CN109277544A - A method of control high-carbon steel slab internal flaw - Google Patents

A method of control high-carbon steel slab internal flaw Download PDF

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Publication number
CN109277544A
CN109277544A CN201710601103.7A CN201710601103A CN109277544A CN 109277544 A CN109277544 A CN 109277544A CN 201710601103 A CN201710601103 A CN 201710601103A CN 109277544 A CN109277544 A CN 109277544A
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Prior art keywords
carbon steel
cooling
crystallizer
big
force
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CN201710601103.7A
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Chinese (zh)
Inventor
汪洪峰
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Shanghai Meishan Iron and Steel Co Ltd
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Shanghai Meishan Iron and Steel Co Ltd
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Priority to CN201710601103.7A priority Critical patent/CN109277544A/en
Publication of CN109277544A publication Critical patent/CN109277544A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/18Controlling or regulating processes or operations for pouring
    • B22D11/181Controlling or regulating processes or operations for pouring responsive to molten metal level or slag level
    • B22D11/182Controlling or regulating processes or operations for pouring responsive to molten metal level or slag level by measuring temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/1206Accessories for subsequent treating or working cast stock in situ for plastic shaping of strands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/124Accessories for subsequent treating or working cast stock in situ for cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/22Controlling or regulating processes or operations for cooling cast stock or mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/22Controlling or regulating processes or operations for cooling cast stock or mould
    • B22D11/225Controlling or regulating processes or operations for cooling cast stock or mould for secondary cooling

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Abstract

The present invention provides a kind of method for controlling high-carbon steel slab internal flaw.It is cooling by force that the method for the present invention includes (1): including crystallizer, cooling and secondary cooling zone high pressure water is cooled down by force by force;(2) high degree of superheat casting: Metal in Tundish is poured degree of superheat control within the scope of 25 ± 5 DEG C;(3) big soft reduction process state modulator: suitable heavy reduction is 6-10mm;Big depressing position is fs=0.5~0.8;Soft reduction rate is not less than 0.288mm/min, and the big pressure is to give certain mechanical drafts in casting blank solidification end to compensate the volume contraction of molten steel in solidification, reinforces feeding stowage capacity, controls green shell bulge.The present invention can be effectively controlled the internal flaws such as center segregation, center porosity and the underbead crack of high-carbon steel slab, mitigate the banded structure rank of high-carbon steel, so as to improve the mechanical property, forming property and processing performance of high carbon steel sheet.

Description

A method of control high-carbon steel slab internal flaw
Technical field:
The present invention relates to a kind of methods for controlling high-carbon steel slab internal flaw, belong to continuous casting steel billet technique in Ferrous Metallurgy Quality field.
Background technique:
High-quality high-carbon steel is widely used in the fastening of all kinds of tools, grinding tool, mechanical structure, spring, steel wire and middle high intensity The purposes such as part, structural member are a kind of high attached value products, have a vast market foreground.With the hair of industrialization and modernization Exhibition, requirement of the market to high-carbon steel quality are higher and higher, it is desirable that high-carbon steel has poker characteristic uniform, and decarburization is few, and tissue is main It for sorbite, is not allow for martensite and network cementite exists, and desired strength is high, extends, good toughness, to adapt to cold-drawn The needs of journey
High-carbon high-strength steel generally all contains higher carbon content and manganese content, and continuous casting billet is easily formed in process of setting The dendritic segregation of the elements such as carbon, manganese causes steel plate to be centrally formed serious banded structure defect.Mechanics of the banded structure to steel plate Performance, forming property and fracture behaviour can generate significant impact.For cold-rolled steel sheet, the presence of banded structure, it will So that material is shown strong anisotropy energy, causes inhomogeneous deformation when deep processing, i.e., the longitudinal fiber along plate width direction Extend inconsistent, formation secondary deformation, or even in stress raiser crack initiation source, influences the service performance of final products.Cause This, in the segregation that how to mitigate and eliminate continuous casting billet to the maximum extent and generate in process of setting, is that continuous casting is urgently to be resolved Problem.
Domestic common method is using traditional " three-lows " process route at present: i.e. low overheat, low pulling rate, low wash water Continuous casting process increase equiaxed zone ratio, and use soft reduction technique reduce center segregation, but the center segregation of high-carbon high-strength steel, in The heart is loose and the slabs internal flaw such as underbead crack is still very serious.And low pulling rate sets production efficiency lowly with conticaster Standby well damage;Low overheat keeps organization of production and continuous casting difficult;Low wash water is that slab bulge is serious, and green shell is thin, bleed-out Risk is big.
Summary of the invention
The purpose of the present invention is providing a kind of method for controlling high-carbon steel slab internal flaw in view of the above problems, It can be effectively controlled the internal flaws such as center segregation, center porosity and the underbead crack of high-carbon steel slab, mitigate the band-like of high-carbon steel Rank is organized, so as to improve the mechanical property, forming property and processing performance of high carbon steel sheet.Improve high-carbon steel product quality, drop Low engineering safety hidden danger, benefits the country and people.
Above-mentioned purpose is achieved through the following technical solutions:
A method of control high-carbon steel slab internal flaw, this method comprises:
(1) strong cooling: including crystallizer, cooling and secondary cooling zone high pressure water is cooled down by force by force;
(2) high degree of superheat casting: Metal in Tundish is poured degree of superheat control within the scope of 25 ± 5 DEG C;
(3) big soft reduction process state modulator: suitable heavy reduction is 6-10mm;Big depressing position be fs=0.5~ 0.8;Soft reduction rate is not less than 0.288mm/min, and the big pressure is given under certain machinery pressure in casting blank solidification end It measures to compensate the volume contraction of molten steel in solidification, reinforces feeding stowage capacity, control green shell bulge, thus mitigate center porosity journey Degree and and promote the soldering of internal fissure, obtain the effect for increasing the central dense degree of slab.
The method of the control high-carbon steel slab internal flaw, the specific process conditions cooling by force are: knot Brilliant device uses parabolic taper: taper 2.3%/m at crystallizer meniscus, prostomum degree 1.1%/m under crystallizer;Crystallizer is cold But the flow velocity of water, 7-10m/s;It is cold by force using high pressure water that slab goes out under crystallizer secondary cooling after mouth, and high-pressure water pressure 15~ 20bar, high pressure water intensity of cooling 1.5-3.0l/min.
The utility model has the advantages that
1. the " three-lows " technique of existing low overheat, low pulling rate, low wash water, purpose inhibits column crystals growth, in expansion The isometric crystalline region of the heart makes center segregation be distributed in entire isometric crystalline region, rather than central area." the high degree of superheat+strong cooling of the invention The new process of+big pressure ", it is therefore an objective to promote slab center pillar crystals growth processed, slab is made to form columnar crystal structure completely, make Heart segregation point is centrally located in very narrow range, improves the uniformity of steel solute concentration in a thickness direction.
2. can be effectively controlled center segregation, center porosity, the underbead crack etc. of high-carbon steel slab using method of the invention Slab internal flaw, high-carbon steel central segregation of slab rank and high-carbon steel slab underbead crack defect are significantly improved. It is substantially improved using the high-carbon steel slab internal soundness that new process of the present invention produces, mitigation high-carbon steel hot rolled steel plate is band-like significantly Rank is organized, so as to improve the mechanical property, forming property and processing performance of high carbon steel sheet.High-carbon steel product quality is improved, is subtracted Few high-carbon steel slab scrap with product quality objection, increase economic efficiency and product market reputation and occupation rate.
Detailed description of the invention
Fig. 1 degree of superheat is to equiax crystal influence curve.
The cold influence diagram to center segregation of Fig. 2 bis-.
Specific embodiment
With reference to embodiment, the present invention is furture elucidated, it should be understood that following specific embodiments are only used for It is bright the present invention rather than limit the scope of the invention.
A method of control high-carbon steel slab internal flaw, this method comprises:
(1) strong cooling: including crystallizer, cooling and secondary cooling zone high pressure water is cooled down by force by force;The tool cooling by force The process conditions of body are: crystallizer uses parabolic taper: taper 2.3%/m at crystallizer meniscus, prostomum under crystallizer Spend 1.1%/m;The flow velocity of crystallizer cooling water, 7-10m/s;It is strong using high pressure water that slab goes out under crystallizer secondary cooling after mouth It is cold, 15~20bar of high-pressure water pressure, high pressure water intensity of cooling 1.5-3.0l/min.Crystallizer is cooling using moisture film out, solidifies base Thickness of the shell increase by 2 times, casting blank surface temperature drastically reduces to go up again, crystal boundary cementite almost eliminates (by force cold index of cementation be 125, tradition is cooled to > 220).Fig. 2 is the two cold influence castings to center segregation.Base center segregation be and solidification liquid phase socket end The volume of mushy zone is related, this area's liquid metals is reached liquidus temperature, due to volume crystallization, concentrates and releases latent heat of solidification It increases green shell temperature and bulging occurs, in addition volume contraction is wanted in whole crystallization, so contracting once swollen one causes solute mother liquor Flowing, cause center gross segregation aggravate.Therefore with the increase of Water Rate for Secondary Cooling Water, Models For Secondary Dendrite Arm spacing reduces.Because For light section slab, when intensity of cooling is larger, casting blank solidification fast speed easily generates the closely spaced solidified structure of dendrite, So cold strong cold playing the role of refining crystal grain using two.It is provided with simultaneously in solidification end and forces water-spraying control area, Qiang Leng Increase green shell intensity, be compacted slab core, center segregation and loose is greatly improved.
(2) high degree of superheat casting: Metal in Tundish is poured degree of superheat control within the scope of 25 ± 5 DEG C;Target superheat degree 25 DEG C, Fig. 1 is influence of the molten steel overheat to slab Center Equiaxial Crystal area, and the high degree of superheat reduces Center Equiaxial Crystal area.Make center Segregation point is centrally located in very narrow range, improves the uniformity of steel solute concentration in a thickness direction.Can avoid because Inclusion floating is difficult in molten steel caused by pouring temperature is too low, covering slag lack of fusion, in the even casting of middle water-coating port dross The problems such as disconnected.
(3) big soft reduction process state modulator: the big pressure is given under certain machinery pressure in casting blank solidification end It measures to compensate the volume contraction of molten steel in solidification, reinforces feeding stowage capacity, control green shell bulge, thus mitigate center porosity journey Degree and and promote the soldering of internal fissure, obtain the effect for increasing the central dense degree of slab, calculated by SOLIDIFICATION MODEL it is found that most Good big pressure initial position should be at critical feeding solid rate, and optimal pressure final position then should be critical flow solid phase At rate.Less than critical feeding solid rate, therefore depressing will not only be such that center segregation is improved at this time, but also if depress Mutually upstream reflux causes the center solid rate of this position to be promoted rapidly to ambassador's central liquid, once it is more than critical feeding solid rate, Small steel ingot is formed, and center cavity will be filled by interdendritic denseization molten steel and cause serious gross segregation.For high-carbon high strength steel plate Base, suitable heavy reduction are 6-10mm;Big depressing position is fs=0.5~0.8;Soft reduction rate is not less than 0.288mm/min.

Claims (2)

1. a kind of method for controlling high-carbon steel slab internal flaw, it is characterized in that: this method comprises:
(1) strong cooling: including crystallizer, cooling and secondary cooling zone high pressure water is cooled down by force by force;
(2) high degree of superheat casting: Metal in Tundish is poured degree of superheat control within the scope of 25 ± 5 DEG C;
(3) big soft reduction process state modulator: suitable heavy reduction is 6-10mm;Big depressing position is fs=0.5~0.8;Pressure Lower rate is not less than 0.288mm/min, and the big pressure is to give certain mechanical drafts in casting blank solidification end to mend The volume contraction of molten steel in solidification is repaid, feeding stowage capacity is reinforced, controls green shell bulge, thus mitigates center porosity degree and simultaneously The soldering for promoting internal fissure obtains the effect for increasing the central dense degree of slab.
2. the method for control high-carbon steel slab internal flaw according to claim 1, it is characterized in that: the cooling by force Specific process conditions are: crystallizer uses parabolic taper: taper 2.3%/m at crystallizer meniscus, mouth under crystallizer Taper 1.1%/m;The flow velocity of crystallizer cooling water, 7-10m/s;It is strong using high pressure water that slab goes out under crystallizer secondary cooling after mouth It is cold, 15~20bar of high-pressure water pressure, high pressure water intensity of cooling 1.5-3.0l/min.
CN201710601103.7A 2017-07-21 2017-07-21 A method of control high-carbon steel slab internal flaw Pending CN109277544A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111570741A (en) * 2020-04-21 2020-08-25 河钢乐亭钢铁有限公司 Casting blank quality control method combining continuous casting process and soft reduction technology
CN112872307A (en) * 2021-02-26 2021-06-01 日照钢铁控股集团有限公司 Production method for direct casting of high-carbon steel 45Mn
CN113385647A (en) * 2021-06-15 2021-09-14 山西太钢不锈钢股份有限公司 High-carbon high-manganese steel vertical bending type slab continuous casting method
CN117226059A (en) * 2023-11-15 2023-12-15 北京科技大学 Reduction control method for improving macro-segregation and semi-macro-segregation of high-carbon low-alloy steel

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111570741A (en) * 2020-04-21 2020-08-25 河钢乐亭钢铁有限公司 Casting blank quality control method combining continuous casting process and soft reduction technology
CN111570741B (en) * 2020-04-21 2022-01-21 河钢乐亭钢铁有限公司 Casting blank quality control method combining continuous casting process and soft reduction technology
CN112872307A (en) * 2021-02-26 2021-06-01 日照钢铁控股集团有限公司 Production method for direct casting of high-carbon steel 45Mn
CN112872307B (en) * 2021-02-26 2022-07-26 日照钢铁控股集团有限公司 Production method for direct casting of high-carbon steel 45Mn
CN113385647A (en) * 2021-06-15 2021-09-14 山西太钢不锈钢股份有限公司 High-carbon high-manganese steel vertical bending type slab continuous casting method
CN117226059A (en) * 2023-11-15 2023-12-15 北京科技大学 Reduction control method for improving macro-segregation and semi-macro-segregation of high-carbon low-alloy steel
CN117226059B (en) * 2023-11-15 2024-01-26 北京科技大学 Reduction control method for improving macro-segregation and semi-macro-segregation of high-carbon low-alloy steel

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