CN109294094A - A kind of thermally conductive new material - Google Patents

A kind of thermally conductive new material Download PDF

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Publication number
CN109294094A
CN109294094A CN201811273054.XA CN201811273054A CN109294094A CN 109294094 A CN109294094 A CN 109294094A CN 201811273054 A CN201811273054 A CN 201811273054A CN 109294094 A CN109294094 A CN 109294094A
Authority
CN
China
Prior art keywords
parts
thermally conductive
methylimidazole
aluminium oxide
copper powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811273054.XA
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Chinese (zh)
Inventor
王源丰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Yue Di Thick Chuang Technology Development Co Ltd
Dongguan South China Design and Innovation Institute
Original Assignee
Guangdong Yue Di Thick Chuang Technology Development Co Ltd
Dongguan South China Design and Innovation Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Yue Di Thick Chuang Technology Development Co Ltd, Dongguan South China Design and Innovation Institute filed Critical Guangdong Yue Di Thick Chuang Technology Development Co Ltd
Priority to CN201811273054.XA priority Critical patent/CN109294094A/en
Publication of CN109294094A publication Critical patent/CN109294094A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08Materials not undergoing a change of physical state when used
    • C09K5/14Solid materials, e.g. powdery or granular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/085Copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of thermally conductive new materials to be made of following raw material according to parts by weight: 1-2 parts of aluminium oxide, 3-4 parts of brominated Polystyrene, 1-2 parts of methylimidazole, 4-6 parts of copper powder, 2-4 parts of polyamide, 1-2 parts of synergist.Compared with prior art, there are following the utility model has the advantages that interacting between each material of the present invention by the present invention, and heating conduction is good, anti-flammability is strong, easy to process, lubricity is strong, internal structure performance is stablized.

Description

A kind of thermally conductive new material
Technical field
The invention belongs to field of new materials, and in particular to a kind of thermally conductive new material.
Background technique
The structural material and the function for the matter that has specific characteristics with excellent properties that new material refers to newly-developed or developing It can material.Structural material mainly utilizes the mechanical performances such as their intensity, toughness, hardness, elasticity.Such as new ceramic material, Amorphous alloy (glassy metal) etc..Functional material mainly utilizes functions and the physics such as its electricity, light, sound, magnetic, heat Effect.In recent years, the new material studied in the world, developed mainly has new metal material, fine ceramics and optical fiber etc..
To there is internal structure in existing Heat Conduction Material unstable in use, and heating conduction is poor, vulnerable to temperature Interference, lack good flame retardant effect and lubricity, make troubles to the use of Heat Conduction Material.
Summary of the invention
It is an object of the invention to overcome the deficiencies of existing technologies, provide a kind of heating conduction is good, anti-flammability is strong, be easy to plus The thermally conductive new material that work, lubricity are strong, internal structure performance is stable.
To achieve the goals above, technical scheme is as follows:
A kind of thermally conductive new material is made of following raw material according to parts by weight:
1-2 parts of aluminium oxide, 1-2 parts of methylimidazole, 4-6 parts of copper powder, 2-4 parts of polyamide, increases 3-4 parts of brominated Polystyrene Agent 1-2 parts of effect.
It is preferred: it is described according to parts by weight, be made of following raw material:
1 part of aluminium oxide, 3 parts of brominated Polystyrene, 1 part of methylimidazole, 4 parts of copper powder, 2 parts of polyamide, 1 part of synergist.
It is preferred: it is described according to parts by weight, be made of following raw material:
1.5 parts of aluminium oxide, 3.5 parts of brominated Polystyrene, 1.5 parts of methylimidazole, 5 parts of copper powder, kymene part, synergist 1.5 part.
It is preferred: it is described according to parts by weight, be made of following raw material:
2 parts of aluminium oxide, 4 parts of brominated Polystyrene, 2 parts of methylimidazole, 6 parts of copper powder, 4 parts of polyamide, 2 parts of synergist.
The performance of each raw material is as follows in the present invention:
Aluminium oxide: amphoteric oxide can be dissolved in inorganic acid and alkaline solution, be practically insoluble in water and nonpolarity is organic molten Agent.Relative density (d204) 4.0, about 2000 DEG C of fusing point;
Brominated Polystyrene: being a kind of bromine system organic fire-retardant, has high flame retardant, thermal stability and photostability etc. good Good mechanical-physical and chemical property;
Methylimidazole: being a kind of important organic intermediate.It also is used as epoxy curing agent and protecting metallic surface Agent etc.;
Copper powder: copper is soft metal, is reddish orange band metallic luster when surface is just cut, simple substance is in aubergine.Extend Property it is good, thermal conductivity and electric conductivity are high;
Polyamide: have good comprehensive performance, including mechanical property, heat resistance, wear resistance, chemical resistance and Self-lubrication, and coefficient of friction is low, there is certain anti-flammability, it is easy to process, it is suitable for being increased with glass fibre and the filling of other fillers It is strong modified, it improves performance and expands application range;
Synergist: holding power is closed as the initial bonding strength for mainly improving product in adhesive;It is mainly improved in coating Increase with the adhesive force of matrix.
Compared with prior art, there are following the utility model has the advantages that interact between each material of the present invention by the present invention, thermal conductivity Energy is good, anti-flammability is strong, easy to process, lubricity is strong, internal structure performance is stablized.
Specific embodiment
The present invention is described in further details below with reference to embodiment.
Embodiment 1:
1 part of aluminium oxide, 3 parts of brominated Polystyrene, 1 part of methylimidazole, 4 parts of copper powder, 2 parts of polyamide, 1 part of synergist.
Heat Conduction Material production method are as follows: by above-mentioned aluminium oxide, brominated Polystyrene, methylimidazole, copper powder, polyamide, increasing Effect agent is proportionally added sequentially in high-speed mixer, and the revolving speed of high-speed mixer is 1000-1200rpm, controls mixing material The temperature of material rises to 145 DEG C, and mixing material is added in low-speed mixer and is cooled down, and the temperature for controlling mixing material is 50- At 60 DEG C, mixing material is taken out;Mixing material is put on the lower electrode dielectric of ion body device, treated, and mixture is put Enter in single screw extrusion machine, process is hot-forming twice, then through air-cooled up to material of the present invention.
Embodiment 2:
1.5 parts of aluminium oxide, 3.5 parts of brominated Polystyrene, 1.5 parts of methylimidazole, 5 parts of copper powder, kymene part, synergist 1.5 part.
Heat Conduction Material production method are as follows: by above-mentioned aluminium oxide, brominated Polystyrene, methylimidazole, copper powder, polyamide, increasing Effect agent is proportionally added sequentially in high-speed mixer, and the revolving speed of high-speed mixer is 1000-1200rpm, controls mixing material The temperature of material rises to 145 DEG C, and mixing material is added in low-speed mixer and is cooled down, and the temperature for controlling mixing material is 50- At 60 DEG C, mixing material is taken out;Mixing material is put on the lower electrode dielectric of ion body device, treated, and mixture is put Enter in single screw extrusion machine, process is hot-forming twice, then through air-cooled up to material of the present invention.
Embodiment 3:
2 parts of aluminium oxide, 4 parts of brominated Polystyrene, 2 parts of methylimidazole, 6 parts of copper powder, 4 parts of polyamide, 2 parts of synergist.
Heat Conduction Material production method are as follows: by above-mentioned aluminium oxide, brominated Polystyrene, methylimidazole, copper powder, polyamide, increasing Effect agent is proportionally added sequentially in high-speed mixer, and the revolving speed of high-speed mixer is 1000-1200rpm, controls mixing material The temperature of material rises to 145 DEG C, and mixing material is added in low-speed mixer and is cooled down, and the temperature for controlling mixing material is 50- At 60 DEG C, mixing material is taken out;Mixing material is put on the lower electrode dielectric of ion body device, treated, and mixture is put Enter in single screw extrusion machine, process is hot-forming twice, then through air-cooled up to material of the present invention.

Claims (4)

1. a kind of thermally conductive new material, it is characterised in that: according to parts by weight, be made of following raw material:
1-2 parts of aluminium oxide, 3-4 parts of brominated Polystyrene, 1-2 parts of methylimidazole, 4-6 parts of copper powder, 2-4 parts of polyamide, synergist 1-2 parts.
2. thermally conductive new material as described in claim 1, it is characterised in that: according to parts by weight, be made of following raw material:
1 part of aluminium oxide, 3 parts of brominated Polystyrene, 1 part of methylimidazole, 4 parts of copper powder, 2 parts of polyamide, 1 part of synergist.
3. thermally conductive new material as described in claim 1, it is characterised in that: according to parts by weight, be made of following raw material:
1.5 parts of aluminium oxide, 3.5 parts of brominated Polystyrene, 1.5 parts of methylimidazole, 5 parts of copper powder, kymene part, synergist 1.5 Part.
4. thermally conductive new material as described in claim 1, it is characterised in that: according to parts by weight, be made of following raw material:
2 parts of aluminium oxide, 4 parts of brominated Polystyrene, 2 parts of methylimidazole, 6 parts of copper powder, 4 parts of polyamide, 2 parts of synergist.
CN201811273054.XA 2018-10-30 2018-10-30 A kind of thermally conductive new material Pending CN109294094A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811273054.XA CN109294094A (en) 2018-10-30 2018-10-30 A kind of thermally conductive new material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811273054.XA CN109294094A (en) 2018-10-30 2018-10-30 A kind of thermally conductive new material

Publications (1)

Publication Number Publication Date
CN109294094A true CN109294094A (en) 2019-02-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811273054.XA Pending CN109294094A (en) 2018-10-30 2018-10-30 A kind of thermally conductive new material

Country Status (1)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102558609A (en) * 2011-12-13 2012-07-11 金发科技股份有限公司 Method for improving thermal conductivity of thermal conductive polymer
CN105199184A (en) * 2015-10-30 2015-12-30 太仓市天合新材料科技有限公司 Novel heat conduction material
CN107698966A (en) * 2017-11-07 2018-02-16 广西小草信息产业有限责任公司 A kind of heat conduction new material and preparation method thereof
US20180094183A1 (en) * 2015-06-30 2018-04-05 Laird Technologies, Inc. Thermal interface materials with low secant modulus of elasticity and high thermal conductivity
CN107880548A (en) * 2017-11-10 2018-04-06 无锡艾科瑞思产品设计与研究有限公司 A kind of computer conductive heat conducting material formula and its preparation technology

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102558609A (en) * 2011-12-13 2012-07-11 金发科技股份有限公司 Method for improving thermal conductivity of thermal conductive polymer
US20180094183A1 (en) * 2015-06-30 2018-04-05 Laird Technologies, Inc. Thermal interface materials with low secant modulus of elasticity and high thermal conductivity
CN105199184A (en) * 2015-10-30 2015-12-30 太仓市天合新材料科技有限公司 Novel heat conduction material
CN107698966A (en) * 2017-11-07 2018-02-16 广西小草信息产业有限责任公司 A kind of heat conduction new material and preparation method thereof
CN107880548A (en) * 2017-11-10 2018-04-06 无锡艾科瑞思产品设计与研究有限公司 A kind of computer conductive heat conducting material formula and its preparation technology

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Application publication date: 20190201