CN109289525A - A kind of FeOOH desulfurizer regeneration method and dedicated screening agitating device - Google Patents
A kind of FeOOH desulfurizer regeneration method and dedicated screening agitating device Download PDFInfo
- Publication number
- CN109289525A CN109289525A CN201810043865.4A CN201810043865A CN109289525A CN 109289525 A CN109289525 A CN 109289525A CN 201810043865 A CN201810043865 A CN 201810043865A CN 109289525 A CN109289525 A CN 109289525A
- Authority
- CN
- China
- Prior art keywords
- fixedly connected
- shaft
- agitating device
- feooh
- screening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910002588 FeOOH Inorganic materials 0.000 title claims abstract description 32
- 238000012216 screening Methods 0.000 title claims abstract description 27
- 238000011069 regeneration method Methods 0.000 title claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000001354 calcination Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 25
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 230000001376 precipitating effect Effects 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 230000002572 peristaltic effect Effects 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims 2
- 239000012495 reaction gas Substances 0.000 claims 1
- 230000003009 desulfurizing effect Effects 0.000 abstract description 18
- 230000008929 regeneration Effects 0.000 abstract description 4
- -1 hydroxyl ferric oxide Chemical compound 0.000 abstract description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 21
- 239000007789 gas Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 7
- 239000005864 Sulphur Substances 0.000 description 7
- 241000790917 Dioxys <bee> Species 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/96—Regeneration, reactivation or recycling of reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/70—Pre-treatment of the materials to be mixed
- B01F23/713—Sieving materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/07—Stirrers characterised by their mounting on the shaft
- B01F27/072—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis
- B01F27/0725—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis on the free end of the rotating axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/28—Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
- B07B1/30—Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens jigging or moving to-and-fro within their own plane in or approximately in or transverse to the direction of conveyance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/602—Oxides
Abstract
The invention discloses a kind of FeOOH desulfurizer regeneration method and dedicated screening agitating devices, the following steps are included: high-temperature roasting kiln roasting will be put into FeOOH desulfurizer material as main component, 500-800 DEG C of maturing temperature, calcining time 6-7 hours；The desulfurizer regeneration method of the present invention by adopting the above technical scheme, can available hydroxyl ferric oxide desulfurizer give up the desulfurizing agent in agent so that desulfurizing agent is regenerated, desulfurizing agent purity is up to 95% after regeneration, while no pollution to the environment；The screening agitating device structure of the present invention by adopting the above technical scheme is simple, screening efficiency is high.
Description
Technical field
The present invention relates to desulfurizing agent technical field more particularly to a kind of FeOOH desulfurizer regeneration method and Special screens
Divide agitating device.
Background technique
Contain a large amount of sulfide in industrial gasses and exhaust gas, the sulfide in industrial gasses will cause in industrial production
The poisoning of catalyst, inactivation, shorten the service life of catalyst, the replacement frequency of catalyst are increased, to improve into
This, the sulfide direct emission in exhaust gas will cause the harm to environment and people and animals, therefore either industrial gasses or exhaust gas
In sulfide should be removed.The method of the gas sweetening generally used uses solid desulfurating agent and gas for gas-solid method
Sulfide in body, which carries out physical absorption or chemical reaction, is purified gas so that sulfide is fixed in desulfurizing agent.
Currently, common desulfurizing agent can only carry out disposable, the desulfurizing agent that generates after use gives up agent mostly using filling out
The modes such as bury to be handled, which not only adds gas purification cost, and desulfurizing agent give up the sulfide in agent still can be right
Environment pollutes.
In recent years, researcher has invented a kind of using FeOOH as the desulfurizing agent of active component, which is used for
After desulfurization, FeOOH therein is changed into iron sulfide, by desulfurizing agent give up agent carry out regeneration treatment after, iron sulfide therein is again
It can be regenerated as FeOOH, to realize the recycling of desulfurizing agent.
The patent of invention that number of patent application is 2012100178819 discloses a kind of using FeOOH as active component
The regeneration method of desulfurizing agent, comprising the following steps:
(1) it will be broken into powder by the useless agent of the desulfurizing agent of active component of FeOOH, into the powder plus water is matched
Suspension is made；
(2) oxygenous gas is passed through in the suspension obtained to step (1) to be aoxidized, vulcanize the iron in suspension
Object is oxidized to FeOOH and sulphur simple substance；
(3) sulphur simple substance of floating obtained in step (2) is separated, the FeOOH of precipitating is filtered, washed,
FeOOH after being regenerated after drying.
Above method complex process, while cannot directly recycle to obtain desulfurizing agent, but obtain FeOOH and sulphur list
Matter, there is presently no good methods can directly recycle desulfurizing agent.
Summary of the invention
The technical problem to be solved by the present invention is to be directed to existing deficiencies in the technology, a kind of hydroxyl oxidation is provided
Iron desulfurizer regeneration method and dedicated screening agitating device, low energy consumption for this method, process flow is simple, recycling desulfurizer purity
It is high, pollution-free；
It is simple using screening plant structure of the invention, screening efficiency is high.
The invention adopts the following technical scheme: a kind of FeOOH desulfurizer regeneration method, comprising the following steps:
A, high-temperature roasting kiln roasting, maturing temperature will be put into FeOOH desulfurizer material as main component
500-800 DEG C, calcining time 6-7 hours；
B, the material after roasting is ground, sieves to obtain 100-150 mesh particle by sieving agitating device, is then placed in
The dilute sulfuric acid of 1mol/L is dispersed, and by screening agitating device stirring 10-20min, the solid-to-liquid ratio of material and dilute sulfuric acid is 1:
2-6 (g/ml), jitter time 10-30min obtain dispersion liquid；
C, above-mentioned dispersion liquid is heated to 60 DEG C under normal pressure, it is same that hydrogen peroxide is then added into dispersion liquid using peristaltic pump
When stir, the flow control that hydrogen peroxide is added is 500mL/min, by vacuumizing the dioxy that transfer generates rapidly while reaction
Change sulphur gas；
D, obtained precipitating is washed with water 3 times after the reaction was completed, filtering reacting liquid, and washing temperature is 60-70 DEG C, so
It is dried at 300-500 DEG C afterwards, obtains regenerated FeOOH desulfurizer.
A kind of FeOOH desulfurizer regenerates dedicated screening agitating device, including cylinder, cylinder it is open at one end another
End sealing, the open end of cylinder are fixedly connected with fixed disk, and the position being located on the outside of cylinder in the disk of fixed disk is fixedly connected
There is motor, shaft is fixedly connected on motor, the end of shaft through fixed disk and is fixedly connected with turntable, fixed on turntable to connect
It is connected to auxiliary screening blade, is connected with swing mechanism in shaft.
The swing mechanism includes two rack gears disposed in parallel, and the tooth of two rack gears is oppositely arranged the both ends of two rack gears
It is fixedly connected respectively by connecting shaft, half gear is equipped between two rack gears, half gear is engaged with two rack gears respectively, half gear
Be fixedly connected in shaft, sunpender be respectively articulated in two connecting shafts, one end of sunpender and connecting shaft are hinged, connecting shaft it is another
One end is hinged with fixed disk；
Rectangular housing is fixedly connected with below swing mechanism, the side of rectangular housing is fixedly connected with rack gear, Rectangular shell
The other side of body is fixedly connected with sieve, and turntable and auxiliary screening blade are arranged in rectangular housing；
Shaft is connected with stirring blade through sieve.
The desulfurizer regeneration method of the present invention by adopting the above technical scheme, can available hydroxyl ferric oxide desulfurizer give up agent in
Desulfurizing agent so that desulfurizing agent is regenerated, desulfurizing agent purity is up to 95% after regeneration, while no pollution to the environment；The present invention
Screening agitating device structure by adopting the above technical scheme is simple, screening efficiency is high.
Detailed description of the invention
Accompanying drawing 1 is the structural representation of the present invention；
Attached drawing 2 is the connection schematic diagram of swing mechanism and half gear in the present invention.
In figure: 1- fixed disk；2- motor；3- shaft；4- cylinder；5- sunpender；6- swing mechanism；7- rectangular housing；8- turns
Disk；9- auxiliary screening blade；10- sieve；Half gear of 11-；601- rack gear；602- connecting shaft；11- stirring blade.
Specific embodiment
Embodiment 1, a kind of FeOOH desulfurizer regeneration method, comprising the following steps:
A, high-temperature roasting kiln roasting, maturing temperature will be put into FeOOH desulfurizer material as main component
500 DEG C, calcining time 6 hours；
B, the material after roasting is ground, sieves to obtain 100-150 mesh particle by sieving agitating device, is then placed in
The dilute sulfuric acid of 1mol/L is dispersed, and by screening agitating device stirring 10min, the solid-to-liquid ratio of material and dilute sulfuric acid is 1: 2 (g/
Ml), jitter time 10min obtains dispersion liquid；
C, above-mentioned dispersion liquid is heated to 60 DEG C under normal pressure, it is same that hydrogen peroxide is then added into dispersion liquid using peristaltic pump
When stir, the flow control that hydrogen peroxide is added is 500mL/min, by vacuumizing the dioxy that transfer generates rapidly while reaction
Change sulphur gas；
D, obtained precipitating is washed with water 3 times after the reaction was completed, filtering reacting liquid, and washing temperature is 60 DEG C, then exists
It is dried at 300 DEG C, obtains regenerated FeOOH desulfurizer.
Embodiment 2, a kind of FeOOH desulfurizer regeneration method, comprising the following steps:
A, high-temperature roasting kiln roasting, maturing temperature will be put into FeOOH desulfurizer material as main component
600 DEG C, calcining time 6.5 hours；
B, the material after roasting is ground, sieves to obtain 100-150 mesh particle by sieving agitating device, is then placed in
The dilute sulfuric acid of 1mol/L is dispersed, and by screening agitating device stirring 15min, the solid-to-liquid ratio of material and dilute sulfuric acid is 1: 4 (g/
Ml), jitter time 20min obtains dispersion liquid；
C, above-mentioned dispersion liquid is heated to 60 DEG C under normal pressure, it is same that hydrogen peroxide is then added into dispersion liquid using peristaltic pump
When stir, the flow control that hydrogen peroxide is added is 500mL/min, by vacuumizing the dioxy that transfer generates rapidly while reaction
Change sulphur gas；
D, obtained precipitating is washed with water 3 times after the reaction was completed, filtering reacting liquid, and washing temperature is 65 DEG C, then exists
It is dried at 400 DEG C, obtains regenerated FeOOH desulfurizer.
Embodiment 3, a kind of FeOOH desulfurizer regeneration method, comprising the following steps:
A, high-temperature roasting kiln roasting, maturing temperature will be put into FeOOH desulfurizer material as main component
800 DEG C, calcining time 7 hours；
B, the material after roasting is ground, sieves to obtain 100-150 mesh particle by sieving agitating device, is then placed in
The dilute sulfuric acid of 1mol/L is dispersed, and by screening agitating device stirring 20min, the solid-to-liquid ratio of material and dilute sulfuric acid is 1: 6 (g/
Ml), jitter time 30min obtains dispersion liquid；
C, above-mentioned dispersion liquid is heated to 60 DEG C under normal pressure, it is same that hydrogen peroxide is then added into dispersion liquid using peristaltic pump
When stir, the flow control that hydrogen peroxide is added is 500mL/min, by vacuumizing the dioxy that transfer generates rapidly while reaction
Change sulphur gas；
D, obtained precipitating is washed with water 3 times after the reaction was completed, filtering reacting liquid, and washing temperature is 70 DEG C, then exists
It is dried at 500 DEG C, obtains regenerated FeOOH desulfurizer.
Embodiment 4, a kind of dedicated screening agitating device of FeOOH desulfurizer regeneration, including cylinder 4, the one of cylinder 4
The sealing of the end opening other end, the open end of cylinder 4 are fixedly connected with fixed disk 1, and 4 outside of cylinder is located in the disk of fixed disk 1
Position be fixedly connected with motor 2, be fixedly connected with shaft 3 on motor 2, the end of shaft 3 through fixed disk 1 and is fixedly connected
There is turntable 8, auxiliary screening blade 9 is fixedly connected on turntable 8, is connected with swing mechanism 6 in shaft 3.
The swing mechanism 6 includes two rack gears 601 disposed in parallel, and the tooth of two rack gears 601 is oppositely arranged two teeth
The both ends of item 601 pass through connecting shaft 602 respectively and are fixedly connected, and half gear 11, half gear 11 difference are equipped between two rack gears 601
It being engaged with two rack gears 601, half gear 11 is fixedly connected in shaft 3, it has been respectively articulated with sunpender 5 in two connecting shafts 602,
One end of sunpender 5 and connecting shaft 602 are hinged, and the other end and fixed disk 1 of connecting shaft 602 are hinged.
The lower section of swing mechanism 6 is fixedly connected with rectangular housing 7, and the side of rectangular housing 7 is fixedly connected with rack gear 601,
The other side of rectangular housing 7 is fixedly connected with sieve 10, and turntable 8 and auxiliary screening blade 9 are arranged in rectangular housing 7.
Shaft 3 is connected with stirring blade 11 through sieve 10.
When work, material to be sieved is placed on sieve 10, dilution heat of sulfuric acid is contained in cylinder 4, motor 2 is with turn
Axis 3 rotates, and shaft 3 drives rectangular housing 7 or so to put with a transmission connection in two rack gears 601 respectively by half gear 11
Dynamic to be sieved, the rotation of turntable 8 is sieved with the material on the dynamic auxiliary screening rotation auxiliary sieve 10 of blade 9, after screening
Material enters in cylinder 4, motor 2 drive shaft 3 rotate, shaft 3 drive stirring blade 11 rotation to the material in cylinder 4 into
Row stirring.
Claims (2)
1. a kind of FeOOH desulfurizer regeneration method, it is characterised in that: the following steps are included:
A, high-temperature roasting kiln roasting, maturing temperature 500- will be put into FeOOH desulfurizer material as main component
800 DEG C, calcining time 6-7 hours；
B, the material after roasting is ground, sieves to obtain 100-150 mesh particle by sieving agitating device, is then placed in 1mol/L
Dilute sulfuric acid dispersed, 10-20min is stirred by screening agitating device, the solid-to-liquid ratio of material and dilute sulfuric acid is 1: 2-6 (g/
Ml), jitter time 10-30min obtains dispersion liquid；
C, above-mentioned dispersion liquid is heated to 60 DEG C under normal pressure, hydrogen peroxide is then added into dispersion liquid using peristaltic pump and is stirred simultaneously
It mixes, the flow control that hydrogen peroxide is added is 500mL/min, by vacuumizing the sulfur dioxide that transfer generates rapidly while reaction
Gas；
D, obtained precipitating is washed with water 3 times after the reaction was completed, filtering reacting liquid, and washing temperature is 60-70 DEG C, then exists
It is dried at 300-500 DEG C, obtains regenerated FeOOH desulfurizer.
2. a kind of FeOOH desulfurizer regenerates dedicated screening agitating device, it is characterised in that: including cylinder (4), cylinder (4)
The other end open at one end sealing, the open end of cylinder (4) is fixedly connected with fixed disk (1), is located in the disk of fixed disk (1)
Position on the outside of cylinder (4) is fixedly connected with motor (2), is fixedly connected on motor (2) shaft (3), and the end of shaft (3) is passed through
It fastens price fixing (1) and is fixedly connected with turntable (8), auxiliary screening blade (9) is fixedly connected on turntable (8), shaft connects on (3)
It is connected to swing mechanism (6)；
The swing mechanism (6) includes two rack gears (601) disposed in parallel, and the tooth of two rack gears (601) is oppositely arranged two
The both ends of rack gear (601) pass through connecting shaft (602) respectively and are fixedly connected, and are equipped with half gear (11) between two rack gears (601), and half
Gear (11) is engaged with two rack gears (601) respectively, and half gear (11) is fixedly connected on shaft (3), two connecting shafts (602)
On be respectively articulated with sunpender (5), one end of sunpender (5) and connecting shaft (602) hingedly, the other end of connecting shaft (602) and fixation
Disk (1) is hinged；
It is fixedly connected with below swing mechanism (6) rectangular housing (7), the side and rack gear (601) of rectangular housing (7) are fixed to be connected
It connects, the other side of rectangular housing (7) is fixedly connected with sieve (10), and turntable (8) and auxiliary screening blade (9) are arranged in Rectangular shell
In body (7)；
Shaft (3) is connected with stirring blade (11) through sieve (10).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810043865.4A CN109289525B (en) | 2018-01-07 | 2018-01-07 | Method for regenerating FeOOH desulfurizer and special screening and stirring device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810043865.4A CN109289525B (en) | 2018-01-07 | 2018-01-07 | Method for regenerating FeOOH desulfurizer and special screening and stirring device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109289525A true CN109289525A (en) | 2019-02-01 |
| CN109289525B CN109289525B (en) | 2021-07-09 |
Family
ID=65167453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810043865.4A Active CN109289525B (en) | 2018-01-07 | 2018-01-07 | Method for regenerating FeOOH desulfurizer and special screening and stirring device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109289525B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110975614A (en) * | 2019-12-30 | 2020-04-10 | 东营市海嘉化工有限公司 | System and method for recycling and utilizing iron oxyhydroxide desulfurizer |
| CN113290989A (en) * | 2021-04-20 | 2021-08-24 | 广西南宁明源木业有限公司 | Photocatalyst antibacterial ecological plate and processing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4478800A (en) * | 1981-08-07 | 1984-10-23 | Veg Gasinstituut N.V. | Process for removal of sulfur compounds from gases |
| US20010005981A1 (en) * | 1997-08-12 | 2001-07-05 | Winchester Eric L. | Removing hydrogen sulfide from a gaseous mixture using iron hydroxide bonded to calcined diatomite |
| CN201445932U (en) * | 2009-05-26 | 2010-05-05 | 常州碳酸钙有限公司 | Integrating device of stirring screen |
| CN103055834A (en) * | 2013-01-28 | 2013-04-24 | 长沙理工大学 | Regeneration method for spent ferric oxide desulfurizer |
| CN107440138A (en) * | 2017-08-22 | 2017-12-08 | 刘家豪 | A kind of agricultural production peanut surface soil high-efficiency washing device |
-
2018
- 2018-01-07 CN CN201810043865.4A patent/CN109289525B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4478800A (en) * | 1981-08-07 | 1984-10-23 | Veg Gasinstituut N.V. | Process for removal of sulfur compounds from gases |
| US20010005981A1 (en) * | 1997-08-12 | 2001-07-05 | Winchester Eric L. | Removing hydrogen sulfide from a gaseous mixture using iron hydroxide bonded to calcined diatomite |
| CN201445932U (en) * | 2009-05-26 | 2010-05-05 | 常州碳酸钙有限公司 | Integrating device of stirring screen |
| CN103055834A (en) * | 2013-01-28 | 2013-04-24 | 长沙理工大学 | Regeneration method for spent ferric oxide desulfurizer |
| CN107440138A (en) * | 2017-08-22 | 2017-12-08 | 刘家豪 | A kind of agricultural production peanut surface soil high-efficiency washing device |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110975614A (en) * | 2019-12-30 | 2020-04-10 | 东营市海嘉化工有限公司 | System and method for recycling and utilizing iron oxyhydroxide desulfurizer |
| CN110975614B (en) * | 2019-12-30 | 2020-11-20 | 山东海嘉石油化工有限公司 | System and method for recycling and utilizing iron oxyhydroxide desulfurizer |
| CN113290989A (en) * | 2021-04-20 | 2021-08-24 | 广西南宁明源木业有限公司 | Photocatalyst antibacterial ecological plate and processing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109289525B (en) | 2021-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109289525A (en) | A kind of FeOOH desulfurizer regeneration method and dedicated screening agitating device | |
| CN103495333A (en) | Treatment technology for Claus tail gas containing sulfur dioxide, hydrogen sulfide and organic sulfur | |
| CN104475165B (en) | A kind of preparation method of oxidation-desulfurizing catalyst | |
| CN103274366A (en) | Method for efficiently recycling elemental sulfur in process of treating sulfur dioxide flue gas by using sodium sulfide | |
| CN207195001U (en) | A kind of automatic automobile exhaust gas purifying installation for changing filter screen | |
| CN108636319A (en) | One kind 2,4,5- trichloroanilines process units and method | |
| CN109550521A (en) | A kind of catalyst, preparation method and its application handling disused aine liquid | |
| CN109731474B (en) | A kind of regenerating desulfurization device and its technique | |
| CN218188921U (en) | Be used for fluidized bed flue gas desulphurization unit | |
| CN106582647A (en) | Preparation method of composite desulfurization and denitrification catalyst | |
| CN110143640A (en) | A kind of method of butyl xanthate in photocatalytic oxidation degradation beneficiation wastewater of sulphide ore | |
| CN105056736B (en) | A kind of device for desulfurization and dedusting | |
| CN106512932A (en) | Preparation method for adsorbent removing hydrogen sulfide, carbonyl sulfide and carbon disulfide simultaneously | |
| CN213913044U (en) | Liquid nitrogen solvent recovery and tail gas treatment system | |
| CN112516857A (en) | Agitating unit of production usefulness of basic zinc carbonate | |
| CN111592145A (en) | Medical wastewater treatment device based on gear transmission principle | |
| CN207680361U (en) | A kind of emission-control equipment based on pesticide producing | |
| CN201254461Y (en) | Chemical carbon production converter | |
| CN107746973A (en) | Utilize desulfurizer in the dry kiln kiln of RKEF method smelting ferronickels | |
| CN105126826A (en) | Manganese oxide/titanium dioxide catalyst for FCC (catalytic cracking) regenerated flue gas denitrification, preparation method therefore and applications | |
| CN206810266U (en) | One kind production sodium kneader of iminodisuccinic acid four | |
| CN208878257U (en) | Plasma oxidation device is used in a kind of processing of industrial waste gas | |
| CN209302526U (en) | A kind of organic synthesis tail gas filter | |
| CN105056737B (en) | A kind of device for desulfurization | |
| CN217449620U (en) | Harmful waste gas recovery device is smelted to copper scrap |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 261000 No.7 Fulin Road, Shikou Town, Dongying District, Dongying City, Shandong Province Applicant after: Shandong Haijia Petrochemical Co.,Ltd. Address before: 261000 west of Xiyi road and south of Weifang Road, Dongying District, Dongying City, Shandong Province Applicant before: DONGYING CITY FINE CHEMICAL Co.,Ltd. |
|
| CB02 | Change of applicant information | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Regeneration Method of Hydroxy Iron Oxide Desulfurizer and Special Sieving Agitator Effective date of registration: 20220928 Granted publication date: 20210709 Pledgee: Dongying Rural Commercial Bank Co.,Ltd. Shikou Sub branch Pledgor: Shandong Haijia Petrochemical Co.,Ltd. Registration number: Y2022980016632 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230921 Granted publication date: 20210709 Pledgee: Dongying Rural Commercial Bank Co.,Ltd. Shikou Sub branch Pledgor: Shandong Haijia Petrochemical Co.,Ltd. Registration number: Y2022980016632 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A regeneration method and dedicated screening and stirring device for hydroxyl iron oxide desulfurizer Effective date of registration: 20231103 Granted publication date: 20210709 Pledgee: Dongying Rural Commercial Bank Co.,Ltd. Shikou Sub branch Pledgor: Shandong Haijia Petrochemical Co.,Ltd. Registration number: Y2023980064051 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |