CN109243718A - A kind of production method of non-metallic sheath silk - Google Patents
A kind of production method of non-metallic sheath silk Download PDFInfo
- Publication number
- CN109243718A CN109243718A CN201811152933.7A CN201811152933A CN109243718A CN 109243718 A CN109243718 A CN 109243718A CN 201811152933 A CN201811152933 A CN 201811152933A CN 109243718 A CN109243718 A CN 109243718A
- Authority
- CN
- China
- Prior art keywords
- metallic sheath
- sheath silk
- inner core
- molecular weight
- high molecular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/22—Sheathing; Armouring; Screening; Applying other protective layers
Abstract
A kind of production method of non-metallic sheath silk, specific steps include: that ultra high molecular weight polyethylene fiber is carried out coupling modifier processing infrared-ray oven baking；Impregnate synthesis of polyurethane resin；It in in-mold molding and is heating and curing, non-metallic sheath silk inner core is made into dragger；It is coated later, non-metallic sheath silk finished product is made.Strong, tensile strength is adapted to environment using the non-metallic sheath silk of method production and stretch modulus performance is good, convenient to use, high suitable for the full deep-sea of myriametre grade, high production efficiency, cost performance；Meanwhile this method can be realized the long length continuous production of non-metallic sheath silk.
Description
Technical field
The present invention relates to a kind of umbilical cables production methods of armouring silk, belong to composite cable field of material technology.
Background technique
Umbilical cables are the critical equipments of deep sea energy source exploitation, are responsible between obtaining from underwater installation subsystem and water surface floating type mother's platform
" signal " is exchanged with " substance ", is occupied highly important status during oil and gas development under water, is underwater oil and gas development
" nervous system " and " life umbilical cord ".
With the continuous breakthrough of the maximum diving depth of remote-controlled vehicle (ROV), the especially full deep-sea ROV of myriametre grade develops item
Mesh constantly promotes, and develops the urgent task that full Deep Unmanned Submersibles umbilical cables have become China's deep-sea technology.However,
The full deep-sea ROV umbilical cables having are metal armouring umbilical cables, using steel wire as armoring material, since steel wire density is larger, are caused
Keep metal armouring umbilical cables own wt heavier, can typically be only used within 6000 meters of seabed.Such as CN201975101U and
Umbilical cable disclosed in CN202650621U, use or weave or winding steel wire armor come meet bear underwater operation when
Tension and measuring body function.Interference is brought in order to avoid steel wire generates magnetic hystersis loss during power transmission simultaneously, in steel wire
Inside will coat one layer of conduction or semiconductive shielding layer.Although this kind of cable can satisfy wanting for ocean engineering cable in a short time
Ask, but its there are still disadvantages: the cable using steel wire as bearing member, steel wire coats steel wire than great outside cable
Afterwards, it causes cable body weight to increase considerably, be both unfavorable for laying and use, be also unfavorable for for deeper seabed；Such
Cable is all made of wire armoring, since steel wire is magnetic metal, generates magnetic hystersis loss in power cables transmission process, causes pair
The interference of core needs to increase shielded layer, therefore increase material inside armor, also increase in order to avoid such interference
Cost；Metal tube and wire armouring are easy to be shaken by deep-water pressure and buoyancy as sampling sampling line and bearing structure
It is dynamic, it causes cable insulation material to damage, cable is made to lead to short circuit because of insulation operation.
With the continuous breakthrough of ROV maximum diving depth, the continuous propulsion of especially full deep-sea ROV research and development program element, invention
The full deep-sea ROV non-metallic sheath umbilical cables for being able to satisfy full deep-sea ROV job requirement have become the tight of China deep-sea technology field
Compel task.Full deep-sea ROV non-metallic sheath umbilical cables are current international frontier nature research projects, it takes full advantage of nonmetallic
The excellent characteristics that composite weight is light, intensity is high, the full deep-sea ROV non-metallic sheath navel being fabricated to non-metallic sheath silk
With cable intensity with higher, weight ratio and excellent corrosion resistance.Notification number is that the utility model of CN203366804U is special
Benefit, although improving load as non-metal reinforced layer using the braid layer that polyethylene fiber peacekeeping non-woven fabrics cladding is constituted
Weight, there are still disadvantage, first, the enhancement layer of braided fabric as a whole is not used as armouring silk, so that
Using and it is inconvenient, be not easy to the depth used according to umbilical cables also adjusting the laying of armor and reach the intensity of requirement；
Second, the integrally stretching intensity and stretch modulus of enhancement layer are unfavorable for controlling；Third, to the adaptability such as temperature, anti-ization of environment
Ability etc. is not strong；4th, it is not easy to produce and assemble.The prior art also useful FRP, aramid fiber as constitute braided fabric
Layer, tensile strength and stretch modulus relative deficiency, also can not production length overlength armouring silk, be unfavorable for deep-sea myriametre with
Lower use.
The prior art does not disclose the production method of suitable high-performance non-metallic sheath silk yet, is especially that by continuous squeeze
It is molded, automatic controlling level is high, high production efficiency, the production method that continuous long length can be achieved, this seriously constrains height
The development of performance non-metallic sheath silk.Therefore, the research for carrying out full deep-sea ROV armouring umbilical cables non-metallic sheath silk can be
The development of the full deep-sea ROV umbilical cables in China provides technical support and mating guarantee, is the full deep-sea ROV non-metallic sheath navel in China
Solid technical foundation is established in production domesticization and industrialization with cable.
Summary of the invention
The object of the present invention is to provide the methods that one kind is capable of large-scale production non-metallic sheath silk, are produced using this method
Non-metallic sheath silk adapt to environment that strong, density is low, tensile strength and stretch modulus performance are good, flexibility is good, conveniently makes
With, to be suitable for the full deep-sea of myriametre grade, high production efficiency, cost performance high；Meanwhile this method can be realized non-metallic sheath silk
Long length continuous production.
In order to achieve the above object, the technical solution of the present invention is to provide a kind of production method of non-metallic sheath silk, tools
Body step includes:
(1), ultra high molecular weight polyethylene fiber is subjected to coupling modifier processing；
(2), modified ultra high molecular weight polyethylene fiber is entered into infrared-ray oven baking；
(3), enter resin storage tank later, impregnate synthesis of polyurethane resin；
(4), it subsequently into mold, in in-mold molding and is heating and curing, is made in non-metallic sheath silk into dragger
Core；
(5), the winding of non-metallic sheath silk inner core on winder；
(6), non-metallic sheath silk inner core is placed on set coating line；
(7), non-metallic sheath silk inner core passes through extrusion die after entering preheating oven；
(8), it is quickly cooled down after coating, non-metallic sheath silk finished product is made.
Preferably, step (4) are heating and curing by the way of three sections of heatings in mold, and the first stage is 80 ± 10 DEG C,
Second stage is 120 ± 10 DEG C, and the phase III is 140 ± 10 DEG C.Due to the difference in mold there are temperature, while resin is molten
The viscosity of body is more sensitive to temperature, and temperature more high viscosity is lower, and mobile performance improves, and the ladder of temperature is arranged in mold
Degree, there is also gradients for the mobility of resin melt, this has large effect to the surface flatness of product, from the point of view of microcosmic, most
The core surface roughness formed afterwards is different, so under ultra-deep water environment aging and corrosion behavior rise
To great influence.Meanwhile the selection of especially second stage temperature, be conducive to resin and ultra high molecular weight polyethylene fiber
It is compound, enhance its intensity.
Preferably, in step (4), the hauling speed of dragger is 0.5m/min-1.5m/min, it is highly preferred that traction speed
Degree is 1m/min, and in this velocity interval, ultra high molecular weight polyethylene fiber impregnates the molding effect of synthesis of polyurethane resin
Good, quality is stablized, and enables to the single continuous production length of armouring silk not less than 50000m.
Preferably, in step (8), coating material is wear resistant nylon.
Preferably, control the ultra high molecular weight polyethylene fiber account for entire non-metallic sheath silk inner core weight ratio 65~
85%.
Preferably, in step (8), control coating thickness is 0.3mm~1.0mm.
Preferably, the outer diameter for controlling the non-metallic sheath silk is 0.5mm~6mm.
Another technical solution of the invention is to provide a kind of non-metallic sheath silk, and the non-metallic sheath silk inner core is superelevation
Molecular weight polyethylene fiber impregnation synthesis of polyurethane resin solidification forms, and outer application has one layer of wearing layer.The non-metallic sheath
Silk is suitble to the umbilical cables of full Deep Unmanned Submersibles to use.
Preferably, the outer diameter of the metal armouring silk is 0.5mm~6mm.
Preferably, wearing layer is wear resistant nylon.
Preferably, wearing layer is with a thickness of 0.3mm~1.0mm.
Preferably, the ultra high molecular weight polyethylene fiber account for entire non-metallic sheath silk inner core weight ratio 65~
85%.
Preferably, the density of the non-metallic sheath silk is 1.00~1.10g/cm3。
Another technical solution of the invention is to provide a kind of full deep-sea remote control diving that above-mentioned non-metallic sheath silk is utilized
Device umbilical cables, including power line, ground wire, fiber unit, inner core sheath, non-metallic sheath silk, outer jacket；The power line,
Ground wire and fiber unit are located in inner core sheath, and non-metallic sheath silk is between inner cladding and outer jacket；The nonmetallic armour
Dress silk inner core be ultra high molecular weight polyethylene fiber impregnate synthesis of polyurethane resin solidification form, outer application have one layer it is wear-resisting
Layer.
The present invention also provides a kind of production equipments of non-metallic sheath silk, comprising: sequentially connected actinobacillus device, coupling change
Property processing unit, the first baking oven, resin storage tank, mold, traction device, the first wrap-up；And sequentially connected unreel dress
It sets, the second baking oven, extruder, cooling trough, blow-dry device, diameter detecting instrument, traction device, the second wrap-up；Wherein put
Line apparatus carries out unwrapping wire to ultra high molecular weight polyethylene fiber, and resin storage tank is loaded with polyurethane resin；First wrap-up to
To non-metallic sheath silk inner core wound, object to be processed as unwinding device afterwards.
Wherein, mold is Split mold, has the function of three sections of heatings, and the first stage is 80 ± 10 DEG C, second stage
It is 120 ± 10 DEG C；Phase III is 140 ± 10 DEG C.
Method of the invention uses ultra high molecular weight polyethylene fiber with the use of polyurethane resin as nonmetallic armour
The inner core for filling silk, hardly by its physical and chemical performance of the influence of water.
Ultra high molecular weight polyethylene fiber is placed in the permanent elongation percentage that long-term static load generates and is known as creep.
1, mechanical property
2, thermal energy performance
The mechanical sexual function of ultra high molecular weight polyethylene fiber receives the influence of temperature；Intensity and modulus is lower than room temperature
Enhance under environment, weakens at higher temperature；Meanwhile ultra high molecular weight polyethylene fiber can be taken the photograph in freezing environment to 70
Long-term exposure is born in the environment of family name's degree.
3, anti-ization ability
Ultra high molecular weight polyethylene fiber is that have very strong anti-chemical capacity.Because he is with extremely high one's share of expenses for a joint undertaking weight
Polyethylene manufacture, he perhaps amides hydroxyl or is easy to by other aggressiveness chemical classes objects without containing any aromatic ring
Matter is influenced.
4. physical property
The very smooth low frictional properties coefficient from them in ultra high molecular weight polyethylene fiber surface, low-density make it
It can keep afloat, water imbibition is inappreciable.
5. Electronic Performance
Polyethylene is to belong to insulator simultaneously without dipole characteristic, and after shampooing, ultra high molecular weight polyethylene fiber is embodied
Very high anti-electrical characteristics, low constant electrolyte and a low-down electrolyte loss factor.
6. acoustic wave character
Ultra high molecular weight polyethylene fiber has very high sonic speed, is higher than transverse direction in axial sonic speed；Sound
Wave resistance impenetrability energy, product density water all similar with lateral sonic speed.
7. optical property
Ultra high molecular weight polyethylene fiber is visually opaque.Fiber can not be seen under w light, this is because low
UV absorption coefficient and the composite factors such as unstressed configuration powder or phosphor powder.He can not also be seen by thermal imaging system simultaneously, because
He has low IR absorption coefficient and high thermal energy conducting power.Low reflection of radar wave also reduces radar visuality simultaneously.
8. fire resistance
The flammability test of multiple standards is passed through with the fabric and panel that manufacture from ultra high molecular weight polyethylene fiber.
9. anti-fatigue performance
Ultra high molecular weight polyethylene fiber product possesses high axial load anti-fatigue ability.
10, environmental adaptability
Ultra high molecular weight polyethylene fiber is suitable under diversified, harsh climatic environment.It can be for many years in air
Maintain stability.So worry in link without more handling and storing, because only that strong oxide media just can be with
Attack his mechanical attributes.When comparing under long-term UV irradiation with other high-intensitive glasses, he shows that minimum intensity subtracts
Weak and fracture elongation.
Compared with prior art, the beneficial effects of the present invention are:
1, the present invention is used as production non-metallic sheath with the use of polyurethane resin using ultra high molecular weight polyethylene fiber
The raw material of silk, the two have mating reaction, greatly strengthen its tensile strength (>=1600MPa, φ 2.9mm；It is preferred that >=
2000MPa, φ 2.9mm) and stretch modulus (>=80Gpa, φ 2.9mm；It is preferred that >=90Gpa, φ 2.9mm), and its specific gravity
Gently, density only has 1.00-1.10g/cm3, only 1/8th or so of steel wire；It has certain rigidity, can resist stranding mistake
The cold events when thermal contraction of journey and deep-sea use；Meanwhile this specific material mating molding is selected, have outstanding soft
Softness, minimum bend diameter are substantially better than other materials；So as the armor of umbilical cables, since it is with excellent
Good performance can be suitable for full Deep Unmanned Submersibles and use.
2, the non-metallic sheath silk using flexible of method of the invention preparation, the intensity that can be needed according to umbilical cables, spirit
Configuration armor living.
3, it is wear resistant nylon material on the outside of the non-metallic sheath silk of method of the invention preparation, can directly makes using when stranding
With, it is not necessarily to resurfacing, it is easy to use.
4, the armouring silk of method of the invention preparation is nonmetallic, can be avoided and generates magnetic hysteresis in power cables transmission process
Loss, causes the interference to core；And since polyethylene is without bipolar characteristic, armouring silk has very high anti-electrical characteristics.
5, method of the invention is heating and curing by the way of three sections of heatings in mold, and the temperature control in each stage
Strictly, due to the difference in mold there are temperature, while the viscosity of resin melt is more sensitive to temperature, and temperature is higher glutinous
Degree is lower, and mobile performance improves, and the gradient of temperature is arranged in mold, there is also gradients for the mobility of resin melt, this is right
The surface flatness of product has large effect, and from the point of view of microcosmic, the core surface roughness finally formed is not
Together, so under ultra-deep water environment aging and corrosion behavior play great influence.Meanwhile especially second stage temperature
The selection of degree is conducive to the compound of resin and ultra high molecular weight polyethylene fiber, enhances its intensity.
6, the nonmetallic composite of the prior art, general size diameter is smaller, and fertile length is longer；And it is of the invention
Method, by selecting suitable raw material, suitable hauling speed cooperates specific temperature, not only contributes to the steady of quality
It is fixed, ensureing non-metallic sheath silk performance indexes (tensile strength, stretch modulus, minimum bend diameter, anti-aging etc.)
On the basis of, realize that its single production length can for (such as inner core diameter be 2.9mm) non-metallic sheath silk of major diameter
It is very long, 50km or more can be reached, that is, realize the long length continuous production of large scale non-metallic sheath silk.
7, method of the invention is before ultra high molecular weight polyethylene fiber cooperation and curable urethane resin, to supra polymer
Weight polyethylene fiber carries out coupling modifier, enhances its wellability, hence it is evident that the interface adhesion of the two is improved, it is final to be promoted
The overall mechanical properties of non-metallic sheath silk inner core.
Detailed description of the invention
Fig. 1 is non-metallic sheath silk structural schematic diagram.
Fig. 2 is non-metallic sheath silk sectional view.
Fig. 3 is the inner core molding machine of non-metallic sheath silk.
Fig. 4 is the coating molding device of non-metallic sheath silk.
Fig. 5 is full Deep Unmanned Submersibles umbilical cables schematic diagram.
Inner core, 2- wearing layer, 3- actinobacillus device, 4- coupling modifier processing unit, the 5- first of 1- non-metallic sheath silk dry
Case, 6- resin storage tank, 7- mold, 8- traction device, the first wrap-up of 9-, 10- unwinding device, the second baking oven of 11-, 12- are squeezed out
Machine, 13- cooling trough, 14- blow-dry device, 15- diameter detecting instrument, 16- traction device, the second wrap-up of 17-, 18- electric power
Line, 19- fiber unit, 20- ground wire, 21- inner core sheath, 22- outer jacket, 23- non-metallic sheath silk.
Specific embodiment
Such as Fig. 1-2, a kind of non-metallic sheath silk, the inner core 1 of non-metallic sheath silk is ultra high molecular weight polyethylene fiber leaching
Stain synthesis of polyurethane resin solidification forms, and outer application has one layer of wearing layer 2.Fig. 5 is the umbilical cord for having used non-metallic sheath silk
Cable, including power line 18, fiber unit 19, ground wire 20, inner core sheath 21, non-metallic sheath silk 23, outer jacket 22；The electricity
The line of force 18, fiber unit 19 and ground wire 20 are located in inner core sheath 21, and non-metallic sheath silk is located at inner core sheath 21 and outer jacket
Between 22.
The production equipment of non-metallic sheath silk is as shown in Figure 3,4, it includes: sequentially connected actinobacillus device 3, coupling modifier
Processing unit 4, the first baking oven 5, resin storage tank 6, mold 7, traction device 8, the first wrap-up 9；And it sequentially connected unreels
Device 10, the second baking oven 11, extruder 12, cooling trough 13, blow-dry device 14, diameter detecting instrument 15, traction device 16,
Two wrap-ups 17.
Wherein, actinobacillus device 3 carries out unwrapping wire to ultra high molecular weight polyethylene fiber, is loaded with polyurethane tree in resin storage tank 6
Rouge；First wrap-up 9 winds obtained non-metallic sheath silk inner core, afterwards the object to be processed as unwinding device 10.
It is all prepared with the following method in following embodiment non-metallic sheath silk (raw material be otherwise noted be replaced), packet
Include following steps:
(1), ultra high molecular weight polyethylene fiber is subjected to coupling modifier processing；
(2), modified ultra high molecular weight polyethylene fiber is entered into infrared-ray oven baking；
(3), enter resin storage tank later, impregnate synthesis of polyurethane resin；
(4), it subsequently into mold, in in-mold molding and is heating and curing, is made in non-metallic sheath silk into dragger
Core；
(5), the winding of non-metallic sheath silk inner core on winder；
(6), non-metallic sheath silk inner core is placed on set coating line；
(7), non-metallic sheath silk inner core passes through extrusion die after entering preheating oven；
(8), it is quickly cooled down after coating, non-metallic sheath silk finished product is made.
Embodiment 1
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 1, table 2, table 3, table 4.
Embodiment 2
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 90 DEG C, and second stage is 120 DEG C, and the phase III is 150 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 1.
Embodiment 3
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 70 DEG C, and second stage is 110 DEG C, and the phase III is 130 DEG C, and the hauling speed of dragger is 0.5m/min.It is interior
Core diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experiment knot
Fruit is shown in Table 1.
Embodiment 4
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 90 DEG C, and second stage is 130 DEG C, and the phase III is 150 DEG C, and the hauling speed of dragger is 1.5m/min.It is interior
Core diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experiment knot
Fruit is shown in Table 1.
Embodiment 5
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 130 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 1.
Embodiment 6
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 150 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 1.
Embodiment 7
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 70 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 1.
Comparative example 1
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 60 DEG C, and second stage is 110 DEG C, and the phase III is 160 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 1.
Comparative example 2
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 60 DEG C, and second stage is 120 DEG C, and the phase III is 160 DEG C, and the hauling speed of dragger is 05m/min.It is interior
Core diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experiment knot
Fruit is shown in Table 1.
Comparative example 3
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 50 DEG C, and second stage is 100 DEG C, and the phase III is 120 DEG C, and the hauling speed of dragger is 0.5m/min.It is interior
Core diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experiment knot
Fruit is shown in Table 1.
Comparative example 4
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein temperature is constant in mold, is 110 DEG C, the traction of dragger
Speed is 0.5m/min.Inner core diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for entire non-metallic sheath silk inner core weight
The 75% of ratio is measured, experimental result is shown in Table 1.
Comparative example 5
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein temperature is constant in mold, is 105 DEG C, the traction of dragger
Speed is 0.5m/min.Inner core diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for entire non-metallic sheath silk inner core weight
The 75% of ratio is measured, experimental result is shown in Table 1.
1 experimental result of table
Wherein, 80 DEG C of first stage, 120 DEG C of second stage, 140 DEG C of phase III, hauling speed are that 1m/min is best
Condition.
Comparative example 6
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the polyimide resin of day benefit Chemical Manufacture, and coating material is that Royal DSM produces nylon 6 material AKULON я F-X9190
PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 2
Comparative example 7
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is that Hensel steps chemical industry acrylic acid epoxy resin, and coating material is that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 180 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 2
Comparative example 8
Raw materials: Supreme Being people aramid fiber 2419Dtex, impregnating resin are the SS- of Shanghai Shun Sheng macromolecule Co., Ltd production
25 polyurethane resins, coating material are that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min, inner core
Diameter is 2.9mm, and aramid fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 9
Raw materials: Supreme Being people aramid fiber 2419Dtex, impregnating resin are the polyimide resin of day benefit Chemical Manufacture, coating
Material is that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min, inner core
Diameter is 2.9mm, and aramid fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 10
Raw materials: Supreme Being people aramid fiber 2419Dtex, impregnating resin are the SS- of Shanghai Shun Sheng macromolecule Co., Ltd production
25 polyurethane resins, coating material are that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 130 DEG C；Phase III is 180 DEG C, and the hauling speed of dragger is 1m/min, inner core
Diameter is 2.9mm, and aramid fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 11
Raw materials: the glass fibre of Chongqing Polycomp International Co., Ltd's production, impregnating resin are Shanghai Shun victory
The SS-25 polyurethane resin of macromolecule Co., Ltd production, coating material are that Royal DSM produces nylon 6 material AKULON я F-
X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and glass fibre accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 12
Raw materials: the glass fibre of Chongqing Polycomp International Co., Ltd's production, impregnating resin are day benefit chemical industry
The polyimide resin of production, coating material are that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and glass fibre accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 13
Raw materials: the glass fibre of Chongqing Polycomp International Co., Ltd's production, impregnating resin are Shanghai Shun victory
The SS-25 polyurethane resin of macromolecule Co., Ltd production, coating material are that Royal DSM produces nylon 6 material AKULON я F-
X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 130 DEG C；Phase III is 180 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and glass fibre accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 14
Raw materials: the nylon fiber of extra large wealth plasticizing Co., Ltd, impregnating resin are that Shanghai Shun wins the limited public affairs of macromolecule
The SS-25 polyurethane resin of production is taken charge of, coating material is that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and nylon fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 15
Raw materials: the nylon fiber of extra large wealth plasticizing Co., Ltd, impregnating resin are that the polyamides of day benefit Chemical Manufacture is sub-
Polyimide resin, coating material are that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and nylon fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 16
Raw materials: the nylon fiber of extra large wealth plasticizing Co., Ltd, impregnating resin are that Shanghai Shun wins the limited public affairs of macromolecule
The SS-25 polyurethane resin of production is taken charge of, coating material is that Royal DSM produces nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 130 DEG C；Phase III is 180 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and nylon fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 17
Raw materials: the pbo fiber of Telon fiber Science and Technology Ltd. of Foshan City, impregnating resin are that Shanghai Shun wins high score
The SS-25 polyurethane resin of sub- Co., Ltd's production, coating material are that Royal DSM produces nylon 6 material AKULON я F-X9190
PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and pbo fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 18
Raw materials: the pbo fiber of Telon fiber Science and Technology Ltd. of Foshan City, impregnating resin are day benefit Chemical Manufacture
Polyimide resin, coating material be Royal DSM produce nylon 6 material AKULON я F-X9190 PA6.
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and pbo fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
Comparative example 19
Raw materials: the pbo fiber of Telon fiber Science and Technology Ltd. of Foshan City, impregnating resin are that Shanghai Shun wins high score
The SS-25 polyurethane resin of sub- Co., Ltd's production, coating material are that Royal DSM produces nylon 6 material AKULON я F-X9190
PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 130 DEG C；Phase III is 180 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and pbo fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, and experimental result is shown in Table 2.
2 experimental result of table
Table 2 is the test of internal core performance, and for fracture elongation, the armouring silk of umbilical cables is usually 4%, and shadow
It rings it and is tensile strength, tensile modulus of elasticity and pliability (minimum bend diameter) in the important performance that deep-sea uses.It is logical
Comparison is crossed as can be seen that the performance that is used cooperatively of ultra high molecular weight polyethylene fiber and polyurethane resin is relative to other fibers
And/or resin is used cooperatively, and has unexpected technical effect.
Embodiment 8
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 80% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 3.
Embodiment 9
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 85% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 3.
Embodiment 10
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 70% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 3.
Embodiment 11
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 65% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 3.
Comparative example 20
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 50% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 3.
Comparative example 21
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2.9mm, and ultra high molecular weight polyethylene fiber accounts for the 90% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table 3.
3 experimental result of table
From table 3 it can be seen that is obtained is non-when ultra high molecular weight polyethylene fiber weight accounts for the 65-85% of inner core ratio
The performance of metal armouring silk is better, and especially accounting is more excellent in the range of 75-85%, and reason may be superhigh molecular weight polyethylene
The performance of both alkene fiber and polyurethane resin itself has difference, and at different temperature and process conditions, different accounts for
The performance more compound than influencing its, finally also influences whether the performance of shaped article.
Embodiment 12
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 2mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result is shown in
Table table 4.
Embodiment 13
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 1.5mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table table 4.
Embodiment 14
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 1mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result is shown in
Table table 4.
Embodiment 15
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 0.5mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table table 4.
Embodiment 16
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 3mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result is shown in
Table table 4.
Embodiment 17
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 3.5mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result
It is shown in Table table 4.
Embodiment 18
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 4mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result is shown in
Table table 4.
Embodiment 19
Raw materials: ultra high molecular weight polyethylene fiber is that the Royal DSM U.S. produces SK78 dtex1760 ASP, dipping tree
Rouge is the SS-25 polyurethane resin of Shanghai Shun Sheng macromolecule Co., Ltd production, and coating material is that Royal DSM produces nylon 6 material
AKULONяF-X9190 PA6。
Non-metallic sheath silk is prepared using preceding method, wherein it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 DEG C, and second stage is 120 DEG C, and the phase III is 140 DEG C, and the hauling speed of dragger is 1m/min.Inner core
Diameter is 5mm, and ultra high molecular weight polyethylene fiber accounts for the 75% of entire non-metallic sheath silk inner core weight ratio, experimental result is shown in
Table table 4.
4 experimental result of table
As can be seen from Table 4, for the production of non-metallic sheath silk, diameter is bigger, and the length of monofilament is more difficult to control.
And non-metallic sheath silk of the invention, pass through the proportion between control raw material, the control of Optimizing Process Parameters such as temperature, Neng Goushi
Under the premise of present major diameter, remain to produce longer filament length, the long length for realizing non-metallic sheath silk is continuously given birth to
It produces.It is worth noting that although the non-metallic sheath silk filament length that inner core diameter is 2.9mm is not longest, for work
It is optimal diameter for industry practice.
Claims (8)
1. a kind of production method of non-metallic sheath silk, specific steps include:
(1), ultra high molecular weight polyethylene fiber is subjected to coupling modifier processing；
(2), modified ultra high molecular weight polyethylene fiber is entered into infrared-ray oven baking；
(3), enter resin storage tank later, impregnate synthesis of polyurethane resin；
(4), it subsequently into mold, in in-mold molding and is heating and curing, non-metallic sheath silk inner core is made into dragger；
(5), the winding of non-metallic sheath silk inner core on winder；
(6), non-metallic sheath silk inner core is placed on set coating line；
(7), non-metallic sheath silk inner core passes through extrusion die after entering preheating oven；
(8), it is quickly cooled down after coating, non-metallic sheath silk finished product is made.
2. production method as described in claim 1, in step (4), it is heating and curing by the way of three sections of heatings in mold,
First stage is 80 ± 10 DEG C, and second stage is 120 ± 10 DEG C, and the phase III is 140 ± 10 DEG C.
3. production method as described in claim 1, in step (4), the hauling speed of dragger is 0.5m/min-1.5m/
Min, it is highly preferred that hauling speed is 1m/min.
4. production method as described in claim 1, in step (8), coating material is wear resistant nylon.
5. production method as described in claim 1 controls the ultra high molecular weight polyethylene fiber and accounts for entire non-metallic sheath
The 65~85% of silk inner core weight ratio.
6. production method as described in claim 1, in step (8), control coating thickness is 0.3mm~1.0mm.
7. production method as described in claim 1, the outer diameter for controlling the non-metallic sheath silk is 0.5mm~6mm.
8. a kind of non-metallic sheath silk, which is characterized in that produce to obtain as the production method as described in claim any one of 1-7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811152933.7A CN109243718B (en) | 2018-09-21 | 2018-09-21 | Production method of non-metal armor wires |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811152933.7A CN109243718B (en) | 2018-09-21 | 2018-09-21 | Production method of non-metal armor wires |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109243718A true CN109243718A (en) | 2019-01-18 |
| CN109243718B CN109243718B (en) | 2020-06-16 |
Family
ID=65055426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811152933.7A Active CN109243718B (en) | 2018-09-21 | 2018-09-21 | Production method of non-metal armor wires |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109243718B (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS626211A (en) * | 1985-02-06 | 1987-01-13 | Sumitomo Electric Ind Ltd | Reinforcing member made of resin with high orientation property and its manufacture |
| JP2004256940A (en) * | 2003-02-25 | 2004-09-16 | Toray Ind Inc | Reinforced fiber for direct molding, molding material and method for producing molding |
| CN101071191A (en) * | 2007-06-19 | 2007-11-14 | 上海晓宝增强塑料有限公司 | Aramid fiber reinforced plastic reinforcement, and its preparing process and use |
| CN103837953A (en) * | 2014-02-21 | 2014-06-04 | 苏州东福电子有限公司 | Elastic composite fiber reinforcing core and manufacturing method thereof |
| CN103993479A (en) * | 2014-04-10 | 2014-08-20 | 东华大学 | Silane cross-linking modified ultra-high molecular weight polyethylene fiber preparation method |
| CN104611961A (en) * | 2015-02-09 | 2015-05-13 | 宁波大成新材料股份有限公司 | Preparing method of ultra high molecular weight polyethylene fiber wear-resisting rope |
| CN107856325A (en) * | 2017-12-07 | 2018-03-30 | 武汉纺织大学 | One kind is used for continuous fiber reinforced thermoplastic matrix composite and preparation method |
| CN109387912A (en) * | 2018-09-21 | 2019-02-26 | 上海晓宝增强塑料有限公司 | A kind of non-metallic sheath silk |
| CN209182554U (en) * | 2018-09-21 | 2019-07-30 | 上海晓宝增强塑料有限公司 | A kind of non-metallic sheath silk |
-
2018
- 2018-09-21 CN CN201811152933.7A patent/CN109243718B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS626211A (en) * | 1985-02-06 | 1987-01-13 | Sumitomo Electric Ind Ltd | Reinforcing member made of resin with high orientation property and its manufacture |
| JP2004256940A (en) * | 2003-02-25 | 2004-09-16 | Toray Ind Inc | Reinforced fiber for direct molding, molding material and method for producing molding |
| CN101071191A (en) * | 2007-06-19 | 2007-11-14 | 上海晓宝增强塑料有限公司 | Aramid fiber reinforced plastic reinforcement, and its preparing process and use |
| CN103837953A (en) * | 2014-02-21 | 2014-06-04 | 苏州东福电子有限公司 | Elastic composite fiber reinforcing core and manufacturing method thereof |
| CN103993479A (en) * | 2014-04-10 | 2014-08-20 | 东华大学 | Silane cross-linking modified ultra-high molecular weight polyethylene fiber preparation method |
| CN104611961A (en) * | 2015-02-09 | 2015-05-13 | 宁波大成新材料股份有限公司 | Preparing method of ultra high molecular weight polyethylene fiber wear-resisting rope |
| CN107856325A (en) * | 2017-12-07 | 2018-03-30 | 武汉纺织大学 | One kind is used for continuous fiber reinforced thermoplastic matrix composite and preparation method |
| CN109387912A (en) * | 2018-09-21 | 2019-02-26 | 上海晓宝增强塑料有限公司 | A kind of non-metallic sheath silk |
| CN209182554U (en) * | 2018-09-21 | 2019-07-30 | 上海晓宝增强塑料有限公司 | A kind of non-metallic sheath silk |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109243718B (en) | 2020-06-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109387912A (en) | A kind of non-metallic sheath silk | |
| CN203311871U (en) | Umbilical cable for ocean engineering | |
| CN101996708B (en) | Offshore floating wind power generation cable | |
| RU2013110893A (en) | REINFORCED BY FIBERS, FILLED WITH NANOPARTICLES THERMAL SUSPENSION POLYMER COMPOSITE WIRES AND CABLES, AND METHODS | |
| CN201707970U (en) | Photoelectricity composite cable for anti-cutting underground measurement | |
| CN205881496U (en) | Full carbon light cable | |
| CN208422465U (en) | A kind of floating on water surface cable | |
| CN206075896U (en) | One kind holds lotus deep water umbilical cable | |
| WO2019080498A1 (en) | Adjustable floating photoelectric hybrid cable for marine detection | |
| CN209182554U (en) | A kind of non-metallic sheath silk | |
| CN107103948A (en) | A kind of marine streamer | |
| CN209365314U (en) | A kind of non-metallic sheath silk production equipment | |
| CN109243718A (en) | A kind of production method of non-metallic sheath silk | |
| CN201000789Y (en) | Optical fibre composite power seabed oil-filled cable | |
| CN209045204U (en) | A kind of full Deep Unmanned Submersibles umbilical cables | |
| CN201000774Y (en) | Composite material core of electric power transmission aluminum stranded wire | |
| CN209912547U (en) | Armored high-strength composite umbilical cable for underwater production system of strong electricity | |
| CN206741946U (en) | A kind of marine streamer | |
| CN204315253U (en) | A kind of reinforcement tensile moving flat flexible cable | |
| CN209249182U (en) | The high-strength cable of photoelectricity | |
| CN204332510U (en) | The compound cable of a kind of marine locator | |
| CN206819779U (en) | A kind of compound umbilical cables of ultra-deep-water forceful electric power | |
| CN207302698U (en) | A kind of adjustable floating photoelectric mixed cable of marine exploration | |
| CN208655261U (en) | A kind of marine seismic prospectiong solid towing cable | |
| CN111474657A (en) | Underwater suspended optical cable and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |