.Preferably, the thionothiolic acid is 2- thioacetic acid, 3- sulfydryl third
At least one of acid, dimercaptosuccinic acid, 4- mercaptobutyric acid, but not limited to this.The alkene solvent is as dissolution solvent, preferably
For the long-chain olefin of carbon atom > 12.Specifically, the alkene solvent includes but is not limited to hexadecylene, octadecylene, icosa alkene, sheet
Inventive embodiments more preferably have preferable deliquescent octadecylene to IA race metal halide and the thionothiolic acid.
In the embodiment of the present invention, it is preferred that the amount ratio of IA race metal halide and the thionothiolic acid be 0.01g~
10g:1ml to have preferable reactivity, and avoids the big subsequent purification technique of the largely residual of the thionothiolic acid and calcium
Titanium ore quantum dot performance bring influences.Preferably, the amount ratio of IA race metal halide and the alkene solvent is
0.01-1g:1ml, to guarantee that IA race metal halide has preferable solute effect.
It dissolves after IA race metal halide, alkene solvent and thionothiolic acid are mixed, is preferably performed under heating conditions
Dissolution, heating temperature are lower than 130 DEG C.Further, after being heated to 130-160 DEG C, reaction 0.1-24 hours under an inert atmosphere,
It is not oxidized for the first presoma of protection, it is cooled to 80-100 DEG C, constant temperature 4-6 hours, prepares the first presoma.Wherein, described
Inert atmosphere includes but is not limited to nitrogen atmosphere.
In above-mentioned steps S012, the lead halide is at least one of lead chloride, lead bromide, lead iodide.The alkene is molten
Agent is as dissolution solvent, the preferably long-chain olefin of carbon atom > 12.It is particularly preferred as that there is compared with good dissolving the lead halide
The octadecylene of property.Lead halide is dissolved in alkene solvent, it is preferred that the amount ratio of the lead halide and the alkene solvent is
0.01~1mol:1L.To prevent the second presoma from aoxidizing, reacts 1-3 hours, further, be added under vacuum conditions
Thionothiolic acid and oleyl amine are heated to 1-100 minutes the second presomas of preparation of 140-220 DEG C of reaction, and temperature is excessively high to will cause quantum dot
Surface ligand is oxidized；Temperature, which crosses low reaction, to be occurred.
In above-mentioned steps S013, under 140-220 DEG C of constant temperature, first presoma and the second forerunner are mixed
Body stablizes reaction so as to the two and generates uniform and stable perovskite quantum dot.Cooling treatment after reaction, then using organic
Solvent crystallization.Preferably, the organic solvent is benzene kind solvent, specific preferred, and the organic solvent is toluene.Using toluene
As crystallization solvent, the perovskite quantum dot for having both high-purity and high yield can be obtained.Further, the dosage of the toluene
5-100% for the solution system total volume obtained after reaction.Perovskite quantum dot is obtained through centrifugation, by the perovskite quantum
Point is dispersed in the solvent, obtains the quantum dot solution that concentration is 0.1-0.2g/L.
In above-mentioned steps S02, polymer monomer and photoinitiator are added in the perovskite quantum dot solution, ultraviolet
Under the conditions of initiated polymerization, the perovskite quantum dot show coat branch winding polymeric layer.The embodiment of the present invention
In, for react formed polymer polymer monomer be the unsaturated polymer monomer containing amino so that cladding institute
It states and contains amino on the polymer of perovskite quantum dot, it is possible thereby to guarantee that the perovskite quantum dot in acid condition will not
Reunite, there is excellent dispersion performance.Specifically, the polymer monomer be the carbochain polymer monomer containing amino or
Heterochain polymer monomer containing amino.Specific preferred, the polymer monomer is N- (3- dimethylamino-propyl) methyl-prop
Acrylamide, 4- aminostyryl, 4- dimethylaminostyrene, aziridine, α-aminoacrylic acid, a- acetylamino propylene
At least one of acid, dimethylaminoethyl acrylate, it is certainly, without being limited thereto.Preferred polymer monomer not only has preferably
Polymerization activity, and also there is preferable reactivity with the perovskite quantum dot, exist so as to stable bond
On the perovskite quantum dot, the stable surface of forming properties coats perovskite quantum dot.
Preferably, the amount ratio of the perovskite quantum dot and the polymer monomer is 20~50g:1L.If described poly-
Monomer adduct content is excessive, then the remaining polymer monomer of meeting in product, and then influences the luminous intensity and hair of perovskite quantum dot
Light efficiency.
In the embodiment of the present invention, the photoinitiator under the irradiation of ultraviolet light, the unsaturated polymer list containing amino
Photopolymerization reaction, and sulfydryl substitution in the amino-containing polymer and thionothiolic acid ligand of photopolymerization reaction generation occur for physical efficiency
Carbon atom is connected, to form the structure of polymeric layer cladding in the perovskite quantum dot surface.Wherein, the photoinitiator
Under ultraviolet irradiation, can promote the methylene that sulfydryl is connected in the thionothiolic acid ligand on the perovskite quantum dot surface or
Methine loses hydrogen atom, forms radical structure, the carbon-carbon double bond being formed by radical structure oxypolymer monomer,
Finally the methylene containing free radical or methine are attached with the carbon atom on carbon-carbon double bond, and polymer monomer is due to double bond
It opens and polymerize and form polymer, reaction generates the amino-containing polymeric outer layer of quantum dot layer surfaces.The embodiment of the present invention
In, the photoinitiator be benzoin and its derivative (such as: styrax, benzoin dimethylether, benzoin ethyl ether, styrax
Isopropyl ether, benzoin isobutyl ether)；Benzil class compound (such as: diphenylethan, α, alpha, alpha-dimethyl oxygroup-α-phenyl acetophenone)；
Benzophenone compound (such as: benzophenone, 2,4 dihydroxyl benzophenone, Michler's keton)；Alkylbenzene ketone compounds (example
Such as: α, α-diethoxy acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones)；Thioxanthones compound (such as thio third
At least one of oxygroup thioxanthone, isopropyl thioxanthone).Preferably, the photoinitiator is benzophenone chemical combination
At least one of object, such as benzophenone, 2,4-DihydroxyBenzophenone, Michler's keton.
The amount for the photoinitiator that the present invention needs to be added is less.In the embodiment of the present invention, the perovskite quantum dot and institute
The amount ratio for stating photoinitiator is 80g-250g:1mol.
As a specific embodiment, the photoinitiator is benzophenone, and the benzophenone can preferably be accelerated
The generation of free radical improves photopolymerization efficiency.
In the embodiment of the present invention, photopolymerization can be carried out in environment in inert atmosphere, air atmosphere, preparing for vacuum atmosphere
Reaction.The water vapour content for preparing environment cannot be excessively high, excessively high that photopolymerization reaction cannot occur, in some instances it may even be possible to since hydrone is joined
Impurity is introduced with other side reactions.Preferably, in the step of preparing the perovskite quantum dot of polymer overmold, environment is prepared
In, vapor volume fraction is lower than 30%.The perovskite quantum dot solution, polymer monomer and the photoinitiator that will be provided
After mixing, ultraviolet irradiation under conditions of water vapour content is lower than 30%.
In the embodiment of the present invention, under the conditions of ultraviolet, the sulfydryl second that has been coated on the perovskite quantum dot surface
Methylene in acid loses hydrogen and forms radical structure, and then radical structure oxypolymer monomer, and it is anti-to form chain grafting
It answers, it is thioacetic acid cladding, the perovskite quantum dot that outside is polymer overmold that final reaction, which generates internal,.Preferably, described
Ultraviolet irradiation condition are as follows: ultraviolet light luminous intensity is 1~10mw/cm2, light application time is 0.2~2 hour.In the embodiment of the present invention,
The thickness of polymeric layer can be adjusted by adjusting ultraviolet light luminous intensity and irradiation time within this range, and then obtain difference
The perovskite quantum dot of luminescent color.Specifically, ultraviolet light light intensity is smaller, light application time is shorter, and clad is thin, the calcium titanium of preparation
Mine quantum point grain diameter is smaller, and perovskite quantum dot emission wavelengths are shorter, and color is bluer；Ultraviolet light light intensity is bigger, when illumination
Between it is longer, coat thickness, the perovskite quantum point grain diameter of preparation is bigger, and perovskite quantum dot emission wavelengths are longer, and color is more inclined
It is red.
Specifically, reaction system can be poured into glass culture dish, quartz plate is covered, is irradiated under strong ultraviolet light, i.e.,
The perovskite quantum dot of polymer overmold can be obtained.
The preparation method of the perovskite quantum dot of polymer overmold provided in an embodiment of the present invention is matched containing thionothiolic acid class
The perovskite quantum dot surface of body introduces the polymer with flexible branch winding, forms densification by Photoinitiated reactions
Clad.On the one hand, contain amino in the polymer that Photoinitiated reactions generate, and perovskite quantum dot itself contains with carboxyl
Thionothiolic acid class ligand, amino and carboxyl while, exist, and improve dispersibility of the perovskite quantum dot in acid or alkali environment, so that poly-
Under acid, alkaline condition coagulation does not occur for the perovskite quantum dot for closing object cladding, improves the quantum of perovskite quantum dot
Yield.On the other hand, fine and close clad is formed in the perovskite quantum dot surface by the polymer, can reduce hair
Optical defect further increases luminous efficiency.
And the embodiment of the invention also provides a kind of perovskite amounts of polymer overmold prepared by the above method
Sub- point.The perovskite quantum dot is coated with polymeric outer layer, and the polymer of the polymeric outer layer is amino-containing polymer.
The perovskite quantum dot of polymer overmold provided in an embodiment of the present invention does not occur under acid, alkaline condition
Coagulation improves the quantum yield of perovskite quantum dot.And since the perovskite quantum dot surface forms fine and close clad,
Emission defects are reduced, luminous efficiency is further increased.
It is illustrated combined with specific embodiments below.
Embodiment 1
A kind of preparation method of the perovskite quantum dot of polymer overmold, comprising the following steps:
S11., perovskite quantum dot is provided, 0.02g perovskite quantum dot is dispersed in 100ml n-hexane and forms perovskite
Quantum dot solution, wherein the perovskite quantum dot is the perovskite quantum dot containing thionothiolic acid class ligand, and preparation method includes
Following steps:
S111. three necks for taking 0.332g potassium iodide and 58ml octadecylene and 3.3ml 2 mercaptopropionic acid to be added to 100ml are burnt
It in bottle, is heated 1 hour at 100 DEG C, is then warming up to 160 DEG C under nitrogen protection, reaction cooled to 100 DEG C after 0.5 hour,
And 100 DEG C are kept the temperature at, prepare the first presoma；
S112. the lead iodide of 0.189mol and the octadecylene of 6ml are added in the three-neck flask of 25ml, it is true at 120 DEG C
It is reacted 1 hour under empty condition.Then 0.5ml 2 mercaptopropionic acid and 0.5ml oleyl amine are rapidly added.It is all molten to lead iodide solid
Reaction temperature is increased to 160 DEG C after solution, prepares the second presoma；
S113. under 160 DEG C of constant temperature, first presoma is rapidly added in second presoma, instead
Cooling treatment after answering 1 minute.Under room temperature state, 300ml volumes toluene is added, solution is made to be in hypersaturated state, after standing
Perovskite quantum dot crystal is collected to be dried.
S12. under magnetic agitation state, N- (the 3- dimethylamino of 0.8ml is added in the perovskite quantum dot solution
Propyl) methacryl amine aqueous solution and 0.2ml concentration be 1mol/L benzophenone ethanol solution, reaction system solution is stirred
It is transferred in vacuum glove box after uniformly, half is taken out in the case where ensuring glove box vapour content lower than 30% and pours into glass
In glass culture dish, quartz plate is covered, luminous intensity keeps 3mw/cm in the case where light source is the high-pressure sodium lamp of 500W2Irradiation 0.5 hour, obtains
The green perovskite quantum dot coated to N- (3- dimethylamino-propyl) methacrylamide polymer.
Embodiment 2
A kind of preparation method of the perovskite quantum dot of polymer overmold, comprising the following steps:
S21., perovskite quantum dot is provided, 0.035g perovskite quantum dot is dissolved in 210ml n-hexane and forms perovskite
Quantum dot solution, wherein the perovskite quantum dot is the perovskite quantum dot containing thionothiolic acid class ligand, and preparation method includes
Following steps:
S211. three necks for taking 0.421g cesium chloride and 35ml octadecylene and 2.5ml 2 mercaptopropionic acid to be added to 100ml are burnt
It in bottle, is heated 1 hour at 130 DEG C, is then warming up to 160 DEG C under nitrogen protection, reaction cooled to 100 DEG C after 1.5 hours,
And 100 DEG C are kept the temperature at, prepare the first presoma；
S212. the lead chloride of 0.164mol and the octadecylene of 4.8ml are added in the three-neck flask of 25ml, at 120 DEG C
It is reacted 1 hour under vacuum condition.Then 0.8ml 2 mercaptopropionic acid and 0.6ml oleyl amine are rapidly added.Lead solid to be chlorinated is whole
Reaction temperature is increased to 180 DEG C after dissolution, prepares the second presoma；
S213. under 180 DEG C of constant temperature, first presoma is rapidly added in second presoma, instead
Cooling treatment after answering 15 minutes.Under room temperature state, 350ml volumes toluene is added, solution is made to be in hypersaturated state, after standing
Perovskite quantum dot crystal is collected to be dried.
S22. under magnetic agitation state, the aziridine solution of 0.75ml is added in the perovskite quantum dot solution
It is the ethanol solution of 1mol/L benzophenone with 0.15ml concentration, reaction system solution is transferred to vacuum glove after mixing evenly
In case, half is taken out in the case where ensuring glove box vapour content lower than 30% and is poured into glass culture dish, quartz is covered
Piece, in the case where light source is the high-pressure sodium lamp of 500W, luminous intensity keeps 5mw/cm2Irradiation 1 hour, obtains polyethyleneimine polymers packet
The red perovskite quantum dot covered.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. a kind of preparation method of the perovskite quantum dot of polymer overmold, which comprises the following steps:
Perovskite quantum dot is provided, perovskite quantum dot dispersion is formed into perovskite quantum dot solution in a solvent, wherein
The ligand of the perovskite quantum dot surface includes thionothiolic acid class ligand；
Polymer monomer and photoinitiator, under the conditions of ultraviolet irradiation, thionothiolic acid are added in the perovskite quantum dot solution
The carbon atom that sulfydryl replaces in class ligand forms free radical and makes polymer monomer that photopolymerization occur, and polymer overmold is prepared
Perovskite quantum dot, wherein the polymer monomer be the unsaturated polymer monomer containing amino.
2. the preparation method of the perovskite quantum dot of polymer overmold as described in claim 1, which is characterized in that described ultraviolet
In the step of preparing the perovskite quantum dot of polymer overmold under irradiation condition, the volume fraction for preparing the vapor in environment is low
In 30%.
3. the preparation method of the perovskite quantum dot of polymer overmold as described in claim 1, which is characterized in that the calcium titanium
The amount ratio of mine quantum dot and the polymer monomer is 20~50g:1L.
4. the preparation method of the perovskite quantum dot of polymer overmold as described in claim 1, which is characterized in that the polymerization
Object monomer is N- (3- dimethylamino-propyl) Methacrylamide, 4- aminostyryl, 4- dimethylaminostyrene, ethylene Asia
At least one of amine, α-aminoacrylic acid, a- acetamidoacrylic acid and dimethylaminoethyl acrylate.
5. the preparation method of the perovskite quantum dot of polymer overmold according to any one of claims 1-4, which is characterized in that
The photoinitiator is benzoin and its derivative, benzil class compound, alkylbenzene ketone compounds and thioxanthones
Close at least one of object.
6. the preparation method of the perovskite quantum dot of polymer overmold as claimed in claim 5, which is characterized in that the light draws
Hair agent is at least one of benzophenone, 2,4 dihydroxyl benzophenone, Michler's keton.
7. the preparation method of the perovskite quantum dot of polymer overmold according to any one of claims 1-4, which is characterized in that
The ultraviolet irradiation condition are as follows: ultraviolet light luminous intensity is 1~10mw/cm2, light application time is 0.2~2 hour.
8. the preparation method of the perovskite quantum dot of polymer overmold according to any one of claims 1-4, which is characterized in that
Solvent in the perovskite quantum dot solution be benzene, carbon tetrachloride, n-hexane, isooctane, toluene, methylene chloride, diphenyl ether,
At least one of chloroform, dichloroethanes, carbon disulfide, hexamethylene, hexane, petroleum ether.
9. the preparation method of the perovskite quantum dot of polymer overmold according to any one of claims 1-4, which is characterized in that
The amount ratio of the perovskite quantum dot and the photoinitiator is 80-250g:1mol.
10. a kind of perovskite quantum dot of polymer overmold, which is characterized in that the perovskite quantum dot is coated with outside polymer
Layer, the polymer of the polymeric outer layer are amino-containing polymer.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106032468A (en) * | 2015-12-31 | 2016-10-19 | 苏州星烁纳米科技有限公司 | Polymerizable quantum dot and application thereof |
| CN106064831A (en) * | 2016-05-13 | 2016-11-02 | 南京工业大学 | Preparation method of composite material formed by embedding nano particles into perovskite nano wires |
| CN106970505A (en) * | 2015-10-26 | 2017-07-21 | 三星电子株式会社 | Quantum dot complex with polymeric outer layer, the photosensitive composition containing it, quanta polymer are combined article pattern and electronic device |
-
2017
- 2017-07-28 CN CN201710631645.9A patent/CN109306265A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106970505A (en) * | 2015-10-26 | 2017-07-21 | 三星电子株式会社 | Quantum dot complex with polymeric outer layer, the photosensitive composition containing it, quanta polymer are combined article pattern and electronic device |
| CN106032468A (en) * | 2015-12-31 | 2016-10-19 | 苏州星烁纳米科技有限公司 | Polymerizable quantum dot and application thereof |
| CN106064831A (en) * | 2016-05-13 | 2016-11-02 | 南京工业大学 | Preparation method of composite material formed by embedding nano particles into perovskite nano wires |
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| CN113321971A (en) * | 2021-04-13 | 2021-08-31 | 北京理工大学 | Photo-curing ink and preparation method thereof |
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| CN116536042A (en) * | 2023-04-28 | 2023-08-04 | 中山大学 | Perovskite-polymer composite luminescent microsphere and preparation method and application thereof |
| CN116536042B (en) * | 2023-04-28 | 2024-04-09 | 中山大学 | Perovskite-polymer composite luminescent microsphere and preparation method and application thereof |
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