CN105504765B - A kind of conductive plastics - Google Patents
A kind of conductive plastics Download PDFInfo
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- CN105504765B CN105504765B CN201510518060.7A CN201510518060A CN105504765B CN 105504765 B CN105504765 B CN 105504765B CN 201510518060 A CN201510518060 A CN 201510518060A CN 105504765 B CN105504765 B CN 105504765B
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- parts
- conductive
- barium stearate
- conductive plastics
- carborundum
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- 239000004033 plastic Substances 0.000 title claims abstract description 22
- 229920003023 plastic Polymers 0.000 title claims abstract description 22
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 20
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims abstract description 20
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000440 bentonite Substances 0.000 claims abstract description 11
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 11
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 11
- 239000010439 graphite Substances 0.000 claims abstract description 11
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 11
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 11
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 10
- 125000004386 diacrylate group Chemical group 0.000 claims abstract description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 10
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract 2
- 238000001816 cooling Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical group [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Conductive Materials (AREA)
Abstract
The invention belongs to electric power field of new materials, discloses a kind of conductive plastics, and it is prepared by the following raw material：Chlorination butadiene, Tissuemat E, polyethyleneglycol diacrylate, epoxy resin, glyceryl tristearate, conductive black, graphite fibre, glass fibre, barium stearate, magnesium hydroxide, barium stearate, talcum powder, lithium bentonite, titanium oxide, zinc oxide, carborundum.The conductive plastics of the present invention also has good tensile strength concurrently while the excellent conductive performance of plastics is maintained.
Description
Technical field
The invention belongs to electric power field of new materials, and in particular to a kind of novel conductive plastics.
Background technology
Plastics are used by people as insulating materials always, because of its high-insulativity, are producing with being also easy to produce electrostatic in use,
There may be various harm for electrostatic.With the development of modern electronics industry and information industry, various industrial automation equipments, micro- electricity
Brain, household electrical appliance and electronic product enter among the every field and people's work living environment of national economy.Static elimination, electricity
The technologies such as magnetic screen have caused the concern of people, and the plastics of conductive energy also just arise at the historic moment, but existing conductive modeling
The tensile strength and high conduction performance of material can not be met simultaneously.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of novel conductive modeling for having tensile strength and electric conductivity concurrently
Material.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
A kind of novel conductive plastics, it is prepared as follows and obtained：
1）Chlorination butadiene 18-25 parts, Tissuemat E 10-15 parts, polyethyleneglycol diacrylate 10- are taken according to parts by weight
15 parts, epoxy resin 8-10 parts, glyceryl tristearate 6-8 parts, conductive black 20-30 parts, graphite fibre 3-5 parts, glass fibers
Tie up 3-4 parts, barium stearate 2-3 parts, magnesium hydroxide 2-3 parts, barium stearate 2-3 parts, talcum powder 1-2 parts, lithium bentonite 1-2
Part, titanium oxide 1-2 parts, zinc oxide 1-2 parts, carborundum 1-2 parts；
2）Chlorination butadiene is taken, Tissuemat E, polyethyleneglycol diacrylate, epoxy resin, glyceryl tristearate, is mixed
Close, heating melting, sequentially add graphite fibre, resin acid barium, magnesium hydroxide, barium stearate, talcum powder, lithium bentonite, oxidation
Titanium, zinc oxide, carborundum, stir；
3）By step 2）Gained mixed liquor is divided into two parts, and portion adds glass fibre, is well mixed, obtains material A；
Another adds conductive black, is well mixed, obtains material B；
4）Material A and material B are well mixed in the molten state, simultaneously cooling and dicing is extruded, produces.
Preferably, conductive black, graphite fibre, glass fibre, resin acid barium, magnesium hydroxide, barium stearate, talcum powder, lithium
Base bentonite, titanium oxide, zinc oxide, the particle diameter of carborundum are controlled more than 100 mesh.
The beneficial effect that the present invention obtains mainly includes the following aspects：
The novel conductive plastics of the present invention also have good tension concurrently while the excellent conductive performance of plastics is maintained
Intensity, and prepare simply, cost is relatively low, there is good application prospect.
Embodiment
In order that those skilled in the art more fully understand the technical scheme in the application, have below in conjunction with the application
Body embodiment, the present invention is more clearly and completely described, it is clear that described embodiment is only the application one
Divide embodiment, rather than whole embodiments.Based on the embodiment in the application, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, should all belong to the scope of protection of the invention.
Embodiment 1
A kind of novel conductive plastics, it is prepared as follows and obtained：
1）25 parts of chlorination butadiene, 15 parts of Tissuemat E, 15 parts of polyethyleneglycol diacrylate, epoxy are taken according to parts by weight
10 parts of resin, 8 parts of glyceryl tristearate, 30 parts of conductive black, 5 parts of graphite fibre, 4 parts of glass fibre, 3 parts of barium stearate,
3 parts of magnesium hydroxide, 3 parts of barium stearate, 2 parts of talcum powder, 2 parts of lithium bentonite, 2 parts of titanium oxide, 2 parts of zinc oxide, carborundum 2
Part；
2）Chlorination butadiene is taken, Tissuemat E, polyethyleneglycol diacrylate, epoxy resin, glyceryl tristearate, is mixed
Close, heating melting, sequentially add graphite fibre, resin acid barium, magnesium hydroxide, barium stearate, talcum powder, lithium bentonite, oxidation
Titanium, zinc oxide, carborundum, stir；
3）By step 2）Gained mixed liquor is divided into two parts, and portion adds glass fibre, is well mixed, obtains material A；
Another adds conductive black, is well mixed, obtains material B；
4）Material A and material B are well mixed in the molten state, simultaneously cooling and dicing is extruded, produces.
Embodiment 2
A kind of novel conductive plastics, it is prepared as follows and obtained：
1）18 parts of chlorination butadiene, 10 parts of Tissuemat E, 10 parts of polyethyleneglycol diacrylate, epoxy are taken according to parts by weight
8 parts of resin, 6 parts of glyceryl tristearate, 20 parts of conductive black, 3 parts of graphite fibre, 3 parts of glass fibre, 2 parts of barium stearate, hydrogen
2 parts of magnesia, 2 parts of barium stearate, 1 part of talcum powder, 1 part of lithium bentonite, 1 part of titanium oxide, 1 part of zinc oxide, 1 part of carborundum；
2）Chlorination butadiene is taken, Tissuemat E, polyethyleneglycol diacrylate, epoxy resin, glyceryl tristearate, is mixed
Close, heating melting, sequentially add graphite fibre, resin acid barium, magnesium hydroxide, barium stearate, talcum powder, lithium bentonite, oxidation
Titanium, zinc oxide, carborundum, stir；
3）By step 2）Gained mixed liquor is divided into two parts, and portion adds glass fibre, is well mixed, obtains material A；
Another adds conductive black, is well mixed, obtains material B；
4）Material A and material B are well mixed in the molten state, simultaneously cooling and dicing is extruded, produces.
Embodiment 3
The performance parameter test of conductive plastics prepared by the present invention：
Test surfaces resistivity is carried out by IEC60093 requirements, it is as a result as follows：The sheet resistance of the conductive plastics of embodiment 1
Rate (Ω) is 2.9 × 104, the surface resistivity (Ω) of the conductive plastics of embodiment 2 is 3.1 × 106；The conductive plastics of embodiment 1
Tensile strength is 10.3N/mm2, the tensile strength of the conductive plastics of embodiment 2 is 9.7N/mm2。
Above in association with specific embodiment, invention has been described, it will be appreciated by those skilled in the art that this
A little descriptions are all exemplary, are not limiting the scope of the invention.Those skilled in the art can be according to the present invention
Spirit and principle various variants and modifications are made to the present invention, these variants and modifications are also within the scope of the invention.
Claims (2)
1. a kind of conductive plastics, it is characterised in that the conductive plastics is prepared by the raw material of following parts by weight：
Chlorination butadiene 18-25 parts, Tissuemat E 10-15 parts, polyethyleneglycol diacrylate 10-15 parts, epoxy resin 8-10
Part, glyceryl tristearate 6-8 parts, conductive black 20-30 parts, graphite fibre 3-5 parts, glass fibre 3-4 parts, magnesium hydroxide 2-
3 parts, barium stearate 2-3 parts, talcum powder 1-2 parts, lithium bentonite 1-2 parts, titanium oxide 1-2 parts, zinc oxide 1-2 parts, carborundum
1-2 parts.
2. conductive plastics according to claim 1, it is characterised in that the preparation method of the conductive plastics includes following step
Suddenly：
1）Chlorination butadiene 18-25 parts, Tissuemat E 10-15 parts, polyethyleneglycol diacrylate 10-15 are taken according to parts by weight
Part, epoxy resin 8-10 parts, glyceryl tristearate 6-8 parts, conductive black 20-30 parts, graphite fibre 3-5 parts, glass fibre
3-4 parts, magnesium hydroxide 2-3 parts, barium stearate 2-3 parts, talcum powder 1-2 parts, lithium bentonite 1-2 parts, titanium oxide 1-2 parts, oxygen
Change zinc 1-2 parts, carborundum 1-2 parts；
2）Chlorination butadiene is taken, Tissuemat E, polyethyleneglycol diacrylate, epoxy resin, glyceryl tristearate, is mixed,
Heating melting, sequentially adds graphite fibre, magnesium hydroxide, barium stearate, talcum powder, lithium bentonite, titanium oxide, zinc oxide,
Carborundum, stir；
3）By step 2）Gained mixed liquor is divided into two parts, and portion adds glass fibre, is well mixed, obtains material A；It is another
Part adds conductive black, is well mixed, obtains material B；
4）Material A and material B are well mixed in the molten state, simultaneously cooling and dicing is extruded, produces.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510518060.7A CN105504765B (en) | 2015-08-21 | 2015-08-21 | A kind of conductive plastics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510518060.7A CN105504765B (en) | 2015-08-21 | 2015-08-21 | A kind of conductive plastics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105504765A CN105504765A (en) | 2016-04-20 |
| CN105504765B true CN105504765B (en) | 2018-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510518060.7A Active CN105504765B (en) | 2015-08-21 | 2015-08-21 | A kind of conductive plastics |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286658A (en) * | 2017-08-02 | 2017-10-24 | 合肥东恒锐电子科技有限公司 | A kind of high temperature resistant conductive plastics and preparation method thereof |
| CN109486162A (en) * | 2018-11-16 | 2019-03-19 | 福州万象三维电子科技有限公司 | Degradable 3D printing material and preparation method thereof |
| CN115109308A (en) * | 2022-08-01 | 2022-09-27 | 广州嘉德乐生化科技有限公司 | Lubricant containing glyceryl monostearate and application thereof in plastics |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260413A (en) * | 2010-05-28 | 2011-11-30 | 合复新材料科技(无锡)有限公司 | Composite material component with high flame retardation performance and high heat conduction performance, and its manufacture method |
| CN104788927A (en) * | 2015-04-18 | 2015-07-22 | 青岛承天伟业机械制造有限公司 | Conductive plastic for electronic product |
| CN104804459A (en) * | 2015-04-17 | 2015-07-29 | 青岛康泰鑫环保科技有限公司 | Conductive plastic |
-
2015
- 2015-08-21 CN CN201510518060.7A patent/CN105504765B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260413A (en) * | 2010-05-28 | 2011-11-30 | 合复新材料科技(无锡)有限公司 | Composite material component with high flame retardation performance and high heat conduction performance, and its manufacture method |
| CN104804459A (en) * | 2015-04-17 | 2015-07-29 | 青岛康泰鑫环保科技有限公司 | Conductive plastic |
| CN104788927A (en) * | 2015-04-18 | 2015-07-22 | 青岛承天伟业机械制造有限公司 | Conductive plastic for electronic product |
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| Publication number | Publication date |
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| CN105504765A (en) | 2016-04-20 |
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Effective date of registration: 20190605 Address after: 226000 New Century Avenue, Nantong High-tech Zone, Jiangsu Province, No. 998, 7107, 7th Floor, Jianghai Yuanmenggu Patentee after: Nantong Maicheng Automobile Technology Co., Ltd. Address before: 276001 No. 130, Jin Shan Shan Road, Lanshan District, Linyi, Shandong Co-patentee before: State Grid Corporation of China Patentee before: Linyi Electric Power Company of Guo Wang Shandong Province Utilities Electric Co. Co-patentee before: STATE GRID SHANDONG FEIXIAN POWER SUPPLY COMPANY |
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