CN109294111A - A kind of micro- contraction crystal slab - Google Patents

A kind of micro- contraction crystal slab Download PDF

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Publication number
CN109294111A
CN109294111A CN201811019114.5A CN201811019114A CN109294111A CN 109294111 A CN109294111 A CN 109294111A CN 201811019114 A CN201811019114 A CN 201811019114A CN 109294111 A CN109294111 A CN 109294111A
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CN
China
Prior art keywords
parts
contraction
micro
crystal slab
processing aid
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Withdrawn
Application number
CN201811019114.5A
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Chinese (zh)
Inventor
李永平
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Individual
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Individual
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Priority to CN201811019114.5A priority Critical patent/CN109294111A/en
Publication of CN109294111A publication Critical patent/CN109294111A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of micro- contraction crystal slab of the present invention, according to parts by weight, 100 parts of polyvinyl chloride;40-60 parts of dioctyl phthalate;2-4 parts of calcium zinc stabilizer;1-3 parts of processing aid, 20-30 parts of plasticizer, the processing aid includes 0.1-0.3 parts along Ding Xier acid anhydrides and 0.2-0.4 parts of ethyl orthosilicates, and by the addition of processing aid, in cutting and in use, micro- contraction, raising product quality only occur for crystal slab.

Description

A kind of micro- contraction crystal slab
Technical field
The invention belongs to PVC technical fields, specifically, being related to a kind of micro- contraction crystal slab.
Background technique
Polyvinyl chloride English abbreviation PVC, crystal slab are the plate being made with PVC material, and generally transparent color is similar In acrylic board.
It is suitable for all table tops such as dining table, desk, desk, nightstand and tea table.Its transparency is high, and energy It is heat-resisting tea, hot soup, freeze proof, the anti-weight that resists cold, non-toxic and tasteless, environmentally protective.Crystal slab has nontoxic, soft and transparent, safety Insulation, it is easy to clean the features such as.
But crystal slab is easy to shrink in cutting and use, and fold occurs, when influencing beauty, and cutting, due to hair It is raw to shrink, cause size to shorten.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides a kind of micro- contraction crystal slab, equal in cutting and use Micro- contraction cuts indeformable, raising product quality.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of micro- contraction crystal slab, according to parts by weight, 100 parts of polyvinyl chloride;40-60 parts of dioctyl phthalate;Calcium 2-4 parts of zinc stabilizer;1-3 parts of processing aid, 20-30 parts of plasticizer, the processing aid includes along Ding Xier acid anhydrides 0.1-0.3 Part and ethyl orthosilicate 0.2-0.4 parts.
Further, the processing aid further includes 0.1-0.2 parts of fluorin modified crylic acid, and 0.1-0.2 parts of nanometer volcanic mud, silicon 0.5-1 parts of mountain flour, 0.1-0.4 parts of lignin fibre, 0.2-0.4 parts of lanthana, 0.1-0.2 parts of mica powder.
Further, the processing aid further includes 0.15 part of fluorin modified crylic acid, and 0.15 part of nanometer volcanic mud, Cab-O-sil 0.8 part, 0.3 part of lignin fibre, 0.3 part of lanthana, 0.15 part of mica powder.
Further, plasticizer includes 1-2 parts of graphene, and 10-13 parts of polyvinyl alcohol of acetalization, 5-10 parts of zinc borate and water glass 2-5 parts of glass.
Further, plasticizer further includes 1-2 parts of titanate esters and 0.1-0.3 parts of nano silicas.
Further, the plasticizer includes 1.5 parts of graphene, and 12 parts of polyvinyl alcohol of acetalization, 8 parts of zinc borate, waterglass 3 1.5 parts and 0.2 part part, titanate esters nano silica.
Compared with prior art, the beneficial effects of the present invention are:
A kind of micro- contraction crystal slab of the present invention, according to parts by weight, 100 parts of polyvinyl chloride;Dioctyl phthalate 40-60 parts;2-4 parts of calcium zinc stabilizer;1-3 parts of processing aid, 20-30 parts of plasticizer, the processing aid includes along Ding Xier 0.1-0.3 parts and ethyl orthosilicate 0.2-0.4 parts of acid anhydrides, by the addition of processing aid, in cutting and in use, crystal slab Micro- contraction only occurs, improves product quality.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of micro- contraction crystal slab, according to parts by weight, 100 parts of polyvinyl chloride;50 parts of dioctyl phthalate;Calcium zinc is steady Determine 3 parts of agent;2.35 parts of processing aid, 26.2 parts of plasticizer, processing aid includes 0.2 part along Ding Xier acid anhydrides, 0.3 part of positive silicic acid Ethyl ester, 0.15 part of fluorin modified crylic acid, 0.15 part of nanometer volcanic mud, 0.8 part of Cab-O-sil, 0.3 part of lignin fibre, lanthana 0.3 part, 0.15 part of mica powder, along the addition of Ding Xier acid anhydrides, keeps crystal slab more compact, be not easy to shrink, add nanometer volcano The addition of mud, Cab-O-sil, lignin fibre, lanthana and mica powder keeps its elasticity smaller, is less susceptible to shrink.
Plasticizer includes 1.5 parts of graphene, and 12 parts of polyvinyl alcohol of acetalization, 8 parts of zinc borate, 3 parts of waterglass, titanate esters 1.5 parts and 0.2 part of nano silica, graphene and nano silica occur graft copolymerization with resin, make glass transition temperature Higher than the decomposition temperature of resin itself, and the decomposition temperature being grafted improves 40~400 DEG C than resin, to can protect at high temperature Good processing fluidity is held, its micro- contraction when using and cut at normal temperature is made.
Indices are as follows:
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention Within the scope of.

Claims (6)

1. a kind of micro- contraction crystal slab, which is characterized in that according to parts by weight, 100 parts of polyvinyl chloride;Dioctyl phthalate 40-60 parts;2-4 parts of calcium zinc stabilizer;1-3 parts of processing aid, 20-30 parts of plasticizer, the processing aid includes along Ding Xier 0.1-0.3 parts and ethyl orthosilicate 0.2-0.4 parts of acid anhydrides.
2. a kind of micro- contraction crystal slab according to claim 1, which is characterized in that the processing aid further includes fluorine richness third 0.1-0.2 parts of olefin(e) acid, 0.1-0.2 parts of nanometer volcanic mud, 0.5-1 parts of Cab-O-sil, 0.1-0.4 parts of lignin fibre, lanthana 0.2-0.4 parts, 0.1-0.2 parts of mica powder.
3. a kind of micro- contraction crystal slab according to claim 2, which is characterized in that the processing aid further includes fluorine richness third 0.15 part of olefin(e) acid, 0.15 part of nanometer volcanic mud, 0.8 part of Cab-O-sil, 0.3 part of lignin fibre, 0.3 part of lanthana, mica powder 0.15 part.
4. a kind of micro- contraction crystal slab according to claim 1, which is characterized in that the plasticizer includes 1-2 parts of graphene, 10-13 parts of polyvinyl alcohol of acetalization, 5-10 parts and waterglass 2-5 parts of zinc borate.
5. a kind of micro- contraction crystal slab according to claim 4, which is characterized in that the plasticizer further includes titanate esters 1-2 Part and 0.1-0.3 parts of nano silicas.
6. a kind of micro- contraction crystal slab according to claim 5, which is characterized in that the plasticizer includes 1.5 parts of graphene, 12 parts of polyvinyl alcohol of acetalization, 1.5 parts and 0.2 part 8 parts of zinc borate, 3 parts of waterglass, titanate esters nano silica.
CN201811019114.5A 2018-09-03 2018-09-03 A kind of micro- contraction crystal slab Withdrawn CN109294111A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811019114.5A CN109294111A (en) 2018-09-03 2018-09-03 A kind of micro- contraction crystal slab

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811019114.5A CN109294111A (en) 2018-09-03 2018-09-03 A kind of micro- contraction crystal slab

Publications (1)

Publication Number Publication Date
CN109294111A true CN109294111A (en) 2019-02-01

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CN201811019114.5A Withdrawn CN109294111A (en) 2018-09-03 2018-09-03 A kind of micro- contraction crystal slab

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CN (1) CN109294111A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101775183A (en) * 2010-02-11 2010-07-14 天津宏茂塑胶有限公司 Low-toxicity white-light bonded crystal board and manufacturing method thereof
CN101775181A (en) * 2010-02-11 2010-07-14 天津宏茂塑胶有限公司 White-light laminated crystal board and making method thereof
CN101775182A (en) * 2010-02-11 2010-07-14 天津宏茂塑胶有限公司 Environment-friendly low-toxicity white-light gluing crystal board and manufacture method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101775183A (en) * 2010-02-11 2010-07-14 天津宏茂塑胶有限公司 Low-toxicity white-light bonded crystal board and manufacturing method thereof
CN101775181A (en) * 2010-02-11 2010-07-14 天津宏茂塑胶有限公司 White-light laminated crystal board and making method thereof
CN101775182A (en) * 2010-02-11 2010-07-14 天津宏茂塑胶有限公司 Environment-friendly low-toxicity white-light gluing crystal board and manufacture method thereof

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Application publication date: 20190201