CN109294640A - A kind of diesel fuel additives and preparation method thereof - Google Patents

A kind of diesel fuel additives and preparation method thereof Download PDF

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Publication number
CN109294640A
CN109294640A CN201811404640.3A CN201811404640A CN109294640A CN 109294640 A CN109294640 A CN 109294640A CN 201811404640 A CN201811404640 A CN 201811404640A CN 109294640 A CN109294640 A CN 109294640A
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diesel fuel
fuel additives
parts
diesel
functional dose
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CN109294640B (en
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林壮
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KAIPING BAOCHIJIE AUTOMOBILE ARTICLE TECHNOLOGY CO.,LTD.
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Guangdong Yue Fu Automobile Products Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/06Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/08Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines
    • C10L2270/026Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)

Abstract

The invention discloses a kind of diesel fuel additives and preparation method thereof, the diesel fuel additives includes multi-functional dose and the aviation kerosine that mass ratio is 1:1-5, according to the mass fraction, wherein described multi-functional dose includes following components: 60-100 parts of 2- ethylhexyl nitrate, 1-20 parts of light solvent naphtha, 1-20 parts of heavy solvent naphtha, 1,2,4- 0.1-10 parts of trimethylbenzene, 1,3,5- 0.1-10 parts of trimethylbenzenes, 0.05-8 parts of naphthalene, 0.05-8 parts of n-propylbenzene, 0.05-5 parts of cumene.Diesel fuel additives of the invention can clean atomizer carbon distribution, keep burning more complete, improve fuel oil utilization efficiency, promote power, can restore the good atomizing effect of fuel oil, improve and be cold-started difficult situation, can effectively improve diesel stability, completely compatible with biodiesel.

Description

A kind of diesel fuel additives and preparation method thereof
Technical field
The invention belongs to fuel oil additive technical fields, and in particular to a kind of diesel fuel additives and preparation method thereof.
Background technique
Compared to gasoline, the unsaturated hydrocarbons impurity content in diesel oil is higher, this results in diesel oil and is not easy completely burned, therefore Diesel engine is easy to produce black smoke, and is easy to appear carbon deposition phenomenon, is easier to form carbon distribution at engine nozzle position, influence Engine work causes fuel consumption to increase, and exhaust emissions deteriorates, and engine life shortens.Diesel oil is non-renewable energy It improves diesel oil cleanliness with the reduction of natural oil storage capacity and diesel oil full combustion is made to be current chemical industry neck in one of source The problem of domain and auto industry are extremely paid close attention to, especially in the currently used diesel oil in China, catalytic cracking diesel oil proportion It is also quite high, therefore also than more serious the problem of diesel oil oxidation generation colloid, paint film and deposit.When engine operates, oil spout Mouth temperature is at 100 DEG C or so, and intake valve temperature is between 200-300 DEG C.At such temperatures, in diesel oil it is unstable at Part, oxidative dimerization is easily generated, colloid and carbon distribution is generated, is deposited on intake valve and atomizer, advanced high pressure-charging hair Motivation and carbon distribution is more prone to produce using the engine of GDI diesel oil direct injection technology.The deposit being deposited on intake valve, will cause Inlet channel sectional area is reduced, and intake efficiency reduces, and power decline can make valve event slow, be not closed completely when serious.Oil spout Mouth carbon distribution can make oil spout unsmooth, diesel oil atomization quality decline, after causing diesel oil to enter combustion chamber, it is difficult to which completely burned causes to send out Motivation difficulty in starting, unstable idle speed and oil consumption increase, and exhaust emissions deteriorates, and especially in winter, these situations are more obvious. Many places have been distinctly claimed non-clean diesel oil and have been not allowed to enter the market.With being widely used for diesel engine, the consumption of diesel oil just by Year increases.However a large amount of consumption of diesel oil also inevitably result in being further exacerbated by for vehicle discharge nuisance.Due to discharging to life State environment, human health and economic development seriously affect, and national governments have formulated strict emission regulation in succession, limit diesel oil The noxious emission of vehicle.Therefore, the oil consumption and pollution for further decreasing diesel-engine road vehicle are current urgent problems to be solved.In crowd In more solutions, the method using diesel fuel additives is not changing vehicle and engine structure, does not also increase the item of equipment Under part, by changing the physical property of fuel, enable fuel full combustion, to realize energy conservation and purification discharge.Improve diesel oil hair Motivation fuel combustion quality is many in the method for reducing tail gas pollution, the use of additive is economically and efficiently one of method.Mesh Before, diesel fuel additives in the prior art exist have a single function, be larger to the corrosivity of engine interior, exhaust emissions nuisance Matter reduces the disadvantages of unobvious.
Summary of the invention
In view of the problems of the existing technology, the present invention provides a kind of diesel fuel additives and preparation method thereof.
The invention adopts the following technical scheme:
A kind of diesel fuel additives, the diesel fuel additives include multi-functional dose and the aviation kerosine that mass ratio is 1:1-5,
According to the mass fraction, wherein described multi-functional dose includes following components:
Further, according to the mass fraction, wherein described multi-functional dose includes following components:
Further, according to the mass fraction, wherein described multi-functional dose includes following components:
Further, the diesel fuel additives includes multi-functional dose and (tasteless) aviation kerosine that mass ratio is 1:1-3, example Such as 35 parts multi-functional dose and 35 parts of (tasteless) aviation kerosines.
Further, No. CAS of the 2- ethylhexyl nitrate is 27247-96-7.Further, light solvent stone Cerebrol is solvent naphtha (petroleum), belongs to light aromatics, and No. CAS is 64742-95-6.Heavy solvent naphtha is solvent stone Cerebrol (petroleum) belongs to heavy arene, and No. CAS is 64742-95-5.No. CAS of 1,2,4- trimethylbenzene is 95-63-6.1,3,5- No. CAS of trimethylbenzene is 108-67-8.No. CAS of n-propylbenzene is 103-65-1.No. CAS of naphthalene is 91-20-3.Cumene No. CAS is 98-82-8.
A kind of preparation method of diesel fuel additives, comprising the following steps:
(1) ingredient in described multi-functional dose is stirred evenly according to the ratio (using fire-proof motor) to get described multi-functional Agent;
(2) described multi-functional dose and aviation kerosine are stirred evenly according to the ratio (using fire-proof motor) to get the diesel oil Additive.
(20 DEG C of multi-functional dose of the density;g/cm3): 0.965;Close cup flash point (DEG C): >=74;Pour point (DEG C): < -48; Kinematic viscosity (40 DEG C, mm2/ S): 6.9;Kinematic viscosity (- 20 DEG C, mm2/ S): 72.7.
Close cup flash point (DEG C, GB/T261) > 70 of the diesel fuel additives, such as 97;Mechanical admixture (mass number %, GB/ T511-2010) < 0.01, mechanical admixture is specifically free of;Moisture content (%, GB/T260) < 0.03, it is specifically not aqueous;Viscosity (40 DEG C, mm2/ S, GB/T265): 3.0~20.0, such as 10.81;Density (20 DEG C, g/cm3, GB/T1884-2008): 0.83~ 0.93, such as 0.835;Low temperature properties: cloud point (DEG C, GB/T6986-2014): < -20, such as -30;Pour point (DEG C, GB/T3535- < -30, such as -40 2006);Condensation point (DEG C, GB/T510-1983) < -30, such as -43;Copper corrosion (50 DEG C, 3 hours, GB/ T5096-1985)≤1b, such as 1b.
Diesel fuel additives of the present invention can be used for all kinds of diesel engines, and high pressure co-rail diesel electric jet vehicle is equally suitable With can provide potent fuel nozzle detergency, promote power and accelerating ability, improving Cetane number (can make diesel oil Cetane number amplification is up to 6), corrosion-inhibiting can be excellent, so that engine component is protected, good diesel oil foam control Performance improves fuel economy, extends engine life, reduces discharge, extends engine life, to direct-injection, high-pressure common rail bavin Oil machine equally has excellent effect, reduces ignition delay time, reduces engine noise and vibration, promotes burning, to reduce Black smoke, stable storing.Every 80-100 rises that fuel tank uses 200mL every time or every 5000 kilometers use 1 time.
Diesel fuel additives of the present invention includes the polar activation factor, can adsorb colloid, greasy filth and carbon distribution, seep Thoroughly, it removes, is discharged after high-temp combustion by tail gas, cleans entire fuel system.It is difficult, idle because being cold-started caused by carbon distribution to solve The problems such as fast unstable, acceleration is powerless, over-emitting black exhaust.This product safety and environmental protection is free of alcohols material, does not corrode or damage engine portion Part.
Beneficial effects of the present invention:
(1) diesel fuel additives of the invention can clean atomizer carbon distribution, keep burning more complete, improve fuel oil using effect Rate promotes power;
(2) preparation method of diesel fuel additives of the invention is easy, at low cost, is suitble to large-scale industrial production application;
(3) diesel fuel additives of the invention can restore the good atomizing effect of fuel oil, improve and be cold-started difficult situation, can be effective Diesel stability is improved, it is completely compatible with biodiesel;
(4) diesel fuel additives of the invention can with lubricating fuel spray nozzle, prevent atomizer adhesion it is stuck and blocking etc. failures;
(5) diesel fuel additives of the invention can clean combustion-chamber deposit, maintain normal compression ratio, reduce pinking, engine knock Phenomena such as;
(6) diesel fuel additives of the invention can reduce noxious gas emission, protect environment.
Specific embodiment
In order to preferably explain the present invention, it is described further now in conjunction with following specific embodiments, but the present invention is unlimited In specific embodiment.
Multi-functional dose in diesel fuel additives is prepared according to table 1.
Table 1: multi-functional dose of component (mass parts) in each embodiment.
The mass ratio of multi-functional dose of the diesel fuel additives of embodiment 1-2 and aviation kerosine is 1:1, the bavin of embodiment 3-4 The mass ratio of multi-functional dose of oil additive and aviation kerosine is 1:2, multi-functional dose and boat of the diesel fuel additives of embodiment 5-6 The mass ratio of empty kerosene is 1:3.
It is peace and quiet that diesel fuel additives (additional amount@1100ppm mg/kg) of the invention is subjected to high-pressure common rail DID engine Property (SHDI) screening test quietness measure of merit, power loss percentage are listed in table 2 with the result of testing time.Testing standard and Test method, GB/T18297-2001, automobile engine method for testing performance.It can be seen that: 1, do not add diesel oil addition of the invention Agent will cause the blocking of high-pressure common rail DID engine nozzle segment, and fuel atomization effect is bad, makes incomplete combustion, causes to move Power loss, and blocking is more serious, power loss is bigger;2, after adding diesel fuel additives of the invention, it is total that high pressure can effectively be cleaned Rail DID engine nozzle deposit carbon keeps burning more complete, improves fuel oil utilization efficiency, restores power;3, from power loss negative As can be seen that diesel fuel additives of the present invention can effectively promote Cetane number, engine power is promoted, saves fuel oil.
Table 2:
Rate of economizing gasoline detection: (testing standard and test method: GBT 14951-2007, vehicle fuel saving technique evaluation are detected Method), it the use of rate of economizing gasoline after diesel fuel additives of the invention is 4.1%.
Discharging pollutants reduces ratio test (testing standard and test method: GB 17691-2005, automobile-used compression-ignited, gas Fluid fuel spark-ignition engine and automobile exhaust dye object emission limit and measurement method (Chinese III, IV, V stage): this hair is used Discharging pollutants after bright diesel fuel additives reduces ratio: CO2It is 3.9%, hydrocarbon 20%, CO 14%, nitrogen oxygen Compound is 0.8%, particulate matter 16%.
Above is only a specific embodiment of the present invention, it is not intended to limit the scope of the invention, all utilizations The equivalent transformation that the present invention makees, is applied directly or indirectly in other relevant technical fields, similarly includes of the invention Among scope of patent protection.

Claims (6)

1. a kind of diesel fuel additives, which is characterized in that the diesel fuel additives includes multi-functional dose that mass ratio is 1:1-5 and boat Empty kerosene,
According to the mass fraction, wherein described multi-functional dose includes following components:
2. diesel fuel additives according to claim 1, which is characterized in that according to the mass fraction, wherein described multi-functional dose Including following components:
3. diesel fuel additives according to claim 1, which is characterized in that according to the mass fraction, wherein described multi-functional dose Including following components:
4. diesel fuel additives according to any one of claim 1-3, which is characterized in that the diesel fuel additives includes matter Amount is than for multi-functional dose of 1:1-3 and aviation kerosine.
5. diesel fuel additives according to any one of claim 1-3, which is characterized in that the 2- ethylhexyl nitrate No. CAS be 27247-96-7.
6. a kind of preparation method of diesel fuel additives according to any one of claims 1-5, which is characterized in that including with Lower step:
(1) ingredient in described multi-functional dose is stirred evenly according to the ratio to get described multi-functional dose;
(2) described multi-functional dose and aviation kerosine are stirred evenly according to the ratio to get the diesel fuel additives.
CN201811404640.3A 2018-11-23 2018-11-23 Diesel oil additive and preparation method thereof Active CN109294640B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112852507A (en) * 2020-12-28 2021-05-28 广东月福汽车用品有限公司 Diesel fuel additive, diesel fuel additive composition and diesel fuel composition

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CN1052324A (en) * 1989-12-07 1991-06-19 河南省鹤壁市应用化学研究所 Diesel-dope
CN1611582A (en) * 2003-10-31 2005-05-04 天津开发区友仁科技发展有限公司 Multifunctional efficent composite fuel additive for engine and preparing method thereof
CN101935563A (en) * 2009-06-29 2011-01-05 姚吉有 Heavy diesel energy-saving agent
CN103103000A (en) * 2013-03-06 2013-05-15 济南恒致达新能源科技有限公司 Multifunctional oil-saving and emission-reducing compound diesel fuel additive composition
CN105695043A (en) * 2016-01-12 2016-06-22 深圳市广昌达石油添加剂有限公司 Industrial oil compound antioxidant and preparing method thereof
US9464251B2 (en) * 2014-05-02 2016-10-11 Silverthorn Industries LLC. Cyclic diene or cyclic triene-based diesel fuel additive
CN106544068A (en) * 2015-09-23 2017-03-29 亚申科技研发中心(上海)有限公司 diesel fuel composition

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1052324A (en) * 1989-12-07 1991-06-19 河南省鹤壁市应用化学研究所 Diesel-dope
CN1611582A (en) * 2003-10-31 2005-05-04 天津开发区友仁科技发展有限公司 Multifunctional efficent composite fuel additive for engine and preparing method thereof
CN101935563A (en) * 2009-06-29 2011-01-05 姚吉有 Heavy diesel energy-saving agent
CN103103000A (en) * 2013-03-06 2013-05-15 济南恒致达新能源科技有限公司 Multifunctional oil-saving and emission-reducing compound diesel fuel additive composition
US9464251B2 (en) * 2014-05-02 2016-10-11 Silverthorn Industries LLC. Cyclic diene or cyclic triene-based diesel fuel additive
CN106544068A (en) * 2015-09-23 2017-03-29 亚申科技研发中心(上海)有限公司 diesel fuel composition
CN105695043A (en) * 2016-01-12 2016-06-22 深圳市广昌达石油添加剂有限公司 Industrial oil compound antioxidant and preparing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112852507A (en) * 2020-12-28 2021-05-28 广东月福汽车用品有限公司 Diesel fuel additive, diesel fuel additive composition and diesel fuel composition

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