CN109267083A - A kind of comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage - Google Patents
A kind of comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage Download PDFInfo
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- CN109267083A CN109267083A CN201811038127.7A CN201811038127A CN109267083A CN 109267083 A CN109267083 A CN 109267083A CN 201811038127 A CN201811038127 A CN 201811038127A CN 109267083 A CN109267083 A CN 109267083A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0015—Organic compounds; Solutions thereof
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03D—WIND MOTORS
- F03D9/00—Adaptations of wind motors for special use; Combinations of wind motors with apparatus driven thereby; Wind motors specially adapted for installation in particular locations
- F03D9/20—Wind motors characterised by the driven apparatus
- F03D9/25—Wind motors characterised by the driven apparatus the apparatus being an electrical generator
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/70—Wind energy
- Y02E10/72—Wind turbines with rotation axis in wind direction
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Sustainable Energy (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Power Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
Abstract
This application discloses a kind of comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage, device for preparing hydrogen, for being hydrogen and oxygen by water electrolysis;Gas fractionation unit and or drying device, connect with the device for preparing hydrogen, for by the hydrogen and the oxygen separation and or drying process;Gas pressurized device, with the gas fractionation unit and or the drying device connect, for be the hydrogen pressurization;Fixed bed hydrogenation reaction unit is connect with the gas pressurized device, for merging the pressurized hydrogen with the organic liquor in the fixed bed hydrogenation reaction unit, obtains hydrogenation organic liquor hydrogen storage material;Wind power generation plant is connect, for powering with the device for preparing hydrogen;Electricity generation system is connect, for generating electricity with the fixed bed hydrogenation reaction unit.Electricity can be transported to the waste for avoiding electric power resource everywhere.
Description
Technical field
This application involves power generator technical field, more particularly to a kind of using wind energy hydrogen manufacturing and organic liquid hydrogen storage
Comprehensive generating system.
Background technique
Currently, China has become, global wind-power electricity generation is largest, fastest-rising market.But more than half China
Wind energy all fail effective exploitation utilization, wind energy also cannot store directly.Wind-driven generator electric energy it is grid-connected, it is especially large-scale
The problem of the electricity generation grid-connecting of wind power plant is there are also to be solved, including construction cost, cost of equipment maintenance, core component stability
The problems such as.In addition, wind-power electricity generation is influenced by the various uncontrollable factors of nature, and it is highly unstable, to the safe power supply of power grid
Greater impact is caused, is limited with the energy output that wind-power electricity generation is basic power-supply system by severe short-term and seasonal variety
System.Therefore, wind-powered electricity generation can not be transported to the waste for directly contributing a large amount of electric power resources everywhere as conventional electric power generation.Meanwhile it is existing
Each there are certain deficiencies in some hydrogen memory technologies, comprising: there are hydrogen-storage density is low and security risk is asked for high-pressure hydrogen storing
Topic;The problem that energy consumption is high for cryogenic liquid hydrogen storage technology, hydrogen storage is at high cost;Then there is unstable, Bu Nengchi in hydride hydrogen-storing
Continuous the problem of using.
Summary of the invention
(1) technical problems to be solved:
The purpose of the present invention is to propose to a kind of comprehensive generating systems using wind energy hydrogen manufacturing and organic liquid hydrogen storage, solve length
Distance transmit electric power increased costs the problem of.
(2) technical solution:
In order to solve the above-mentioned technical problem, this application provides a kind of synthesis using wind energy hydrogen manufacturing and organic liquid hydrogen storage
Electricity generation system comprising: device for preparing hydrogen, for being hydrogen and oxygen by water electrolysis;Gas fractionation unit and or drying
Device is connect with the device for preparing hydrogen, for by the hydrogen and the oxygen separation and or drying process;Gas
Body supercharging device, with the gas fractionation unit and or the drying device connect, for be the hydrogen pressurization;It is fixed
Bed hydroprocessing reaction unit is connect with the gas pressurized device, for adding the pressurized hydrogen with the fixed bed
Organic liquor fusion in hydrogen reaction unit, obtains hydrogenation organic liquor hydrogen storage material;Wind power generation plant, with the electrolysis water system
Hydrogen production device connection, for powering;Electricity generation system is connect, for generating electricity with the fixed bed hydrogenation reaction unit.
In one embodiment, optionally, further include normal temperature and pressure accumulating tank, be located at the electricity generation system and described solid
It between fixed bed hydrogenation reaction device, and is connect with the fixed bed hydrogenation reaction unit and the electricity generation system, for storing
State hydrogenation organic liquor hydrogen storage material.
It in one embodiment, optionally, further include control device, with the wind power generation plant, the electrolysis water
Device for producing hydrogen, the gas fractionation unit and or the drying device, the gas pressurized device, the fixed bed hydrogenation it is anti-
Answer device to connect, for control the wind power generation plant, the device for preparing hydrogen, the gas fractionation unit and or
The opening and closing of the drying device, the gas pressurized device, the fixed bed hydrogenation reaction unit.
In one embodiment, optionally, the electricity generation system includes first device and fixed-bed dehydrogenation reaction unit;Institute
It states fixed-bed dehydrogenation reaction unit and the room temperature pressure accumulating tank connect, for by the institute hydrogenated in organic liquor hydrogen storage material
State hydrogen abjection;The fixed-bed dehydrogenation reaction unit is connect with the first device, for providing combustion for the first device
Material, so that the first device generates electricity.
In one embodiment, optionally, the first device is hydrogen internal combustion engine or fuel cell power supply.
In one embodiment, optionally, the wind power generation plant also with the gas fractionation unit and or it is described dry
Dry device, the gas pressurized device, fixed bed hydrogenation reaction unit connection are for powering.
(3) the utility model has the advantages that
The technical solution of the application, by device for preparing hydrogen by water electrolysis be hydrogen and oxygen, gas fractionation unit
With or drying device by hydrogen and oxygen separation and or drying process, gas pressurized device be hydrogen pressurization, fixed bed hydrogenation
Reaction unit merges pressurized hydrogen with the organic liquor in fixed bed hydrogenation reaction unit, obtains hydrogenation organic liquor hydrogen storage material
Material, electricity generation system are generated electricity using hydrogenation organic liquor hydrogen storage material, and electricity can be transported to the waste for avoiding electric power resource everywhere.
According to the accompanying drawings to the detailed description of the specific embodiment of the application, those skilled in the art will be more
Above-mentioned and other purposes, the advantages and features of the application are illustrated.
Detailed description of the invention
Some specific embodiments of the application are described in detail by way of example and not limitation with reference to the accompanying drawings hereinafter.
Identical appended drawing reference denotes same or similar part or part in attached drawing.It should be appreciated by those skilled in the art that these
What attached drawing was not necessarily drawn to scale.In attached drawing:
Fig. 1 is the comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage according to the application one embodiment
Structural block diagram.
Appended drawing reference:
1, wind power generation plant;
2, device for preparing hydrogen;
3, gas fractionation unit and or drying device;
4, gas pressurized device;
5, fixed bed hydrogenation reaction unit;
6, normal temperature and pressure accumulating tank;
7, control device;
8, first device;
9, electricity generation system;
10, fixed-bed dehydrogenation reaction unit.
Specific embodiment
Below by specific embodiment combination attached drawing, the application is described in further detail.Following embodiment is used for
Illustrate the application, but is not limited to scope of the present application.
In the description of the present application, it should be noted that unless there are specific regulation and limitation, term " installation ", " phase
Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can
To be mechanical connection, it is also possible to be electrically connected;It can be and be directly connected to, can also be indirectly connected with by intermediary.It can be
Connection inside two elements." first " " second " " third " " the 4th " does not represent any sequence relation, merely for convenience
The differentiation carried out is described.For those of ordinary skill in the art, above-mentioned term can be understood in this application with concrete condition
Concrete meaning.
The problem of increasing due to current long distance delivery power cost, the application, which provides, utilizes wind energy hydrogen manufacturing and organic liquid
The comprehensive generating system of hydrogen storage.
Product etc. will be described in detail by basic engineering, extension design and alternative design below.
Embodiment 1:
As shown in Figure 1, a kind of comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage, by water electrolysis hydrogen production
Device 2, gas fractionation unit and or drying device 3, gas pressurized device 4, fixed bed hydrogenation reaction unit 5 and electricity generation system 9
It constitutes, wherein the device for preparing hydrogen 2, for being hydrogen and oxygen by water electrolysis.The gas fractionation unit and or
The drying device 3 is connect with the device for preparing hydrogen 2, for by the hydrogen and the oxygen separation and or it is dry
Dry processing.The gas pressurized device 4, with the gas fractionation unit and or the drying device 3 connect, for for institute
State hydrogen pressurization.The fixed bed hydrogenation reaction unit 5 is connect with the gas pressurized device 4, is used for pressurized institute
It states hydrogen to merge with the organic liquor in the fixed bed hydrogenation reaction unit 5, obtains hydrogenation organic liquor hydrogen storage material.The power generation
System 9 is connect, for generating electricity with the fixed bed hydrogenation reaction unit 5.Electricity can be transported to everywhere, avoid electric power resource
Waste.Using powered by wind energy abundant, using wind energy water electrolysis hydrogen production-organic liquid hydrogen storage-fuel cell (hydrogen internal combustion engine),
On the one hand solve the problems, such as that the electric power from far-off regions of wind energy enrichment can not be effectively grid-connected, on the other hand but also Hydrogen Energy is storing
It is ensured with the safety problem in transportational process, clean and environmental protection, so that energy utilization rate is substantially improved.
Gas derives from the electric power that wind power plant cannot be grid-connected and carries out obtained by electrolysis water, not additional energy consumption.In addition, having
Machine liquid hydrogen storage material is made of according to a certain percentage N- ethyl carbazole, N- ethylindole and 6- methylquinoline, belongs to eutectic
Mixture, fusing point is low, and boiling point is high, and hydrogen storage content is high, is advantageously used for its storage, transport and recycling in the entire system, with
Internal combustion engine or fuel battery combination can become stable power supply system, solve the problems, such as that wind-power electricity generation can not be grid-connected, avoid
The significant wastages of wind power resources.
In this embodiment, optionally, the device for preparing hydrogen 2 is existing device for preparing hydrogen, the gas
Body separator and or the drying device 3 be existing gas fractionation unit and or drying device, gas boosting dress
4 are set as existing gas pressurized device, the fixed bed hydrogenation reaction unit 5 is existing fixed bed hydrogenation reaction unit, institute
Stating electricity generation system 9 is existing electricity generation system.
Embodiment 2:
As shown in Figure 1, the embodiment is increased new design on the basis of embodiment 1, to solve existing hydrogen storage
There are certain deficiencies for technology, such as: high-pressure hydrogen storing has that hydrogen-storage density is low and security risk;Cryogenic liquid hydrogen storage skill
The problem that energy consumption is high for art, hydrogen storage is at high cost;Then there is the problem of unstable, use cannot be continued in hydride hydrogen-storing.
Optionally, the normal temperature and pressure accumulating tank 6 is located at the electricity generation system 9 and fixed bed hydrogenation reaction dress
It sets between 5, and is connect with the fixed bed hydrogenation reaction unit 5 and the electricity generation system 9, for storing the hydrogenation organic liquor
Hydrogen storage material.
It is low in cost, stable, can hold by hydrogenating organic liquor hydrogen storage material described in 6 storage and transportation of normal temperature and pressure accumulating tank
It is continuous to use.
Herein it should be understood that the normal temperature and pressure accumulating tank 6 is existing normal temperature and pressure accumulating tank, the room temperature is normal
Pressure accumulating tank 6 is also possible to normal temperature and pressure storage and transportation pipeline.
Embodiment 3:
As shown in Figure 1, the embodiment is increased new design on the basis of embodiment 1, in order to realize each device
Power supply, wind power generation plant 1, respectively with the device for preparing hydrogen 2, the gas fractionation unit and or the drying
Device 3, the gas pressurized device 4, the fixed bed hydrogenation reaction unit 5 connection, for powering.
Specifically, the wind power generation plant 1 converts wind energy into electric energy, then gives electrical energy transportation to the water electrolysis hydrogen production
Device 2, the gas fractionation unit and or the drying device 3, the gas pressurized device 4, the fixed bed hydrogenation reaction
Device 5 realizes power supply.
In this embodiment, the wind power generation plant 1 is existing wind power generation plant.
In this embodiment, optionally, the wind power generation plant 1 can individually with the device for preparing hydrogen 2
Connection power supply, the gas fractionation unit at this time and or the drying device 3, the gas pressurized device 4, the fixation
Bed hydroprocessing reaction unit 5 is connect with external power supply respectively.
Embodiment 4:
As shown in Figure 1, the embodiment is increased new design on the basis of embodiment 2, automatically controlled to realize, control
Device 7 processed, with the wind power generation plant 1, the device for preparing hydrogen 2, the gas fractionation unit or the drying
Device 3, the gas pressurized device 4, the fixed bed hydrogenation reaction unit 5 connection, for controlling the wind power generation plant
1, the device for preparing hydrogen 2, the gas fractionation unit and or the drying device 3, the gas pressurized device 4, institute
State the opening and closing of fixed bed hydrogenation reaction unit 5.
Specifically, the control device 7 controls the wind power generation plant 1 and opens work, and by the electrical energy transportation of conversion
To the device for preparing hydrogen 2, the gas fractionation unit and or the drying device 3, the gas pressurized device 4, institute
State fixed bed hydrogenation reaction unit 5.The control device 7 controls the device for preparing hydrogen 2 and opens work, is by water electrolysis
Hydrogen and oxygen, after the completion by the hydrogen and oxygen be delivered to the gas fractionation unit and or the drying device 3.Institute
State control device 7 control the gas fractionation unit and or the drying device 3 open work, by the hydrogen and the oxygen
Gas separation and or drying process, the hydrogen is delivered to the gas pressurized device 4 after the completion.The control device 7 controls
The gas pressurized device 7 opens work, is the hydrogen pressurization, the hydrogen of pressurization is delivered to the fixation after the completion
Bed hydroprocessing reaction unit 5.The control device 7 controls the fixed bed hydrogenation reaction unit 5 and opens work, by pressurized institute
It states hydrogen to merge with the organic liquor in the fixed bed hydrogenation reaction unit 5, obtains hydrogenation organic liquor hydrogen storage material, to realize certainly
Dynamic control.
In this embodiment, the control device 7 is computer or single-chip microcontroller etc., and Multiple Type can be used.
Embodiment 5:
The embodiment is further described to the electricity generation system 9 in embodiment 1, the electricity generation system 9 its by first
Device 8 and fixed-bed dehydrogenation reaction unit 10 form, wherein the fixed-bed dehydrogenation reaction unit 10 presses storage and transportation with the room temperature
Tank 6 connects, for deviating from the hydrogen in the hydrogenation organic liquor hydrogen storage material.The fixed-bed dehydrogenation reaction unit 10
It is connect with the first device 8, for providing fuel for the first device 8.Further, the first device 8 is in hydrogen
Combustion engine or fuel cell power supply.
In this embodiment, optionally, the fixed-bed dehydrogenation reaction unit 10 is existing fixed-bed dehydrogenation reaction dress
It sets, the hydrogen internal combustion engine is existing hydrogen internal combustion engine, and the fuel cell power supply is existing fuel cell power supply.
The wind power generation plant 1 converts wind energy into electric energy, and electric energy is transported to the subsequent device for needing electricity consumption, described
Device for preparing hydrogen 2 by water electrolysis be hydrogen and oxygen, the gas fractionation unit and or the drying device 3 with it is described
Device for preparing hydrogen 2 connects, and directly by hydrogen and oxygen separation, and is able to achieve dry purpose, the gas pressurized device 4
With the gas fractionation unit and or the drying device 3 be connected, by hydrogen pressurization to certain pressure, be transported to organic liquid
The fixed bed hydrogenation reaction unit 5, fixed bed hydrogenation reaction unit 5 described in organic liquid is by organic liquid hydrogen storage material one
Determine hydrogen pressure plus hydrogen obtains the organic liquid hydrogen storage material of hydrogenation by hydrogen storage in unhydrided organic liquid hydrogen storage material
Material, the organic liquid hydrogen storage material of hydrogenation are transported to the fixed-bed dehydrogenation reaction unit in electricity generation system 9 described in Hydrogen Energy
10, hydrogen is used as the hydrogen by abjection from the organic liquid hydrogen storage material of hydrogenation by the fixed-bed dehydrogenation reaction unit 10
The fuel of internal combustion engine or the fuel cell, the control device 7 are used to manage concentratedly and control the normal operation of each equipment.
When specifically used:
1. the hydrogenation process of organic liquid hydrogen storage material is completed in wind power plant first;
2. needed to the organic liquid hydrogen storage material after hydrogenation is transported at normal temperatures and pressures by transport vehicle or pipeline
Area;
Dehydrogenation energy supply is completed 3. being fed in hydrogen energy power generation system using the organic liquid hydrogen storage material of hydrogenation as raw material;
4. the later organic liquid hydrogen storage material recycling of dehydrogenation is transported to factory and completes to add hydrogen again, storage so can be achieved
The recycling of hydrogen material.
Whole process is safe and efficient pollution-free, and is conducive to transport and uses.
The preferable specific embodiment of the above, only the application, but the protection scope of the application is not limited thereto,
Within the technical scope of the present application, any changes or substitutions that can be easily thought of by anyone skilled in the art,
Should all it cover within the scope of protection of this application.Therefore, the protection scope of the application should be with scope of protection of the claims
Subject to.
Claims (6)
1. a kind of comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage, comprising:
Device for preparing hydrogen, for being hydrogen and oxygen by water electrolysis;
Gas fractionation unit and or drying device, connect with the device for preparing hydrogen, for by the hydrogen and described
Oxygen separation and or drying process;
Gas pressurized device, with the gas fractionation unit and or the drying device connect, for for the hydrogen increase
Pressure;
Fixed bed hydrogenation reaction unit is connect with the gas pressurized device, for by the pressurized hydrogen with it is described
Organic liquor fusion in fixed bed hydrogenation reaction unit, obtains hydrogenation organic liquor hydrogen storage material;
Wind power generation plant is connect, for powering with the device for preparing hydrogen;
Electricity generation system is connect, for generating electricity with the fixed bed hydrogenation reaction unit.
2. the comprehensive generating system according to claim 1 using wind energy hydrogen manufacturing and organic liquid hydrogen storage, it is characterised in that:
It further include normal temperature and pressure accumulating tank, between the electricity generation system and the fixed bed hydrogenation reaction unit, and with
The fixed bed hydrogenation reaction unit is connected with the electricity generation system, for storing the hydrogenation organic liquor hydrogen storage material.
3. the comprehensive generating system according to claim 1 using wind energy hydrogen manufacturing and organic liquid hydrogen storage, it is characterised in that:
It further include control device, with the wind power generation plant, the device for preparing hydrogen, the gas fractionation unit
With or the drying device, the gas pressurized device, the fixed bed hydrogenation reaction unit connect, for controlling the wind
Power generation device, the device for preparing hydrogen, the gas fractionation unit and or the drying device, the gas boosting
The opening and closing of device, the fixed bed hydrogenation reaction unit.
4. the comprehensive generating system according to claim 1 using wind energy hydrogen manufacturing and organic liquid hydrogen storage, it is characterised in that:
The electricity generation system includes first device and fixed-bed dehydrogenation reaction unit;
The fixed-bed dehydrogenation reaction unit is connect with room temperature pressure accumulating tank, is used for the hydrogenation organic liquor hydrogen storage material
In the hydrogen abjection;
The fixed-bed dehydrogenation reaction unit is connect with the first device, for providing fuel for the first device, so that
Obtain the first device power generation.
5. the comprehensive generating system according to claim 4 using wind energy hydrogen manufacturing and organic liquid hydrogen storage, it is characterised in that:
The first device is hydrogen internal combustion engine or fuel cell power supply.
6. the comprehensive generating system according to claim 1 using wind energy hydrogen manufacturing and organic liquid hydrogen storage, it is characterised in that:
The wind power generation plant also with the gas fractionation unit and or the drying device, the gas pressurized device, institute
The connection of fixed bed hydrogenation reaction unit is stated for powering.
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CN201811038127.7A CN109267083A (en) | 2018-09-06 | 2018-09-06 | A kind of comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage |
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CN201811038127.7A CN109267083A (en) | 2018-09-06 | 2018-09-06 | A kind of comprehensive generating system using wind energy hydrogen manufacturing and organic liquid hydrogen storage |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110820008A (en) * | 2019-11-27 | 2020-02-21 | 云南电网有限责任公司电力科学研究院 | Water electrolytic cell for absorbing hydrogen by organic liquid |
CN117004970A (en) * | 2023-10-08 | 2023-11-07 | 陕西氢易能源科技有限公司 | PEM reactor based on organic liquid electrochemical hydrogenation and system thereof |
CN117026260A (en) * | 2023-10-08 | 2023-11-10 | 陕西氢易能源科技有限公司 | PEM reactor for electrochemical hydrogenation and system thereof |
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CN106208910A (en) * | 2016-08-27 | 2016-12-07 | 温州集智科技有限公司 | A kind of complementary power generation system based on ocean energy, solar energy and Hydrogen Energy |
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2018
- 2018-09-06 CN CN201811038127.7A patent/CN109267083A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106208910A (en) * | 2016-08-27 | 2016-12-07 | 温州集智科技有限公司 | A kind of complementary power generation system based on ocean energy, solar energy and Hydrogen Energy |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110820008A (en) * | 2019-11-27 | 2020-02-21 | 云南电网有限责任公司电力科学研究院 | Water electrolytic cell for absorbing hydrogen by organic liquid |
CN117004970A (en) * | 2023-10-08 | 2023-11-07 | 陕西氢易能源科技有限公司 | PEM reactor based on organic liquid electrochemical hydrogenation and system thereof |
CN117026260A (en) * | 2023-10-08 | 2023-11-10 | 陕西氢易能源科技有限公司 | PEM reactor for electrochemical hydrogenation and system thereof |
CN117004970B (en) * | 2023-10-08 | 2024-02-06 | 陕西氢易能源科技有限公司 | PEM reactor based on organic liquid electrochemical hydrogenation and system thereof |
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Application publication date: 20190125 |