CN109306122A - A kind of medical COC bottles of materials - Google Patents

A kind of medical COC bottles of materials Download PDF

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Publication number
CN109306122A
CN109306122A CN201811138598.5A CN201811138598A CN109306122A CN 109306122 A CN109306122 A CN 109306122A CN 201811138598 A CN201811138598 A CN 201811138598A CN 109306122 A CN109306122 A CN 109306122A
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CN
China
Prior art keywords
parts
powder
coc
bottles
medical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811138598.5A
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Chinese (zh)
Inventor
潘杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongcheng Shuanggang Senke Plastic Factory
Original Assignee
Tongcheng Shuanggang Senke Plastic Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongcheng Shuanggang Senke Plastic Factory filed Critical Tongcheng Shuanggang Senke Plastic Factory
Priority to CN201811138598.5A priority Critical patent/CN109306122A/en
Publication of CN109306122A publication Critical patent/CN109306122A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/01Magnetic additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/14Gas barrier composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/02Applications for biomedical use
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/10Applications used for bottles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)
  • Medicinal Preparation (AREA)

Abstract

The invention discloses a kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC30-40 parts, 15-30 parts of Rare-Earth Magnetic NdFeB magnetic powder, 0.5-2.0 parts of ethyl acetate, 100-150 parts of polypropylene, 50-60 parts of Lauxite, 1-1.5 parts of sericite in powder, 13-15 parts of ABS high glue powder, 4-6 parts of palygorskite, 2-5 parts of tributoxyethyl phosphate, 2-4 parts of styrene-butadiene latex, 2-5 parts of ethoxy ethanol, 2-5 parts of dimethyl ether, 0.5-1.0 parts of methylimidazole.This material include using COC as major ingredient, the copolymer of COC system cyclic polyolefin and vinyl monomer, with high transparency, high water vapor barrier property and gas barrier property, low water absorbable, resistance to chemical reagents and it is low dissolution etc. characteristics.

Description

A kind of medical COC bottles of materials
Technical field
The invention belongs to plastic material fields, and in particular to a kind of medical COC bottles of material.
Background technique
With the development of economy, packaging industry has significant progress.But the packaging of medicine trade is in addition to commercial value, The breakthrough of even more important technology.
Drug has harsh requirement to packaging.Packaging material, structure, stability etc. combined factors consider.Such as hand Anesthetic,general-sevoflurane that art uses, about 2000 yuan of 250 milliliters of price.Direct competitive opponent is that Abbott Laboratories and hundred are special.
Vial is not suitable for packaging " sevoflurane ", and glass can cause impurity excessive by slight erosion.General-purpose plastics (PE, PP, PET) and common high performance plastics (PEN) mostly by the protection of some big biomedical company's patented technology barriers.Metallic aluminium Bottle is limited by certain unit commercial contract, can only be limited to certain technical fields and be used.
Summary of the invention
The purpose of the present invention is to provide a kind of medical COC bottles of materials.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter:: COC30-40 parts, Rare-Earth Magnetic neodymium iron 15-30 parts of boron magnetic powder, 0.5-2.0 parts of ethyl acetate, 100-150 parts of polypropylene, 50-60 parts of Lauxite, sericite in powder 1-1.5 Part, 13-15 parts of ABS high glue powder, 4-6 parts of palygorskite, 2-5 parts of tributoxyethyl phosphate, 2-4 parts of styrene-butadiene latex, ethyoxyl second 2-5 parts of alcohol, 2-5 parts of dimethyl ether, 0.5-1.0 parts of methylimidazole.
A kind of medical COC bottles of material, includes the following raw material according to mass fraction meter: COC30 parts, Rare-Earth Magnetic neodymium 15 parts of iron boron magnetic powder, 2.0 parts of ethyl acetate, 150 parts of polypropylene, 50 parts of Lauxite, 1.5 parts of sericite in powder, ABS high glue powder 13 Part, 6 parts of palygorskite, 5 parts of tributoxyethyl phosphate, 2 parts of styrene-butadiene latex, 5 parts of ethoxy ethanol, 2 parts of dimethyl ether, methylimidazole 1.0 part.
A kind of medical COC bottles of material, includes the following raw material according to mass fraction meter: COC35 parts, Rare-Earth Magnetic neodymium 20 parts of iron boron magnetic powder, 1 part of ethyl acetate, 120 parts of polypropylene, 55 parts of Lauxite, 1 part of sericite in powder, 14 parts of ABS high glue powder, 5 parts of palygorskite, 3 parts of tributoxyethyl phosphate, 3 parts of styrene-butadiene latex, 3 parts of ethoxy ethanol, 3 parts of dimethyl ether, methylimidazole 1 Part.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
The step S2 middling speed is 800-1200rpm, and storage room temperature is 18-26 DEG C.
The Rare-Earth Magnetic NdFeB magnetic powder partial size is 50-100nm, and the partial size of the palygorskite is 10-100nm.
Beneficial effects of the present invention: this material includes using COC as major ingredient, and COC system cyclic polyolefin and vinyl monomer are total to Polymers, with high transparency, high water vapor barrier property and gas barrier property, low water absorbable, resistance to chemical reagents and it is low dissolution etc. characteristics.
Specific embodiment
Present invention is further described in detail combined with specific embodiments below.
Embodiment 1:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC30 parts, Rare-Earth Magnetic neodymium-iron-boron 15 parts of powder, 0.5 part of ethyl acetate, 100 parts of polypropylene, 50 parts of Lauxite, 1 part of sericite in powder, 13 parts of ABS high glue powder, slope thread 4 parts of stone, 2 parts of tributoxyethyl phosphate, 2 parts of styrene-butadiene latex, 2 parts of ethoxy ethanol, 2 parts of dimethyl ether, 0.5 part of methylimidazole.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
Embodiment 2:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC40 parts, Rare-Earth Magnetic neodymium-iron-boron 30 parts of powder, 2.0 parts of ethyl acetate, 150 parts of polypropylene, 60 parts of Lauxite, 1.5 parts of sericite in powder, 15 parts of ABS high glue powder, slope 6 parts of thread stone, 5 parts of tributoxyethyl phosphate, 4 parts of styrene-butadiene latex, 5 parts of ethoxy ethanol, 5 parts of dimethyl ether, methylimidazole 1.0 Part.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
Embodiment 3:
A kind of medical COC bottles of materials, include the following raw material according to mass fraction meter: COC35 parts, Rare-Earth Magnetic neodymium-iron-boron 20 parts of powder, 1 part of ethyl acetate, 120 parts of polypropylene, 55 parts of Lauxite, 1 part of sericite in powder, 14 parts of ABS high glue powder, palygorskite 5 Part, 3 parts of tributoxyethyl phosphate, 3 parts of styrene-butadiene latex, 3 parts of ethoxy ethanol, 3 parts of dimethyl ether, 1 part of methylimidazole.
A kind of medical COC bottles of materials, preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material Sieving, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, second Ethoxy-ethanol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring mix It closes, moderate-speed mixer is uniform;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
Above content is only citing made for the present invention and explanation, affiliated those skilled in the art are to being retouched The specific embodiment stated does various modifications or additions or is substituted in a similar manner, as long as it does not deviate from the concept of invention Or beyond the scope defined by this claim, it is within the scope of protection of the invention.

Claims (6)

1. a kind of medical COC bottles of materials, which is characterized in that according to mass fraction meter include the following raw material: COC30-40 parts, dilute 15-30 parts of native magnetic NdFeB magnetic powder, 0.5-2.0 parts of ethyl acetate, 100-150 parts of polypropylene, 50-60 parts of Lauxite, thin,tough silk cloud 1-1.5 parts of female powder, 13-15 parts of ABS high glue powder, 4-6 parts of palygorskite, 2-5 parts of tributoxyethyl phosphate, 2-4 parts of styrene-butadiene latex, 2-5 parts of ethoxy ethanol, 2-5 parts of dimethyl ether, 0.5-1.0 parts of methylimidazole.
2. a kind of medical COC bottles of material according to claim 1, which is characterized in that according to mass fraction meter including such as Lower raw material: COC30 parts, 15 parts of Rare-Earth Magnetic NdFeB magnetic powder, 2.0 parts of ethyl acetate, 150 parts of polypropylene, 50 parts of Lauxite, thin,tough silk 1.5 parts of mica powder, 13 parts of ABS high glue powder, 6 parts of palygorskite, 5 parts of tributoxyethyl phosphate, 2 parts of styrene-butadiene latex, ethyoxyl second 5 parts of alcohol, 2 parts of dimethyl ether, 1.0 parts of methylimidazole.
3. a kind of medical COC bottles of material according to claim 1, which is characterized in that according to mass fraction meter including such as Lower raw material: COC35 parts, 20 parts of Rare-Earth Magnetic NdFeB magnetic powder, 1 part of ethyl acetate, 120 parts of polypropylene, 55 parts of Lauxite, thin,tough silk cloud 1 part of female powder, 14 parts of ABS high glue powder, 5 parts of palygorskite, 3 parts of tributoxyethyl phosphate, 3 parts of styrene-butadiene latex, ethoxy ethanol 3 Part, 3 parts of dimethyl ether, 1 part of methylimidazole.
4. a kind of medical COC bottles of material according to claim 1, which is characterized in that preparation method the following steps are included:
S1 material prepares: according to formula, preparing Rare-Earth Magnetic NdFeB magnetic powder and palygorskite;Sieving, drying, by solid material mistake Sieve, 45-60 DEG C of drying;
S2 plastics are prepared;It weighs, prepare, weigh COC, ethoxy ethanol, tributoxyethyl phosphate, styrene-butadiene latex, ethyoxyl Ethyl alcohol, dimethyl ether, methylimidazole, polypropylene, sericite in powder, ABS high glue powder, Lauxite, ethyl acetate, stirring, mixing, in Speed stirs evenly;Conveying, storage, convey warehouse room temperature storage;
The processing of S3 one step processing;Raw material after above-mentioned processing is taken out from warehouse, product are blow molded into after injection molding.
5. a kind of medical COC bottles of material according to claim 1, which is characterized in that the step S2 middling speed is 800- 1200rpm, storage room temperature are 18-26 DEG C.
6. a kind of medical COC bottles of material according to claim 1, which is characterized in that the Rare-Earth Magnetic NdFeB magnetic powder Partial size is 50-100nm, and the partial size of the palygorskite is 10-100nm.
CN201811138598.5A 2018-09-28 2018-09-28 A kind of medical COC bottles of materials Pending CN109306122A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811138598.5A CN109306122A (en) 2018-09-28 2018-09-28 A kind of medical COC bottles of materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811138598.5A CN109306122A (en) 2018-09-28 2018-09-28 A kind of medical COC bottles of materials

Publications (1)

Publication Number Publication Date
CN109306122A true CN109306122A (en) 2019-02-05

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CN201811138598.5A Pending CN109306122A (en) 2018-09-28 2018-09-28 A kind of medical COC bottles of materials

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103797063A (en) * 2011-09-13 2014-05-14 住友电木株式会社 Packaging sheet
CN104045973A (en) * 2014-06-23 2014-09-17 青岛祥海电子有限公司 Medical environment-friendly rubber biomaterial
CN104558854A (en) * 2013-10-28 2015-04-29 中国石油化工股份有限公司 Polypropylene composition for ampoule bottle

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103797063A (en) * 2011-09-13 2014-05-14 住友电木株式会社 Packaging sheet
CN104558854A (en) * 2013-10-28 2015-04-29 中国石油化工股份有限公司 Polypropylene composition for ampoule bottle
CN104045973A (en) * 2014-06-23 2014-09-17 青岛祥海电子有限公司 Medical environment-friendly rubber biomaterial

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Application publication date: 20190205

RJ01 Rejection of invention patent application after publication