CN109252235A - A kind of preparation method of the health care filler of garment material - Google Patents
A kind of preparation method of the health care filler of garment material Download PDFInfo
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- CN109252235A CN109252235A CN201810773033.8A CN201810773033A CN109252235A CN 109252235 A CN109252235 A CN 109252235A CN 201810773033 A CN201810773033 A CN 201810773033A CN 109252235 A CN109252235 A CN 109252235A
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- Manufacturing & Machinery (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
The invention discloses a kind of preparation method of the health care filler of garment material, include the following steps: that the pretreatment of (1) inorganic particle, (2) once-combined processing, (3) secondary combined processing, (4) are dried.Each step setting of the method for the present invention is simple, collocation is reasonable, it is easy to promote and utilize, health care filler stability in use obtained is good, anion generation burst size is big, to the good health care effect of human body, makes an addition in fabric and imparts the good health care characteristics of clothes, improves the market competitiveness and economic benefit.
Description
Technical field
The invention belongs to garment material technical fields, and in particular to a kind of preparation side of the health care filler of garment material
Method.
Background technique
Clothes refer to the general name of clothes shoes packet toy ornament etc., refer to clothes more.Clothes are early stage human social development
Just occur, a variety of materials that can be found at one's side are made into coarse and crude " clothes " to flak jacket by men of old.The initial clothes of the mankind
It is made of animal skin, earliest " fabric " for wrapping up body is made of bast-fibre and grass etc..
Fabric of the modern society for clothes manufacture is many kinds of, but majority only has the function of warming, sun-proof etc., fresh rare
To the fabric with characteristics such as health cares, the fabric of such functional categories more lacks on the market.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of preparation side of the health care filler of garment material is provided
Method.
The present invention is achieved by the following technical solutions:
A kind of preparation method of the health care filler of garment material, includes the following steps:
(1) inorganic particle pre-processes:
A. nano-titanium dioxide is put into ultraviolet irradiation instrument and carries out ultraviolet irradiation processing, by nanometer two after 1 ~ 1.2h
Titanium oxide takes out spare；
B. iron tourmaline powder is put into microwave irradiation instrument and carries out microwave irradiation processing, by iron tourmaline powder after 40 ~ 45min
It takes out spare；
C. lanthana is put into plasma radiation instrument and carries out plasma radiation processing, by lanthana after 30 ~ 35min
It takes out spare；Ultraviolet light, microwave and corona treatment are used to above-mentioned three kinds of ingredients respectively, can be good at promoting inorganic particle
The activity and activity group content on surface facilitate compatible combination and mutual grafting to effective component in subsequent processing liquid
It is fixed, improve stability and using effect；
(2) once-combined processing:
By step (1) operation b treated iron tourmaline powder, step (1) operation c treated lanthana according to weight ratio 3 ~ 4:
8 ~ 9 are mixed, and are then put into single treatment liquid jointly, and it is 55 ~ 60 DEG C that heating, which keeps the temperature of single treatment liquid, ultrasound
It is filtered after 1 ~ 1.5h of processing, it is spare to obtain compound material A after finally being rinsed one time with deionized water to filter residue；The primary place
Liquid is managed by the material composition of following parts by weight: 8 ~ 10 parts of corn fiber gums, 6 ~ 9 parts of fatty alcohol polyoxyethylene ether, 1 ~ 3 part of pyrophosphoric acid
Sodium, 4 ~ 6 parts of polyethylene glycol, 25 ~ 30 parts of ethyl acetate, 0.2 ~ 0.4 part of urea, 0.1 ~ 0.3 part of ammonium chloride, 0.2 ~ 0.5 part of second two
Amine tetraacethyl disodium, 180 ~ 200 parts of water；Form of small iron particles tourmaline powder is effectively fixed in large-particle lanthanum oxide after present treatment,
Form the double-layer structure that a kind of grafting of iron tourmaline powder wraps lanthana；
(3) secondary combined processing:
By compound material A made from step (1) operation a treated nano-titanium dioxide, step (2) according to 1 ~ 1.5:7 of weight ratio ~
8 are mixed, and are then put into secondary treatment liquid jointly, and it is 70 ~ 74 DEG C that heating, which keeps the temperature of secondary treatment liquid, at ultrasound
It is filtered after 2 ~ 3h of reason, it is spare to obtain compound material B after finally being rinsed one time with deionized water to filter residue；The secondary treatment liquid
By the material composition of following parts by weight: 8 ~ 12 parts of silane coupling agents, 5 ~ 8 parts of neopelexes, 3 ~ 5 parts of polyvinyl alcohol,
130 ~ 150 parts of water；Nanoscale little particle nano-titanium dioxide is effectively fixed on the outer surface of compound material A after present treatment, namely
On the outer surface of iron tourmaline powder particles, a kind of outermost layer nano-titanium dioxide, middle layer iron tourmaline powder, innermost layer are formd
The three-decker of lanthana, iron tourmaline powder are not itself sustained release anions, this does not meet the law of indestructibility of matter yet, and
It is that neutral molecule ionization in air is excited to generate anion using the weak electric field of the spontaneous polarization effect generation of itself, so
After discharged.The effect that tourmaline powder discharges anion as time increases is more and more weaker, and it is bad to lead to stablize persistence,
The filler of above-mentioned three-decker is devised to this application, the lanthanum element in the lanthana of innermost layer being capable of catalysed promoted ferroelectricity gas
Ionization of the mountain flour to neutral molecule, outermost nano-titanium dioxide promote outside air and iron tourmaline powder space gas nearby
The exchange of body, so that air inwardly flows into, anion flows outwardly, this is used cooperatively so that the steady and sustained output of anion,
And then it ensure that the lasting of health-care efficacy；
(4) it is dried:
The resulting compound material B of step (3) is put into drying box, is taken out after being dried 1 ~ 1.5h.
Further, the grain diameter of nano-titanium dioxide described in step (1) operation a is 15 ~ 65nm, the purple
Power when outside line radiation treatment is 950 ~ 1000W, and the wavelength control of ultraviolet light is 260 ~ 320nm.
Further, the grain diameter of iron tourmaline powder described in step (1) operation b is 1 ~ 5 μm, the microwave spoke
Power when according to processing is 1200 ~ 1400W.
Further, the grain diameter of lanthana described in step (1) operation c is 20 ~ 25 μm, the plasma
Radiation treatment carries out radiation treatment using inert gas plasma.
Further, the frequency of ultrasonic wave is 450 ~ 500kHz when ultrasonic treatment described in step (2).
Further, the frequency of ultrasonic wave is 530 ~ 580kHz when ultrasonic treatment described in step (3).
Further, silane coupling agent described in step (3) be silane coupling agent kh550, silane coupling agent kh560,
Any one in silane coupling agent kh570.
Further, it is 80 ~ 85 DEG C that the temperature in drying box is kept when drying process described in step (4).
The present invention provides a kind of preparation method of health care filler, filler obtained has good health-care efficacy, is used for
In the preparation of fabric, it can assign fabric pretty good health properties, improve the market competitiveness and using effect.Wherein, mainly
Three kinds of nano-titanium dioxide, iron tourmaline powder and lanthana inorganic particle ingredients are had chosen as main substance, it is answered
It closes modification to be made, wherein iron tourmaline powder can discharge anion, far infrared etc., and the blood that can promote improvement human body follows
Ring enhances human immunity, and has good health care characteristics, and in order to enhance its using effect and stability, and selected and received
Rice titanium dioxide and lanthana are used in compounding, and wherein the rare earth lanthanum element in lanthana can be catalyzed enhancing iron tourmaline powder
The ability of anion is discharged, a large amount of nano-titanium dioxide has absorption, commutativity well, promotes atmosphere outside
Circulation between iron tourmaline powder ambient gas exchanges, and ensure that uniform, the stable release of anion, final health care obtained are filled out
Material stability in use is good, anion generation burst size is big, to the good health care effect of human body.
The present invention has the advantage that compared with prior art
Each step setting of the method for the present invention is simple, collocation is reasonable, easy to promote and utilize, health care filler stability in use obtained
Good, anion generate burst size it is big, to the good health care effect of human body, make an addition in fabric that impart the good health care of clothes special
Property, improve the market competitiveness and economic benefit.
Specific embodiment
Embodiment 1
A kind of preparation method of the health care filler of garment material, includes the following steps:
(1) inorganic particle pre-processes:
A. nano-titanium dioxide is put into ultraviolet irradiation instrument and carries out ultraviolet irradiation processing, by nanometer titanium dioxide after 1h
Titanium takes out spare；
B. iron tourmaline powder is put into progress microwave irradiation processing in microwave irradiation instrument, takes iron tourmaline powder after 40min
It is spare out；
C. lanthana is put into progress plasma radiation processing in plasma radiation instrument, takes lanthana after 30min
It is spare out；
(2) once-combined processing:
By step (1) operation b treated iron tourmaline powder, step (1) operation c treated lanthana according to weight ratio 3:8
It is mixed, is then put into single treatment liquid jointly, it is 55 DEG C that heating, which keeps the temperature of single treatment liquid, is ultrasonically treated 1h
After be filtered, finally with deionized water to filter residue rinse one time after compound material A it is spare；The single treatment liquid is by as follows
The material composition of parts by weight: 8 parts of corn fiber gums, 6 parts of fatty alcohol polyoxyethylene ether, 1 part of sodium pyrophosphate, 4 parts of polyethylene glycol, 25
Part ethyl acetate, 0.2 part of urea, 0.1 part of ammonium chloride, 0.2 part of disodium ethylene diamine tetraacetate, 180 parts of water；
(3) secondary combined processing:
Compound material A made from step (1) operation a treated nano-titanium dioxide, step (2) is carried out according to weight ratio 1:7
Mixing, then puts into secondary treatment liquid jointly, and it is 70 DEG C that heating, which keeps the temperature of secondary treatment liquid, and ultrasonic treatment 2h is laggard
It is spare to obtain compound material B after finally being rinsed one time with deionized water to filter residue for row filtering；The secondary treatment liquid is by following weight
The material composition of part: 8 parts of silane coupling agents, 5 parts of neopelexes, 3 parts of polyvinyl alcohol, 130 parts of water；
(4) it is dried:
The resulting compound material B of step (3) is put into drying box, is taken out after being dried 1h.
Further, the grain diameter of nano-titanium dioxide described in step (1) operation a is 15 ~ 65nm, the purple
Power when outside line radiation treatment is 950W, and the wavelength control of ultraviolet light is 260 ~ 320nm.
Further, the grain diameter of iron tourmaline powder described in step (1) operation b is 1 ~ 5 μm, the microwave spoke
Power when according to processing is 1200W.
Further, the grain diameter of lanthana described in step (1) operation c is 20 ~ 25 μm, the plasma
Radiation treatment carries out radiation treatment using inert gas plasma.
Further, the frequency of ultrasonic wave is 450kHz when ultrasonic treatment described in step (2).
Further, the frequency of ultrasonic wave is 530kHz when ultrasonic treatment described in step (3).
Further, silane coupling agent described in step (3) is silane coupling agent kh550.
Further, it is 80 DEG C that the temperature in drying box is kept when drying process described in step (4).
Embodiment 2
A kind of preparation method of the health care filler of garment material, includes the following steps:
(1) inorganic particle pre-processes:
A. nano-titanium dioxide is put into ultraviolet irradiation instrument and carries out ultraviolet irradiation processing, by nano-silica after 1.1h
It is spare to change titanium taking-up；
B. iron tourmaline powder is put into progress microwave irradiation processing in microwave irradiation instrument, takes iron tourmaline powder after 43min
It is spare out；
C. lanthana is put into progress plasma radiation processing in plasma radiation instrument, takes lanthana after 32min
It is spare out；
(2) once-combined processing:
By step (1) operation b treated iron tourmaline powder, step (1) operation c treated lanthana according to weight ratio 3.5:
7.6 are mixed, and are then put into single treatment liquid jointly, and it is 58 DEG C that heating, which keeps the temperature of single treatment liquid, at ultrasound
It is filtered after reason 1.3h, it is spare to obtain compound material A after finally being rinsed one time with deionized water to filter residue；The single treatment liquid
By the material composition of following parts by weight: 9 parts of corn fiber gums, 8 parts of fatty alcohol polyoxyethylene ether, 2 parts of sodium pyrophosphates, 5 parts of poly- second
Glycol, 28 parts of ethyl acetate, 0.3 part of urea, 0.2 part of ammonium chloride, 0.4 part of disodium ethylene diamine tetraacetate, 190 parts of water；
(3) secondary combined processing:
By compound material A made from step (1) operation a treated nano-titanium dioxide, step (2) according to weight ratio 1.2:7.5
It is mixed, is then put into secondary treatment liquid jointly, it is 72 DEG C that heating, which keeps the temperature of secondary treatment liquid, ultrasonic treatment
It is filtered after 2.5h, it is spare to obtain compound material B after finally being rinsed one time with deionized water to filter residue；The secondary treatment liquid by
The material composition of following parts by weight: 10 parts of silane coupling agents, 7 parts of neopelexes, 4 parts of polyvinyl alcohol, 140 parts of water；
(4) it is dried:
The resulting compound material B of step (3) is put into drying box, is taken out after being dried 1.3h.
Further, the grain diameter of nano-titanium dioxide described in step (1) operation a is 15 ~ 65nm, the purple
Power when outside line radiation treatment is 970W, and the wavelength control of ultraviolet light is 260 ~ 320nm.
Further, the grain diameter of iron tourmaline powder described in step (1) operation b is 1 ~ 5 μm, the microwave spoke
Power when according to processing is 1300W.
Further, the grain diameter of lanthana described in step (1) operation c is 20 ~ 25 μm, the plasma
Radiation treatment carries out radiation treatment using inert gas plasma.
Further, the frequency of ultrasonic wave is 480kHz when ultrasonic treatment described in step (2).
Further, the frequency of ultrasonic wave is 550kHz when ultrasonic treatment described in step (3).
Further, silane coupling agent described in step (3) is silane coupling agent kh560.
Further, it is 83 DEG C that the temperature in drying box is kept when drying process described in step (4).
Embodiment 3
A kind of preparation method of the health care filler of garment material, includes the following steps:
(1) inorganic particle pre-processes:
A. nano-titanium dioxide is put into ultraviolet irradiation instrument and carries out ultraviolet irradiation processing, by nano-silica after 1.2h
It is spare to change titanium taking-up；
B. iron tourmaline powder is put into progress microwave irradiation processing in microwave irradiation instrument, takes iron tourmaline powder after 45min
It is spare out；
C. lanthana is put into progress plasma radiation processing in plasma radiation instrument, takes lanthana after 35min
It is spare out；
(2) once-combined processing:
By step (1) operation b treated iron tourmaline powder, step (1) operation c treated lanthana according to weight ratio 4:9
It is mixed, is then put into single treatment liquid jointly, it is 60 DEG C that heating, which keeps the temperature of single treatment liquid, ultrasonic treatment
It is filtered after 1.5h, it is spare to obtain compound material A after finally being rinsed one time with deionized water to filter residue；The single treatment liquid by
The material composition of following parts by weight: 10 parts of corn fiber gums, 9 parts of fatty alcohol polyoxyethylene ether, 3 parts of sodium pyrophosphates, 6 parts of poly- second two
Alcohol, 30 parts of ethyl acetate, 0.4 part of urea, 0.3 part of ammonium chloride, 0.5 part of disodium ethylene diamine tetraacetate, 200 parts of water；
(3) secondary combined processing:
By compound material A made from step (1) operation a treated nano-titanium dioxide, step (2) according to weight ratio 1.5:8 into
Row mixing, then puts into secondary treatment liquid jointly, and it is 74 DEG C that heating, which keeps the temperature of secondary treatment liquid, after being ultrasonically treated 3h
It is filtered, it is spare to obtain compound material B after finally being rinsed one time with deionized water to filter residue；The secondary treatment liquid by weighing as follows
Measure the material composition of part: 12 parts of silane coupling agents, 8 parts of neopelexes, 5 parts of polyvinyl alcohol, 150 parts of water；
(4) it is dried:
The resulting compound material B of step (3) is put into drying box, is taken out after being dried 1.5h.
Further, the grain diameter of nano-titanium dioxide described in step (1) operation a is 15 ~ 65nm, the purple
Power when outside line radiation treatment is 1000W, and the wavelength control of ultraviolet light is 260 ~ 320nm.
Further, the grain diameter of iron tourmaline powder described in step (1) operation b is 1 ~ 5 μm, the microwave spoke
Power when according to processing is 1400W.
Further, the grain diameter of lanthana described in step (1) operation c is 20 ~ 25 μm, the plasma
Radiation treatment carries out radiation treatment using inert gas plasma.
Further, the frequency of ultrasonic wave is 500kHz when ultrasonic treatment described in step (2).
Further, the frequency of ultrasonic wave is 580kHz when ultrasonic treatment described in step (3).
Further, silane coupling agent described in step (3) is silane coupling agent kh570.
Further, it is 85 DEG C that the temperature in drying box is kept when drying process described in step (4).
Comparative example 1
This comparative example 1 compared with Example 2, eliminates nano-titanium dioxide ingredient and subsequent corresponding processing operation, removes
Furthermore method and step is all the same.
Comparative example 2
This comparative example 2 compared with Example 2, eliminates lanthana ingredient and subsequent corresponding processing operation, in addition to this
Method and step is all the same.
Control group
Using commercially available iron tourmaline powder as health care filler.
In order to compare effect of the present invention, to above-described embodiment 2, comparative example 1, comparative example 2, the corresponding system of control group
The health care filler obtained is tested for the property, and specific correlation data is as shown in table 1 below:
Table 1
Note: the instrument that the measurement of anion value described in upper table 1 uses is the manufacture of Japanese COM-SYSTEM INC Co., Ltd.
Ore anionic textiles instrument, model COM-3010pro；Experiment concrete operations are: the corresponding health care filler of each group is mutual
It is spaced apart to be laid on glass plate, it stacks into cylindrical body, the height of cylindrical body is 1cm, and cylindrical body bottom circular diameter is
3cm, then one anionic textiles of setting are popped one's head at 3cm right above the circle center of surface on the cylinder, for detecting position herein
Anion concentration, with characterize filler anion generate ability (anion concentration is extremely low in the air of experimental situation ignores not
Meter)；What the anion value A was indicated is to test the average value that anion concentration is detected in first day, is carried out every 2h primary
Detection, is then averaged；What the anion value B was indicated is to test the average value that anion concentration is detected in third day,
Detection method is same as above；What the anion value C was indicated is to test the average value that anion concentration is detected in the 7th day, detection side
Method is same as above；What the anion value D was indicated is to test the average value that anion concentration is detected in the 30th day, and detection method is same
On.
The health care filler made from the method for the present invention it can be seen from upper table 1 can stablize, lasting release anion, and
Yield is larger, has good health care using effect.
Claims (8)
1. a kind of preparation method of the health care filler of garment material, which comprises the steps of:
(1) inorganic particle pre-processes:
A. nano-titanium dioxide is put into ultraviolet irradiation instrument and carries out ultraviolet irradiation processing, by nanometer two after 1 ~ 1.2h
Titanium oxide takes out spare；
B. iron tourmaline powder is put into microwave irradiation instrument and carries out microwave irradiation processing, by iron tourmaline powder after 40 ~ 45min
It takes out spare；
C. lanthana is put into plasma radiation instrument and carries out plasma radiation processing, by lanthana after 30 ~ 35min
It takes out spare；
(2) once-combined processing:
By step (1) operation b treated iron tourmaline powder, step (1) operation c treated lanthana according to weight ratio 3 ~ 4:
8 ~ 9 are mixed, and are then put into single treatment liquid jointly, and it is 55 ~ 60 DEG C that heating, which keeps the temperature of single treatment liquid, ultrasound
It is filtered after 1 ~ 1.5h of processing, it is spare to obtain compound material A after finally being rinsed one time with deionized water to filter residue；The primary place
Liquid is managed by the material composition of following parts by weight: 8 ~ 10 parts of corn fiber gums, 6 ~ 9 parts of fatty alcohol polyoxyethylene ether, 1 ~ 3 part of pyrophosphoric acid
Sodium, 4 ~ 6 parts of polyethylene glycol, 25 ~ 30 parts of ethyl acetate, 0.2 ~ 0.4 part of urea, 0.1 ~ 0.3 part of ammonium chloride, 0.2 ~ 0.5 part of second two
Amine tetraacethyl disodium, 180 ~ 200 parts of water；
(3) secondary combined processing:
By compound material A made from step (1) operation a treated nano-titanium dioxide, step (2) according to 1 ~ 1.5:7 of weight ratio ~
8 are mixed, and are then put into secondary treatment liquid jointly, and it is 70 ~ 74 DEG C that heating, which keeps the temperature of secondary treatment liquid, at ultrasound
It is filtered after 2 ~ 3h of reason, it is spare to obtain compound material B after finally being rinsed one time with deionized water to filter residue；The secondary treatment liquid
By the material composition of following parts by weight: 8 ~ 12 parts of silane coupling agents, 5 ~ 8 parts of neopelexes, 3 ~ 5 parts of polyvinyl alcohol,
130 ~ 150 parts of water；
(4) it is dried:
The resulting compound material B of step (3) is put into drying box, is taken out after being dried 1 ~ 1.5h.
2. a kind of preparation method of the health care filler of garment material according to claim 1, which is characterized in that step
(1) grain diameter for operating nano-titanium dioxide described in a is 15 ~ 65nm, the power when ultraviolet irradiation is handled
For 950 ~ 1000W, the wavelength control of ultraviolet light is 260 ~ 320nm.
3. a kind of preparation method of the health care filler of garment material according to claim 1, which is characterized in that step
(1) grain diameter for operating iron tourmaline powder described in b is 1 ~ 5 μm, power when the described microwave irradiation processing is 1200 ~
1400W。
4. a kind of preparation method of the health care filler of garment material according to claim 1, which is characterized in that step
(1) grain diameter for operating lanthana described in c is 20 ~ 25 μm, and the plasma radiation is handled using inertia
Gaseous plasma carries out radiation treatment.
5. a kind of preparation method of the health care filler of garment material according to claim 1, which is characterized in that step
(2) frequency of ultrasonic wave is 450 ~ 500kHz when ultrasonic treatment described in.
6. a kind of preparation method of the health care filler of garment material according to claim 1, which is characterized in that step
(3) frequency of ultrasonic wave is 530 ~ 580kHz when ultrasonic treatment described in.
7. a kind of preparation method of the health care filler of garment material according to claim 1, which is characterized in that step
(3) silane coupling agent described in is silane coupling agent kh550, appointing in silane coupling agent kh560, silane coupling agent kh570
It anticipates one kind.
8. a kind of preparation method of the health care filler of garment material according to claim 1, which is characterized in that step
(4) it is 80 ~ 85 DEG C that the temperature in drying box is kept when drying process described in.
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| CN201810773033.8A CN109252235A (en) | 2018-07-14 | 2018-07-14 | A kind of preparation method of the health care filler of garment material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109662519A (en) * | 2019-01-29 | 2019-04-23 | 刘群英 | A kind of combined bed mattress |
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2018
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109662519A (en) * | 2019-01-29 | 2019-04-23 | 刘群英 | A kind of combined bed mattress |
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Application publication date: 20190122 |