CN109280497A - A kind of fire-retardant flocking adhesive - Google Patents
A kind of fire-retardant flocking adhesive Download PDFInfo
- Publication number
- CN109280497A CN109280497A CN201811016558.3A CN201811016558A CN109280497A CN 109280497 A CN109280497 A CN 109280497A CN 201811016558 A CN201811016558 A CN 201811016558A CN 109280497 A CN109280497 A CN 109280497A
- Authority
- CN
- China
- Prior art keywords
- parts
- fire
- phenolic aldehyde
- flocking adhesive
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The present invention relates to field of adhesive technology, and disclose a kind of fire-retardant flocking adhesive, it is formulated by weight, it is 150-180 parts including cellulose ester, vinyl polymer is 9-15 parts, polyacrylate is 260-300 parts, a- cyanoacrylate is 300-330 parts, 4-6 parts of Pioloform, polyvinyl acetal, ethane-acetic acid ethyenyl ester is 200-220 parts, melamine-formaldehyde resin is 190-230 parts, organic siliconresin is 230-260 parts, acrylic resin is 300-330 parts, polyimides is 15-20 parts, 5-8 parts of polybenzimidazoles, phenolic aldehyde-Pioloform, polyvinyl acetal is 3-5 parts, phenolic aldehyde-polyamide is 2-3 parts, phenolic aldehyde-epoxy resin is 150-180 parts, epoxy-polyamide is 5-7 parts, deca-BDE It is 10-13 parts.The fire-retardant flocking adhesive has many advantages, such as that raw material is easy to get and is easy to make, heat resistance is strong, anti-flammability is high, good in oxidation resistance and bond effect are good.
Description
Technical field
The present invention relates to field of adhesive technology, specially a kind of fire-retardant flocking adhesive.
Background technique
It is glued (bonding, bonding, cementing, gluing) and refers to the skill that homogeneous or heterogeneous surface is linked together with adhesive
The features such as art has stress distribution continuous, light-weight, or sealing, most technological temperatures are low, is glued especially suitable for different materials
The connection of matter, different-thickness, ultra-thin specification and complex component, splicing RECENT DEVELOPMENTS is most fast, and application industry is extremely wide, and to high-new section
Learning technological progress and people's daily life improvement has significant impact, therefore, it is very heavy to study, develop and produce all kinds of adhesive
It wants.
But flocking adhesive in the prior art is easy to happen thawing, poor heat resistance at high temperature, and is easy to be burned,
It is oxidized easily, and is easy to fall off, therefore propose a kind of fire-retardant flocking adhesive after flocking adhesive bonds for a long time.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of fire-retardant flocking adhesive, and there is raw material to be easy to get and be easy to
Production, the advantages that heat resistance is strong, anti-flammability is high, good in oxidation resistance and bond effect are good solve Flock Adhesive now on the market
It is stick heat resistance and poor fire, oxidizable and the problem of be easy to fall off.
(2) technical solution
For the purpose that the above-mentioned heat resistance of realization is strong, anti-flammability is high, good in oxidation resistance and bond effect are good, the present invention is provided such as
Lower technical solution: a kind of fire-retardant flocking adhesive, including cellulose ester, vinyl polymer, polyacrylate, a- alpha-cyanoacrylate
Ester, Pioloform, polyvinyl acetal, ethane-acetic acid ethyenyl ester, melamine-formaldehyde resin, organic siliconresin, acrylic resin, polyamides are sub-
Amine, polybenzimidazoles, phenolic aldehyde-Pioloform, polyvinyl acetal, phenolic aldehyde-polyamide, phenolic aldehyde-epoxy resin, epoxy-polyamide and ten bromines two
Phenylate, by weight, the cellulose ester is 150-180 parts to formula, and the vinyl polymer is 9-15 parts, the polypropylene
Acid esters be 260-300 part, the a- cyanoacrylate be 300-330 parts, described Pioloform, polyvinyl acetal 4-6 parts, the ethylene-
Vinyl acetate is 200-220 parts, and the melamine-formaldehyde resin is 190-230 parts, and the organic siliconresin is 230-260
Part, the acrylic resin be 300-330 part, the polyimides be 15-20 parts, described polybenzimidazoles 5-8 parts, the phenol
Aldehyde-Pioloform, polyvinyl acetal is 3-5 parts, and the phenolic aldehyde-polyamide is 2-3 parts, and the phenolic aldehyde-epoxy resin is 150-180 parts, institute
Stating epoxy-polyamide is 5-7 parts, and the deca-BDE is 10-13 parts.
Preferably, by weight, the cellulose ester is 160 parts to formula, and the vinyl polymer is 10 parts, described
Polyacrylate is 290 parts, and the a- cyanoacrylate is 310 parts, 4 parts of the Pioloform, polyvinyl acetal, the ethylene-acetate
Vinyl acetate is 210 parts, and the melamine-formaldehyde resin is 200 parts, and the organic siliconresin is 240 parts, the acrylic acid tree
Rouge is 310 parts, and the polyimides is 17 parts, 6 parts of the polybenzimidazoles, and the phenolic aldehyde-Pioloform, polyvinyl acetal is 3 parts, institute
Stating phenolic aldehyde-polyamide is 2 parts, and the phenolic aldehyde-epoxy resin is 160 parts, and the epoxy-polyamide is 5 parts, the decabrominated dipheny
Ether is 12 parts.
Preferably, the vinyl polymer is polyvinyl acetate, polyvinyl alcohol, Vinylidene Chloride, one in polyisobutene
Kind or a variety of mixing composition.
Preferably, the solvent in the fire-retardant flocking adhesive is deionized water.
Preferably, promotor can also be added in the fire-retardant flocking adhesive, the promotor is tetramethyl thiourea, acetyl
Acetone vanadium, acetylacetone,2,4-pentanedione, triphenylphosphine, cobalt naphthenate, cobalt iso-octoate, zinc Isoocatanoate, two kinds in n,N-Dimethylaniline or
A variety of mixing compositions.
Preferably, coupling agent can also be added in the fire-retardant flocking adhesive, the coupling agent is titanate coupling agent.
Preferably, the temperature that the fire-retardant flocking adhesive is mixed in a solvent is 100 DEG C, and being stirred the time is
30min。
(3) beneficial effect
Compared with prior art, the present invention provides a kind of fire-retardant flocking adhesive, have it is following the utility model has the advantages that
1, there is raw material to be easy to get and be easy to make for the fire-retardant flocking adhesive, heat resistance is strong, anti-flammability is high, inoxidizability
The advantages that good and bond effect is good.
Specific embodiment
Here is that technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
A kind of fire-retardant flocking adhesive, including cellulose ester, vinyl polymer, polyacrylate, a- cyanoacrylate,
Pioloform, polyvinyl acetal, ethane-acetic acid ethyenyl ester, melamine-formaldehyde resin, organic siliconresin, acrylic resin, polyimides,
Polybenzimidazoles, phenolic aldehyde-Pioloform, polyvinyl acetal, phenolic aldehyde-polyamide, phenolic aldehyde-epoxy resin, epoxy-polyamide and decabrominated dipheny
Ether, by weight, cellulose ester is 150-180 parts to formula, and vinyl polymer is 9-15 parts, polyacrylate 260-300
Part, a- cyanoacrylate be 300-330 part, 4-6 parts of Pioloform, polyvinyl acetal, ethane-acetic acid ethyenyl ester be 200-220 parts, three
Paracyanogen-formaldehyde resin is 190-230 parts, and organic siliconresin is 230-260 parts, and acrylic resin is 300-330 parts, polyimides
It is 15-20 parts, 5-8 parts of polybenzimidazoles, phenolic aldehyde-Pioloform, polyvinyl acetal is 3-5 parts, and phenolic aldehyde-polyamide is 2-3 parts, phenolic aldehyde-ring
Oxygen resin is 150-180 parts, and epoxy-polyamide is 5-7 parts, and deca-BDE is 10-13 parts, molten in fire-retardant flocking adhesive
Agent is deionized water, convenient for multiple compounds are carried out dissolution mixing, vinyl polymer be polyvinyl acetate, polyvinyl alcohol,
One of Vinylidene Chloride, polyisobutene are a variety of, can be improved the thermoplasticity of adhesive, can also add in fire-retardant flocking adhesive
Enter promotor, promotor is tetramethyl thiourea, vanadium acetylacetonate, acetylacetone,2,4-pentanedione, triphenylphosphine, cobalt naphthenate, cobalt iso-octoate, different
Two or more mixing in zinc octoate, n,N-Dimethylaniline, can promote the reaction rate of adhesive, fire-retardant flocking gluing
Coupling agent can also be added in agent, coupling agent is titanate coupling agent, can increase antirust, anti-oxidant, the fire-retardant effect of adhesive
Fruit, the temperature that fire-retardant flocking adhesive is mixed in a solvent are 100 DEG C, and being stirred the time is 30min, can be made a variety of
Organic or inorganic compound is uniformly mixed, to improve the production efficiency and the quality of production of adhesive.
A kind of fire-retardant flocking adhesive, by weight, cellulose ester is 160 parts to formula, and vinyl polymer is 10 parts, is gathered
Acrylate be 290 parts, a- cyanoacrylate be 310 parts, 4 parts of Pioloform, polyvinyl acetal, ethane-acetic acid ethyenyl ester 210
Part, melamine-formaldehyde resin is 200 parts, and organic siliconresin is 240 parts, and acrylic resin is 310 parts, polyimides 17
Part, 6 parts of polybenzimidazoles, phenolic aldehyde-Pioloform, polyvinyl acetal is 3 parts, and phenolic aldehyde-polyamide is 2 parts, and phenolic aldehyde-epoxy resin is 160
Part, epoxy-polyamide is 5 parts, and deca-BDE is 12 parts.
In conclusion the fire-retardant flocking adhesive, there is raw material to be easy to get and be easy to make, heat resistance is strong, anti-flammability is high, anti-
The advantages that oxidisability is good and bond effect is good.
It should be noted that the terms "include", "comprise" or its any other variant are intended to the packet of nonexcludability
Contain, so that the process, method, article or equipment for including a series of elements not only includes those elements, but also including
Other elements that are not explicitly listed, or further include for elements inherent to such a process, method, article, or device.
In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that including the element
Process, method, article or equipment in there is also other identical elements.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of fire-retardant flocking adhesive, it is characterised in that: including cellulose ester, vinyl polymer, polyacrylate, a- cyano
Acrylate, Pioloform, polyvinyl acetal, ethane-acetic acid ethyenyl ester, melamine-formaldehyde resin, organic siliconresin, acrylic resin,
Polyimides, polybenzimidazoles, phenolic aldehyde-Pioloform, polyvinyl acetal, phenolic aldehyde-polyamide, phenolic aldehyde-epoxy resin, epoxy-polyamide and
Deca-BDE, by weight, the cellulose ester is 150-180 parts to formula, and the vinyl polymer is 9-15 parts, described
Polyacrylate be 260-300 part, the a- cyanoacrylate be 300-330 parts, described Pioloform, polyvinyl acetal 4-6 parts, institute
Stating ethane-acetic acid ethyenyl ester is 200-220 parts, and the melamine-formaldehyde resin is 190-230 parts, and the organic siliconresin is
230-260 parts, the acrylic resin is 300-330 parts, and the polyimides is 15-20 parts, the polybenzimidazoles 5-8
Part, the phenolic aldehyde-Pioloform, polyvinyl acetal is 3-5 parts, and the phenolic aldehyde-polyamide is 2-3 parts, and the phenolic aldehyde-epoxy resin is
150-180 parts, the epoxy-polyamide is 5-7 parts, and the deca-BDE is 10-13 parts.
2. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: it is formulated by weight, the fibre
Tieing up plain rouge is 160 parts, and the vinyl polymer is 10 parts, and the polyacrylate is 290 parts, and the a- cyanoacrylate is
310 parts, 4 parts of the Pioloform, polyvinyl acetal, the ethane-acetic acid ethyenyl ester is 210 parts, and the melamine-formaldehyde resin is 200
Part, the organic siliconresin is 240 parts, and the acrylic resin is 310 parts, and the polyimides is 17 parts, and the polyphenyl is simultaneously
6 parts of imidazoles, the phenolic aldehyde-Pioloform, polyvinyl acetal is 3 parts, and the phenolic aldehyde-polyamide is 2 parts, and the phenolic aldehyde-epoxy resin is
160 parts, the epoxy-polyamide is 5 parts, and the deca-BDE is 12 parts.
3. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: the vinyl polymer is poly- acetic acid
One of vinyl acetate, polyvinyl alcohol, Vinylidene Chloride, polyisobutene are a variety of.
4. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: in the fire-retardant flocking adhesive
Solvent is deionized water.
5. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: in the fire-retardant flocking adhesive also
Promotor can be added, the promotor is tetramethyl thiourea, vanadium acetylacetonate, acetylacetone,2,4-pentanedione, triphenylphosphine, cobalt naphthenate, different
Cobalt octoate, zinc Isoocatanoate, two or more mixing in n,N-Dimethylaniline.
6. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: in the fire-retardant flocking adhesive also
Coupling agent can be added, the coupling agent is titanate coupling agent.
7. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: the fire-retardant flocking adhesive is molten
The temperature being mixed in agent is 100 DEG C, and being stirred the time is 30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811016558.3A CN109280497A (en) | 2018-09-03 | 2018-09-03 | A kind of fire-retardant flocking adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811016558.3A CN109280497A (en) | 2018-09-03 | 2018-09-03 | A kind of fire-retardant flocking adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109280497A true CN109280497A (en) | 2019-01-29 |
Family
ID=65184310
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811016558.3A Pending CN109280497A (en) | 2018-09-03 | 2018-09-03 | A kind of fire-retardant flocking adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN109280497A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093117A (en) * | 2019-05-06 | 2019-08-06 | 湖北君邦新材料科技有限公司 | A kind of high-elastic glue of environment-friendly type and its production technology |
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| CN101824283A (en) * | 2009-03-04 | 2010-09-08 | 日东电工株式会社 | Heat-releasable pressure sensitive adhesion sheet and be used for the method for cut-processing laminated ceramic sheet |
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2018
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093117A (en) * | 2019-05-06 | 2019-08-06 | 湖北君邦新材料科技有限公司 | A kind of high-elastic glue of environment-friendly type and its production technology |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190129 |
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| RJ01 | Rejection of invention patent application after publication |