CN109294237A - The preparation method of high-damping composite environmental-friendly rubber material - Google Patents
The preparation method of high-damping composite environmental-friendly rubber material Download PDFInfo
- Publication number
- CN109294237A CN109294237A CN201811035729.7A CN201811035729A CN109294237A CN 109294237 A CN109294237 A CN 109294237A CN 201811035729 A CN201811035729 A CN 201811035729A CN 109294237 A CN109294237 A CN 109294237A
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- parts
- rubber
- preparation
- damping composite
- rubber material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses the preparation method of high-damping composite environmental-friendly rubber material, the component including following parts by weight: 35~46 parts of methyl vinyl silicone rubber, 20~30 parts of nanoclay, 12~23 parts of silane coupling agent, 8~11 parts of zinc oxide, 5~7 parts of paraffin, 20~37 parts of carbon black, N- cyclohexyl -3~6 parts of 4-aminodiphenylamine, 11~16 parts of pine tar, 3~4 parts of Sulfur, 8~19 parts of aluminium hydroxide, 22~34 parts of nitrile rubber, 11~16 parts of neoprene, 14~28 parts of magnesia, 9~17 parts of silica.Service efficiency of the present invention is higher, more convenient to use.
Description
Technical field
The present invention relates to environment protection fields, and in particular to the preparation method of high-damping composite environmental-friendly rubber material.
Background technique
Rubber material is a kind of high molecular material that can restore deformation rapidly under large deformation, it is the important of national economy
One of basic industry daily, medical provides light industry rubber product to be indispensable in people's daily life;For digging, traffic,
The heavy industry such as building, machinery, electronics and new industry provide various rubber system production equipments or rubber components, application are very wide
It is general.
In recent years, the rapid development of rubber industry, to rubber product, more stringent requirements are proposed, and rubber material must be towards
Functionalization, fining and the direction of diversification are developed.Traditional single rubber material cannot fully meet making for rapid development
With requiring.Rubber belong to elastomer lack crystallizing power, intermolecular force is small, and free volume is big, thus its intensity, hardness,
The performances such as wear-resisting and tired are not high, so to pass through reinforcement to rubber, improve its performance.
Summary of the invention
Not environmentally and service efficiency is poor the technical problem to be solved by the present invention is to existing rubber material, purpose exists
In providing the preparation method of high-damping composite environmental-friendly rubber material, the use of rubber material is solved the problems, such as.
The present invention is achieved through the following technical solutions:
The preparation method of high-damping composite environmental-friendly rubber material, the component including following parts by weight: methyl ethylene silicon
35~46 parts of rubber, 20~30 parts of nanoclay, 12~23 parts of silane coupling agent, 8~11 parts of zinc oxide, 5~7 parts of paraffin, carbon
Black 20~37 parts, N- cyclohexyl -3~6 parts of 4-aminodiphenylamine, 11~16 parts of pine tar, 3~4 parts of Sulfur, aluminium hydroxide 8
~19 parts, 22~34 parts of nitrile rubber, 11~16 parts of neoprene, 14~28 parts of magnesia, 9~17 parts of silica.
The preparation method of high-damping composite environmental-friendly rubber material, the component including following parts by weight: methyl ethylene silicon
38~42 parts of rubber, 25~28 parts of nanoclay, 14~21 parts of silane coupling agent, 9~11 parts of zinc oxide, 6~7 parts of paraffin, carbon
Black 22~35 parts, N- cyclohexyl -4~6 parts of 4-aminodiphenylamine, 14~16 parts of pine tar, 3~4 parts of Sulfur, aluminium hydroxide 10
~17 parts, 24~32 parts of nitrile rubber, 13~15 parts of neoprene, 16~23 parts of magnesia, 1~13 part of silica 1.
The preparation method of high-damping composite environmental-friendly rubber material, the component including following parts by weight: methyl ethylene silicon
40 parts of rubber, 27 parts of nanoclay, 19 parts of silane coupling agent, 10 parts of zinc oxide, 6 parts of paraffin, 33 parts of carbon black, N- cyclohexyl-N-
5 parts of diphenyl-para-phenylene diamine, 15 parts of pine tar, 4 parts of Sulfur, 16 parts of aluminium hydroxide, 29 parts of nitrile rubber, 14 parts of neoprene, oxygen
Change 18 parts of magnesium, 2 parts of silica 1.
The present invention the following steps are included:
(1) according to parts by weight than weighing each raw material component;
(2) by methyl vinyl silicone rubber, silane coupling agent, nitrile rubber, neoprene, N- cyclohexyl-N- phenyl pair
Phenylenediamine, aluminium hydroxide are added in rubber mixing machine and are kneaded at 80~110 DEG C;
(3) it is added nanoclay in the rubber mixing machine in step (2), zinc oxide, paraffin, pine tar, Sulfur is uniformly mixed
Afterwards, it is kneaded 40~60 minutes at 50~70 DEG C, obtains mixing virgin rubber;
(4) to step (magnesia, carbon black, silica is added in the mixing virgin rubber in (3) and stirs 20 at 40~60 DEG C
~30 minutes, then natural cooling, obtained the rubber composite material.
Compared with prior art, the present invention having the following advantages and benefits:
1, the preparation method of high-damping composite environmental-friendly rubber material of the present invention, rubber material of the invention is more environmentally-friendly, more
Convenient for being used for a long time;
2, the preparation method of high-damping composite environmental-friendly rubber material of the present invention, service efficiency of the present invention is higher, using more
It is convenient.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer, below with reference to embodiment, the present invention is made
Further to be described in detail, exemplary embodiment of the invention and its explanation for explaining only the invention, are not intended as to this
The restriction of invention.
Embodiment 1
The preparation method of high-damping composite environmental-friendly rubber material of the present invention, the component including following parts by weight: methyl second
35~46 parts of alkenyl silicon rubber, 20~30 parts of nanoclay, 12~23 parts of silane coupling agent, 8~11 parts of zinc oxide, paraffin 5~7
Part, 20~37 parts of carbon black, N- cyclohexyl -3~6 parts of 4-aminodiphenylamine, 11~16 parts of pine tar, 3~4 parts of Sulfur, hydrogen-oxygen
Change 8~19 parts of aluminium, 22~34 parts of nitrile rubber, 11~16 parts of neoprene, 14~28 parts of magnesia, 9~17 parts of silica.
The preparation method of the high-damping composite environmental-friendly rubber material, the component including following parts by weight: methyl second
38~42 parts of alkenyl silicon rubber, 25~28 parts of nanoclay, 14~21 parts of silane coupling agent, 9~11 parts of zinc oxide, paraffin 6~7
Part, 22~35 parts of carbon black, N- cyclohexyl -4~6 parts of 4-aminodiphenylamine, 14~16 parts of pine tar, 3~4 parts of Sulfur, hydrogen-oxygen
Change 10~17 parts of aluminium, 24~32 parts of nitrile rubber, 13~15 parts of neoprene, 16~23 parts of magnesia, silica 1 1~13
Part.
The preparation method of the high-damping composite environmental-friendly rubber material, the component including following parts by weight: methyl second
40 parts of alkenyl silicon rubber, 27 parts of nanoclay, 19 parts of silane coupling agent, 10 parts of zinc oxide, 6 parts of paraffin, 33 parts of carbon black, N- hexamethylene
5 parts of base -4-aminodiphenylamine, 15 parts of pine tar, 4 parts of Sulfur, 16 parts of aluminium hydroxide, 29 parts of nitrile rubber, neoprene 14
Part, 18 parts of magnesia, 2 parts of silica 1.
Above-described specific embodiment has carried out further the purpose of the present invention, technical scheme and beneficial effects
It is described in detail, it should be understood that being not intended to limit the present invention the foregoing is merely a specific embodiment of the invention
Protection scope, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include
Within protection scope of the present invention.
Claims (3)
1. the preparation method of high-damping composite environmental-friendly rubber material, which comprises the following steps:
(1) according to parts by weight than weighing each raw material component;
(2) by methyl vinyl silicone rubber, silane coupling agent, nitrile rubber, neoprene, N- cyclohexyl-N- phenyl to benzene two
Amine, aluminium hydroxide are added in rubber mixing machine and are kneaded under;
(3) nanoclay is added in the rubber mixing machine in step (2), zinc oxide, paraffin, pine tar, Sulfur is uniformly mixed, obtains
To mixing virgin rubber;
(4) to step (magnesia, carbon black, silica is added in the mixing virgin rubber in (3) and stirs 20~30 at 40~60 DEG C
Minute, then natural cooling, obtains the rubber composite material.
2. the preparation method of high-damping composite environmental-friendly rubber material according to claim 1, which is characterized in that the step
(2) rubber mixing machine is kneaded at 80~110 DEG C in.
3. the preparation method of high-damping composite environmental-friendly rubber material according to claim 1, which is characterized in that the step
(3) it is kneaded 40~60 minutes at 50~70 DEG C in.
Priority Applications (1)
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CN201811035729.7A CN109294237A (en) | 2018-09-06 | 2018-09-06 | The preparation method of high-damping composite environmental-friendly rubber material |
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CN201811035729.7A CN109294237A (en) | 2018-09-06 | 2018-09-06 | The preparation method of high-damping composite environmental-friendly rubber material |
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CN109294237A true CN109294237A (en) | 2019-02-01 |
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CN201811035729.7A Withdrawn CN109294237A (en) | 2018-09-06 | 2018-09-06 | The preparation method of high-damping composite environmental-friendly rubber material |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112210216A (en) * | 2020-08-31 | 2021-01-12 | 四川中物材料股份有限公司 | High-damping phenyl silicone rubber and preparation method and application thereof |
-
2018
- 2018-09-06 CN CN201811035729.7A patent/CN109294237A/en not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112210216A (en) * | 2020-08-31 | 2021-01-12 | 四川中物材料股份有限公司 | High-damping phenyl silicone rubber and preparation method and application thereof |
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Application publication date: 20190201 |