CN109288724A - Aqua product, method and the application of fountain type appearance are presented when beating - Google Patents

Aqua product, method and the application of fountain type appearance are presented when beating Download PDF

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Publication number
CN109288724A
CN109288724A CN201811193646.0A CN201811193646A CN109288724A CN 109288724 A CN109288724 A CN 109288724A CN 201811193646 A CN201811193646 A CN 201811193646A CN 109288724 A CN109288724 A CN 109288724A
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CN
China
Prior art keywords
aqua
polyethylene glycol
aqua product
presented
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811193646.0A
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Chinese (zh)
Inventor
于丽丽
袁旻嘉
黄天怿
童柯锋
唐兆林
程伟峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Yi Chemical Co Ltd
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Shanghai Yi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Yi Chemical Co Ltd filed Critical Shanghai Yi Chemical Co Ltd
Priority to CN201811193646.0A priority Critical patent/CN109288724A/en
Publication of CN109288724A publication Critical patent/CN109288724A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The invention belongs to cosmetic technical fields, and in order to improve water spray effect when cosmetics are patted, the invention discloses aqua product, method and applications that fountain type appearance is presented when a kind of beating.Wherein aqua product of the invention is based on mass percentage including following component: suspension thickener: 0.001-1%;High molecular polyethylene glycol: 0.001-3%;Sodium Polyacrylate: 0.001-3%;Helper component: 3-30%;Surplus is water.Aqua product of the invention has the advantages that water spray effect when cosmetics are patted can be improved.

Description

Aqua product, method and the application of fountain type appearance are presented when beating
Technical field
The present invention relates to cosmetic technical fields, and in particular to when a kind of beating present fountain type appearance aqua product, Method and application.
Background technique
The present invention belongs to the relevant technologies related to the present invention for the description of background technique, be only used for explanation and just In understanding summary of the invention of the invention, it should not be construed as applicant and be specifically identified to or estimate applicant being considered of the invention for the first time The prior art for the applying date filed an application.
In recent years have more and more daily chemical products in the market, it is also higher and higher to cosmetics requirement, for skin type Product is innovated into development trend, also just there is the demand of more and more differentiation in market to improve competitiveness.Innovation It include many aspects, such as external-talent's form and design, product usage mode, the appearance forrns etc. of product.
Summary of the invention
The purpose of the embodiment of the present invention is that the aqua product of fountain type appearance, method are presented when providing a kind of beating and answers With aqua product provided in an embodiment of the present invention has yield value high, grabs the high advantage of waterpower.
The purpose of the embodiment of the present invention is that be achieved through the following technical solutions:
The embodiment of first aspect present invention provides the aqua product that fountain type appearance is presented when a kind of beating, by quality Percentage composition meter includes following component:
Further, the suspension thickener includes acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymeric At least one of object series, carbomer series and xanthan gum.
Further, the acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters crosslinking series of polymers includes Pemulen TR-1、Pemulen TR-2、CARBOPOL ULTREZ 20 POLYMER、CARBOPOL ULTREZ 20 At least one of POLYMER, CARBOPOL SC-200 POLYMER and AQUPEC SER W-300C (CT-1).
Further, the carbomer series includes Acritamer 940, Carbopol 941, carbomer 934, carbomer934 At least one of with Carbopol.
Further, the high molecular polyethylene glycol includes polyethylene glycol -2M, polyethylene glycol -7M, polyethylene glycol - At least one of 23M, polyethylene glycol -14M, polyethylene glycol -45M and polyethylene glycol -90M.
Further, the helper component include polyalcohol, chelating agent, skin conditioning agent, preservative, essence, solubilizer, At least one of water-soluble silicon oil and pigment.
Further, the weight ratio of the suspension thickener, macromolecule polyethylene glycol and Sodium Polyacrylate is 1:0.1- 3:0.1-3.
The embodiment of second aspect of the present invention provides the preparation that the aqua product of fountain type appearance is presented when a kind of beating Method includes the following steps:
Main still is added water to, uniform, the no agglomeration that is dispersed to system of suspension thickener is sprinkled into, helper component, macromolecule is added Polyethylene glycol and Sodium Polyacrylate, obtain the aqua product.
Further, include the following steps:
Add water to main still, be sprinkled into acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer be dispersed with stirring to System is uniform, no agglomeration, sequentially adds chelating agent, and preservative stirs and is heated to 80-85 DEG C, heat preservation 15min;Poly- second 1% polyalcohol of glycol -90M and aqua quality of item premix uniformly, is added in main still and stirs to the uniform no agglomeration of system;
Main still is cooled to 45-50 DEG C, and the 1% polyalcohol premix of Sodium Polyacrylate and aqua quality of item uniformly, is added It stirs in main still to the uniform no agglomeration of system.
Main still is cooled to 40-45 DEG C, and main still is added in skin conditioning agent, is stirred uniform to system;Solubilizer is pre- with essence It mixes into main still, stirs to system is uniform and obtain the aqua product.
The embodiment of third aspect present invention provides a kind of application of aqua product in cosmetics, the aqua system Product are above-mentioned aqua product or aqua product prepared by above-mentioned preparation method.
The embodiment of the present invention has the following beneficial effects:
Using having long rheological behavior raw material in hydrodynamics in the present patent application, make hydrone orderly long-range in space Arrangement is atomized under the action of centainly patting power as spraying " fountain " shape.
Detailed description of the invention
Fig. 1 is that aqua produces in one embodiment of the aqua product that fountain type appearance is presented when the present invention pats, method and application Product Slap figure.
Specific embodiment
The application is further introduced with reference to the accompanying drawings and examples.
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, Detailed description of the invention will be compareed below A specific embodiment of the invention.In the following description, what different " embodiment " or " embodiment " referred to is not necessarily same Embodiment.In addition, drawings discussed below is only some embodiments of the present invention, can be replaced between different embodiments or Merge combination, it for those of ordinary skill in the art, without creative efforts, can also be according to these Attached drawing obtains other attached drawings, and obtains other embodiments.
The embodiment of first aspect present invention provides the aqua product that fountain type appearance is presented when a kind of beating, by quality Percentage composition meter includes following component:
The present embodiment makes hydrone orderly long-range row in space using having long rheological behavior raw material in hydrodynamics Column are atomized under the action of centainly patting power as spraying " fountain " shape.
Above technical scheme, which can achieve to improve, grabs the purpose of waterpower, herein below on the basis of provide preferred embodiment.
In some embodiments of the invention, the suspension thickener includes acrylic acid (ester) class/C10-30 alkanol third At least one of olefin(e) acid ester crosslinking series of polymers, carbomer series and xanthan gum.
In some embodiments of the invention, the acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymeric Object series includes Pemulen TR-1, Pemulen TR-2, CARBOPOL ULTREZ 20 POLYMER, CARBOPOL At least one in 20 POLYMER of ULTREZ, CARBOPOL SC-200 POLYMER and AQUPEC SER W-300C (CT-1) Kind.
In some embodiments of the invention, the carbomer series includes Acritamer 940, Carbopol 941, carbomer 934, at least one of carbomer934 and Carbopol.
In some embodiments of the invention, the high molecular polyethylene glycol includes polyethylene glycol -2M, polyethylene glycol - At least one of 7M, polyethylene glycol -23M, polyethylene glycol -14M, polyethylene glycol -45M and polyethylene glycol -90M.
In some embodiments of the invention, the helper component includes polyalcohol, chelating agent, skin conditioning agent, anti-corrosion At least one of agent, essence, solubilizer, water-soluble silicon oil and pigment.
In some embodiments of the invention, the polyalcohol be 1,2-PD, 1,3-PD, 1,3-BDO, Glycerol, polyethylene glycol-8, at least one of polyethylene glycol -32, dipropylene glycol and pungent glycol.
In some embodiments of the invention, the suspension thickener, macromolecule polyethylene glycol and Sodium Polyacrylate Weight ratio is 1:0.1-3:0.1-3.
The embodiment of second aspect of the present invention provides the preparation that the aqua product of fountain type appearance is presented when a kind of beating Method includes the following steps:
Main still is added water to, uniform, the no agglomeration that is dispersed to system of suspension thickener is sprinkled into, helper component, macromolecule is added Polyethylene glycol and Sodium Polyacrylate, obtain the aqua product.
In some embodiments of the invention, include the following steps:
Add water to main still, be sprinkled into acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer be dispersed with stirring to System is uniform, no agglomeration, sequentially adds chelating agent, and preservative stirs and is heated to 80-85 DEG C, heat preservation 15min;Poly- second The polyalcohol of glycol -90M and aqua quality of item 1% premix uniformly, is added in main still and stirs to the uniform no agglomeration of system;
Main still is cooled to 45-50 DEG C, and uniformly, master is added in the polyalcohol premix of Sodium Polyacrylate and aqua quality of item 1% It stirs in kettle to the uniform no agglomeration of system.
Main still is cooled to 40-45 DEG C, and main still is added in skin conditioning agent, is stirred uniform to system;Solubilizer is pre- with essence It mixes into main still, stirs to system is uniform and obtain the aqua product.
The embodiment of third aspect present invention provides a kind of application of aqua product in cosmetics, the aqua system Product are above-mentioned aqua product or aqua product prepared by above-mentioned preparation method.
In general, cross-linked polymer and acrylic copolymer have higher yield value, possess higher suspension, But it itself can not bring the experience of fountain type.
Sodium Polyacrylate is the high-molecular compound with hydrophilic radical, and hydrophilic group can bring water retention.It used Not pleasant skin sense can mostly be brought.
High molecular polyethylene glycol belongs to non-ionic polyalcohol, is a kind of hydroaropic substance, has very strong water imbibition, Its property is stablized, and to no skin irritation, and has lubricity, sticky skin sense can be brought when dosage is more.
The present invention has obtained a aqua product that can take fountain type appearance by matched combined, and does not glue after absorbing It is greasy.
The preparation method that the aqua product of fountain type appearance is presented when a kind of beating, includes the following steps:
Add water to main still, be sprinkled into acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer be dispersed with stirring to System is uniform, no agglomeration, sequentially adds chelating agent, and preservative stirs and is heated to 80-85 DEG C, heat preservation 15min.
Uniformly, stirring in main still (80-85 DEG C) is added in the polyalcohol of polyethylene glycol -90M and aqua quality of item 1% premix To the uniform no agglomeration of system.
Main still is cooled to 45-50 DEG C, and uniformly, master is added in the polyalcohol premix of Sodium Polyacrylate and aqua quality of item 1% It stirs in kettle to the uniform no agglomeration of system.
Main still is cooled to 40-45 DEG C, and main still is added in skin conditioning agent, stirs uniform to system;Solubilizer and essence premix Main still is added, stirs uniform to system.
Prepare aqua product according to the method described above, material requested weighs that (wherein each component weight is that unit is according to table 1 G), the material of embodiment 1-8 is as shown in table 1.
Table 1
Embodiment 9-16
Change polyethylene glycol -90M in embodiment 1-8 into polyethylene glycol -14M, other compositions are constant.
According to method identical with embodiment 1-16, the aqua product of comparative example 1-4, formula and beating are prepared according to table 2 Effect is shown in Table 2 (it is g that wherein each component weight, which is unit).
Table 2
For this special appearance, we are characterized wire-drawing effect with two methods, first is that Texture instrument comes Wire drawing is characterized, and the yield value of the water holding capacity erupted after wire drawing rheometer is characterized, concrete outcome is shown in Table 3:
Table 3
Prototype Name Work of Adhesion (unit g.sec)
Embodiment 1 -2.82
Comparative example 1 -2.03
Comparative example 2 -2.57
Comparative example 3 -2.30
From the point of view of Texture instrument test result (table 3), this combination of embodiment 1 needs Texture instrument work done to be the largest, The wire-drawing effect reflected from side is most strong, and is consistent with water effect is clapped.
Table 4
25 DEG C of and of amplitude oscillatory@1rad/s Yield stress by G'/G " cross over (unit Pa)
Embodiment 1 0.67
Comparative example 1 0.39
Comparative example 2 0.57
Comparative example 3 0.36
From the point of view of the yield value result (table 4) of rheometer test, the yield value of embodiment 1 be also it is highest, grab outlet capacity And it is strongest, Fig. 1 is the Slap figure of the aqua product of the embodiment of the present invention 1, it will be seen from figure 1 that the water of embodiment 1 Agent product, which is finally reached silk, has no progeny and bursts out water mist state.
Upper composition comparison accordingly, we have obtained a aqua product that can take fountain type appearance, and after absorption not It is sticky.
It should be noted that above-described embodiment can be freely combined as needed.Described above is only of the invention preferred Embodiment is not intended to restrict the invention, for those skilled in the art, the present invention can have it is various change and Variation.All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in this hair Within bright protection scope.

Claims (10)

1. the aqua product of fountain type appearance is presented when a kind of beating, which is characterized in that including as follows based on mass percentage Component:
2. the aqua product of fountain type appearance is presented when beating according to claim 1, which is characterized in that the suspension Thickener includes in acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters crosslinking series of polymers, carbomer series and xanthan gum At least one.
3. the aqua product of fountain type appearance is presented when beating according to claim 2, which is characterized in that the propylene Sour (ester) class/C10-30 alkylol acrylamide acid esters crosslinking series of polymers include Pemulen TR-1, Pemulen TR-2, CARBOPOL ULTREZ 20 POLYMER、CARBOPOL ULTREZ 20 POLYMER、CARBOPOL SC-200 POLYMER At least one of with AQUPEC SER W-300C (CT-1).
4. the aqua product of fountain type appearance is presented when beating according to claim 2, which is characterized in that the card wave Nurse series includes at least one of Acritamer 940, Carbopol 941, carbomer 934, carbomer934 and Carbopol.
5. the aqua product of fountain type appearance is presented when beating according to claim 1, which is characterized in that the macromolecule Polyethylene glycol include polyethylene glycol -2M, polyethylene glycol -7M, polyethylene glycol -23M, polyethylene glycol -14M, polyethylene glycol -45M At least one of with polyethylene glycol -90M.
6. the aqua product of fountain type appearance is presented when beating according to claim 1, which is characterized in that the assisted group Divide including at least one in polyalcohol, chelating agent, skin conditioning agent, preservative, essence, solubilizer, water-soluble silicon oil and pigment Kind.
7. the aqua product of fountain type appearance is presented when beating according to claim 1, which is characterized in that the suspension The weight ratio of thickener, macromolecule polyethylene glycol and Sodium Polyacrylate is 1:0.1-3:0.1-3.
8. the preparation method of the aqua product of fountain type appearance is presented when a kind of described in any item beatings of claim 1-7, It is characterized in that, includes the following steps:
Main still is added water to, uniform, the no agglomeration that is dispersed to system of suspension thickener is sprinkled into, helper component, high molecular poly- is added Ethylene glycol and Sodium Polyacrylate obtain the aqua product.
9. preparation method according to claim 8, which comprises the steps of:
Main still is added water to, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer is sprinkled into and is dispersed with stirring to system Uniform, no agglomeration sequentially adds chelating agent, and preservative stirs and is heated to 80-85 DEG C, heat preservation 15min;Polyethylene glycol- 1% polyalcohol of 90M and aqua quality of item premix uniformly, is added in main still and stirs to the uniform no agglomeration of system;
Main still is cooled to 45-50 DEG C, and uniformly, main still is added in the 1% polyalcohol premix of Sodium Polyacrylate and aqua quality of item It is middle to stir to the uniform no agglomeration of system.
Main still is cooled to 40-45 DEG C, and main still is added in skin conditioning agent, is stirred uniform to system;Solubilizer is mixed in advance with essence Enter main still, stirs to system is uniform and obtain the aqua product.
10. a kind of application of aqua product in cosmetics, which is characterized in that the aqua product is claim 1-7 institute The aqua product of the preparation of preparation method described in the aqua product or claim 8 or 9 stated.
CN201811193646.0A 2018-10-12 2018-10-12 Aqua product, method and the application of fountain type appearance are presented when beating Pending CN109288724A (en)

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CN201811193646.0A CN109288724A (en) 2018-10-12 2018-10-12 Aqua product, method and the application of fountain type appearance are presented when beating

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110507594A (en) * 2019-09-17 2019-11-29 上海百雀羚生物科技有限公司 A kind of toner and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102046142A (en) * 2008-05-30 2011-05-04 株式会社资生堂 Oil-in-water type topical agent for skin

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102046142A (en) * 2008-05-30 2011-05-04 株式会社资生堂 Oil-in-water type topical agent for skin

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
国产非特殊用途化妆品备案网: "欧贝斯活颜弹力美容液", 《国产非特殊用途化妆品备案网》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110507594A (en) * 2019-09-17 2019-11-29 上海百雀羚生物科技有限公司 A kind of toner and preparation method thereof
CN110507594B (en) * 2019-09-17 2022-06-17 上海百雀羚生物科技有限公司 Toning lotion and preparation method thereof

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Application publication date: 20190201