CN109265092B - Soil alloy building material compound with strength and toughness - Google Patents

Soil alloy building material compound with strength and toughness Download PDF

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Publication number
CN109265092B
CN109265092B CN201811269390.7A CN201811269390A CN109265092B CN 109265092 B CN109265092 B CN 109265092B CN 201811269390 A CN201811269390 A CN 201811269390A CN 109265092 B CN109265092 B CN 109265092B
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parts
building material
soil
toughness
strength
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CN109265092A (en
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王雪艳
王保勤
陆宇
杨立永
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Hebei Liang'an Electric Power Engineering Co ltd
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Hebei Liang'an Electric Power Engineering Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/005Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing gelatineous or gel forming binders, e.g. gelatineous Al(OH)3, sol-gel binders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a soil alloy building material compound with both strength and toughness, which comprises fly ash, slag powder, steel slag crushed stone, bentonite, attapulgite, straw crushed material and/or wood dust material, wherein the materials are prepared by bonding special composite mucilage and then curing and molding; the special composite mucilage comprises cassava starch, inorganic water-based mucilage and self-warming quick-setting gel powder. The invention takes industrial and agricultural wastes as main bodies, realizes the solidification and molding of the powder material through the gelling auxiliary agent, and the obtained building material has high strength and high toughness and has the outstanding characteristic of quick solidification and molding.

Description

Soil alloy building material compound with strength and toughness
Technical Field
The invention relates to the technical field of novel inorganic materials, in particular to a civil engineering material compound.
Background
The current building materials still use six types of cement as absolute main bodies, and are rarely seen in other types of building materials. The method has important practical application value for the research and development of building materials with the same performance, in particular the research and development of novel building materials which can be compatible with industrial and agricultural waste recycling.
Disclosure of Invention
The invention aims to solve the technical problem of providing a soil alloy building material compound with both strength and toughness, which takes industrial and agricultural wastes as main bodies and realizes powder material solidification molding through a gelling auxiliary agent, and the obtained building material has both high strength and high toughness.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
a soil-based building material composite with both strength and toughness comprises fly ash, slag powder, steel slag broken stone, bentonite, attapulgite, straw crushed material and/or wood chip material, wherein the materials are prepared by bonding special composite mucilage and curing and molding; the special composite mucilage comprises cassava starch, inorganic water-based mucilage and self-warming quick-setting gel powder.
As a preferred technical scheme of the invention, the fineness of the fly ash and the slag powder is less than 50 microns.
As a preferable technical scheme of the invention, the particle size of the steel slag crushed stone is less than 5 cm.
As a preferable technical scheme of the invention, the particle size of the rice straw crushed materials and/or the sawdust materials is less than 1 cm.
As a preferable technical scheme of the invention, the weight ratio of the fly ash to the slag powder is 1: (0.1-10).
As a preferable technical scheme of the invention, the soil-based building material compound comprises the following components in parts by weight: the material is prepared by adding 10-30 parts of water, 1-3 parts of cassava starch, 2-4 parts of inorganic aqueous cement and 3-6 parts of self-warming quick-setting adhesive powder into 100 parts of fly ash and slag powder, 10-30 parts of steel slag crushed stone, 3-6 parts of bentonite, 2-5 parts of attapulgite, and 5-10 parts of straw crushed material and/or wood chip material, quickly stirring and uniformly mixing, and then heating, cooling and molding.
As a preferable technical scheme of the invention, the soil-based building material compound comprises the following components in parts by weight: the material is prepared by adding 15-25 parts of water, 1.5-2.5 parts of cassava starch, 2.5-3.5 parts of inorganic aqueous mucilage and 4-5.5 parts of self-warming quick-setting glue powder into 100 parts of fly ash and slag powder, 15-25 parts of steel slag crushed stone, 4-5 parts of bentonite, 3-4 parts of attapulgite, 6-8 parts of rice straw crushed material and/or wood chip material, quickly stirring and uniformly mixing, and then heating, cooling and molding.
As a preferable technical scheme of the invention, the soil-based building material compound comprises the following components in parts by weight: the composite material is prepared by adding 18 parts of water, 2 parts of cassava starch, 3 parts of inorganic aqueous adhesive cement and 5 parts of self-warming quick-setting adhesive powder into 100 parts of fly ash and slag powder, 20 parts of steel slag crushed stone, 4 parts of bentonite, 3.5 parts of attapulgite, and 7 parts of straw crushed material and/or wood chip material, rapidly stirring and uniformly mixing, and then heating, cooling and molding.
Adopt the produced beneficial effect of above-mentioned technical scheme to lie in:
the novel building material compound provided by the invention takes industrial and agricultural wastes as main bodies, realizes powder solidification forming through a gelling auxiliary agent, and has high strength and high toughness.
The invention has the outstanding characteristics that after the raw materials are uniformly mixed, the temperature is raised and then the temperature is reduced, the rapid curing and forming can be carried out within 1-3h, and the curing rate is greatly improved compared with the curing rate of the conventional cement.
The building material product can replace cement and stone, the hardness is obviously higher than that of a cement product, and the c35-c45 is detected, meanwhile, due to the addition of the fiber waste, the building material product has better toughness and buffering performance, and the comprehensive performance is obviously improved compared with the existing building material product.
The novel building material has wide application, can be used for plastering new and old wall surfaces, can be plastered at one time, is not collapsed or cracked, is hard and not afraid of collision, is simple and convenient to construct, and saves labor and materials; meanwhile, the material is suitable for repairing highways, floors and various building surfaces, and can also be used as building bricks, plates and the like.
Particularly, the invention has low manufacturing cost and is green and environment-friendly. The main raw material of the invention is industrial and agricultural waste, which belongs to the environment-friendly harmless treatment and secondary utilization of waste, and the invention has low cost and is a green and environment-friendly product.
Detailed Description
Example 1, optimized formulation of the invention.
A soil alloy building material compound with both strength and toughness comprises the following components in parts by weight: the composite material is prepared by adding 18 parts of water, 2 parts of cassava starch, 3 parts of inorganic aqueous adhesive cement and 5 parts of self-warming quick-setting adhesive powder into 100 parts of fly ash and slag powder, 20 parts of steel slag crushed stone, 4 parts of bentonite, 3.5 parts of attapulgite, and 7 parts of straw crushed material and/or wood chip material, rapidly stirring and uniformly mixing, and then heating, cooling and molding. Wherein: the fineness of the fly ash and the slag powder is less than 50 micrometers; the particle size of the steel slag crushed stone is less than 3 cm; the particle size of the rice straw crushed materials and/or the wood scraps is less than 0.3cm, and the three materials can be randomly mixed, and are generally taken as 1:1: 1; the weight ratio of the fly ash to the slag powder is 1: (0.1-10), generally 1: 1.
The inorganic water-based adhesive cement of the invention preferably adopts 9-0-1 type inorganic high-strength special adhesive produced by Shanghai, Zhongnan, building materials, Inc.
The self-temperature-raising quick-setting gel powder preferably adopts MK-1610 or MK-1620 latex powder of Shandong MeiKai chemical technology Co., Ltd
The following are the test data for testing the compressive strength of the novel building material composite provided by the invention.
Figure BDA0001845649730000041
The source is as follows: a Guangan construction engineering quality detection center in Shijiazhuang Gangcheng area; report number: B180902350.
the composite material has the advantages that the average compressive strength reaches the C35 level, and the forming and curing are obviously advantageous.
Example 2, application example of the composite material of the present invention-pole crash protection squat.
At present, a plurality of electric poles are integrally made of steel pipes, and are easily collided by automobiles when traffic accidents happen, so that not only can serious traffic accidents be caused, but also the electric poles can be seriously collided to cause the interruption of power transmission. Therefore, the firm stability of pole needs to be strengthened, generally is to install the anticollision fender mound additional in the bottom of pole and protects the pole. However, the common anti-collision pier is mainly built by bricks, concrete or stones, and although the anti-collision pier can play a strong role in isolating and protecting the electric pole, the hard anti-collision pier hardly has any buffer effect on the vehicle, and once the anti-collision pier is collided, serious accidents can be caused due to the overlarge rigidity of the anti-collision pier.
The material disclosed by the invention is filled in a buffer area of the anti-collision squat protection of the telegraph pole to serve as a soil-based buffer material, and the soil-based buffer material comprises the following components in parts by weight: the composite material is prepared by adding 18 parts of water, 2 parts of cassava starch, 3 parts of inorganic aqueous adhesive cement and 5 parts of self-warming quick-setting adhesive powder into 100 parts of fly ash and slag powder, 12 parts of steel slag crushed stone, 3 parts of bentonite, 2 parts of attapulgite, 10 parts of crushed rice and/or crushed straw and/or wood chip material, rapidly stirring and uniformly mixing, then heating, cooling and molding.
Slag and waste material crushed aggregates used in the buffer are common visible substances, are crushed and then are uniformly mixed with special adhesive, and are filled into an anti-collision squat buffer area, so that a high-strength and tough soil alloy can be formed after solidification, and the buffer is free of steel, corrosion, rustiness, moisture, water and fire, hard and durable, and waste materials are changed into valuable substances.
The above description is only presented as an enabling solution for the present invention and should not be taken as a sole limitation on the solution itself.

Claims (7)

1. A soil alloy building material compound with both strength and toughness is characterized in that: the soil-based building material compound comprises fly ash, slag powder, steel slag crushed stone, bentonite, attapulgite, straw crushed material and/or wood dust material, and the material is prepared by curing and molding after being bonded by special composite mucilage; the special composite mucilage comprises cassava starch, inorganic water-based mucilage and self-warming quick-setting gel powder;
the soil-based building material compound comprises the following components in parts by weight: the material is prepared by adding 10-30 parts of water, 1-3 parts of cassava starch, 2-4 parts of inorganic aqueous cement and 3-6 parts of self-warming quick-setting adhesive powder into 100 parts of fly ash and slag powder, 10-30 parts of steel slag crushed stone, 3-6 parts of bentonite, 2-5 parts of attapulgite, and 5-10 parts of straw crushed material and/or wood chip material, quickly stirring and uniformly mixing, and then heating, cooling and molding.
2. The soil alloy building material composite with both strength and toughness of claim 1, wherein: the fineness of the fly ash and the slag powder is less than 50 microns.
3. The soil alloy building material composite with both strength and toughness of claim 1, wherein: the particle size of the steel slag crushed stone is less than 5 cm.
4. The soil alloy building material composite with both strength and toughness of claim 1, wherein: the particle size of the rice straw crushed materials and/or the wood chip materials is less than 1 cm.
5. The soil alloy building material composite with both strength and toughness of claim 1, wherein: the weight ratio of the fly ash to the slag powder is 1: (0.1-10).
6. The soil alloy building material composite with both strength and toughness of claim 1, wherein: the soil-based building material compound comprises the following components in parts by weight: the material is prepared by adding 15-25 parts of water, 1.5-2.5 parts of cassava starch, 2.5-3.5 parts of inorganic aqueous mucilage and 4-5.5 parts of self-warming quick-setting glue powder into 100 parts of fly ash and slag powder, 15-25 parts of steel slag crushed stone, 4-5 parts of bentonite, 3-4 parts of attapulgite, 6-8 parts of rice straw crushed material and/or wood chip material, quickly stirring and uniformly mixing, and then heating, cooling and molding.
7. The soil alloy building material composite with both strength and toughness of claim 1, wherein: the soil-based building material compound comprises the following components in parts by weight: the composite material is prepared by adding 18 parts of water, 2 parts of cassava starch, 3 parts of inorganic aqueous adhesive cement and 5 parts of self-warming quick-setting adhesive powder into 100 parts of fly ash and slag powder, 20 parts of steel slag crushed stone, 4 parts of bentonite, 3.5 parts of attapulgite, and 7 parts of straw crushed material and/or wood chip material, rapidly stirring and uniformly mixing, and then heating, cooling and molding.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050241543A1 (en) * 2004-04-27 2005-11-03 Wolfgang Hagen Cement-based systems using plastification/extrusion auxiliaries prepared from raw cotton linters
CN101880147A (en) * 2010-05-01 2010-11-10 马鞍山市黄河水处理工程有限公司 Steel slag eco-concrete, steel slag eco-concrete product and preparation method thereof
CN105948596A (en) * 2016-06-08 2016-09-21 广东惠众新材料科技股份有限公司 Ecological precast concrete mixture
CN108264276A (en) * 2017-12-11 2018-07-10 华北水利水电大学 Based on stalk and the light steel-framed composite wall of solid waste filling land used polymer matrix foam concrete

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050241543A1 (en) * 2004-04-27 2005-11-03 Wolfgang Hagen Cement-based systems using plastification/extrusion auxiliaries prepared from raw cotton linters
CN101880147A (en) * 2010-05-01 2010-11-10 马鞍山市黄河水处理工程有限公司 Steel slag eco-concrete, steel slag eco-concrete product and preparation method thereof
CN105948596A (en) * 2016-06-08 2016-09-21 广东惠众新材料科技股份有限公司 Ecological precast concrete mixture
CN108264276A (en) * 2017-12-11 2018-07-10 华北水利水电大学 Based on stalk and the light steel-framed composite wall of solid waste filling land used polymer matrix foam concrete

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