CN109280293A - A kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure - Google Patents
A kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure Download PDFInfo
- Publication number
- CN109280293A CN109280293A CN201811069378.1A CN201811069378A CN109280293A CN 109280293 A CN109280293 A CN 109280293A CN 201811069378 A CN201811069378 A CN 201811069378A CN 109280293 A CN109280293 A CN 109280293A
- Authority
- CN
- China
- Prior art keywords
- polyether
- ether
- beta
- parts
- diketon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/02—Condensation polymers of aldehydes or ketones with phenols only of ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention relates to buildings in general partitions or the constructions of partition wall, more particularly to a kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure, according to parts by weight, formula composition are as follows: 80-100 parts of PVC resin powder, 15-25 parts of the polyether-ether-ketone keto-resin of the structure containing beta-diketon, 0.5-0.8 parts of calcium zinc macromolecular compound stabilizer, 2-5 parts of powder type titanate coupling agent, 20-40 parts of inorganic filler.The present invention has synthesized the polyether-ether-ketone keto-resin of the structure containing beta-diketon, and absorption and transfer of the beta-diketon structure to free radical are aided with calcium zinc macromolecular compound stabilizer, so that the thermal stability of PVC board of the present invention and photostability are more preferable.The flexural strength of PVC board of the present invention, anti-flammability, resistant to chemical etching and high temperature resistance are preferable.
Description
Technical field
The present invention relates to the constructions of buildings in general partitions or partition wall more particularly to a kind of based on beta-diketon structure
The ageing-resistant PVC board of polyether-ether-ketone keto-resin, belongs to building board field.
Background technique
PVC composite board can be used for building template and indoor decorative panel, for decorative panel, PVC composite plate one
As include middle layer and two layers of surface layer decorative layer.Intermediate layer material is wood moulding, and the structure of decorative layer includes carrier plate layer and decorative pattern
Paster changes the decorative pattern and pattern of decoration, imitation wood line and marble grain etc., to increase decorative panel by change paster
Ornamental value.In the technique of existing manufacture PVC composite plate, middle layer is molded first with extruder, then again in middle layer
Surface mount adorns layer, and the combination of decorative layer and middle layer can be through glue or thermally printed.After a period of use, due to dress
It adorns and is easy blistering on layer, the combination of decorative layer and middle layer will appear cracking, to seriously affect the ornamental value of PVC composite plate.
It would therefore be highly desirable to solve above-mentioned technical problem.
Chinese patent CN201510479359.6 discloses a kind of PVC base and preparation method thereof and PVC composite board,
In, PVC base includes following raw materials in parts by weight: PVC60-80 parts, heavy sodium carbonate, 3-10 parts of stabilizer, balance lubrication
0.5-2 parts of agent, 0.5-2 parts of foaming agent, 5-10 parts of foaming control agent；Wherein, PVC includes SG-5 type PVC and SG-8 type PVC, PVC
Weight fraction ratio with heavy sodium carbonate is 1:1-1.3.PVC composite board includes PVC base and the semihard positioned at substrate surface
Matter layer of PVC.Advantage is that the PVC base of the invention has good continuous extrusion ability, gained substrate characteristics in production
Continuous-stable, tensile strength, the impact strength of substrate are very good, and dimensional contraction rate is smaller.The PVC composite board of the invention is more existing
There is product ratio to have a higher mechanical strength and longer service life, but that there are high temperature resistances is poor, acid and alkali-resistance is rotten for the invention
The disadvantage of corrosion energy difference.
Polyether ether ketone ketone is poly- containing the height constituted there are two the repetitive unit of ketonic bond and two ehter bonds in backbone structure
Object belongs to special polymer material, has the physical and chemical performances such as high temperature resistant, high flame retardant, chemical resistance corrosion.The present invention is quasi-
Modified polyether ether ketone with special construction is used for PVC board, increases its anti-flammability, resistant to chemical etching and heat-resisting quantity
Energy.
Summary of the invention
It is in order to overcome the shortcomings of the prior art and insufficient, the present invention is intended to provide a kind of polyether-ether-ketone based on beta-diketon structure
The ageing-resistant PVC board of ketone resin.
To overcome shortcoming and defect of the existing technology, the present invention is the following technical schemes are provided: a kind of be based on beta-diketon
The ageing-resistant PVC board of the polyether-ether-ketone keto-resin of structure, which is characterized in that according to parts by weight, formula composition are as follows: polyvinyl chloride resin
80-100 parts of powder, 15-25 parts of the polyether-ether-ketone keto-resin of the structure containing beta-diketon, 0.5-0.8 parts of calcium zinc macromolecular compound stabilizer,
2-5 parts of powder type titanate coupling agent, 20-40 parts of inorganic filler.
The calcium zinc macromolecular compound stabilizer is calcium stearate, zinc stearate, calcium linoleate, calcium linoleate zinc, oil
At least one of sour calcium, zinc oleate.
The main ingredient of the PVC resin powder is polyvinyl chloride, is a kind of polymeric material of vinyl, can be from market
On directly buy.
The powder type titanate coupling agent is divided into four classes: monoalkoxy type, monoalkoxy pyrophosphate by its structure
Type, integrated and coordination figure.Wherein, the structural formula of monoalkoxy type coupling agent are as follows: RO-Ti (OX-R-Y) 3.The powder
The preferred isopropyl triisostearoyltitanate of type titanate coupling agent (TTS) can directly be bought from the market.
The filler is at least one of aluminium-magnesium silicate, calcium silicates, barium sulfate, titanium dioxide.
The structural formula of the polyether-ether-ketone keto-resin of the structure containing beta-diketon is that (wherein R is alkyl or aromatic group, n
For 80-200):
The synthetic method of the polyether-ether-ketone keto-resin of the structure containing beta-diketon are as follows: according to parts by weight, lead to nitrogen item
Under part, dihydric phenol, 1,3- bis- (4- fluorophenyl) -1 are added in the reactor, 3 propanedione, weak base, dipole solvent, low boiling point are molten
Agent is heated to 120-140 DEG C under stirring, remove water insulation reaction 1-2h, then releases low boiling point solvent and reaction system heats up
To 185-195 DEG C, polyase 13-5h is kept the temperature, room temperature is cooled to, methanol, filtering precipitating, with deionized water, ethyl alcohol are added into system
Repeated washing is finally dried for 24 hours at 50 DEG C, is ground to obtain the final product.
Further, the synthetic method of the polyether-ether-ketone keto-resin of the structure containing beta-diketon are as follows: logical condition of nitrogen gas
Under, 12-20 parts of dihydric phenols, 10-15 part 1,3- bis- are added in the reactor that division box, heating device, agitating device are housed
(4- fluorophenyl) -1,3 propanedione, 6-8 part weak base, 60-65 parts of dipole solvents, 30-35 parts of low boiling point solvents, is heated under stirring
120-140 DEG C, the water generated in dereaction, 120-140 DEG C of insulation reaction 1-2h, then by dividing constantly are removed by division box
Hydrophone releases low boiling point solvent and reaction system is warming up to 185-195 DEG C, keeps the temperature polyase 13-5h, has precipitating to analyse in polymerization process
Out, be cooled to room temperature, 40-50 part methanol be added into system, there is a large amount of Precipitations at this time, filtering precipitates, with deionized water,
Ethyl alcohol washes repeatedly 5-8 times, and finally 50 DEG C of dryings for 24 hours, must contain the polyethers of beta-diketon structure in vacuum drying oven after grinding
Ether ketone ketone resin.
The dihydric phenol is 6,6 '-two (4- hydroxyphenyl) hendecanes, 1,4- dihydroxy phenol, 4,4 '-dihydroxybiphenyls
At least one of.
The weak base is at least one of sodium carbonate, potassium carbonate.
The dipole solvent is at least one of sulfolane, dimethyl sulfoxide, 2,4- dimethylsulfolane.
The low boiling point solvent is at least one of benzene, toluene, normal octane, dodecane.
The ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure, it is characterised in that: its preparation side
Method includes the following steps: a, mixing: weighing in good addition batch mixer each component according to formula composition and heats and stir, mixing
Machine controls temperature and is cooled to after the completion of 145 ± 5 DEG C, 1400 ± 100r/min of mixing speed, 20 ± 2min of mixing time, mixing
50 ± 5 DEG C to get mixture；B, it squeezes out: mixture in a being put into screw extruder, melting extrusion obtains semi-finished product；C, fixed
Type, concora crush: semi-finished product are carried out shaping into concora crush；D, Length-fixing cutting: the plate after concora crush of being formed is cut as needed.
Compared with the existing technology, the invention has the following advantages that
1, the polyether-ether-ketone keto-resin of the structure containing beta-diketon has been synthesized for the first time, beta-diketon structure is to the absorption of free radical and turns
It moves, can reduce the decomposition of polyvinyl chloride under photo-thermal, while being aided with calcium zinc macromolecular compound stabilizer, so that of the present invention
The thermal stability and photostability of PVC board are more preferable；The two is all resin type stabilizer, has and is not easy to dissociate, stablizes timeliness length
Advantage.
2, modified resin of the invention is polyether-ether-ketone keto-resin, increases flexural strength, the anti-flammability, resistance toization of PVC board
Learn corrosion and high temperature resistance.
3, the powder type titanate coupling agent that is added of the present invention is during plate is embarked on journey, the macromolecule resin in system with
It generates chemical coupling between inorganic filler to be combined as a whole, the present invention is more preferable than common PVC plate toughness；It inorganic is filled out due to used
Material is flame retardant type, and flame retardant property of the invention is preferable.
Specific embodiment
Below with reference to embodiment to a kind of ageing-resistant PVC of polyether-ether-ketone keto-resin based on beta-diketon structure of the invention
Plate is further described.It is understood that specific embodiment described herein is used only for explaining related invention, rather than
Restriction to the invention.
Embodiment 1
A kind of polyether-ether-ketone keto-resin A of the structure containing beta-diketon, synthetic method according to parts by weight are as follows:
Under logical condition of nitrogen gas, 20 parts of Isosorbide-5-Nitraes-two are added in the reactor that division box, heating device, agitating device are housed
Hydroxyl phenol, 15 parts of -1,3 propanedione of 1,3- bis- (4- fluorophenyl), 8 parts of potassium carbonate, 65 parts of 2,4- dimethylsulfolanes, 30 parts of first
Benzene is heated to 140 DEG C under stirring, constantly remove the water generated in dereaction by division box, 140 DEG C of insulation reaction 1h, then
Low boiling point solvent is released by water segregator, reaction system is warming up to 195 DEG C, keep the temperature polyase 13 h, have precipitating to analyse in polymerization process
Out, it is cooled to room temperature, 50 parts of methanol are added into system, there is a large amount of Precipitations, filtering precipitating, with deionized water, second at this time
Alcohol washes repeatedly 8 times, and finally 50 DEG C of dryings for 24 hours, must contain the polyether-ether-ketone of beta-diketon structure in vacuum drying oven after grinding
Ketone resin A.
Embodiment 2
A kind of polyether-ether-ketone keto-resin B of the structure containing beta-diketon, synthetic method according to parts by weight are as follows:
Under logical condition of nitrogen gas, 12 part 6 of addition in the reactor that division box, heating device, agitating device are housed, 6 '-
Two (4- hydroxyphenyl) hendecanes, 10 parts of -1,3 propanedione of 1,3- bis- (4- fluorophenyl), 6 parts of potassium carbonate, 60 parts of dimethyl sulfoxides, 35 parts
Benzene is heated to 120 DEG C under stirring, constantly remove the water generated in dereaction by division box, 120 DEG C of insulation reaction 2h, then
Low boiling point solvent is released by water segregator, reaction system is warming up to 185 DEG C, heat preservation polymerization 5h, have precipitating to analyse in polymerization process
Out, it is cooled to room temperature, 40 parts of methanol are added into system, there is a large amount of Precipitations, filtering precipitating, with deionized water, second at this time
Alcohol washes repeatedly 5 times, and finally 50 DEG C of dryings for 24 hours, must contain the polyether-ether-ketone of beta-diketon structure in vacuum drying oven after grinding
Ketone resin B.
Embodiment 3
A kind of polyether-ether-ketone keto-resin C of the structure containing beta-diketon, synthetic method according to parts by weight are as follows:
Under logical condition of nitrogen gas, 15 part 4 of addition in the reactor that division box, heating device, agitating device are housed, 4 '-
Dihydroxybiphenyl, 12 parts of 1,3- bis- (4- fluorophenyl) -1,3 propanedione, 7 parts of potassium carbonate, 61 parts of sulfolane, 32 parts of dodecanes stir
It mixes down and is heated to 130 DEG C, the water generated in dereaction is constantly removed by division box, then 130 DEG C of insulation reaction 1.4h pass through
Water segregator releases low boiling point solvent and reaction system is warming up to 187 DEG C, heat preservation polymerization 4h, has Precipitation in polymerization process, drops
It warms to room temperature, 42 parts of methanol is added into system, there is a large amount of Precipitations at this time, filtering precipitating is repeated with deionized water, ethyl alcohol
Washing 6 times, finally 50 DEG C of dryings for 24 hours, must contain the polyether-ether-ketone keto-resin of beta-diketon structure in vacuum drying oven after grinding
C。
Embodiment 4
A kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure, which is characterized in that in parts by weight
Meter, formula composition are as follows: 90 parts of PVC resin powder, the structure containing beta-diketon 0.6 part of A17 parts of polyether-ether-ketone keto-resin, calcium stearate,
3 parts, 26 parts aluminium-magnesium silicates of powder type titanate coupling agent.
Embodiment 5
A kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure, which is characterized in that in parts by weight
Meter, formula composition are as follows: 100 parts of PVC resin powder, the structure containing beta-diketon 0.8 part of B15 parts of polyether-ether-ketone keto-resin, zinc stearate,
2 parts, 40 parts barium sulfate of powder type titanate coupling agent.
Embodiment 6
A kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure, which is characterized in that in parts by weight
Meter, formula composition are as follows: 0.5 part of C25 parts of polyether-ether-ketone keto-resin, zinc oleate, the powder of 80 parts of PVC resin powder, the structure containing beta-diketon
5 parts, 20 parts calcium silicates of figure titanate coupling agent.
The ageing-resistant PVC board preparation method of polyether-ether-ketone keto-resin of one of the embodiment 4-6 based on beta-diketon structure,
Include the following steps:
A, mixing: weighing each component in good addition batch mixer according to formula composition and heat and stir, batch mixer control temperature
Degree is cooled to 50 ± 5 DEG C after the completion of 145 ± 5 DEG C, 1400 ± 100r/min of mixing speed, 20 ± 2min of mixing time, mixing,
Up to mixture；B, it squeezes out: mixture in a being put into screw extruder, melting extrusion obtains semi-finished product；C, sizing, concora crush:
Semi-finished product are carried out shaping into concora crush；D, Length-fixing cutting: the plate after concora crush of being formed is cut as needed.
By a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure and city made from embodiment 4-6
Certain brand flame-proof PVC plate (comparative example) is sold, is tested for the property under the same conditions, test data such as the following table 1:
Table one: the performance of PVC board
As can be seen from the above table flame retardant property close under conditions of, it is of the present invention a kind of based on beta-diketon structure
Ageing-resistant performance, bending strength, shore hardness and the dimensional stability of the ageing-resistant PVC board of polyether-ether-ketone keto-resin are better than
Commercially available flame-proof PVC plate.
Although the present invention has been explained in detail and has referred to embodiment, for those of ordinary skill in the art, show
Various schemes, modification and the change that can so make as specified above, should be construed as being included within the scope of the claims.
Claims (10)
1. a kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure, which is characterized in that in parts by weight
Meter, formula composition are as follows: 80-100 parts of PVC resin powder, the structure containing beta-diketon 15-25 parts of polyether-ether-ketone keto-resin, calcium zinc divide greatly
Sub- compound stabilizer 0.5-0.8 parts, 2-5 parts of powder type titanate coupling agent, 20-40 parts of inorganic filler.
2. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 1, special
Sign is, the structural formula of the polyether-ether-ketone keto-resin of the structure containing beta-diketon are as follows:
Wherein, R is alkyl or aromatic group, n 80-200.
3. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 1, special
Sign is, according to parts by weight, the synthetic method of the polyether-ether-ketone keto-resin of the structure containing beta-diketon are as follows:
Under logical condition of nitrogen gas, dihydric phenol, 1,3- bis- (4- fluorophenyl) -1 are added in the reactor, 3 propanedione, weak base, dipole are molten
Agent, low boiling point solvent are heated to 120-140 DEG C under stirring, remove water insulation reaction 1-2h, and then releasing low boiling point solvent will be anti-
It answers system to be warming up to 185-195 DEG C, keeps the temperature polyase 13-5h, be cooled to room temperature, methanol is added into system, filtering precipitating is spent
Ionized water, ethyl alcohol repeated washing, finally dry for 24 hours at 50 DEG C, grind to obtain the final product.
4. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 3, special
Sign is, the dihydric phenol is 6,6 '-two (4- hydroxyphenyl) hendecanes, Isosorbide-5-Nitrae-dihydroxy phenol, 4, in 4 '-dihydroxybiphenyls
At least one.
5. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 3, special
Sign is that the weak base is at least one of sodium carbonate, potassium carbonate.
6. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 3, special
Sign is that the dipole solvent is at least one of sulfolane, dimethyl sulfoxide, 2,4- dimethylsulfolane；Described is low
Boiling point solvent is at least one of benzene, toluene, normal octane, dodecane.
7. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 1, special
Sign is that the calcium zinc macromolecular compound stabilizer is calcium stearate, zinc stearate, calcium linoleate, calcium linoleate zinc, oleic acid
At least one of calcium, zinc oleate.
8. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 1, special
Sign is that the powder type titanate coupling agent is monoalkoxy type coupling agent, and structural formula is RO-Ti (OX-R-Y) 3.
9. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 8, special
Sign is that the powder type titanate coupling agent is isopropyl triisostearoyltitanate.
10. a kind of ageing-resistant PVC board of polyether-ether-ketone keto-resin based on beta-diketon structure according to claim 1,
It is characterized in that, the inorganic filler is at least one of aluminium-magnesium silicate, calcium silicates, barium sulfate, titanium dioxide.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011141061.1A CN112143142A (en) | 2018-09-13 | 2018-09-13 | Preparation method of anti-aging PVC (polyvinyl chloride) plate based on polyether-ether-ketone resin with beta-diketone structure |
| CN202011141078.7A CN112142933A (en) | 2018-09-13 | 2018-09-13 | Polyether-ether-ketone resin containing beta-diketone structure and application thereof in anti-aging PVC (polyvinyl chloride) plate |
| CN201811069378.1A CN109280293B (en) | 2018-09-13 | 2018-09-13 | Anti-aging PVC (polyvinyl chloride) plate of polyether-ether-ketone resin based on beta-diketone structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811069378.1A CN109280293B (en) | 2018-09-13 | 2018-09-13 | Anti-aging PVC (polyvinyl chloride) plate of polyether-ether-ketone resin based on beta-diketone structure |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011141061.1A Division CN112143142A (en) | 2018-09-13 | 2018-09-13 | Preparation method of anti-aging PVC (polyvinyl chloride) plate based on polyether-ether-ketone resin with beta-diketone structure |
| CN202011141078.7A Division CN112142933A (en) | 2018-09-13 | 2018-09-13 | Polyether-ether-ketone resin containing beta-diketone structure and application thereof in anti-aging PVC (polyvinyl chloride) plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109280293A true CN109280293A (en) | 2019-01-29 |
| CN109280293B CN109280293B (en) | 2021-08-27 |
Family
ID=65180573
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811069378.1A Active CN109280293B (en) | 2018-09-13 | 2018-09-13 | Anti-aging PVC (polyvinyl chloride) plate of polyether-ether-ketone resin based on beta-diketone structure |
| CN202011141061.1A Withdrawn CN112143142A (en) | 2018-09-13 | 2018-09-13 | Preparation method of anti-aging PVC (polyvinyl chloride) plate based on polyether-ether-ketone resin with beta-diketone structure |
| CN202011141078.7A Withdrawn CN112142933A (en) | 2018-09-13 | 2018-09-13 | Polyether-ether-ketone resin containing beta-diketone structure and application thereof in anti-aging PVC (polyvinyl chloride) plate |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011141061.1A Withdrawn CN112143142A (en) | 2018-09-13 | 2018-09-13 | Preparation method of anti-aging PVC (polyvinyl chloride) plate based on polyether-ether-ketone resin with beta-diketone structure |
| CN202011141078.7A Withdrawn CN112142933A (en) | 2018-09-13 | 2018-09-13 | Polyether-ether-ketone resin containing beta-diketone structure and application thereof in anti-aging PVC (polyvinyl chloride) plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN109280293B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602863A (en) * | 2009-06-22 | 2009-12-16 | 温州天盛塑料助剂有限公司 | The environmental-friendly dust-free calcium-zinc composite heat stabilizer that is used for PVC processing |
| CN104910565A (en) * | 2015-05-12 | 2015-09-16 | 蚌埠市耀得保温容器有限公司 | Impact resistant vacuum flask |
| CN104947915A (en) * | 2015-07-20 | 2015-09-30 | 江苏锐升新材料有限公司 | PVC composite floor with high-temperature resistant and flame-retardant structure and production process thereof |
| CN105330798A (en) * | 2015-11-30 | 2016-02-17 | 江门市优巨新材料有限公司 | Industrialized synthesis method of end-capped polyether-ether-ketone resin |
| WO2017067504A1 (en) * | 2015-10-21 | 2017-04-27 | 大电塑料（上海）有限公司 | Foamed pvc material, preparation method and use thereof |
-
2018
- 2018-09-13 CN CN201811069378.1A patent/CN109280293B/en active Active
- 2018-09-13 CN CN202011141061.1A patent/CN112143142A/en not_active Withdrawn
- 2018-09-13 CN CN202011141078.7A patent/CN112142933A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602863A (en) * | 2009-06-22 | 2009-12-16 | 温州天盛塑料助剂有限公司 | The environmental-friendly dust-free calcium-zinc composite heat stabilizer that is used for PVC processing |
| CN104910565A (en) * | 2015-05-12 | 2015-09-16 | 蚌埠市耀得保温容器有限公司 | Impact resistant vacuum flask |
| CN104947915A (en) * | 2015-07-20 | 2015-09-30 | 江苏锐升新材料有限公司 | PVC composite floor with high-temperature resistant and flame-retardant structure and production process thereof |
| WO2017067504A1 (en) * | 2015-10-21 | 2017-04-27 | 大电塑料（上海）有限公司 | Foamed pvc material, preparation method and use thereof |
| CN105330798A (en) * | 2015-11-30 | 2016-02-17 | 江门市优巨新材料有限公司 | Industrialized synthesis method of end-capped polyether-ether-ketone resin |
Non-Patent Citations (1)
| Title |
|---|
| 晏苏学等: ""β-二酮在钙/锌皂复合稳定剂中的应用"", 《塑料助剂》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112142933A (en) | 2020-12-29 |
| CN109280293B (en) | 2021-08-27 |
| CN112143142A (en) | 2020-12-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20100301286A1 (en) | Flame retarded thermosets | |
| CN103980708B (en) | Halogen-free flame-retardant thermosetting resin composition of integrated circuit, prepreg and laminate | |
| CN101550221A (en) | Resin composition, prepreg and metal-foil-clad laminate | |
| CN103842397A (en) | Resin composition, prepreg, and metal foil-clad laminate | |
| CN105315615A (en) | Epoxy resin composition and prepreg and copper clad laminate manufactured by using epoxy resin composition | |
| CN106147104A (en) | A kind of flame-retarded unsaturated polyester resin and enhancing method of modifying thereof | |
| CN105419348A (en) | Resin composition and presoaking material and laminated board using same | |
| US20140342161A1 (en) | Epoxy Resin Composition and Prepreg and Copper Clad Laminate Manufactured by Using the Same | |
| CN100547033C (en) | Polyphenyl ether resin composition, prepreg and veneer sheet | |
| CN109280293A (en) | A kind of ageing-resistant PVC board of the polyether-ether-ketone keto-resin based on beta-diketon structure | |
| US4237236A (en) | Plastics material and method of producing said material | |
| EP0133600B1 (en) | Epoxy resin and composition | |
| JP2000309623A (en) | Phosphorus-containing flame-retardant epoxy resin | |
| JPS6159330B2 (en) | ||
| CN105440897B (en) | A kind of piano fire-retardant black gel coat and preparation method | |
| EP0869148B1 (en) | Epoxy resin composition and method for producing the same | |
| CN112358798A (en) | Manufacturing method of floor waterproof material | |
| JPS58194952A (en) | Production of flame retarder | |
| TW201641593A (en) | A preparation method for polyphenylene ether micelle dispersion | |
| US6410145B1 (en) | Thermosetting resin composition for build-up | |
| CN109707138B (en) | Multilayer-structure antistatic environment-friendly epoxy resin terrace and preparation method thereof | |
| CN102373621A (en) | Resin varnish composition with high temperature of glass transition for glass fiber laminated plate use | |
| JPS6346100B2 (en) | ||
| JPS63118347A (en) | Polymer blend containing ionometric elastomer | |
| CN114752103A (en) | Formula and process for manufacturing phenolic resin plate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230104 Address after: 063000 North of Huozhuangzi Village, Fengrun Town, Fengrun District, Tangshan City, Hebei Province Patentee after: Tangshan Ouding Technology Co.,Ltd. Address before: 4-1-49, 4 / F, building C5, huangjinchuangye Park, Wangcheng economic and Technological Development Zone, Changsha City, Hunan Province Patentee before: HUNAN CHENLI NEW MATERIAL Co.,Ltd. |
|
| TR01 | Transfer of patent right |