CN109273796A - A kind of temperature automatically controlled energy storage mould group - Google Patents
A kind of temperature automatically controlled energy storage mould group Download PDFInfo
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- CN109273796A CN109273796A CN201811191972.8A CN201811191972A CN109273796A CN 109273796 A CN109273796 A CN 109273796A CN 201811191972 A CN201811191972 A CN 201811191972A CN 109273796 A CN109273796 A CN 109273796A
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- temperature
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- battery core
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- 238000004146 energy storage Methods 0.000 title claims abstract description 31
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 202
- 239000007788 liquid Substances 0.000 claims abstract description 104
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 101
- 229910052751 metal Inorganic materials 0.000 claims abstract description 37
- 239000002184 metal Substances 0.000 claims abstract description 37
- 238000005452 bending Methods 0.000 claims description 3
- 239000005439 thermosphere Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 2
- 238000005057 refrigeration Methods 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000011217 control strategy Methods 0.000 description 6
- 230000005611 electricity Effects 0.000 description 6
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- 210000004027 cell Anatomy 0.000 description 4
- 238000002309 gasification Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000012782 phase change material Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 238000013528 artificial neural network Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000012983 electrochemical energy storage Methods 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 210000000352 storage cell Anatomy 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/61—Types of temperature control
- H01M10/613—Cooling or keeping cold
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
- H01M10/486—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for measuring temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/63—Control systems
- H01M10/635—Control systems based on ambient temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/655—Solid structures for heat exchange or heat conduction
- H01M10/6552—Closed pipes transferring heat by thermal conductivity or phase transition, e.g. heat pipes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Automation & Control Theory (AREA)
Abstract
The invention discloses a kind of temperature automatically controlled energy storage mould groups, including cabinet (8), controller (3), battery core (6), temperature sensor (2), metal heat-conducting tube (5), flow control instrument (4) and liquid nitrogen source (1)；Battery core is placed in cabinet；Temperature sensor is arranged in battery core, and temperature sensor is used to detect the temperature value of battery core；Temperature sensor is connected with controller；The surface layout of battery core has metal heat-conducting tube；Metal heat-conducting tube is connected by the flow quantity control instrument with liquid nitrogen source；Flow quantity control instrument is used to control the flow velocity and flow of liquid nitrogen；Flow quantity control instrument is controlled by controller.Temperature automatically controlled energy storage mould group of the invention is easy to implement, and refrigeration effect is good, can effective guarantee battery core safe and stable operation.
Description
Technical field
The present invention relates to a kind of temperature automatically controlled energy storage mould groups.
Background technique
In face of increasingly depleted traditional energy and continuous aggravating circumstances, Gao An must be greatly developed by developing New Energy Industry
Entirely, the long-life, high-energy density energy-storage battery.Electrochemical energy storage cell mainly have sodium-sulphur battery, vanadium cell, lead-acid battery,
Lithium ion battery etc., wherein lithium ion battery is the most common electrochemical energy storage cell, has been supplied in mobile phone, laptop etc.
Field.It is well known that the performance of battery and battery temperature are closely related, 50 DEG C of temperatures above can accelerate battery aging, 120 DEG C with
Upper high temperature can then cause battery thermal runaway.
Power-type 48V/100AH battery modules in the present invention have the discharge capability of 0~1000A, maximum 10C electric discharge energy
Power has 100*10=1000A electric current.When battery modules are in high-multiplying power discharge state, the build-in attribute and battery mould of battery
Group is influenced by ambient temperature, and leading to battery, calorific value is very big during discharge, excessively high battery temperature and environment
Temperature will have a direct impact on the performance and service life of entire battery modules.As it can be seen that the internal resistance of cell increases with the decaying of battery performance
Greatly, battery temperature rise increases considerably, and in order to maintain the normal work of battery modules, a kind of automatic cooling temperature control method is to battery mould
The heat dissipation of group is of crucial importance.
The existing battery modules type of cooling mainly has air-cooled, liquid cooling and phase-change material heat absorption etc..As " battery modules are automatic
Change thermal management algorithm " (application number CN201611212606.7), a kind of " heat management device of battery pack " (application number
) etc. CN201620148812.5 patents all use air-cooled this radiating mode, maximum the disadvantage is that radiating efficiency is low, though it has done
To can automatically adjust wind speed, but the temperature difference of air inlet and air outlet is larger, and inside battery wind speed has differences with flow, leads to electricity
Pond internal heat dissipating is unbalanced, it is difficult to solve the problems, such as that battery pack temperature rise is excessively high.
For another example in the patents such as " lithium battery pack " (CN201610895738.8), " battery pack " (CN201120067293.7)
The radiating mode for referring to liquid cooling is required to install complicated liquid circulation lines inside battery modules, also to install in,
The equipment such as outer heat-exchanger and kinetic pump, significantly occupy the space of battery modules, increase the size of battery modules.
Also have and be embedded in patent of the phase-change material heat absorption as heat dissipation channel, such as " a kind of 48V system lithium battery in battery pack
Group power supply heat sinking scheme " (application number CN201710053662.9), a kind of " battery group temperature control system " (application number
CN201610666288.5).It does not need moving component though having for the phase-change material in battery modules heat management system, be not required to
The advantage of the extra consumption energy content of battery is wanted, but in long-term phase transition process, there is also latent heat declines, appearance simultaneously for phase-change material
The disadvantage of mutability, stability difference.
It can be seen that it is really necessary to provide a kind of simplicity, practical temperature automatically controlled energy storage mould group to overcome the prior art
Shortage.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of temperature automatically controlled energy storage mould groups, and of the invention is temperature automatically controlled
Energy storage mould group it is easy to implement, refrigeration effect is good, can effective guarantee battery core safe and stable operation.
Technical solution of the invention is as follows:
A kind of temperature automatically controlled energy storage mould group, including cabinet (8), controller (3), battery core (6), temperature sensor (2), gold
Belong to heat conducting pipe (5), flow control instrument (4) and liquid nitrogen source (1)；Battery core is placed in cabinet；
Temperature sensor is arranged in battery core, and temperature sensor is used to detect the temperature value of battery core；Temperature sensor and control
Device processed is connected；
The surface layout of battery core has metal heat-conducting tube；
Metal heat-conducting tube is connected by the flow quantity control instrument with liquid nitrogen source；Flow quantity control instrument is used to control the stream of liquid nitrogen
Speed and flow；
Flow quantity control instrument is controlled by controller.
Metal heat-conducting layer (7) are equipped on the surface of battery core；The temperature sensor and metal heat-conducting tube is arranged at gold
Belong on heat-conducting layer.
Temperature sensor is multiple.
It is arranged in multiple lines and multiple rows array.As 2 rows 2 in embodiment 1 arrange arrangement.
The controller is MCU.
The U-shaped bending of metal heat-conducting tube is attached on metal heat-conducting layer.
For controller using the temperature value of the battery core detected as feedback quantity, the temperature of battery core drops in the flow velocity by controlling liquid nitrogen
Into default temperature.
Implement to control using Discrete control mode:
Default 5 temperature value T1~T5 and 5 liquid nitrogen flow speed value F1~F5；
(1) as battery core temperature Th< T1, the closing of flow quantity control instrument valve；
(2) if T1≤Th< T2When, flow quantity control instrument is opened, and release liquid nitrogen flow velocity is F1；
(3)T2≤Th< T3When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,2；
(4)T3≤Th< T4When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,3；
(5)T4≤Th< T5When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,4；
(6)Th≥T5When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,5。
T1≤40 DEG C, T2 value interval be (40 DEG C, 50 DEG C], T3 value interval be (50 DEG C, 60 DEG C] T4 value interval is
(60 DEG C, 70 DEG C]；T5>70℃.
The value interval of F1≤1, F2 be (1,5], the value interval of F3 be (5,10], the value interval of F4 be (10,15],
F5 >=20, unit are cm3/s。
Work as ThRoll back T1-T5In corresponding range, then discharges flow and be reduced to analog value or close flow valve.
This system can also be using PID control strategy or fuzzy control strategy or Control Strategy with Neural Network.
The liquid nitrogen source is fluid reservoir, stores low temperature liquid nitrogen in tank, is connect with flow quantity control instrument by conduit.
The conduit is attached to heat-conducting layer and battery modules upper surface, side and lower surface is bent to U respectively from top to bottom
Type surrounds mould group, is finally discharged in mould group bottom.
The temperature detecting unit includes multiple temperature sensors, using multi way temperature monitor mode, acquires each group battery core
Temperature.
Lithium ion battery cell is multiple groups, such as 4 groups.
The temperature detecting unit is temperature sensor, for monitoring battery core multi-point temperature in real time, implements multi way temperature prison
Detected temperature information is fed back to control unit while control.
Described control unit is processing controller, and storage inside has 5 temperature threshold T1、T2、T3、T4、T5(respectively 40,
50,60,70,80 DEG C), and alignment programs are set, by the maximum temperature T in the single group battery core of temperature detecting unit feedbackhWith T1-
T5Comparison assigns instruction to the liquid nitrogen of execution unit release corresponding discharge.
The execution unit is flow quantity control instrument, discharges different flow F in real time according to the instruction of control unit1-F5(respectively
For 1,5,10,15,20cm3/ s) liquid nitrogen.
The liquid nitrogen source is fluid reservoir, stores low temperature liquid nitrogen in tank, is connect with flow quantity control instrument by conduit.
The metal heat-conducting layer can radiate but also protect battery core, and conduit is attached to heat-conducting layer from top to bottom for battery modules
Upper surface, side and lower surface bend to U-shaped respectively, and mould group is surrounded, and are finally discharged in mould group bottom.
Another technical solution of the invention is that on above-mentioned basis, the temperature detecting unit includes at least four temperature
Sensor is spent, using multi way temperature monitor mode, the temperature of each group battery core is acquired, effectively avoids single group battery core temperature excessively high and drop
The performance of low entirety energy storage mould group.
The flow quantity control instrument discharges the liquid nitrogen of different flow with battery core temperature fluctuation, can be effectively controlled temperature and is pacifying
Total temperature range and save liquid nitrogen source.
Another technical solution of the invention is that on above-mentioned basis, the controller storage compares temperature T1-T5With phase
Answer liquid nitrogen flow F1-F5It tests all in accordance with 48V100Ah lithium ion battery actual discharge and is determined jointly with theoretical calculation, is specifically shown in attached
Scheme explanation.Under different battery modules and different ambient temperature conditions, T is different from F corresponding relationship.
Another technical solution of the invention is that on above-mentioned basis, the liquid nitrogen source is using colourless, odorless, nothing
The liquid nitrogen of corrosivity, non-combustible and temperature extremely low (- 196 DEG C), is greatly improved the safety of energy storage mould group, and extremely low liquid
Nitrogen temperature, which can be effectively reduced, crosses high temperature rise caused by energy storage mould group high-multiplying power discharge.
The utility model has the advantages that
The present invention proposes a kind of temperature automatically controlled energy storage mould group, and the energy storage mould group further includes lithium ion battery cell, gold
Belong to heat-conducting layer and cabinet, the temperature detecting unit is temperature sensor, and described control unit is processing controller, storage inside
There are multiple temperature thresholds, the execution unit is flow quantity control instrument, discharges different flow in real time according to the instruction of control unit
Liquid nitrogen, the liquid nitrogen source are fluid reservoir, are connect with flow quantity control instrument by conduit, the conduit is attached to heat-conducting layer from top to bottom
Battery modules upper surface, side and lower surface are bent to respectively U-shaped, the temperature detecting unit includes multiple temperature sensing
Device, using multi way temperature monitor mode.Energy storage mould group of the present invention has that multipoint temperature monitoring, temperature control be timely and effective, liquid nitrogen
The features such as consumption is low.
Detailed description of the invention
Fig. 1 is the general structure schematic diagram of temperature automatically controlled energy storage mould group.
Label declaration: 1- liquid nitrogen source, 2- temperature sensor, 3- controller, 4- flow quantity control instrument, 5- metal heat-conducting tube, 6-
Battery core, 7- metal heat-conducting layer, 8- cabinet.
Specific embodiment
The present invention is described in further details below with reference to the drawings and specific embodiments:
Embodiment 1: such as Fig. 1, a kind of temperature automatically controlled energy storage mould group, including cabinet 8, controller 3, battery core 6, temperature sensing
Device 2, metal heat-conducting tube 5, flow control instrument 4 and liquid nitrogen source 1；Battery core is placed in cabinet；
Temperature sensor is arranged in battery core, and temperature sensor is used to detect the temperature value of battery core；Temperature sensor and control
Device processed is connected；
The surface layout of battery core has metal heat-conducting tube；
Metal heat-conducting tube is connected by the flow quantity control instrument with liquid nitrogen source；Flow quantity control instrument is used to control the stream of liquid nitrogen
Speed and flow；
Flow quantity control instrument is controlled by controller.
Metal heat-conducting layer 7 is equipped on the surface of battery core；The temperature sensor and metal heat-conducting tube is arranged at metal
On heat-conducting layer.
Temperature sensor is multiple.
It is arranged in multiple lines and multiple rows array.As 2 rows 2 in embodiment 1 arrange arrangement.
The controller is MCU.
The U-shaped bending of metal heat-conducting tube is attached on metal heat-conducting layer.
For controller using the temperature value of the battery core detected as feedback quantity, the temperature of battery core drops in the flow velocity by controlling liquid nitrogen
Into default temperature.
Implement to control using Discrete control mode:
Default 5 temperature value T1~T5 and 5 liquid nitrogen flow speed value F1~F5；
(1) as battery core temperature Th< T1, the closing of flow quantity control instrument valve；
(2) if T1≤Th< T2When, flow quantity control instrument is opened, and release liquid nitrogen flow velocity is F1；
(3)T2≤Th< T3When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,2；
(4)T3≤Th< T4When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,3；
(5)T4≤Th< T5When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,4；
(6)Th≥T5When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,5。
T1≤40 DEG C, T2 value interval be (40 DEG C, 50 DEG C], T3 value interval be (50 DEG C, 60 DEG C] T4 value interval is
(60 DEG C, 70 DEG C]；T5>70℃.
The value interval of F1≤1, F2 be (1,5], the value interval of F3 be (5,10], the value interval of F4 be (10,15],
F5 >=20, unit are cm3/s。
This system can also be using PID control strategy or fuzzy control strategy or Control Strategy with Neural Network.
A kind of automatic temperature-controlled method of energy storage mould group, battery core is placed in cabinet；Temperature sensor is arranged in battery core,
Temperature sensor is used to detect the temperature value of battery core；The battery core temperature value of temperature sensor detection is sent in controller as anti-
Feedback amount；
The surface layout of battery core has metal heat-conducting tube；
Metal heat-conducting tube is connected by the flow quantity control instrument with liquid nitrogen source；Flow quantity control instrument is used to control the stream of liquid nitrogen
Speed makes the surface cooling of battery core；
Flow quantity control instrument is controlled by controller as the executing agency of control system.
Metal heat-conducting layer (7) are equipped on the surface of battery core；The temperature sensor and metal heat-conducting tube is arranged at gold
Belong on heat-conducting layer.
Temperature sensor be it is multiple so as to improve detection temperature value reliability (in use, taking maximum temperature value conduct
Value of feedback).
Temperature automatically controlled energy storage mould group, including 1,4 temperature sensor 2 of liquid nitrogen source, controller 3, flow quantity control instrument 4, gold
Belong to 5, four groups of battery cores 6 of heat conducting pipe, metal heat-conducting layer 7 and cabinet 8.Liquid nitrogen source 1 is the steel cylinder for containing liquid nitrogen, and liquid nitrogen source picks out one
Metal heat-conducting tube 5, the intracorporal flow quantity control instrument 4 of 5 connecting box of metal heat-conducting tube, flow quantity control instrument 4 and controller 3 and 4 temperature
Sensor 2 is spent to connect.The upper and lower surfaces of the covering battery modules of metal heat-conducting tube 5 and a side, it is U-shaped on each face
It is close to metal heat-conducting layer 7, is finally pierced by cabinet 8 in 6 lower surface of battery core.
The temperature sensor 2 monitors the temperature of four groups of battery cores 6 in real time, and the temperature information of every group of battery core all can Real-time Feedback
To controller 3.
After the controller 3 receives temperature information, alignment programs are executed.By highest temperature T thereinhInside controller 3
5 temperature threshold T of storage1=40 DEG C, T2=50 DEG C, T3=60 DEG C, T4=70 DEG C, T5=80 DEG C compare.When battery charge and discharge
Electricity and when generating heat, will lead to module temperature raising, when temperature reaches a certain threshold value, after via controller 3 judges, assigning is
The instruction of no release liquid nitrogen and corresponding discharge is to flow quantity control instrument 4.
The flow quantity control instrument 4 discharges the corresponding relationship of liquid nitrogen flow and temperature threshold are as follows:
(1) when battery modules do not carry out charge and discharge, initial temperature T0It is 20 DEG C, flow quantity control instrument 4 is closed at this time.
(2) when battery modules carry out charge and discharge, module temperature starts to increase.Highest temperature T in four groups of 6 temperature of battery coreh
< T1, 4 valve of flow quantity control instrument still closes；
(3) if temperature increases, T1≤Th< T2When, flow quantity control instrument 4 is opened, and release liquid nitrogen flow is F1=1cm3/s；
(4)T2≤Th< T3When, it is F that flow quantity control instrument 4, which controls liquid nitrogen flow,2=5cm3/s；
(5)T3≤Th< T4When, it is F that flow quantity control instrument 4, which controls liquid nitrogen flow,3=10cm3/s；
(6)T4≤Th< T5When, it is F that flow quantity control instrument 4, which controls liquid nitrogen flow,4=15cm3/s；
(7)Th≥T5When, it is F that flow quantity control instrument 4, which controls liquid nitrogen flow,5=20cm3/s。
(8) work as ThRoll back T1-T5In corresponding range, then discharges flow and be reduced to analog value or close flow valve.
On the basis of the above embodiments, table 1 is the actual temperature of mould group, practical temperature rise, theory under different discharge-rates
The corresponding relationship of temperature rise and theoretical liquid nitrogen flow.It is steeply risen since big multiplying power discharging will lead to module temperature, more than battery
Safe operating temperature, thus only 1,2, the decentralization electrical measurement of 3C multiplying power obtain actual temperature and practical temperature rise, wherein temperature measurement value
It is consistent with calculated value.The theoretical liquid nitrogen flow calculated under each multiplying power can neutralize the heat that battery is released under the multiplying power just
Amount.
On the basis of the above embodiments, when battery modules are discharged under 1C multiplying power, temperature sensor 2 measures each group electricity
Core temperature simultaneously feeds back information to controller 3, wherein 6 maximum temperature T of battery coreh=30 DEG C.Because of Th<T1, then flow quantity control instrument is still protected
Hold closing.
On the basis of the above embodiments, when battery modules are discharged under 2C multiplying power, temperature sensor 2 measures each group electricity
6 temperature of core simultaneously feeds back information to controller 3.Work as ThAt=40 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, flow control
It is F that instrument 4 processed, which is opened and discharges flow,1=1cm3The liquid nitrogen of/s is discharged after liquid nitrogen gasification heat absorption.Due to F1Greater than under 2C multiplying power
Theoretical liquid nitrogen flow, so ThIt will not continue to rise after reaching 40 DEG C, but decline, work as ThFlow valve is closed after < 40 DEG C, so
Repeatedly, mould group maximum temperature is controlled always at 40 DEG C.
On the basis of the above embodiments, when battery modules are discharged under 6C multiplying power, temperature sensor 2 measures each group electricity
6 temperature of core simultaneously feeds back information to controller 3.Work as ThAt=40 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, flow control
It is F that instrument 4 processed, which is opened and discharges flow,1=1cm3The liquid nitrogen of/s is discharged after liquid nitrogen gasification heat absorption.Due to F1Less than under 6C multiplying power
Theoretical liquid nitrogen flow, temperature continue to increase.Work as ThAt=50 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, it is desirable that flow
Controller 4 increases liquid nitrogen flow, and liquid nitrogen flow is F at this time2=5cm3/ s, still less than liquid nitrogen flow theoretical under the multiplying power, temperature
Continue to increase.Work as ThAt=60 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, it is desirable that flow quantity control instrument 4 increases liquid nitrogen stream
It measures to F3=10cm3/ s, the flow are greater than the theoretical flow temperature decline under 6C multiplying power, work as ThLiquid nitrogen flow when dropping to 50 DEG C
It is decreased to F2, temperature increases again.Repeatedly, maximum temperature ThFinal control is at 50-60 DEG C.
On the basis of the above embodiments, when battery modules are discharged under 9C multiplying power, temperature sensor 2 measures each group electricity
6 temperature of core simultaneously feeds back information to controller 3.Work as ThAt=40 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, flow control
It is F that instrument 4 processed, which is opened and discharges flow,1=1cm3The liquid nitrogen of/s is discharged after liquid nitrogen gasification heat absorption.Due to F1Less than under 9C multiplying power
Theoretical liquid nitrogen flow 14.8cm3/ s, temperature continue to increase.Work as ThAt=50 DEG C, controller 3, which is assigned, to be instructed to flow quantity control instrument 4,
It is required that flow quantity control instrument 4 increases liquid nitrogen flow, liquid nitrogen flow is F at this time2=5cm3/ s, still less than liquid nitrogen theoretical under the multiplying power
Flow, temperature continue to increase.Work as ThAt=60 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, it is desirable that flow quantity control instrument 4 adds
Big liquid nitrogen flow is to F3=10cm3/ s, the flow continue to increase still less than the theoretical liquid nitrogen flow under the multiplying power, temperature.Work as ThIt rises
At up to 70 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, it is desirable that flow quantity control instrument 4 increases liquid nitrogen flow to F4=
15cm3/ s, flow is greater than theoretical liquid nitrogen flow under the multiplying power at this time, so final battery modules maximum temperature control is in 60-70
℃。
On the basis of the above embodiments, when battery modules are discharged under 10C multiplying power, temperature sensor 2 measures each group
6 temperature of battery core simultaneously feeds back information to controller 3.Work as ThAt=40 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, flow
It is F that controller 4, which is opened and discharges flow,1=1cm3The liquid nitrogen of/s is discharged after liquid nitrogen gasification heat absorption.Due to F1Less than under 10C multiplying power
Theoretical liquid nitrogen flow 18.27cm3/ s, temperature continue to increase.Work as ThAt=50 DEG C, controller 3 assigns instruction to flow quantity control instrument
4, it is desirable that flow quantity control instrument 4 increases liquid nitrogen flow, and liquid nitrogen flow is F at this time2=5cm3/ s, still less than liquid theoretical under the multiplying power
Nitrogen flow, temperature continue to increase.Work as ThAt=60 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, it is desirable that flow quantity control instrument 4
Liquid nitrogen flow is increased to F3=10cm3/ s, the flow continue to increase still less than the theoretical liquid nitrogen flow under the multiplying power, temperature.Work as Th
At=70 DEG C, controller 3 assigns instruction to flow quantity control instrument 4, it is desirable that flow quantity control instrument 4 increases liquid nitrogen flow to F4=15cm3/
S, flow continues to increase still less than liquid nitrogen flow theoretical under the multiplying power, temperature at this time.Work as ThWhen being increased to 80 DEG C, under controller 3
Up to instruction to flow quantity control instrument 4, it is desirable that flow quantity control instrument 4 increases liquid nitrogen flow to F5=20cm3/ s, liquid nitrogen flow is greater than at this time
Theoretical liquid nitrogen flow, temperature are begun to decline under the multiplying power.Under discharging under 10C multiplying power, battery modules maximum temperature ThFinal control
At 70-80 DEG C.
Table 1.
The advantages of can be seen that the temperature automatically controlled mould group in conjunction with the detailed description of above example is: multipoint temperature monitoring
It can guarantee that each group battery core all controls in safe temperature range；Big multiplying power discharging will lead to the huge heat of energy storage mould group generation and lead
It causes temperature rise huge, the huge heat of mould group generation can be neutralized as coolant using liquid nitrogen；Flow quantity control instrument is with battery core temperature
Degree rises and falls and discharges the liquid nitrogen of different flow, can be effectively controlled temperature in safe temperature range and saves liquid nitrogen.
Claims (10)
1. a kind of temperature automatically controlled energy storage mould group, which is characterized in that passed including cabinet (8), controller (3), battery core (6), temperature
Sensor (2), metal heat-conducting tube (5), flow control instrument (4) and liquid nitrogen source (1)；Battery core is placed in cabinet；
Temperature sensor is arranged in battery core, and temperature sensor is used to detect the temperature value of battery core；Temperature sensor and controller
It is connected；
The surface layout of battery core has metal heat-conducting tube；
Metal heat-conducting tube is connected by the flow quantity control instrument with liquid nitrogen source；Flow quantity control instrument be used to control the flow velocity of liquid nitrogen with
Flow；
Flow quantity control instrument is controlled by controller.
2. temperature automatically controlled energy storage mould group according to claim 1, which is characterized in that led on the surface of battery core equipped with metal
Thermosphere (7)；The temperature sensor and metal heat-conducting tube is arranged on metal heat-conducting layer.
3. temperature automatically controlled energy storage mould group according to claim 1, which is characterized in that temperature sensor is multiple.
4. temperature automatically controlled energy storage mould group according to claim 3, which is characterized in that be arranged in multiple lines and multiple rows array.
5. temperature automatically controlled energy storage mould group according to claim 1, which is characterized in that the controller is MCU.
6. temperature automatically controlled energy storage mould group according to claim 2, which is characterized in that the U-shaped bending of metal heat-conducting tube is attached
On metal heat-conducting layer.
7. temperature automatically controlled energy storage mould group according to claim 1-6, which is characterized in that controller is to detect
For the temperature value of battery core as feedback quantity, the flow velocity by controlling liquid nitrogen drops to the temperature of battery core within the scope of default temperature.
8. temperature automatically controlled energy storage mould group according to claim 7, which is characterized in that implement control using Discrete control mode
System:
Default 5 temperature value T1~T5 and 5 liquid nitrogen flow speed value F1~F5；
(1) as battery core temperature Th< T1, the closing of flow quantity control instrument valve；
(2) if T1≤Th< T2When, flow quantity control instrument is opened, and release liquid nitrogen flow velocity is F1；
(3)T2≤Th< T3When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,2；
(4)T3≤Th< T4When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,3；
(5)T4≤Th< T5When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,4；
(6)Th≥T5When, it is F that flow quantity control instrument, which controls liquid nitrogen flow velocity,5。
9. temperature automatically controlled energy storage mould group according to claim 8, which is characterized in that T1≤40 DEG C, T2 value interval are
(40 DEG C, 50 DEG C], T3 value interval be (50 DEG C, 60 DEG C] T4 value interval be (60 DEG C, 70 DEG C]；T5>70℃.
10. temperature automatically controlled energy storage mould group according to claim 9, which is characterized in that the value interval of F1≤1, F2 is
(1,5], the value interval of F3 be (5,10], the value interval of F4 be (10,15], F5 >=20, unit is cm3/s。
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111509332A (en) * | 2019-05-07 | 2020-08-07 | 国网电力科学研究院武汉南瑞有限责任公司 | Temperature control method for lithium battery module |
| US20230115830A1 (en) * | 2021-10-12 | 2023-04-13 | Thru Tubing Solutions, Inc. | Electrical power generation system with battery temperature regulation |
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| CN104716396A (en) * | 2013-12-11 | 2015-06-17 | 观致汽车有限公司 | Cooling system of power battery pack for vehicle |
| CN107565075A (en) * | 2017-09-13 | 2018-01-09 | 华霆（合肥）动力技术有限公司 | Rectangular cell module and thermal management algorithm |
| CN108091959A (en) * | 2017-11-15 | 2018-05-29 | 浙江衡远新能源科技有限公司 | A kind of power battery pack thermal runaway control system and method |
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| WO2012040022A2 (en) * | 2010-09-23 | 2012-03-29 | Magna E-Car Systems Of America, Inc. | Thermal management system for battery electric vehicle |
| CN102760920A (en) * | 2011-04-29 | 2012-10-31 | 肖克建 | Liquid-nitrogen cooling method and device for automotive power battery pack |
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| CN111509332B (en) * | 2019-05-07 | 2021-08-24 | 国网电力科学研究院武汉南瑞有限责任公司 | Temperature control method for lithium battery module |
| US20230115830A1 (en) * | 2021-10-12 | 2023-04-13 | Thru Tubing Solutions, Inc. | Electrical power generation system with battery temperature regulation |
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Application publication date: 20190125 |