CN109294120A - A kind of compound barium-zinc liquid stabilizer and preparation method thereof - Google Patents
A kind of compound barium-zinc liquid stabilizer and preparation method thereof Download PDFInfo
- Publication number
- CN109294120A CN109294120A CN201811164991.1A CN201811164991A CN109294120A CN 109294120 A CN109294120 A CN 109294120A CN 201811164991 A CN201811164991 A CN 201811164991A CN 109294120 A CN109294120 A CN 109294120A
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- Prior art keywords
- barium
- zinc
- compound
- zinc liquid
- antioxidant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Abstract
The present invention provides a kind of compound barium-zinc liquid stabilizers and preparation method thereof, the compound barium-zinc liquid stabilizer is prepared by following components: vegetable oil acid, isooctyl acid, a water barium, zinc oxide, dibenzoyl methane, antioxidant, anti-precipitation solvent, liquid barium zinc compound stabilizer is prepared using One-step production, equally reach with the requirement such as nontoxic, thermal stability, photostability, the transparency and good weatherability, particular for the PVC product industry of the relatively environment-friendly high requests such as packaging material for food, I class of toy for children film, medical supplies；Stabilising system equally has the function of inhibition and absorbs HCL, keeps initial coloration, control " zinc burning " phenomenon and is precipitated, exudation result.
Description
Technical field
The present invention relates to a kind of PVC heat stabilizers, and in particular to arrives a kind of compound barium-zinc liquid stabilizer and its preparation side
Method.
Background technique
PVC product application range is extremely extensive, as environmental requirement is increasingly stringent, raw material-environmental protection that PVC industry uses
Type stabilizer product also tends to diversification, diversification, is especially applied to children's class product and medical class product, therewith environment-friendly type
The compound barium-zinc liquid stabilizer of PVC plastic processing aid should have the characteristics that efficient, multi-functional, nontoxic, nuisanceless.
Traditional PVC plastic auxiliary agent is processed mostly based on combined producing tech, as produces required monomer soaps respectively
It after barium oleate, zinc oleate, is needed according to itself production, raw and auxiliary material Compound Machining is selected to be made.Because its by production equipment,
All various restrictions such as process flow, production management, have that production cycle long, easy cross contamination, cost be excessively high, former auxiliary material more
Expect the problems such as type is excessive, causes liquid barium zinc compound stabilizer unstable product quality, production technology complication, easy output solid
Useless, the high status of price fluctuation rate.
Summary of the invention
In order to solve a series of problems existing for existing liquid barium zinc compound stabilizer and its production technology, the present invention is mentioned
For a kind of compound barium-zinc liquid stabilizer and preparation method thereof, liquid barium zinc compound stabilizer is prepared using One-step production, together
Sample reach with nontoxic, thermal stability, photostability, the transparency and good weatherability etc. requirement, particular for packaging material for food,
The PVC product industry of the relatively environment-friendly high requests such as I class of toy for children film, medical supplies.Stabilising system equally has inhibition and suction
HCL function is received, initial coloration, control " zinc burning " phenomenon are kept and is precipitated, oozes out as a result, reaching stablizing effect.
The present invention includes following content:
A kind of compound barium-zinc liquid stabilizer, the compound barium-zinc liquid stabilizer are prepared by following components: being planted
Object oleic acid, isooctyl acid, a water barium, zinc oxide, dibenzoyl methane, antioxidant, anti-precipitation solvent；
Wherein the mass percent of each component is as follows；
Vegetable oil acid 35.0%~45.0%
Isooctyl acid 20.0%~25.0%
One water barium 10.0%~20.0%
Zinc oxide 15.0%~20.0%
Dibenzoyl methane 1.0%~2.0%
Antioxidant 1.0%~2.0%
Anti- precipitation solvent 1.5%~2.5%；
The total amount of above-mentioned each component is 100%.
Preferably, the compound barium-zinc liquid stabilizer is prepared by following components:
Vegetable oil acid 40.0%
Isooctyl acid 21.0%
One water barium 15.0%
Zinc oxide 19.0%
Dibenzoyl methane 1.5%
Antioxidant 1.5%
Anti- precipitation solvent 2.0%.
A kind of preparation method of compound barium-zinc liquid stabilizer, includes the following steps:
Step 1: by vegetable oil acid, isooctyl acid, a water barium, zinc oxide, dibenzoyl methane, antioxidant, anti-precipitation solvent
It is mixed in a kettle, temperature is 125 DEG C~135 DEG C, heat preservation to fully reacting；
Step 2: controlling temperature in 120 DEG C~125 DEG C progress vacuum dehydrations after fully reacting；
Step 3: the resulting product of step 2 is carried out filters pressing, temperature is controlled at 80 DEG C~90 DEG C, obtains finished product.
This reaction is applied using the high alkalinity metal barium for not containing nonyl phenol using high alkalinity metal barium (content >=35%)
In liquid barium zinc compound stabilizer, preparation process uses one-step method, assists with lubrication prescription, outer lubrication prescription, antioxidant etc. in other
Cooperation adjustment formulation composition, it is energy saving and avoid pollution with solid waste output, prepare out the series of products to accord with the demands of the market, answer
For the PVC plastic material products of current environmentally friendly type, not only number capable of reducing using reduced cost, but also can to promote PVC product processed
Corresponding requirements in journey, can more reach its product at the international level in environmental requirement, can also be mentioned when for stabilizer plasticized PVC
For its enough self-sliping energy.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, following embodiment be explanation of the invention and
The invention is not limited to following embodiments.
Embodiment:
A kind of compound barium-zinc liquid stabilizer is present embodiments provided to be prepared by following components:
The preparation method of the compound barium-zinc liquid stabilizer, includes the following steps:
Step 1: by vegetable oil acid, isooctyl acid, a water barium, zinc oxide, dibenzoyl methane, antioxidant, anti-precipitation solvent
Be mixed in a kettle, temperature be 125 DEG C insulation reaction 2 hours；
Step 2: controlling temperature in 120 DEG C of progress vacuum dehydration general half an hours after fully reacting；
Step 3: the resulting product of step 2 is carried out filters pressing, temperature is controlled at 80 DEG C, obtains finished product.
In addition, it should be noted that, the specific embodiments described in this specification, raw material named title used etc.
It can be different.The equivalent or simple change that all principles described according to the invention patent design are done, is included in the invention patent
Protection scope in.Those skilled in the art can do described specific embodiment various
The similar mode of modify or supplement or adopt substitutes, and without departing from structure of the invention or surmounts the claims and determines
The range of justice, is within the scope of protection of the invention.
Claims (3)
1. a kind of compound barium-zinc liquid stabilizer, it is characterised in that: the compound barium-zinc liquid stabilizer presses following component systems
It is standby to obtain: vegetable oil acid, isooctyl acid, a water barium, zinc oxide, dibenzoyl methane, antioxidant, anti-precipitation solvent；
Wherein the mass percent of each component is as follows；
Vegetable oil acid 35.0%~45.0%
Isooctyl acid 20.0%~25.0%
One water barium 10.0%~20.0%
Zinc oxide 15.0%~20.0%
Dibenzoyl methane 1.0%~2.0%
Antioxidant 1.0%~2.0%
Anti- precipitation solvent 1.5%~2.5%；
The total amount of above-mentioned each component is 100%.
2. compound barium-zinc liquid stabilizer according to claim 1, it is characterised in that: the compound barium-zinc liquid is stablized
Agent is prepared by following components:
Vegetable oil acid 40.0%
Isooctyl acid 21.0%
One water barium 15.0%
Zinc oxide 19.0%
Dibenzoyl methane 1.5%
Antioxidant 1.5%
Anti- precipitation solvent 2.0%.
3. a kind of preparation method of compound barium-zinc liquid stabilizer as described in claim 1 or 2, includes the following steps:
Step 1: by vegetable oil acid, isooctyl acid, a water barium, zinc oxide, dibenzoyl methane, antioxidant, anti-precipitation solvent anti-
It answers in kettle and is mixed, temperature is 125 DEG C~135 DEG C, heat preservation to fully reacting；
Step 2: controlling temperature in 120 DEG C~125 DEG C progress vacuum dehydrations after fully reacting；
Step 3: the resulting product of step 2 is carried out filters pressing, temperature is controlled at 80 DEG C~90 DEG C, obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811164991.1A CN109294120A (en) | 2018-10-07 | 2018-10-07 | A kind of compound barium-zinc liquid stabilizer and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811164991.1A CN109294120A (en) | 2018-10-07 | 2018-10-07 | A kind of compound barium-zinc liquid stabilizer and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109294120A true CN109294120A (en) | 2019-02-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811164991.1A Pending CN109294120A (en) | 2018-10-07 | 2018-10-07 | A kind of compound barium-zinc liquid stabilizer and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111499924A (en) * | 2020-05-25 | 2020-08-07 | 德清县东来化学有限公司 | Improved barium-zinc liquid stabilizer and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105218967A (en) * | 2015-09-10 | 2016-01-06 | 广州盈塑新材料科技有限公司 | The equipment of a kind of liquid barium/zinc heat stabilizer, its preparation method and enforcement the method |
| CN106397831A (en) * | 2016-08-31 | 2017-02-15 | 湖北犇星化工有限责任公司 | Liquid barium zinc heat stabilizer, and preparation method and applications thereof |
-
2018
- 2018-10-07 CN CN201811164991.1A patent/CN109294120A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105218967A (en) * | 2015-09-10 | 2016-01-06 | 广州盈塑新材料科技有限公司 | The equipment of a kind of liquid barium/zinc heat stabilizer, its preparation method and enforcement the method |
| CN106397831A (en) * | 2016-08-31 | 2017-02-15 | 湖北犇星化工有限责任公司 | Liquid barium zinc heat stabilizer, and preparation method and applications thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111499924A (en) * | 2020-05-25 | 2020-08-07 | 德清县东来化学有限公司 | Improved barium-zinc liquid stabilizer and preparation method and application thereof |
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Application publication date: 20190201 |