CN108795062A - A kind of high-damping composite environmental-friendly rubber material - Google Patents
A kind of high-damping composite environmental-friendly rubber material Download PDFInfo
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- CN108795062A CN108795062A CN201811035762.XA CN201811035762A CN108795062A CN 108795062 A CN108795062 A CN 108795062A CN 201811035762 A CN201811035762 A CN 201811035762A CN 108795062 A CN108795062 A CN 108795062A
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- rubber
- rubber material
- damping composite
- composite environmental
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of high-damping composite environmental-friendly rubber materials, include the component of following parts by weight:35~46 parts of methyl vinyl silicone rubber, 20~30 parts of nanoclay, 12~23 parts of silane coupling agent, 8~11 parts of zinc oxide, 5~7 parts of paraffin, 20~37 parts of carbon black, N- cyclohexyl -3~6 parts of 4-aminodiphenylamine, 11~16 parts of pine tar, 3~4 parts of Sulfur, 8~19 parts of aluminium hydroxide, 22~34 parts of nitrile rubber, 11~16 parts of neoprene, 14~28 parts of magnesia, 9~17 parts of silica.Service efficiency of the present invention is higher, more convenient to use.
Description
Technical field
The present invention relates to field of environment protection, and in particular to a kind of high-damping composite environmental-friendly rubber material.
Background technology
Rubber material is a kind of high molecular material that can restore deformation rapidly under large deformation, it is the important of national economy
One of basic industry daily, medical provides light industry rubber product to be indispensable in people's daily life;For digging, traffic,
The heavy industry such as building, machinery, electronics and new industry provide various rubber system production equipments or rubber components, application are very wide
It is general.
In recent years, the rapid development of rubber industry, to rubber product, more stringent requirements are proposed, and rubber material must be towards
Functionalization, fining and the direction of diversification are developed.Traditional single rubber material cannot fully meet making for rapid development
With requiring.Rubber belong to elastomer lack crystallizing power, intermolecular force is small, and free volume is big, thus its intensity, hardness,
The performances such as wear-resisting and tired are not high, so to pass through reinforcement to rubber, improve its performance.
Invention content
The technical problem to be solved by the present invention is to existing rubber materials not environmentally and service efficiency is poor, and purpose exists
In providing a kind of high-damping composite environmental-friendly rubber material, the use of rubber material is solved the problems, such as.
The present invention is achieved through the following technical solutions:
A kind of high-damping composite environmental-friendly rubber material, includes the component of following parts by weight:Methyl vinyl silicone rubber 35
~46 parts, 20~30 parts of nanoclay, 12~23 parts of silane coupling agent, 8~11 parts of zinc oxide, 5~7 parts of paraffin, carbon black 20~
37 parts, N- cyclohexyl -3~6 parts of 4-aminodiphenylamine, 11~16 parts of pine tar, 3~4 parts of Sulfur, 8~19 parts of aluminium hydroxide,
22~34 parts of nitrile rubber, 11~16 parts of neoprene, 14~28 parts of magnesia, 9~17 parts of silica.
A kind of high-damping composite environmental-friendly rubber material, includes the component of following parts by weight:Methyl vinyl silicone rubber 38
~42 parts, 25~28 parts of nanoclay, 14~21 parts of silane coupling agent, 9~11 parts of zinc oxide, 6~7 parts of paraffin, carbon black 22~
35 parts, N- cyclohexyl -4~6 parts of 4-aminodiphenylamine, 14~16 parts of pine tar, 3~4 parts of Sulfur, aluminium hydroxide 10~17
Part, 24~32 parts of nitrile rubber, 13~15 parts of neoprene, 16~23 parts of magnesia, 1~13 part of silica 1.
A kind of high-damping composite environmental-friendly rubber material, includes the component of following parts by weight:Methyl vinyl silicone rubber 40
Part, 27 parts of nanoclay, 19 parts of silane coupling agent, 10 parts of zinc oxide, 6 parts of paraffin, 33 parts of carbon black, N- cyclohexyl-N- phenyl pair
5 parts of phenylenediamine, 15 parts of pine tar, 4 parts of Sulfur, 16 parts of aluminium hydroxide, 29 parts of nitrile rubber, 14 parts of neoprene, magnesia 18
Part, 2 parts of silica 1.
The present invention includes the following steps:
(1) each raw material component is weighed according to weight part ratio;
(2) by methyl vinyl silicone rubber, silane coupling agent, nitrile rubber, neoprene, N- cyclohexyl-N- phenyl pair
Phenylenediamine, aluminium hydroxide are added in rubber mixing machine and are kneaded at 80~110 DEG C;
(3) it is added nanoclay in the rubber mixing machine into step (2), zinc oxide, paraffin, pine tar, Sulfur is uniformly mixed
Afterwards, it is kneaded 40~60 minutes at 50~70 DEG C, obtains mixing virgin rubber;
(4) to step (magnesia, carbon black, silica is added in the mixing virgin rubber in (3) and stirs 20 at 40~60 DEG C
~30 minutes, then natural cooling, obtained the rubber composite material.
Compared with prior art, the present invention having the following advantages and advantages:
1, a kind of high-damping composite environmental-friendly rubber material of the present invention, rubber material of the invention is more environmentally-friendly, is more convenient for growing
Phase uses;
2, a kind of high-damping composite environmental-friendly rubber material of the present invention, service efficiency of the present invention is higher, more convenient to use.
Specific implementation mode
To make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiment, the present invention is made
Further to be described in detail, exemplary embodiment of the invention and its explanation are only used for explaining the present invention, are not intended as to this
The restriction of invention.
Embodiment 1
A kind of high-damping composite environmental-friendly rubber material of the present invention, includes the component of following parts by weight:Methyl ethylene silicon
35~46 parts of rubber, 20~30 parts of nanoclay, 12~23 parts of silane coupling agent, 8~11 parts of zinc oxide, 5~7 parts of paraffin, carbon
Black 20~37 parts, N- cyclohexyl -3~6 parts of 4-aminodiphenylamine, 11~16 parts of pine tar, 3~4 parts of Sulfur, aluminium hydroxide 8
~19 parts, 22~34 parts of nitrile rubber, 11~16 parts of neoprene, 14~28 parts of magnesia, 9~17 parts of silica.
A kind of high-damping composite environmental-friendly rubber material, includes the component of following parts by weight:Methyl ethylene silicon
38~42 parts of rubber, 25~28 parts of nanoclay, 14~21 parts of silane coupling agent, 9~11 parts of zinc oxide, 6~7 parts of paraffin, carbon
Black 22~35 parts, N- cyclohexyl -4~6 parts of 4-aminodiphenylamine, 14~16 parts of pine tar, 3~4 parts of Sulfur, aluminium hydroxide 10
~17 parts, 24~32 parts of nitrile rubber, 13~15 parts of neoprene, 16~23 parts of magnesia, 1~13 part of silica 1.
A kind of high-damping composite environmental-friendly rubber material, includes the component of following parts by weight:Methyl ethylene silicon
40 parts of rubber, 27 parts of nanoclay, 19 parts of silane coupling agent, 10 parts of zinc oxide, 6 parts of paraffin, 33 parts of carbon black, N- cyclohexyl-N-
5 parts of diphenyl-para-phenylene diamine, 15 parts of pine tar, 4 parts of Sulfur, 16 parts of aluminium hydroxide, 29 parts of nitrile rubber, 14 parts of neoprene, oxygen
Change 18 parts of magnesium, 2 parts of silica 1.
Above-described specific implementation mode has carried out further the purpose of the present invention, technical solution and advantageous effect
It is described in detail, it should be understood that the foregoing is merely the specific implementation mode of the present invention, is not intended to limit the present invention
Protection domain, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include
Within protection scope of the present invention.
Claims (3)
1. a kind of high-damping composite environmental-friendly rubber material, which is characterized in that include the component of following parts by weight:Methyl ethylene
35~46 parts of silicon rubber, 20~30 parts of nanoclay, 12~23 parts of silane coupling agent, 8~11 parts of zinc oxide, 5~7 parts of paraffin,
20~37 parts of carbon black, N- cyclohexyl -3~6 parts of 4-aminodiphenylamine, 11~16 parts of pine tar, 3~4 parts of Sulfur, aluminium hydroxide
8~19 parts, 22~34 parts of nitrile rubber, 11~16 parts of neoprene, 14~28 parts of magnesia, 9~17 parts of silica.
2. a kind of high-damping composite environmental-friendly rubber material according to claim 1, which is characterized in that including following parts by weight
Several components:38~42 parts of methyl vinyl silicone rubber, 25~28 parts of nanoclay, 14~21 parts of silane coupling agent, zinc oxide 9
~11 parts, 6~7 parts of paraffin, 22~35 parts of carbon black, N- cyclohexyl -4~6 parts of 4-aminodiphenylamine, 14~16 parts of pine tar,
3~4 parts of Sulfur, 10~17 parts of aluminium hydroxide, 24~32 parts of nitrile rubber, 13~15 parts of neoprene, 16~23 parts of magnesia,
1~13 part of silica 1.
3. a kind of high-damping composite environmental-friendly rubber material according to claim 1, which is characterized in that including following parts by weight
Several components:40 parts of methyl vinyl silicone rubber, 27 parts of nanoclay, 19 parts of silane coupling agent, 10 parts of zinc oxide, 6 parts of paraffin,
33 parts of carbon black, N- cyclohexyl -5 parts of 4-aminodiphenylamine, 15 parts of pine tar, 4 parts of Sulfur, 16 parts of aluminium hydroxide, nitrile rubber
29 parts, 14 parts of neoprene, 18 parts of magnesia, 2 parts of silica 1.
Priority Applications (1)
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CN201811035762.XA CN108795062A (en) | 2018-09-06 | 2018-09-06 | A kind of high-damping composite environmental-friendly rubber material |
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CN201811035762.XA CN108795062A (en) | 2018-09-06 | 2018-09-06 | A kind of high-damping composite environmental-friendly rubber material |
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CN108795062A true CN108795062A (en) | 2018-11-13 |
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CN201811035762.XA Withdrawn CN108795062A (en) | 2018-09-06 | 2018-09-06 | A kind of high-damping composite environmental-friendly rubber material |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112210216A (en) * | 2020-08-31 | 2021-01-12 | 四川中物材料股份有限公司 | High-damping phenyl silicone rubber and preparation method and application thereof |
-
2018
- 2018-09-06 CN CN201811035762.XA patent/CN108795062A/en not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112210216A (en) * | 2020-08-31 | 2021-01-12 | 四川中物材料股份有限公司 | High-damping phenyl silicone rubber and preparation method and application thereof |
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Application publication date: 20181113 |