CN109266190B - Organic fluorescent pigment color protection film and use method thereof - Google Patents
Organic fluorescent pigment color protection film and use method thereof Download PDFInfo
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- CN109266190B CN109266190B CN201810982504.6A CN201810982504A CN109266190B CN 109266190 B CN109266190 B CN 109266190B CN 201810982504 A CN201810982504 A CN 201810982504A CN 109266190 B CN109266190 B CN 109266190B
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- fluorescent pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The invention discloses an organic fluorescent pigment color protective film and a using method thereof, wherein the organic fluorescent pigment color protective film comprises the following components in percentage by mass: 87-99.7% of optical transparent resin, 0.1-2% of light stabilizer, 0.1-1% of antioxidant and 0.1-10% of light absorber. The organic fluorescent pigment color protective film contains the light absorber, can effectively absorb ultraviolet and blue light with specific wavelength which generates color changing effect on the color of the fluorescent pigment, and protects the color of the fluorescent pigment. The organic fluorescent pigment color protective film composition is convenient to use, can be coated on the surface of a color band made of the organic fluorescent pigment to be protected only by uniformly mixing, stirring and dissolving the protective film composition, and can form a protective film after vacuum drying and curing, and the process is simple and the cost is low.
Description
Technical Field
The invention belongs to the technical field of organic fluorescent pigments, and particularly relates to an organic fluorescent pigment color protective film and a using method thereof.
Background
Organic fluorescent toners yellow, toners red, toners orange pigments have a strong absorption at 280 and 450nm, so that they are frequently used as blue light absorbers in the field of blue light protection. When used as pigments in the fields of clothing and shoe materials, they have the opportunity to absorb the uv and blue light of sunlight and gradually lose their original color due to the inevitable long-term exposure to the sunlight environment during wearing. In general, when manufacturing fluorescent color ribbons for clothing and footwear, an anti-aging agent and a blue light absorber are added to the formulation and mixed with fluorescent pigments to prevent the pigments from fading. However, since the amount of the pigment is not excessive (blooming is likely to occur when the amount is excessive), the amount of the pigment actually coated around the pigment after dispersion is small, and the effect of preventing discoloration is very limited.
Disclosure of Invention
The invention aims to solve the technical problem of a protective film for preventing the color of organic fluorescent pigment from changing and a using method thereof.
The organic fluorescent pigment color protective film composition comprises the following components in percentage by mass: 87-99.7% of optical transparent resin, 0.1-2% of light stabilizer, 0.1-1% of antioxidant and 0.1-10% of light absorber.
The preferable organic fluorescent pigment color protective film composition comprises the following components in percentage by mass: 88.7-93.6% of optical transparent resin, 1-1.5% of light stabilizer, 0.4-0.8% of antioxidant and 5-9% of light absorber.
The optimal organic fluorescent pigment color protective film composition comprises the following components in percentage by mass: 90.2 percent of optical transparent resin, 1.2 percent of light stabilizer, 0.6 percent of antioxidant and 8 percent of light absorber.
The optical transparent resin is Thermoplastic Polyurethane (TPU), polymethyl methacrylate (PMMA), ethylene-vinyl acetate copolymer (EVA) or colorless transparent organic silicon resin.
The light stabilizer is bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate, polysuccinic acid (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidyl ethanol) ester or 4-benzoyloxy-2, 2,6, 6-tetramethylpiperidine.
The antioxidant is 4,4' -thiobis (6-tert-butyl-m-cresol), tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester, dilauryl thiodipropionate or distearyl thiodipropionate.
The light absorbent is selected from absorbents with the absorption wavelength range of 250-500 nm and the maximum absorption wavelength range of 400-500 nm. The light absorbent is GeigengLQ 01, GeigengBL 1227 or Oldham TM 46.
The application method of the organic fluorescent pigment color-changing protective film comprises the following steps: and (2) uniformly mixing the organic fluorescent pigment color protection film composition, dissolving the mixture by using a solvent benzene, toluene, xylene or chloroform, wherein the mass ratio of the composition to the solvent is 1: 3-5: 4, uniformly stirring and dissolving, coating the mixture on an organic fluorescent pigment color tape, drying and curing in vacuum, and curing to obtain the organic fluorescent pigment color protection film.
The invention has the advantages that: the organic fluorescent pigment color protective film composition contains the light absorber, can effectively absorb ultraviolet and blue light with specific wavelength which generates color changing effect on the color of the organic fluorescent pigment, and protects the organic fluorescent pigment from color changing under the action of sunlight. Secondly, the organic fluorescent pigment color protective film composition is convenient to use, and the protective film composition is coated on an organic fluorescent color belt after being mixed, stirred and dissolved uniformly, and is dried and cured in vacuum, so that the process is simple and the cost is low.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1
The fluorescent pigment color protective film composition comprises the following components in parts by mass: basf TPU S85A 9.4.4 g, bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate 0.05g, 4,4' -thiobis (6-tert-butyl-m-cresol) 0.15g, and commercially available jiegeng lq010.4g.
Example 2
The fluorescent pigment color protective film composition comprises the following components in parts by mass: basf TPU 1185a 10U 9.0g, bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate 0.05g, 4,4' -thiobis (6-tert-butyl-m-cresol) 0.15g, and commercially available jiegenging lq010.8g.
Example 3
The fluorescent pigment color protective film composition comprises the following components in parts by mass: dow Corning 12577 transparent silicone resin 9.2g, poly succinic acid (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidine ethanol) ester 0.05g, four [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester 0.15g, Oldham's TM460.8g.
Example 4
The fluorescent pigment color protective film composition comprises the following components in parts by mass: mitsubishi yang IRD-70 PMMA 9.1g, 4-benzoyloxy-2, 2,6, 6-tetramethylpiperidine 0.05g, dilauryl thiodipropionate 0.15g, commercially available JergenM BL12270.8g.
Example 5
The fluorescent pigment color protective film composition comprises the following components in parts by mass: bayer TPU 3690AU 9.1g, polysuccinic acid (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol) 0.05g, distearyl thiodipropionate 0.15g and commercially available Jende Ying LQ010.8g.
Example 6
The fluorescent pigment color protective film composition comprises the following components in parts by mass: 9.1g of Mitsui chemical 40LX EVA, 0.05g of polysuccinic acid (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidineethanol), 0.15g of distearyl thiodipropionate and 7g of Oubard TM460.7 g.
The protective film compositions of the above examples were mixed, dissolved in benzene, toluene, xylene or chloroform as solvents with stirring to be completely uniform, applied to red, yellow and pink organic fluorescent tapes by a wire bar coater, and vacuum-dried for 12 hours to cure, and the thickness of the cured protective film was about 50 μm. After the test of yellowing resistance, the color fastness is tested according to the national standard GB/T250-. The color fastness was found to be 3,5, 5, 5, 5, 4, respectively.
Compared with the prior art, the protective film composition provided by the invention has the advantages that the color fastness of the organic fluorescent pigment color band prepared by the technology is greatly improved, and the color fastness of the fluorescent color band is kept constant under the sunlight condition.
The present invention is not limited to the above-described embodiments, and various changes and modifications may be made without departing from the spirit and scope of the present invention, and these changes and modifications fall within the scope of the claimed invention.
Claims (5)
1. The organic fluorescent pigment color protective film composition is characterized by comprising the following components in percentage by mass: 87-99.7% of optical transparent resin, 0.1-2% of light stabilizer, 0.1-1% of antioxidant and 0.1-10% of light absorber;
the optical transparent resin is thermoplastic polyurethane, polymethyl methacrylate, ethylene-vinyl acetate copolymer or colorless transparent organic silicon resin;
the light stabilizer is bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate, polysuccinic acid (4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidyl ethanol) ester or 4-benzoyloxy-2, 2,6, 6-tetramethylpiperidine;
the antioxidant is 4,4' -thiobis (6-tert-butyl-m-cresol), tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester, dilauryl thiodipropionate or distearyl thiodipropionate;
the light absorbent is selected from absorbents with the absorption wavelength range of 250-500 nm and the maximum absorption wavelength range of 400-500 nm.
2. The organic fluorescent pigment color protective film composition according to claim 1, characterized by comprising the following components in percentage by mass: 88.7-93.6% of optical transparent resin, 1-1.5% of light stabilizer, 0.4-0.8% of antioxidant and 5-9% of light absorber.
3. The organic fluorescent pigment color protective film composition according to claim 1 or 2, characterized by comprising the following components in percentage by mass: 90.2 percent of optical transparent resin, 1.2 percent of light stabilizer, 0.6 percent of antioxidant and 8 percent of light absorber.
4. The protective film composition according to claim 1, wherein the light absorber is commercially available jequirity LQ01, jequirity BL1227 or ohandd TM 46.
5. The method for using the organic fluorescent pigment color protective film according to claim 1, comprising the steps of: and (2) uniformly mixing the organic fluorescent pigment color protection film composition, dissolving the mixture by using a solvent benzene, toluene, xylene or chloroform, wherein the mass ratio of the composition to the solvent is 1: 3-5: 4, uniformly stirring and dissolving, coating the mixture on an organic fluorescent pigment color tape, drying and curing in vacuum, and curing to obtain the organic fluorescent pigment color protection film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810982504.6A CN109266190B (en) | 2018-08-27 | 2018-08-27 | Organic fluorescent pigment color protection film and use method thereof |
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| CN201810982504.6A CN109266190B (en) | 2018-08-27 | 2018-08-27 | Organic fluorescent pigment color protection film and use method thereof |
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| CN109266190A CN109266190A (en) | 2019-01-25 |
| CN109266190B true CN109266190B (en) | 2020-11-10 |
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| CN103756286A (en) * | 2014-01-16 | 2014-04-30 | 珠海汉胜科技股份有限公司 | Thermoplastic polyurethane cable sheath material and preparation method |
| CN102775939B (en) * | 2012-08-21 | 2015-02-18 | 东方电气集团东方汽轮机有限公司 | Solar battery encapsulation adhesive film |
| KR20160095647A (en) * | 2016-07-11 | 2016-08-11 | 현대모비스 주식회사 | Uv-curable composition for hard-coat paining |
| CN106543915A (en) * | 2016-11-26 | 2017-03-29 | 马益元 | The mobile phone screen surface protection film that a kind of low temperature environment is suitable for |
| CN106590484A (en) * | 2016-11-24 | 2017-04-26 | 南京汇鑫光电材料有限公司 | Acrylate OCA optical adhesive film, and preparation method and application thereof |
| WO2018055010A1 (en) * | 2016-09-20 | 2018-03-29 | Essilor International | Polycarbonate resin compositions with consistent color and stable blue-cut performance |
-
2018
- 2018-08-27 CN CN201810982504.6A patent/CN109266190B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775939B (en) * | 2012-08-21 | 2015-02-18 | 东方电气集团东方汽轮机有限公司 | Solar battery encapsulation adhesive film |
| CN103448312A (en) * | 2013-09-10 | 2013-12-18 | 温志光 | Screen protection film capable of filtering blue light and preparation method of screen protection film |
| CN103756286A (en) * | 2014-01-16 | 2014-04-30 | 珠海汉胜科技股份有限公司 | Thermoplastic polyurethane cable sheath material and preparation method |
| KR20160095647A (en) * | 2016-07-11 | 2016-08-11 | 현대모비스 주식회사 | Uv-curable composition for hard-coat paining |
| WO2018055010A1 (en) * | 2016-09-20 | 2018-03-29 | Essilor International | Polycarbonate resin compositions with consistent color and stable blue-cut performance |
| CN106590484A (en) * | 2016-11-24 | 2017-04-26 | 南京汇鑫光电材料有限公司 | Acrylate OCA optical adhesive film, and preparation method and application thereof |
| CN106543915A (en) * | 2016-11-26 | 2017-03-29 | 马益元 | The mobile phone screen surface protection film that a kind of low temperature environment is suitable for |
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| CN109266190A (en) | 2019-01-25 |
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Address after: 510000 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee after: Institute of rare metals, Guangdong Academy of Sciences Address before: 510000 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee before: GUANGDONG INSTITUTE OF RARE METALS |
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Effective date of registration: 20230403 Address after: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee after: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Address before: 510000 363 Changxin Road, Tianhe District, Guangzhou, Guangdong. Patentee before: Institute of rare metals, Guangdong Academy of Sciences |
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