CN109306122A - A kind of medical COC bottles of materials - Google Patents
A kind of medical COC bottles of materials Download PDFInfo
- Publication number
- CN109306122A CN109306122A CN201811138598.5A CN201811138598A CN109306122A CN 109306122 A CN109306122 A CN 109306122A CN 201811138598 A CN201811138598 A CN 201811138598A CN 109306122 A CN109306122 A CN 109306122A
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- Prior art keywords
- parts
- powder
- coc
- bottles
- medical
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/02—Applications for biomedical use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/10—Applications used for bottles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
- Medicinal Preparation (AREA)
Abstract
The invention discloses a kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC30-40 parts, 15-30 parts of Rare-Earth Magnetic NdFeB magnetic powder, 0.5-2.0 parts of ethyl acetate, 100-150 parts of polypropylene, 50-60 parts of Lauxite, 1-1.5 parts of sericite in powder, 13-15 parts of ABS high glue powder, 4-6 parts of palygorskite, 2-5 parts of tributoxyethyl phosphate, 2-4 parts of styrene-butadiene latex, 2-5 parts of ethoxy ethanol, 2-5 parts of dimethyl ether, 0.5-1.0 parts of methylimidazole.This material include using COC as major ingredient, the copolymer of COC system cyclic polyolefin and vinyl monomer, with high transparency, high water vapor barrier property and gas barrier property, low water absorbable, resistance to chemical reagents and it is low dissolution etc. characteristics.
Description
Technical field
The invention belongs to plastic material fields, and in particular to a kind of medical COC bottles of material.
Background technique
With the development of economy, packaging industry has significant progress.But the packaging of medicine trade is in addition to commercial value,
The breakthrough of even more important technology.
Drug has harsh requirement to packaging.Packaging material, structure, stability etc. combined factors consider.Such as hand
Anesthetic,general-sevoflurane that art uses, about 2000 yuan of 250 milliliters of price.Direct competitive opponent is that Abbott Laboratories and hundred are special.
Vial is not suitable for packaging " sevoflurane ", and glass can cause impurity excessive by slight erosion.General-purpose plastics (PE,
PP, PET) and common high performance plastics (PEN) mostly by the protection of some big biomedical company's patented technology barriers.Metallic aluminium
Bottle is limited by certain unit commercial contract, can only be limited to certain technical fields and be used.
Summary of the invention
The purpose of the present invention is to provide a kind of medical COC bottles of materials.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter:: COC30-40 parts, Rare-Earth Magnetic neodymium iron
15-30 parts of boron magnetic powder, 0.5-2.0 parts of ethyl acetate, 100-150 parts of polypropylene, 50-60 parts of Lauxite, sericite in powder 1-1.5
Part, 13-15 parts of ABS high glue powder, 4-6 parts of palygorskite, 2-5 parts of tributoxyethyl phosphate, 2-4 parts of styrene-butadiene latex, ethyoxyl second
2-5 parts of alcohol, 2-5 parts of dimethyl ether, 0.5-1.0 parts of methylimidazole.
A kind of medical COC bottles of material, includes the following raw material according to mass fraction meter: COC30 parts, Rare-Earth Magnetic neodymium
15 parts of iron boron magnetic powder, 2.0 parts of ethyl acetate, 150 parts of polypropylene, 50 parts of Lauxite, 1.5 parts of sericite in powder, ABS high glue powder 13
Part, 6 parts of palygorskite, 5 parts of tributoxyethyl phosphate, 2 parts of styrene-butadiene latex, 5 parts of ethoxy ethanol, 2 parts of dimethyl ether, methylimidazole
1.0 part.
A kind of medical COC bottles of material, includes the following raw material according to mass fraction meter: COC35 parts, Rare-Earth Magnetic neodymium
20 parts of iron boron magnetic powder, 1 part of ethyl acetate, 120 parts of polypropylene, 55 parts of Lauxite, 1 part of sericite in powder, 14 parts of ABS high glue powder,
5 parts of palygorskite, 3 parts of tributoxyethyl phosphate, 3 parts of styrene-butadiene latex, 3 parts of ethoxy ethanol, 3 parts of dimethyl ether, methylimidazole 1
Part.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material
Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second
Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix
It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
The step S2 middling speed is 800-1200rpm, and storage room temperature is 18-26 DEG C.
The Rare-Earth Magnetic NdFeB magnetic powder partial size is 50-100nm, and the partial size of the palygorskite is 10-100nm.
Beneficial effects of the present invention: this material includes using COC as major ingredient, and COC system cyclic polyolefin and vinyl monomer are total to
Polymers, with high transparency, high water vapor barrier property and gas barrier property, low water absorbable, resistance to chemical reagents and it is low dissolution etc. characteristics.
Specific embodiment
Present invention is further described in detail combined with specific embodiments below.
Embodiment 1:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC30 parts, Rare-Earth Magnetic neodymium-iron-boron
15 parts of powder, 0.5 part of ethyl acetate, 100 parts of polypropylene, 50 parts of Lauxite, 1 part of sericite in powder, 13 parts of ABS high glue powder, slope thread
4 parts of stone, 2 parts of tributoxyethyl phosphate, 2 parts of styrene-butadiene latex, 2 parts of ethoxy ethanol, 2 parts of dimethyl ether, 0.5 part of methylimidazole.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material
Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second
Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix
It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
Embodiment 2:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC40 parts, Rare-Earth Magnetic neodymium-iron-boron
30 parts of powder, 2.0 parts of ethyl acetate, 150 parts of polypropylene, 60 parts of Lauxite, 1.5 parts of sericite in powder, 15 parts of ABS high glue powder, slope
6 parts of thread stone, 5 parts of tributoxyethyl phosphate, 4 parts of styrene-butadiene latex, 5 parts of ethoxy ethanol, 5 parts of dimethyl ether, methylimidazole 1.0
Part.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material
Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second
Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix
It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
Embodiment 3:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC35 parts, Rare-Earth Magnetic neodymium-iron-boron
20 parts of powder, 1 part of ethyl acetate, 120 parts of polypropylene, 55 parts of Lauxite, 1 part of sericite in powder, 14 parts of ABS high glue powder, palygorskite 5
Part, 3 parts of tributoxyethyl phosphate, 3 parts of styrene-butadiene latex, 3 parts of ethoxy ethanol, 3 parts of dimethyl ether, 1 part of methylimidazole.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material
Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second
Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix
It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
Above content is only citing made for the present invention and explanation, affiliated those skilled in the art are to being retouched
The specific embodiment stated does various modifications or additions or is substituted in a similar manner, as long as it does not deviate from the concept of invention
Or beyond the scope defined by this claim, it is within the scope of protection of the invention.
Claims (6)
1. a kind of medical COC bottles of materials, which is characterized in that according to mass fraction meter include the following raw material: COC30-40 parts, dilute
15-30 parts of native magnetic NdFeB magnetic powder, 0.5-2.0 parts of ethyl acetate, 100-150 parts of polypropylene, 50-60 parts of Lauxite, thin,tough silk cloud
1-1.5 parts of female powder, 13-15 parts of ABS high glue powder, 4-6 parts of palygorskite, 2-5 parts of tributoxyethyl phosphate, 2-4 parts of styrene-butadiene latex,
2-5 parts of ethoxy ethanol, 2-5 parts of dimethyl ether, 0.5-1.0 parts of methylimidazole.
2. a kind of medical COC bottles of material according to claim 1, which is characterized in that according to mass fraction meter including such as
Lower raw material: COC30 parts, 15 parts of Rare-Earth Magnetic NdFeB magnetic powder, 2.0 parts of ethyl acetate, 150 parts of polypropylene, 50 parts of Lauxite, thin,tough silk
1.5 parts of mica powder, 13 parts of ABS high glue powder, 6 parts of palygorskite, 5 parts of tributoxyethyl phosphate, 2 parts of styrene-butadiene latex, ethyoxyl second
5 parts of alcohol, 2 parts of dimethyl ether, 1.0 parts of methylimidazole.
3. a kind of medical COC bottles of material according to claim 1, which is characterized in that according to mass fraction meter including such as
Lower raw material: COC35 parts, 20 parts of Rare-Earth Magnetic NdFeB magnetic powder, 1 part of ethyl acetate, 120 parts of polypropylene, 55 parts of Lauxite, thin,tough silk cloud
1 part of female powder, 14 parts of ABS high glue powder, 5 parts of palygorskite, 3 parts of tributoxyethyl phosphate, 3 parts of styrene-butadiene latex, ethoxy ethanol 3
Part, 3 parts of dimethyl ether, 1 part of methylimidazole.
4. a kind of medical COC bottles of material according to claim 1, which is characterized in that preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material mistake
Sieve, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, ethyoxyl
Ethyl alcohol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring, mixing, in
Speed stirs evenly;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
5. a kind of medical COC bottles of material according to claim 1, which is characterized in that the step S2 middling speed is 800-
1200rpm, storage room temperature are 18-26 DEG C.
6. a kind of medical COC bottles of material according to claim 1, which is characterized in that the Rare-Earth Magnetic NdFeB magnetic powder
Partial size is 50-100nm, and the partial size of the palygorskite is 10-100nm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811138598.5A CN109306122A (en) | 2018-09-28 | 2018-09-28 | A kind of medical COC bottles of materials |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811138598.5A CN109306122A (en) | 2018-09-28 | 2018-09-28 | A kind of medical COC bottles of materials |
Publications (1)
Publication Number | Publication Date |
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CN109306122A true CN109306122A (en) | 2019-02-05 |
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ID=65225061
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CN201811138598.5A Pending CN109306122A (en) | 2018-09-28 | 2018-09-28 | A kind of medical COC bottles of materials |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103797063A (en) * | 2011-09-13 | 2014-05-14 | 住友电木株式会社 | Packaging sheet |
CN104045973A (en) * | 2014-06-23 | 2014-09-17 | 青岛祥海电子有限公司 | Medical environment-friendly rubber biomaterial |
CN104558854A (en) * | 2013-10-28 | 2015-04-29 | 中国石油化工股份有限公司 | Polypropylene composition for ampoule bottle |
-
2018
- 2018-09-28 CN CN201811138598.5A patent/CN109306122A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103797063A (en) * | 2011-09-13 | 2014-05-14 | 住友电木株式会社 | Packaging sheet |
CN104558854A (en) * | 2013-10-28 | 2015-04-29 | 中国石油化工股份有限公司 | Polypropylene composition for ampoule bottle |
CN104045973A (en) * | 2014-06-23 | 2014-09-17 | 青岛祥海电子有限公司 | Medical environment-friendly rubber biomaterial |
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RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190205 |
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RJ01 | Rejection of invention patent application after publication |