CN109306251A - Colored stone metal tile acrylic acid adhesive and preparation method thereof - Google Patents
Colored stone metal tile acrylic acid adhesive and preparation method thereof Download PDFInfo
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- CN109306251A CN109306251A CN201811037711.0A CN201811037711A CN109306251A CN 109306251 A CN109306251 A CN 109306251A CN 201811037711 A CN201811037711 A CN 201811037711A CN 109306251 A CN109306251 A CN 109306251A
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- component
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- acrylic acid
- adhesive
- colored stone
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- 239000000853 adhesive Substances 0.000 title claims abstract description 77
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 77
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000004575 stone Substances 0.000 title claims abstract description 43
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 37
- 239000002184 metal Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000178 monomer Substances 0.000 claims abstract description 43
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 239000003999 initiator Substances 0.000 claims abstract description 19
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000012875 nonionic emulsifier Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 30
- 230000008569 process Effects 0.000 claims description 27
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 18
- -1 phosphate ester Chemical class 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 14
- 238000004945 emulsification Methods 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 8
- 239000006210 lotion Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 239000005639 Lauric acid Substances 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 2
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 229940125717 barbiturate Drugs 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000004383 yellowing Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 229920003180 amino resin Polymers 0.000 description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical group N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910018137 Al-Zn Inorganic materials 0.000 description 3
- 229910018573 Al—Zn Inorganic materials 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 238000009877 rendering Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 239000011258 core-shell material Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical group CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical group CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical group CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000005321 cobalt glass Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/02—Homopolymers or copolymers of monomers containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of colored stone metal tile acrylic acid adhesives and preparation method thereof, acrylic acid adhesive includes bottom adhesive and face adhesive, and the composition of raw materials of bottom adhesive includes: 205~255 parts of acrylic acid soft monomers, 120~150 parts of acrylic acid hard monomers, 25~55 parts of functional polymerizable monomers, 2~3 parts of initiators, 0~4 part of nonionic emulsifier, 3.5~10 parts of reactive emulsifiers, 45~65 parts of other auxiliary agents；The composition of raw materials of face adhesive includes: 185~220 parts of acrylic acid soft monomers, 135~155 parts of acrylic acid hard monomers, 25~55 parts of functional polymerizable monomers, 2~5 parts of initiators, 5~15 parts of reactive emulsifiers, 0~10 part of silane coupling agent, 45~65 parts of other auxiliary agents.The acrylic acid adhesive has excellent resistance to soiling and yellowing resistance, has high reaction activity at 100 DEG C or more, can reduce the energy consumption of colored stone metal tile production process.
Description
Technical field
The present invention relates to gluing agent material for building fields, in particular it relates to a kind of colored stone metal tile propylene
Sour adhesive and preparation method thereof.
Background technique
Colored stone metal tile is to use the Al-Zn coated steel of new and high technology production haveing excellent performance using anti-corrosion as substrate, with weather-proof
Property extremely strong acrylic resin be binder, using colored natural grit as the novel advanced roofing of surface layer.Because it is beautiful, light
Ingeniously, durable, environmentally friendly, have become the main product of international roofing in recent years, domestic top-grade building uses.Acrylate is poly-
Close object as watt special adhesion material, it makes Al-Zn coated steel and colored sand grains carries out bonds well, and effect is very big, simultaneously
The effects of as the protective layer on surface, it is played again prevents rain leakage, absorption ultraviolet light, insulation, can extend sand grains
The service life of color and metal tile ensure that the comfortable of living environment.
Currently on the market there are some defects in used colored stone metal tile adhesive in use, mainly there is two o'clock:
1. colored stone metal tile process needs high-temperature baking (150~180 DEG C of * 30min) that could embody the performance of adhesive,
This results in the need for wasting more energy；2. bonding force is weak, poor water resistance, bending resistance is bad, easy xanthochromia, and alternating hot and cold adapts to
Property poor (hot sticky cold crisp), cause the shelf-life of colored stone metal tile short, defective products is excessive, cause resource largely lose and wave
Take, product competitiveness decline.Therefore, a kind of high performance colored stone metal tile is studied to be had become with water-and acrylate emulsion binding agent
For urgent problem.
Summary of the invention
Based on this, the invention reside in overcoming the deficiencies of existing technologies, a kind of new colored stone metal tile acrylate glue is provided
Glutinous agent, by using the compounding design of core-shell structure, the colored stone metal tile acrylic acid adhesive prepared has excellent resistance to
Aqueous, resistant to bending, weatherability, cold-hot alternation, freeze-thaw stability and mechanical stability, and also with excellent resistance to soiling and
Yellowing resistance, in addition, the colored stone metal tile has very high reactivity at 100 DEG C or more with acrylic acid adhesive, thus
The energy consumption for reducing colored stone metal tile production process, is reduced to 100-120 DEG C of * 30min from 160-180 DEG C of * 30min.
Another object of the present invention is to provide the preparation methods of the colored stone metal tile acrylic acid adhesive.
Its technical solution is as follows:
Colored stone metal tile acrylic acid adhesive, including bottom adhesive and face adhesive, the raw material of the bottom adhesive are matched
Fang Zufen includes: that 205~255 parts of acrylic acid soft monomers, 120~150 parts of acrylic acid hard monomers, 25~55 parts of functionality are polymerizable
Monomer, 2~3 parts of initiators, 0~4 part of nonionic emulsifier, 3.5~10 parts of reactive emulsifiers, 45~65 parts of other auxiliary agents；
The composition of raw materials component of the face adhesive includes: 185~220 parts of acrylic acid soft monomers, 135~155 parts of propylene
Sour hard monomer, 25~55 parts of functional polymerizable monomers, 2~5 parts of initiators, 5~15 parts of reactive emulsifiers, 0~10 part of silicon
Alkane coupling agent, 45~65 parts of other auxiliary agents；
The functional polymerizable monomer includes acrylic acid, phosphate ester monomer, N hydroxymethyl acrylamide, (methyl) propylene
Sour hydroxy ester.
The acrylic acid soft monomer is butyl acrylate, Isooctyl acrylate monomer in one of the embodiments,.
The acrylic acid hard monomer is methyl methacrylate and/or methyl acrylate in one of the embodiments,.
The nonionic emulsifier is ethoxylated dodecyl alcohol, lauric acid polyoxyethylene in one of the embodiments,
One of ester, polyoxyethylene oleic acid ester are a variety of.
The reactive emulsifier is 2- acrylamido -2- methyI-oropvD sulfonic acid, 2- in one of the embodiments,
One of acrylamido -2- methyI-oropvD sulfonate sodium, 2- acrylic acid amido -2- methyI-oropvD sulfonic acid ammonium salt are more
Kind.
In one of the embodiments, the phosphate ester monomer be one of PM-1, PM-2, PAM-200, COPS-3 or
It is a variety of.
(methyl) crylic acid hydroxy ester is hydroxyethyl methacrylate, metering system in one of the embodiments,
One or more of sour hydroxypropyl rouge, hydroxy-ethyl acrylate, hydroxypropyl acrylate.
Other described auxiliary agents are multifunctional assistant, defoaming agent, mould inhibitor, thickener and consolidate in one of the embodiments,
Agent.
The curing agent is amino resins in one of the embodiments, more specifically, the curing agent is cyanogen spy 325.
The initiator is persulfuric acid salt initiator in one of the embodiments,.Specifically, the initiator can be with
For one of potassium peroxydisulfate, sodium peroxydisulfate and ammonium persulfate or a variety of.
The composition of raw materials component of the bottom adhesive includes: in one of the embodiments,
Component C (initiator solution): 2-3 parts of ammonium persulfate；
90-110 parts of water；
The composition of raw materials component of the face adhesive includes: in one of the embodiments,
H component (initiator solution): 2-5 parts of ammonium persulfate；
90-110 parts of water；
I component (emulsifier solution): 3-6 parts of methyI-oropvD sulfonic acid of 2- acrylamido -2-；
250-350 parts of water；
The colored stone metal tile preparation method of acrylic acid adhesive, includes the following steps:
(1) bottom adhesive is prepared:
1) component A, B component, component C, D component preparatory process: are prepared；
2) core mix monomer, shell mix monomer pre-emulsification process: by the respective pre-emulsification 20-60min of component A, B component；
3) seeded emulsion polymerization process: D component being added in reaction kettle and is stirred evenly, and the A group of 15-25% is then added
Point, it stirring evenly, the component C of 40-60% is added when being warming up to 60-70 DEG C, observation lotion has obvious blue light to occur starting timing,
Control 78-82 DEG C of insulation reaction 20-60min of temperature；
4) polymerization process: starting the component C that remaining component A and 5%-15% is added dropwise, temperature control 78-82 DEG C it
Between, the tear drop time is 1.5-2 hours, keeps the temperature 20-60min after dripping off, and is further continued for that B component and remaining component C, temperature control is added dropwise
For system at 78-82 DEG C, the tear drop time is 2-2.5 hours, and 85-88 DEG C is warming up to after dripping off, and keeps the temperature 30-90min；
5) it compounds process: cooling to 45-55 DEG C, component E is added, stirs evenly and obtains bottom adhesive；
(2) face adhesive is prepared:
1) F component, G component, H component, I component preparatory process: are prepared；
2) core mix monomer, shell mix monomer pre-emulsification process: by the respective pre-emulsification 20-60min of F component, G component；
3) seeded emulsion polymerization process: I component being added in reaction kettle and is stirred evenly, and the F group of 15-25% is then added
Point, it stirring evenly, the H component of 40-60% is added when being warming up to 60-70 DEG C, observation lotion has obvious blue light to occur starting timing,
Control 78-82 DEG C of insulation reaction 20-60min of temperature；
4) polymerization process: starting the H component that remaining F component and 5%-15% is added dropwise, temperature control 78-82 DEG C it
Between, the tear drop time is 1.5-2 hours, keeps the temperature 20-60min after dripping off, and is further continued for that G component and remaining H component, temperature control is added dropwise
For system at 78-82 DEG C, the tear drop time is 2-2.5 hours, and 85-88 DEG C is warming up to after dripping off, and keeps the temperature 30-90min；
5) it compounds process: cooling to 45-55 DEG C, J component is added, stirs evenly and obtains face adhesive.
The pH adjusting agent is dimethylethanolamine and/or 2- amino-2-methyl -1- third in one of the embodiments,
Alcohol.
The compounding process in one of the embodiments, are as follows: cool to 45-55 DEG C, sequentially add in order multi-functional
Auxiliary agent, defoaming agent, mould inhibitor, thickener, amino resins.
In the present invention, the method for bottom adhesive and face adhesive for colored stone watt are as follows:
Colored stone watt preparation:
1) it first by substrate compression moulding, degreases and dust；
2) bottom adhesive is sprayed on substrate, then is sprinkled with colored gravel, is placed in 5 minutes progress surface dryings of 100-120 DEG C of baking；
3) it further takes out and cools to 50 DEG C, spray-coating surface adhesive is done solid work being placed in 100-120 DEG C of baking, taken for 25 minutes
Out, it places and is cooled to room temperature to get colored stone watt is arrived.
The beneficial effects of the present invention are:
(1) present invention is designed using the synthesis technology of core-shell structure, the colored stone metal tile acrylic acid adhesive prepared
Good with excellent flexibility, adaptable under bear dirty non-sticky ash, alternating hot and cold environment, easily construction, sag resistance energy are good, to coloured silk
The colour rendering of smalt grain is good, and gloss is high, and adhesive force is good, water-tolerant；
(2) present invention is in monomer by introducing functional monomers and the organosilicon radical, curing agent such as phosphate, into one
While step improves water resistance and adhesive force, the weatherability, resistance to soiling and resistance to ag(e)ing of emulsion binding agent are improved, especially
Resistance to soiling is detected according to GB/T 9780-2005 test method, the completely not viscous ash of paint film；
(3) present invention uses acrylic monomers, and does not have to the monomer of this kind of not color inhibition of styrene, so having good
Anti-yellowing property；
(4) present invention uses intermediate temperature curing agent amino resins (cyanogen spy 325), and collocation pH adjusting agent uses, in addition designing
In the feeding sequence of compounding process, while so that it is kept good storage stability at normal temperature, have very at 100 DEG C or more
High reactivity is reduced to 100-120 from 160-180 DEG C of * 30min to reduce the energy consumption of colored stone metal tile production process
℃*30min；
(5) colored stone metal tile of the present invention is free of VOC with acrylic acid adhesive, and environmental pollution is small, safety and environmental protection；
(6) colored stone metal tile of the present invention is Clear & Transparent with acrylic acid adhesive paint film, soaks colour rendering to colored stone
It is good.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention more comprehensible, below in conjunction with specific embodiment, to this
Invention is described in further detail.It should be understood that the specific embodiments described herein are only to explain this hair
It is bright, and the scope of protection of the present invention is not limited.
Embodiment 1
A kind of colored stone metal tile acrylate emulsion adhesive, including bottom adhesive and face adhesive, the primer are glutinous
The composition of raw materials component of agent is as follows:
Component C (initiator solution): 2.5 parts of ammonium persulfate；
100 parts of deionized water；
D component (emulsifier solution): 1.5 parts of succinate；
3 parts of sulfonic acid of 2- acrylamido -2- methyI-oropvD；
300 parts of deionized water；
The composition of raw materials component of the face adhesive is as follows:
H component (initiator solution): 2.5 parts of ammonium persulfate；
100 parts of deionized water；
I component (emulsifier solution): 4.5 parts of sulfonic acid of 2- acrylamido -2- methyI-oropvD；
300 parts of deionized water；
Colored stone metal tile acrylic acid adhesive the preparation method is as follows:
(1) bottom adhesive is prepared:
1) component A, B component, component C, D component preparatory process: are prepared；
2) core mix monomer, shell mix monomer pre-emulsification process: by the respectively pre-emulsification standby in 0.5 hour of component A and B component
With；
3) seeded emulsion polymerization process: D component being added in reaction kettle and is stirred evenly, and 20% component A is added, and stirring is equal
It is even, it is warming up to 65 DEG C under stirring, 50% component C is added, observation lotion has obvious blue light to occur, starts timing, will be warm
Degree control keeps the temperature 0.5 hour between 78-82 DEG C；
4) polymerization process: starting the component C that remaining component A and 10% is added dropwise, and temperature controls between 78-82 DEG C, drop
Expect that the time is 1.5-2 hours, keep the temperature 0.5 hour after dripping off, is further continued for that the component C of B component and 40% is added dropwise, temperature control exists
78-82 DEG C, the tear drop time is 2-2.5 hours, and 85-88 DEG C is warming up to after dripping off, and keeps the temperature 1 hour；
5) it compounds process: cooling to 50 DEG C, sequentially add AMP-95, A202, MB-16, RHEOLATE 278, amino tree
Rouge stirs evenly, and tests the viscosity, pH value and solid content of lotion, qualified (viscosity 8000-10000mPa.s, pH are 7~9, Gu
Content 40%~45%) after, filtering and discharging obtains bottom adhesive.
(2) face adhesive is prepared
1) F component, G component, H component, I component preparatory process: are prepared；
2) core mix monomer, shell mix monomer pre-emulsification process: by the respectively pre-emulsification standby in 0.5 hour of F component and G component
With；
3) seeded emulsion polymerization process: I component being added in reaction kettle and is stirred evenly, and 20% F component is added, and stirring is equal
It is even, it is warming up to 65 DEG C under stirring, 50% H component is added, observation lotion has obvious blue light to occur, starts timing, will be warm
Degree control keeps the temperature 0.5 hour between 78-82 DEG C；
4) polymerization process: starting the H component that remaining F component and 10% is added dropwise, and temperature controls between 78-82 DEG C, drop
Expect that the time is 1.5-2 hours, keep the temperature 0.5 hour after dripping off, is further continued for that G component and 40%H component is added dropwise, temperature is controlled in 78-
82 DEG C, the tear drop time is 2-2.5 hours, and 85-88 DEG C is warming up to after dripping off, and keeps the temperature 1 hour；
5) it compounds process: cooling to 50 DEG C, sequentially add AMP-95, A202, MB-16, RHEOLATE in J component
278, amino resins stirs evenly, and tests the viscosity, pH value and solid content of lotion, qualification (viscosity 8000-10000mPa.s, pH
It is 7~9, solid content 40~45%) after, filtering and discharging obtains face adhesive.
It is prepared as follows colored stone watt:
1) taking Al-Zn coated steel is substrate, is degreased and dust；
2) bottom adhesive is sprayed on substrate, then is sprinkled with colored gravel, is placed in 5 minutes progress surface dryings of 100-120 DEG C of baking；
3) it further takes out and cools to 50 DEG C, spray-coating surface adhesive is done solid work being placed in 100-120 DEG C of baking, taken for 25 minutes
Out, it places and is cooled to room temperature to get colored stone watt is arrived.
Its performance test results is shown in Table 1, and (paint film is prepared under the conditions of 100~120 DEG C of * 30, min, the test of adhesive force
It is before spray-coating surface adhesive).
Table 1
Embodiment 2
A kind of colored stone metal tile acrylate emulsion adhesive, including bottom adhesive and face adhesive, the primer are glutinous
The composition of raw materials component of agent is as follows:
Component C (initiator solution): 2.5 parts of ammonium persulfate；
100 parts of deionized water；
D component (emulsifier solution): 3 parts of lauric acid polyoxyethylene ester；
1.5 parts of sulfonic acid of 2- acrylamido -2- methyI-oropvD；
300 parts of deionized water；
The composition of raw materials component of the face adhesive is as follows:
H component (initiator solution): 2.5 parts of ammonium persulfate；
100 parts of deionized water；
I component (emulsifier solution): 4.5 parts of sulfonic acid of 2- acrylamido -2- methyI-oropvD；
300 parts of deionized water；
The preparation method of colored stone metal tile acrylate emulsion adhesive described in the present embodiment 2 and the basic phase of embodiment 1
Together, details are not described herein again.
Its performance test methods is same as Example 1, and the results are shown in Table 2, (paint film is under the conditions of 100~120 DEG C of * 30, min
Preparation, the test of adhesive force is before spray-coating surface adhesive).
Table 2
From the performance test results of Tables 1 and 2 it is found that colored stone metal tile acrylic acid adhesive prepared by the present invention has
Excellent water resistance, resistant to bending, weatherability, cold-hot alternation, freeze-thaw stability and mechanical stability, and also have excellent
Resistance to soiling and yellowing resistance, the 30min, that is, curable under the conditions of 100-120 DEG C, low energy consumption, and paint film is Clear & Transparent, to colored stone
It is good to soak colour rendering.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. colored stone metal tile acrylic acid adhesive, which is characterized in that including bottom adhesive and face adhesive, the bottom adhesive
Composition of raw materials component include: 205~255 parts of acrylic acid soft monomers, 120~150 parts of acrylic acid hard monomers, 25~55 parts of functions
Property polymerisable monomer, 2~3 parts of initiators, 0~4 part of nonionic emulsifier, 3.5~10 parts of reactive emulsifiers, 45~65 parts its
His auxiliary agent；
The composition of raw materials component of the face adhesive includes: that 185~220 parts of acrylic acid soft monomers, 135~155 parts of acrylic acid are hard
Monomer, 25~55 parts of functional polymerizable monomers, 2~5 parts of initiators, 5~15 parts of reactive emulsifiers, 0~10 part of silane idol
Join agent, 45~65 parts of other auxiliary agents；
The functional polymerizable monomer includes acrylic acid, phosphate ester monomer, N hydroxymethyl acrylamide, (methyl) acrylic acid hydroxyl
Base ester.
2. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that the acrylic acid soft monomer
For butyl acrylate, Isooctyl acrylate monomer.
3. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that the acrylic acid hard monomer
For methyl methacrylate and/or methyl acrylate.
4. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that the nonionic emulsifier
For one of ethoxylated dodecyl alcohol, lauric acid polyoxyethylene ester, polyoxyethylene oleic acid ester or a variety of.
5. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that the reactive emulsifier
For 2- acrylamido -2- methyI-oropvD sulfonic acid, 2- acrylamido -2- methyI-oropvD sulfonate sodium, 2- acrylic acid amido -
One of 2- methyI-oropvD sulfonic acid ammonium salt is a variety of.
6. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that other described auxiliary agents are more
Function additive, defoaming agent, mould inhibitor, thickener and curing agent.
7. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that the initiator is over cure
Barbiturates initiator.
8. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that the original of the bottom adhesive
Material formula component includes:
Component C (initiator solution): 2-3 parts of ammonium persulfate；
90-110 parts of water；
9. colored stone metal tile acrylic acid adhesive according to claim 1, which is characterized in that the original of the face adhesive
Material formula component includes:
H component (initiator solution): 2-5 parts of ammonium persulfate；
90-110 parts of water；
I component (emulsifier solution): 3-6 parts of methyI-oropvD sulfonic acid of 2- acrylamido -2-；
250-350 parts of water；
10. the colored stone metal tile preparation method of acrylic acid adhesive, which comprises the steps of:
(1) bottom adhesive is prepared:
1) component A, B component, component C, D component preparatory process: are prepared；
2) core mix monomer, shell mix monomer pre-emulsification process: by the respective pre-emulsification 20-60min of component A, B component；
3) seeded emulsion polymerization process: D component being added in reaction kettle and is stirred evenly, and the component A of 15-25% is then added, stirs
The component C that 40-60% is added when being uniformly warming up to 60-70 DEG C is mixed, observation lotion has obvious blue light to occur starting timing, control
78-82 DEG C of insulation reaction 20-60min of temperature；
4) polymerization process: starting the component C that remaining component A and 5%-15% is added dropwise, and temperature controls between 78-82 DEG C, drop
Expect that the time is 1.5-2 hours, keep the temperature 20-60min after dripping off, is further continued for that B component and remaining component C is added dropwise, temperature control exists
78-82 DEG C, the tear drop time is 2-2.5 hours, and 85-88 DEG C is warming up to after dripping off, and keeps the temperature 30-90min；
5) it compounds process: cooling to 45-55 DEG C, component E is added, stirs evenly and obtains bottom adhesive；
(2) face adhesive is prepared:
1) F component, G component, H component, I component preparatory process: are prepared；
2) core mix monomer, shell mix monomer pre-emulsification process: by the respective pre-emulsification 20-60min of F component, G component；
3) seeded emulsion polymerization process: I component being added in reaction kettle and is stirred evenly, and the F component of 15-25% is then added, stirs
The H component that 40-60% is added when being uniformly warming up to 60-70 DEG C is mixed, observation lotion has obvious blue light to occur starting timing, control
78-82 DEG C of insulation reaction 20-60min of temperature；
4) polymerization process: starting the H component that remaining F component and 5%-15% is added dropwise, and temperature controls between 78-82 DEG C, drop
Expect that the time is 1.5-2 hours, keep the temperature 20-60min after dripping off, is further continued for that G component and remaining H component is added dropwise, temperature control exists
78-82 DEG C, the tear drop time is 2-2.5 hours, and 85-88 DEG C is warming up to after dripping off, and keeps the temperature 30-90min；
5) it compounds process: cooling to 45-55 DEG C, J component is added, stirs evenly and obtains face adhesive.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811037711.0A CN109306251A (en) | 2018-09-06 | 2018-09-06 | Colored stone metal tile acrylic acid adhesive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811037711.0A CN109306251A (en) | 2018-09-06 | 2018-09-06 | Colored stone metal tile acrylic acid adhesive and preparation method thereof |
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| CN109306251A true CN109306251A (en) | 2019-02-05 |
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ID=65224641
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093125A (en) * | 2019-04-04 | 2019-08-06 | 佛山市三水灏诚合成树脂有限公司 | Colored stone watt adhesive and preparation method thereof, application method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103626912A (en) * | 2013-05-17 | 2014-03-12 | 佛山市三水灏诚合成树脂有限公司 | Aqueous acrylate emulsion adhesive for colorful metallic tiles and preparation method thereof |
| KR101371583B1 (en) * | 2012-09-21 | 2014-03-27 | 주식회사 페루프 | Method for manufacturing stone chip coated steel tile |
| CN107603533A (en) * | 2017-11-03 | 2018-01-19 | 江苏特福特建材有限公司 | Chromatic metallic watt water-and acrylate emulsion binding agent and preparation method thereof |
| CN207177109U (en) * | 2017-08-02 | 2018-04-03 | 江苏特福特建材有限公司 | A kind of wood grain type colored stone metal tile |
-
2018
- 2018-09-06 CN CN201811037711.0A patent/CN109306251A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101371583B1 (en) * | 2012-09-21 | 2014-03-27 | 주식회사 페루프 | Method for manufacturing stone chip coated steel tile |
| CN103626912A (en) * | 2013-05-17 | 2014-03-12 | 佛山市三水灏诚合成树脂有限公司 | Aqueous acrylate emulsion adhesive for colorful metallic tiles and preparation method thereof |
| CN207177109U (en) * | 2017-08-02 | 2018-04-03 | 江苏特福特建材有限公司 | A kind of wood grain type colored stone metal tile |
| CN107603533A (en) * | 2017-11-03 | 2018-01-19 | 江苏特福特建材有限公司 | Chromatic metallic watt water-and acrylate emulsion binding agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093125A (en) * | 2019-04-04 | 2019-08-06 | 佛山市三水灏诚合成树脂有限公司 | Colored stone watt adhesive and preparation method thereof, application method |
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Application publication date: 20190205 |