CN109280298A - A kind of antistatic wear-resistant PVC material of elasticity - Google Patents
A kind of antistatic wear-resistant PVC material of elasticity Download PDFInfo
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- CN109280298A CN109280298A CN201811140161.5A CN201811140161A CN109280298A CN 109280298 A CN109280298 A CN 109280298A CN 201811140161 A CN201811140161 A CN 201811140161A CN 109280298 A CN109280298 A CN 109280298A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of antistatic wear-resistant PVC materials of elasticity, are made of the raw material of following parts by weight: 40-50 parts of polyvinyl chloride resin, 13-18 parts of elastomer, 10-15 parts of polytetrafluoroethyl-ne super fine, 6-9 parts of Kafra fiber, 2-6 parts of glass fibre, 2-4 parts of crosslinking agent, 2-6 parts of vinal, 3-5 parts of metakaolin, 2-4 parts of anti-impact modifier, 1-2 parts of transparent antistatic agent, 3-6 parts of plasticizer, 2-5 parts of lubricant, 2-4 parts of modified nano zinc oxide, 2-5 parts of silicon nitride, 4-8 parts of nanofiber lithium titanate, 1-2 parts of antioxidant.The present invention is made of by the way that elastomer, elastomer is added acrylic resin, polyurethane resin, natural rubber, so that PVC material obtained has higher elasticity.
Description
Technical field
The present invention relates to plastic applications, specifically a kind of antistatic wear-resistant PVC material of elasticity.
Background technique
Pvc pipe is more common a kind of tubing in daily life, and traditional polyvinyl chloride (PVC) feed pipe is with polychlorostyrene
Vinyl is primary raw material, and suitable age resister, modifying agent etc. is added, and is prepared through techniques such as mixing, calendering, vacuum formings
Made of material, have the shortcomings that wearability, elasticity, antistatic property are poor.Thus we release a kind of wearability, elasticity, resist it is quiet
Electrically high PVC material solves the above problems.
Summary of the invention
The purpose of the present invention is to provide a kind of antistatic wear-resistant PVC materials of elasticity, to solve in above-mentioned background technique
The problem of proposition.
To achieve the above object, the invention provides the following technical scheme:
A kind of antistatic wear-resistant PVC material of elasticity, is made of the raw material of following parts by weight:
40-50 parts of polyvinyl chloride resin, 13-18 parts of elastomer, 10-15 parts of polytetrafluoroethyl-ne super fine, 6-9 parts of Kafra fiber,
2-6 parts of glass fibre, 2-4 parts of crosslinking agent, 2-6 parts of vinal, 3-5 parts of metakaolin, 2-4 parts of anti-impact modifier,
1-2 parts of transparent antistatic agent, 2-5 parts of lubricant, 2-4 parts of modified nano zinc oxide, 2-5 parts of silicon nitride, is received 3-6 parts of plasticizer
Rice 4-8 parts of titanate fiber lithium, 1-2 parts of antioxidant.
A kind of antistatic wear-resistant PVC material of elasticity, is made of the raw material of following parts by weight:
40 parts of polyvinyl chloride resin, 13 parts of elastomer, 10 parts of polytetrafluoroethyl-ne super fine, 6 parts of Kafra fiber, glass fibre 2
Part, 2 parts of crosslinking agent, 2 parts of vinal, 3 parts of metakaolin, 2 parts of anti-impact modifier, 1 part of transparent antistatic agent, plasticising
3 parts of agent, 2 parts of lubricant, 2 parts of modified nano zinc oxide, 2 parts of silicon nitride, 4 parts of nanofiber lithium titanate, 1 part of antioxidant.
A kind of antistatic wear-resistant PVC material of elasticity, is made of the raw material of following parts by weight:
50 parts of polyvinyl chloride resin, 18 parts of elastomer, 15 parts of polytetrafluoroethyl-ne super fine, 9 parts of Kafra fiber, glass fibre 6
Part, 4 parts of crosslinking agent, 6 parts of vinal, 5 parts of metakaolin, 4 parts of anti-impact modifier, 2 parts of transparent antistatic agent, plasticising
6 parts of agent, 5 parts of lubricant, 4 parts of modified nano zinc oxide, 5 parts of silicon nitride, 8 parts of nanofiber lithium titanate, 2 parts of antioxidant.
A kind of antistatic wear-resistant PVC material of elasticity, is made of the raw material of following parts by weight:
46 parts of polyvinyl chloride resin, 16 parts of elastomer, 13 parts of polytetrafluoroethyl-ne super fine, 8 parts of Kafra fiber, glass fibre 4
Part, 1.5 parts of transparent antistatic agent, increases 3 parts of crosslinking agent, 4 parts of vinal, 4 parts of metakaolin, 3 parts of anti-impact modifier
Mould 5 parts of agent, 4 parts of lubricant, 3 parts of modified nano zinc oxide, 3.5 parts of silicon nitride, 6 parts of nanofiber lithium titanate, antioxidant 1.5
Part.
The lubricant is pentaerythrite palmitate, lauric acid amide of ethanol, one in Myrj 45
Kind or numerous compositions.
The plasticizer is diphenyl octyl phosphate, thio-2 acid [2- (2- fourth oxygen ethyoxyl) ethyl] ester, poly- second two
One of alcohol dehydrogenase abietate or numerous compositions.
The antioxidant is one in BHT antioxidant, CA antioxidant, 1010 antioxidants and 1076 antioxidants
Kind or numerous compositions.
The elastomer is mixed by acrylic resin, polyurethane resin, natural rubber according to mass ratio 2:1:2.
The modified nano zinc oxide the preparation method is as follows: being slowly added in the liquor zinci chloridi of 0.2-0.4mol/L
The glucose ester of 0.1-0.2g/L, stirs while adding, and after mixing, it is 0.5- that obtained mixed solution, which is added to concentration,
In the sodium hydroxide solution of 0.7mol/L, such as processing 1-2 hours ultrasonic reaction 20-30 minutes, is separated, and washing is dried to obtain and changes
Property nano zine oxide.
The partial size of the modified nano zinc oxide is 50-80nm.
The transparent antistatic agent is trifluoromethanesulfonimide lithium.
Compared with prior art, the beneficial effects of the present invention are:
The present invention is made of by the way that elastomer, elastomer is added acrylic resin, polyurethane resin, natural rubber, so that
PVC material obtained has higher elasticity.By polytetrafluoroethyl-ne super fine, the corrosion-resistant of PVC material can be improved, it can be right
Most of chemicals and solvent, show inertia, can strong alkali-acid resistance, water and various organic solvents, can be with by crosslinking agent
The intensity and elasticity for improving plastics, improve wear-resisting property.
Use makees enhancing component, Kafra fiber with Kafra fiber, glass fibre, vinal, metakaolin
It is low with density, intensity is high, good toughness, high temperature resistant, flame retardant type, it is easy to process and molding so that PVC material of the invention has
High-wearing feature, high temperature resistant and anti-flammability.
Modified nano zinc oxide, transparent antistatic agent and nanofiber lithium titanate addition, improve the wear-resisting of PVC material
Damage and antistatic property.
Specific embodiment
Embodiment 1
A kind of antistatic wear-resistant PVC material of elasticity, is made of the raw material of following parts by weight:
40 parts of polyvinyl chloride resin, 13 parts of elastomer, 10 parts of polytetrafluoroethyl-ne super fine, 6 parts of Kafra fiber, glass fibre 2
Part, 2 parts of crosslinking agent, 2 parts of vinal, 3 parts of metakaolin, 2 parts of anti-impact modifier, 1 part of transparent antistatic agent, plasticising
3 parts of agent, 2 parts of lubricant, 2 parts of modified nano zinc oxide, 2 parts of silicon nitride, 4 parts of nanofiber lithium titanate, 1 part of antioxidant.
The lubricant is pentaerythrite palmitate, lauric acid amide of ethanol, one in Myrj 45
Kind or numerous compositions.
The plasticizer is diphenyl octyl phosphate, thio-2 acid [2- (2- fourth oxygen ethyoxyl) ethyl] ester, poly- second two
One of alcohol dehydrogenase abietate or numerous compositions.
The antioxidant is one in BHT antioxidant, CA antioxidant, 1010 antioxidants and 1076 antioxidants
Kind or numerous compositions.
The elastomer is mixed by acrylic resin, polyurethane resin, natural rubber according to mass ratio 2:1:2.
The modified nano zinc oxide the preparation method is as follows: being slowly added in the liquor zinci chloridi of 0.2-0.4mol/L
The glucose ester of 0.1-0.2g/L, stirs while adding, and after mixing, it is 0.5- that obtained mixed solution, which is added to concentration,
In the sodium hydroxide solution of 0.7mol/L, such as processing 1-2 hours ultrasonic reaction 20-30 minutes, is separated, and washing is dried to obtain and changes
Property nano zine oxide.
The partial size of the modified nano zinc oxide is 50-80nm.
The transparent antistatic agent is trifluoromethanesulfonimide lithium.
Embodiment 2
A kind of antistatic wear-resistant PVC material of elasticity, is made of the raw material of following parts by weight:
50 parts of polyvinyl chloride resin, 18 parts of elastomer, 15 parts of polytetrafluoroethyl-ne super fine, 9 parts of Kafra fiber, glass fibre 6
Part, 4 parts of crosslinking agent, 6 parts of vinal, 5 parts of metakaolin, 4 parts of anti-impact modifier, 2 parts of transparent antistatic agent, plasticising
6 parts of agent, 5 parts of lubricant, 4 parts of modified nano zinc oxide, 5 parts of silicon nitride, 8 parts of nanofiber lithium titanate, 2 parts of antioxidant.
The lubricant is pentaerythrite palmitate, lauric acid amide of ethanol, one in Myrj 45
Kind or numerous compositions.
The plasticizer is diphenyl octyl phosphate, thio-2 acid [2- (2- fourth oxygen ethyoxyl) ethyl] ester, poly- second two
One of alcohol dehydrogenase abietate or numerous compositions.
The antioxidant is one in BHT antioxidant, CA antioxidant, 1010 antioxidants and 1076 antioxidants
Kind or numerous compositions.
The elastomer is mixed by acrylic resin, polyurethane resin, natural rubber according to mass ratio 2:1:2.
The modified nano zinc oxide the preparation method is as follows: being slowly added in the liquor zinci chloridi of 0.2-0.4mol/L
The glucose ester of 0.1-0.2g/L, stirs while adding, and after mixing, it is 0.5- that obtained mixed solution, which is added to concentration,
In the sodium hydroxide solution of 0.7mol/L, such as processing 1-2 hours ultrasonic reaction 20-30 minutes, is separated, and washing is dried to obtain and changes
Property nano zine oxide.
The partial size of the modified nano zinc oxide is 50-80nm.
The transparent antistatic agent is trifluoromethanesulfonimide lithium.
Embodiment 3
A kind of antistatic wear-resistant PVC material of elasticity, is made of the raw material of following parts by weight:
46 parts of polyvinyl chloride resin, 16 parts of elastomer, 13 parts of polytetrafluoroethyl-ne super fine, 8 parts of Kafra fiber, glass fibre 4
Part, 1.5 parts of transparent antistatic agent, increases 3 parts of crosslinking agent, 4 parts of vinal, 4 parts of metakaolin, 3 parts of anti-impact modifier
Mould 5 parts of agent, 4 parts of lubricant, 3 parts of modified nano zinc oxide, 3.5 parts of silicon nitride, 6 parts of nanofiber lithium titanate, antioxidant 1.5
Part.
The lubricant is pentaerythrite palmitate, lauric acid amide of ethanol, one in Myrj 45
Kind or numerous compositions.
The plasticizer is diphenyl octyl phosphate, thio-2 acid [2- (2- fourth oxygen ethyoxyl) ethyl] ester, poly- second two
One of alcohol dehydrogenase abietate or numerous compositions.
The antioxidant is one in BHT antioxidant, CA antioxidant, 1010 antioxidants and 1076 antioxidants
Kind or numerous compositions.
The elastomer is mixed by acrylic resin, polyurethane resin, natural rubber according to mass ratio 2:1:2.
The modified nano zinc oxide the preparation method is as follows: being slowly added in the liquor zinci chloridi of 0.2-0.4mol/L
The glucose ester of 0.1-0.2g/L, stirs while adding, and after mixing, it is 0.5- that obtained mixed solution, which is added to concentration,
In the sodium hydroxide solution of 0.7mol/L, such as processing 1-2 hours ultrasonic reaction 20-30 minutes, is separated, and washing is dried to obtain and changes
Property nano zine oxide.
The partial size of the modified nano zinc oxide is 50-80nm.
The transparent antistatic agent is trifluoromethanesulfonimide lithium.
Claims (9)
1. a kind of antistatic wear-resistant PVC material of elasticity, which is characterized in that be made of the raw material of following parts by weight:
40-50 parts of polyvinyl chloride resin, 13-18 parts of elastomer, 10-15 parts of polytetrafluoroethyl-ne super fine, 6-9 parts of Kafra fiber, glass
It is 2-6 parts of fiber, 2-4 parts of crosslinking agent, 2-6 parts of vinal, 3-5 parts of metakaolin, 2-4 parts of anti-impact modifier, transparent
1-2 parts of antistatic agent, 3-6 parts of plasticizer, 2-5 parts of lubricant, 2-4 parts of modified nano zinc oxide, 2-5 parts of silicon nitride, Nanowire
Lithium titanate 4-8 parts, 1-2 parts of antioxidant of dimension.
2. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that by the original of following parts by weight
Material composition:
40 parts of polyvinyl chloride resin, 10 parts of polytetrafluoroethyl-ne super fine, 6 parts of Kafra fiber, 2 parts of glass fibre, is handed over 13 parts of elastomer
Join 2 parts of agent, 2 parts of vinal, 3 parts of metakaolin, 2 parts of anti-impact modifier, 1 part of transparent antistatic agent, plasticizer 3
Part, 2 parts of lubricant, 2 parts of modified nano zinc oxide, 2 parts of silicon nitride, 4 parts of nanofiber lithium titanate, 1 part of antioxidant.
3. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that by the original of following parts by weight
Material composition:
50 parts of polyvinyl chloride resin, 15 parts of polytetrafluoroethyl-ne super fine, 9 parts of Kafra fiber, 6 parts of glass fibre, is handed over 18 parts of elastomer
Join 4 parts of agent, 6 parts of vinal, 5 parts of metakaolin, 4 parts of anti-impact modifier, 2 parts of transparent antistatic agent, plasticizer 6
Part, 5 parts of lubricant, 4 parts of modified nano zinc oxide, 5 parts of silicon nitride, 8 parts of nanofiber lithium titanate, 2 parts of antioxidant.
4. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that by the original of following parts by weight
Material composition:
46 parts of polyvinyl chloride resin, 13 parts of polytetrafluoroethyl-ne super fine, 8 parts of Kafra fiber, 4 parts of glass fibre, is handed over 16 parts of elastomer
Join 3 parts of agent, 4 parts of vinal, 4 parts of metakaolin, 3 parts of anti-impact modifier, 1.5 parts of transparent antistatic agent, plasticizer 5
Part, 4 parts of lubricant, 3 parts of modified nano zinc oxide, 3.5 parts of silicon nitride, 6 parts of nanofiber lithium titanate, 1.5 parts of antioxidant.
5. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that the lubricant is season penta
One of tetrol palmitate, lauric acid amide of ethanol, Myrj 45 or numerous compositions.
6. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that the plasticizer is phosphoric acid
One of one monooctyl ester of hexichol, thio-2 acid [2- (2- fourth oxygen ethyoxyl) ethyl] ester, polyethylene glycol dehydroabietic acid ester are more
Kind composition.
7. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that the antioxidant is BHT
One of antioxidant, CA antioxidant, 1010 antioxidants and 1076 antioxidants or numerous compositions；It is described transparent anti-
Electrostatic agent is trifluoromethanesulfonimide lithium.
8. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that the elastomer is by propylene
Acid resin, polyurethane resin, natural rubber are mixed according to mass ratio 2:1:2.
9. the antistatic wear-resistant PVC material of elasticity according to claim 1, which is characterized in that the modified Nano oxidation
Zinc the preparation method is as follows: being slowly added to the glucose ester of 0.1-0.2g/L, side in the liquor zinci chloridi of 0.2-0.4mol/L
Side stirring is added, after mixing, obtained mixed solution is added to the sodium hydroxide solution for being 0.5-0.7mol/L to concentration
In, such as processing 1-2 hours ultrasonic reaction 20-30 minutes, separates, and washing is dried to obtain modified nano zinc oxide；The modification
The partial size of nano zine oxide is 50-80nm.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5194498A (en) * | 1991-09-09 | 1993-03-16 | Rohm And Haas Company | Poly(vinyl chloride) blends and additives therefor |
| JP2004091518A (en) * | 2002-08-29 | 2004-03-25 | Sekisui Chem Co Ltd | Vinyl chloride resin molded product |
| US20100292379A1 (en) * | 2009-05-12 | 2010-11-18 | Nan Ya Plastics Corporation | PVC resin composition and products made of the same |
| CN104194201A (en) * | 2014-07-29 | 2014-12-10 | 锐展(铜陵)科技有限公司 | Low-temperature-resistant high impact PVC (polyvinyl chloride) tubular product and preparation method thereof |
| CN105885293A (en) * | 2016-06-12 | 2016-08-24 | 安徽天元电缆有限公司 | Flexible, cold-proof and light abrasion-resistant cable material |
| CN106147066A (en) * | 2015-03-27 | 2016-11-23 | 安徽瑞鑫自动化仪表有限公司 | A kind of high-performance modified pvc material |
-
2018
- 2018-09-28 CN CN201811140161.5A patent/CN109280298A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5194498A (en) * | 1991-09-09 | 1993-03-16 | Rohm And Haas Company | Poly(vinyl chloride) blends and additives therefor |
| JP2004091518A (en) * | 2002-08-29 | 2004-03-25 | Sekisui Chem Co Ltd | Vinyl chloride resin molded product |
| US20100292379A1 (en) * | 2009-05-12 | 2010-11-18 | Nan Ya Plastics Corporation | PVC resin composition and products made of the same |
| CN104194201A (en) * | 2014-07-29 | 2014-12-10 | 锐展(铜陵)科技有限公司 | Low-temperature-resistant high impact PVC (polyvinyl chloride) tubular product and preparation method thereof |
| CN106147066A (en) * | 2015-03-27 | 2016-11-23 | 安徽瑞鑫自动化仪表有限公司 | A kind of high-performance modified pvc material |
| CN105885293A (en) * | 2016-06-12 | 2016-08-24 | 安徽天元电缆有限公司 | Flexible, cold-proof and light abrasion-resistant cable material |
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Application publication date: 20190129 |