CN109281170A - 一种免洗剂及经其处理得到的服装面料 - Google Patents
一种免洗剂及经其处理得到的服装面料 Download PDFInfo
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- 239000000463 material Substances 0.000 title claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical group N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920001577 copolymer Polymers 0.000 claims abstract description 14
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 12
- 150000008064 anhydrides Chemical class 0.000 claims abstract description 12
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 12
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 11
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 8
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 8
- 125000005456 glyceride group Chemical group 0.000 claims abstract description 8
- 239000004744 fabric Substances 0.000 claims description 35
- -1 polysiloxane Polymers 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 125000005375 organosiloxane group Chemical group 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 238000005202 decontamination Methods 0.000 abstract description 3
- 230000003588 decontaminative effect Effects 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
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- 230000008569 process Effects 0.000 description 6
- 229920000289 Polyquaternium Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000003115 biocidal effect Effects 0.000 description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
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- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- RDBMUARQWLPMNW-UHFFFAOYSA-N phosphanylmethanol Chemical compound OCP RDBMUARQWLPMNW-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
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- 230000004048 modification Effects 0.000 description 1
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- 239000000178 monomer Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000003075 superhydrophobic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
本发明公开一种免洗剂,其特征在于,按照重量份数计,该免洗剂包括:氟碳化合物共聚物2‑4份,脂肪酸甘油酯6‑9份,二烷基二甲基铵盐3‑5份,烷基三甲基铵盐7‑10份,聚季鏻铵盐1‑4份,季铵盐3‑5份,载银纳米二氧化钛粉体10‑20份,硅烷偶联剂KH570 0.5‑1份,顺丁稀二酸酐0.5‑1份,磷酸三辛脂0.5‑1份,对羟基苯甲酸丁酯0.5‑1份;去离子水20‑30份,酒精10‑20份。本发明的技术方案提供了一种具有免洗、防水、去污、抗菌的免洗剂。
Description
技术领域
本发明涉及服装面料技术领域,特别涉及一种多功能免洗服装面料。
背景技术
自清洁面料是指通过后期加工整理使面料具备表面超疏水或者光催化降解污染物的特殊性能以此来减少衣物的洗涤次数或实现衣物免洗减少洗涤剂的使用最终达到节能节水和环境友好的目的其中光催化自清洁面料的制备是将具有光催化效应的纳米颗粒负载于织物材料之上从而使材料不仅可以通过光催化降解有机污染物同时兼具杀菌除臭和防紫外线能力光催化自清洁面料由于其多功能性和较高的附加值已经成为服装工业倍受关注的热点方向之一。然而现有技术中的免洗面料可达到较优的免洗及防水效果,然而在抗菌性方面的性能仍然差强人意,需要进一步改进,以获得更优的抗菌效果。
发明内容
本发明的主要目的是提出一种免洗剂及经其处理得到的服装面料,该免洗剂可使服装面料具有去污及强抗菌的特点。
为实现上述目的,本发明提出一种免洗剂,按照重量份数计,该免洗剂包括:氟碳化合物共聚物2-4份,脂肪酸甘油酯6-9份,二烷基二甲基铵盐3-5份,烷基三甲基铵盐7-10份,聚季鏻铵盐1-4份,季铵盐3-5份,载银纳米二氧化钛粉体10-20份,硅烷偶联剂KH5700.5-1份,顺丁稀二酸酐0.5-1份,磷酸三辛脂0.5-1份,对羟基苯甲酸丁酯0.5-1份,去离子水20-30份,酒精10-20份。
进一步地,该免洗剂包括:氟碳化合物共聚物2份,脂肪酸甘油酯7份,二烷基二甲基铵盐3份,烷基三甲基铵盐7份,聚季鏻铵盐3份,季铵盐3份,载银纳米二氧化钛粉体16份,硅烷偶联剂KH570 0.6份,顺丁稀二酸酐0.6份,磷酸三辛脂0.6份;羟基苯甲酸丁酯0.6份,去离子水25份,酒精13份。
进一步地,所述载银纳米二氧化钛粉体的粒径为15-19nm。
进一步地,所述免洗剂还包括聚有机硅氧烷,所述聚有机硅氧烷的重量份数为3-5份
本发明还提供了一种服装面料,其由以上提到的免洗剂处理坯布制得。
本发明技术方案提供的免洗剂,加入了载银纳米二氧化钛、硅烷偶联剂KH570、顺丁稀二酸酐、磷酸三辛脂、对羟基苯甲酸丁酯、聚季鏻铵盐,其中,通过硅烷偶联剂KH570、顺丁稀二酸酐、磷酸三辛脂及对羟基苯甲酸丁酯对载银纳米二氧化钛进行改性,使改性载银纳米二氧化钛具有优异的抗菌效果及较好的吸附性,其可与氟碳化合物共聚物和聚季鏻铵盐结合,氟碳化合物共聚物具有优异的防水防油作用,聚季鏻铵盐和季铵盐的复配物具有良好的抗菌作用,通过改性载银二氧化钛的桥梁作用,使得氟碳化合物共聚物跟载银改性纳米二氧化钛以及聚季鏻铵盐和季铵盐的复配物相互交缠结合在一起,形成保护物质,从而赋予织物面料较好的防水、去污、抗菌等性能。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
另外,各个实施例之间的技术方案可以相互结合,但是必须是以本领域普通技术人员能够实现为基础,当技术方案的结合出现相互矛盾或无法实现时应当认为这种技术方案的结合不存在,也不在本发明要求的保护范围之内。
本发明提出了一种免洗剂及经其处理得到的服装面料,其中,该免洗剂处理得到的服装面料具有免洗及抗菌等特点。
本发明提出的免洗剂,按照重量份数计,包括:氟碳化合物共聚物2-4份,脂肪酸甘油酯6-9份,二烷基二甲基铵盐3-5份,烷基三甲基铵盐7-10份,聚季鏻铵盐1-4份,季铵盐3-5份,载银纳米二氧化钛粉体10-20份,硅烷偶联剂KH5700.5-1份,顺丁稀二酸酐0.5-1份,磷酸三辛脂0.5-1份,对羟基苯甲酸丁酯0.5-1份,去离子水20-30份,酒精10-20份。
通过对载银二氧化钛粉体进行表征,包括其粒径分析、透镜电镜分析和成分分析,并采用硅烷偶联剂KH570、顺丁稀二酸酐、磷酸三辛脂、对羟基苯甲酸丁酯等改性剂对载银二氧化钛进行改性,以获得最佳改性效果的改性剂和较佳的改性配比,改性后的载银纳米二氧化钛粉体具有较优的抗菌效果。
在本实施例中,所述聚季鏻铵盐的制备主要分两步,首先以环氧氯丙烷和二甲胺作为反应单体,乙二胺为交联剂,通过逐步聚合反应制备聚季铵盐,然后利用醚化接枝反应,将带有P+的四羟甲基硫酸磷接枝到聚季铵盐的侧链上。具体地,聚季鏻铵盐的制备方法包括:
第一步,聚季铵盐的合成
将装有温度计、冷凝管、搅拌器的四口烧瓶置于冰水浴中,向烧瓶加入二甲胺水溶液,待反应体系的温度降至10℃左右,用常压滴液漏斗缓慢滴加环氧氯丙烷,整个滴加过程始终保持反应体系的温度为10℃—20℃,滴完后加入少量交联剂,继续反应一段时间得到聚季铵盐,整个反应过程始终保持机械搅拌。
第二步,聚季铵盐与四羟甲基硫酸磷的醚化接枝反应
取第一步产物20ml加入装有温度计、冷凝管、搅拌器和常压滴液漏斗的四口烧瓶。在不断搅拌的情况下,待水浴升温至65℃,通过滴液漏斗缓慢滴加NaOH作为催化剂,滴完以后恒温反应一段时间,最后得到淡黄色的粘稠液体,即聚季鏻铵盐。其中,该聚季鏻铵盐的结构式如下:
在本实施例中,所述聚季鏻铵盐的粘度范围为600-700mPa.s。因为在制备聚季鏻铵盐时,当聚季鏻铵盐的粘度过大,会导致其阳离子度减小,所以为了使得聚季鏻铵盐具有合适的粘度和阳离子度,选择控制聚季鏻铵盐的粘度范围为600-700mPa.s。
进一步地,所述免洗剂还包括聚有机硅氧烷,所述聚有机硅氧烷的重量份数为3-5份。
本发明还提供一种服装面料,所述服装面料采用上述免洗剂处理坯布制得。
其中,所述处理坯布的过程包括:将坯布加入免洗剂中进行充分的超声浸渍,将充分浸渍后的面料在100-200℃温度下进行烘干,将烘干后的面料进行打卷。坯布在免洗剂中超声浸渍,使得免洗剂中的有效成分可快速且充分地进入坯布的纤维之间,甚至渗透至纤维内部,从而使坯布中的纤维受到多功能免洗剂中有效成分的充分保护,经100-200℃温度烘干后,浸泡过程中与坯布纤维充分结合的多功能免洗剂中的有效成分会随着烘干过程中水分的散失而牢固地与纤维结合,在坯布纤维的表面形成疏水、亲水物质相互交错排列,从而使坯布既可达到优异的抗水效果,又具有耐脏的效果。
在此,需要说明的是,坯布在免洗剂中超声浸渍时,小分子季铵盐可渗透到纤维的内部,对纤维内部进行改性,而大分子聚季鏻铵盐则主要吸附在纤维的表面,实现对纤维表面的改性。如此,通过小分子季铵盐与大分子聚季鏻铵盐的复配改性,可以更好地实现对纤维进行改性,赋予纤维优异的抗菌性等。
下面将结合具体实施例来对本发明的技术方案作进一步的阐述。
实施例1:
一种多功能免洗剂,按照重量份数计,包括:氟碳化合物共聚物1份,
氟碳化合物共聚物2份,脂肪酸甘油酯7份,二烷基二甲基铵盐3份,烷基三甲基铵盐7份,聚季鏻铵盐3份,季铵盐3份,载银纳米二氧化钛粉体16份,硅烷偶联剂KH570 0.6份,顺丁稀二酸酐0.6份,磷酸三辛脂0.6份;羟基苯甲酸丁酯0.6份,去离子水25份,酒精13份。
其中,所述聚季鏻铵盐的粘度为600mPa.s,所述载银纳米二氧化钛粉体的粒径为15-19nm。
一种服装面料,所述服装面料采用上述免洗剂处理坯布制得。其中,所述处理坯布的过程包括:将坯布加入免洗剂中进行充分的超声浸渍,将充分浸渍后的面料在100-200℃温度下进行烘干,将烘干后的面料进行打卷。
实施例2:
一种多功能免洗剂,按照重量份数计,包括:氟碳化合物共聚物2.5份,
氟碳化合物共聚物3份,脂肪酸甘油酯8份,二烷基二甲基铵盐4份,烷基三甲基铵盐8份,聚季鏻铵盐2份,季铵盐4份,载银纳米二氧化钛粉体12份,硅烷偶联剂KH570 0.7份,顺丁稀二酸酐0.5份,磷酸三辛脂0.7份,对羟基苯甲酸丁酯0.5份,去离子水20份,酒精10份。其中,所述聚季鏻铵盐的粘度为650mPa.s,所述载银纳米二氧化钛粉体的粒径为10-20nm。
一种服装面料,所述服装面料采用上述多功能免洗剂处理坯布制得。其中,所述处理坯布的过程包括:将坯布加入多功能免洗剂中进行充分的超声浸渍,将充分浸渍后的面料在100-200℃温度下进行烘干,将烘干后的面料进行打卷。
实施例3:
一种多功能免洗剂,按照重量份数计,包括:氟碳化合物共聚物4份,脂肪酸甘油酯9份,二烷基二甲基铵盐5份,烷基三甲基铵盐10份,聚季鏻铵盐4份,季铵盐5份,载银纳米二氧化钛粉体20份,硅烷偶联剂KH5700 1份,顺丁稀二酸酐1份,磷酸三辛脂1份,对羟基苯甲酸丁酯1份,去离子水20份,酒精10份。其中,所述聚季鏻铵盐的粘度为680mPa.s,所述载银纳米二氧化钛粉体的粒径为15nm。
一种服装面料,所述服装面料采用上述多功能免洗剂处理坯布制得。其中,所述处理坯布的过程包括:将坯布加入多功能免洗剂中进行充分的超声浸渍,将充分浸渍后的面料在100-200℃温度下进行烘干,将烘干后的面料进行打卷。
为了对本发明制备的服装面料的性能进行研究,对上述实施例1至实施例3制备的服装面料分别进行了测试,测试结果如下:
表1服装面料测试结果
其中,柔软性测试采用多人触摸的方式测定,规定最高等级为5,等级越高,织物柔软性越好。拒水性测试以水滴在织物表面3min后的接触角表征(接触角大于130°即说明表面具有较好的拒水性),采用静态接触角测试仪测试,抗菌性测试,使用的是大肠杆菌和金黄色葡萄球菌,采用振荡烧瓶法测试。
根据表1可知,经过本发明实施例1至实施例3制得的服装面料,具有较好的手感,且水滴在服装面料的表面3min后的接触角都大于130°,说明该服装面料具有较好的拒水性,另外,经过本发明实施例1至实施例3制得的服装面料,还具有较高的抑菌率,抗菌性较好。
以上所述仅为本发明的优选实施例,并非因此限制本发明的专利范围,凡是在本发明的发明构思下,利用本发明说明书内容所作的等效结构变换,或直接/间接运用在其他相关的技术领域均包括在本发明的专利保护范围内。
Claims (5)
1.一种免洗剂,其特征在于,按照重量份数计,该免洗剂包括:
氟碳化合物共聚物2-4份,
脂肪酸甘油酯6-9份,
二烷基二甲基铵盐3-5份,
烷基三甲基铵盐7-10份,
聚季鏻铵盐1-4份,
季铵盐3-5份,
载银纳米二氧化钛粉体10-20份,
硅烷偶联剂KH570 0.5-1份,
顺丁稀二酸酐0.5-1份,
磷酸三辛脂0.5-1份;
对羟基苯甲酸丁酯0.5-1份;
去离子水20-30份;
酒精10-20份。
2.如权利要求1所述的免洗剂,其特征在于,该免洗剂包括:
氟碳化合物共聚物2份,
脂肪酸甘油酯7份,
二烷基二甲基铵盐3份,
烷基三甲基铵盐7份,
聚季鏻铵盐3份,
季铵盐3份,
载银纳米二氧化钛粉体16份,
硅烷偶联剂KH570 0.6份,
顺丁稀二酸酐0.6份,
磷酸三辛脂0.6份;
对羟基苯甲酸丁酯0.6份;
去离子水25份;
酒精13份。
3.如权利要求1所述的免洗剂,其特征在于,所述载银纳米二氧化钛粉体的粒径为15-19nm。
4.如权利要求1所述的免洗剂,其特征在于,所述免洗剂还包括聚有机硅氧烷,所述聚有机硅氧烷的重量份数为3-5份。
5.一种服装面料,其特征在于,采用如权利要求1至4中任一项所述的免洗剂处理坯布制得。
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101851862A (zh) * | 2009-03-30 | 2010-10-06 | 上海皇宇科技发展有限公司 | 一种防水剂组合物及其应用 |
CN105908502A (zh) * | 2016-06-23 | 2016-08-31 | 杭州余杭兴隆绸厂 | 一种免洗剂以及采用该免洗剂处理得到的免洗面料 |
-
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- 2018-09-04 CN CN201811027128.1A patent/CN109281170A/zh active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101851862A (zh) * | 2009-03-30 | 2010-10-06 | 上海皇宇科技发展有限公司 | 一种防水剂组合物及其应用 |
CN105908502A (zh) * | 2016-06-23 | 2016-08-31 | 杭州余杭兴隆绸厂 | 一种免洗剂以及采用该免洗剂处理得到的免洗面料 |
Non-Patent Citations (2)
Title |
---|
孙玉绣等: "《小化工产品配方与制备》", 30 November 2015, 中国纺织出版社 * |
郑雪梅: "《粘胶纤维阳离子改性剂的合成及应用》", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
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