CN109240037A - A kind of aobvious fixing bath liquid of environmental protection - Google Patents
A kind of aobvious fixing bath liquid of environmental protection Download PDFInfo
- Publication number
- CN109240037A CN109240037A CN201811316813.6A CN201811316813A CN109240037A CN 109240037 A CN109240037 A CN 109240037A CN 201811316813 A CN201811316813 A CN 201811316813A CN 109240037 A CN109240037 A CN 109240037A
- Authority
- CN
- China
- Prior art keywords
- environmental protection
- hydroquinone
- fixing bath
- bath liquid
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 56
- 230000007613 environmental effect Effects 0.000 title claims abstract description 24
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 78
- 239000003223 protective agent Substances 0.000 claims abstract description 33
- 239000003112 inhibitor Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 24
- 239000011734 sodium Substances 0.000 claims abstract description 24
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 24
- 150000003839 salts Chemical class 0.000 claims abstract description 21
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 18
- -1 promotor Substances 0.000 claims abstract description 16
- 238000012545 processing Methods 0.000 claims abstract description 14
- 238000011010 flushing procedure Methods 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims description 30
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 14
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 14
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 9
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical group [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 7
- 206010001497 Agitation Diseases 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 6
- 239000000523 sample Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000012267 brine Substances 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 235000010265 sodium sulphite Nutrition 0.000 claims description 4
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 4
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 150000004780 naphthols Chemical class 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 230000031709 bromination Effects 0.000 claims 1
- 238000005893 bromination reaction Methods 0.000 claims 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims 1
- 230000001737 promoting effect Effects 0.000 claims 1
- 230000001629 suppression Effects 0.000 claims 1
- 238000003672 processing method Methods 0.000 abstract description 7
- 238000009472 formulation Methods 0.000 abstract description 4
- 238000012360 testing method Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 239000002671 adjuvant Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/30—Developers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/38—Fixing; Developing-fixing; Hardening-fixing
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/407—Development processes or agents therefor
- G03C7/413—Developers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
The invention discloses a kind of aobvious fixing bath liquid of environmental protection; developer solution flushing liquor includes developer, protective agent, promotor, inhibitor composition developer; wherein the environmental protection shows fixing bath liquid also packet defoaming agent, dispersing agent and sodium cellulosate salt water; the developer is by Mitouer and hydroquinone or individually will to be made by mixing to obtain developer using hydroquinone; wherein the mass ratio of Mitouer and hydroquinone is respectively 2-3g, and hydroquinone uses 5-12g.Compared with prior art, the present invention mainly can effectively disperse liquid during the preparation process, and then prevent the boring cohesion in liquid from agglomerating, so that the aobvious fixing bath liquid of environmental protection has good dispersibility and mobility, and fabrication processing is simplified, Concentration Testing can be carried out to configuration liquid after the completion of primary configuration, by using vacuum processing method, configuration liquid can be effectively prevent to be contaminated, it is different by the mass ratio of formulation ratio, the developer solution flushing liquor of different degrees of performance can be prepared.
Description
Technical field
The invention belongs to show fixing technologies field, and in particular to a kind of aobvious fixing bath liquid of environmental protection.
Background technique
Film is exactly silver salt photographic film, is also the film.It is made by PC/PP/PET/PVC material.Film generally refers to
Film can also refer to the egative film in plate making.The film is all black, and generally there is an English symbol in the corner of the film,
The number of the film, indicate the film be in C, M, Y, K which, one of them (or spot color number), indicate this film
It is that color exports, if not provided, the angle of linked network can be seen, is what color to distinguish, is needed during film production
Aobvious fixing bath liquid is rinsed film face, so that film develops, wherein developer solution flushing liquor is referred to
Chemical agent applicable when photograph is washed, main component has sulfuric acid, nitric acid and benzene, methanol, silver halide, boric acid, hydroquinone etc..Have
Poison not directly contacts skin, and it is the dissolvable region for dissolving the photoresist as caused by exposing that meeting heavy corrosion, which is to developer solution,
A kind of chemical solvent.
And in existing aobvious fixing bath liquid manufacturing process, due to production process complexity, and processing cost is higher, wherein
Due to will directly processed in proportion adjuvant importing processing tank in preparation process, it is easy to so that liquid is contaminated, in turn
Preparation quality is influenced, to cause the waste of raw material, and is easy to so that damage of the adjuvant molecular structure by various factors
It is bad, and be easy to generate agglomeration in process, between adjuvant, and then influence the performance performance of adjuvant, thus indirectly
The influence of property has aobvious fixing bath liquid processing effect.
Summary of the invention
It is an object of the invention to overcome the deficiencies of existing technologies, providing one kind during the preparation process can be effectively by liquid
Dispersed, and then prevent the boring cohesion in liquid from agglomerating so that the aobvious fixing bath liquid of environmental protection have good dispersibility with
And mobility, and fabrication processing is simplified, and Concentration Testing can be carried out to configuration liquid after the completion of primary configuration, by adopting
With vacuum processing method, configuration liquid can be effectively prevent to be contaminated, it is different by the mass ratio of formulation ratio, it can prepare
The environmental protection of the developer solution flushing liquor of different degrees of performance shows fixing bath liquid out.
To achieve the goals above, technical scheme is as follows:
A kind of aobvious fixing bath liquid of environmental protection, developer solution flushing liquor include developer, protective agent, promotor, inhibitor composition
Developer, wherein the environmental protection shows fixing bath liquid also packet defoaming agent, dispersing agent and sodium cellulosate salt water, it is described
Developer is by Mitouer and hydroquinone or individually will to be made by mixing to obtain developer using hydroquinone, and wherein rice is spat
The mass ratio of you and hydroquinone is respectively 2-3g, and hydroquinone uses 5-12g.
Preferably, the promotor usually selects the stronger sodium carbonate of alkalinity perhaps sodium hydroxide sodium carbonate or hydrogen
It is 45-70PH value 9.0 or more that sodium oxide molybdena, which uses mass ratio,；The weaker promotor of alkalinity, such as borax, kodalk, borax or
The mass ratio of kodalk is 2-6g；PH value is between 7.5-9.0.
Preferably, the inhibitor is potassium bromide, the mass ratio 2-5g of potassium bromide.
Preferably, the protective agent of the developer solution is a kind of more active reducing agent, and common protective agent has black and white aobvious
Sodium sulfite in shadow liquid and therewith and for the azanol in colour display screen, wherein the mass ratio of sodium sulfite and azanol is 45-100g.
Preferably, the defoaming agent is by fatty alcohol, polyethers, hydro carbons composition.
Preferably, the dispersing agent be styrylphenol polyoxyethylene ether, diphenylethyllene phenol polyoxyethylene ether,
Styrylphenol polyoxyethylene ether sulfonate, naphthols polyethenoxy ether sulphonate, styrylphenol polyoxyethylene ether sulfuric acid
Salt etc. is one such or several.
Preferably, including the following steps: by Mitouer and hydroquinone or delivery pipe individually will be passed through using hydroquinone
It is delivered in batch tank, and batch tank uses vacuum processing method, and batch tank inner vacuum is extracted out and kept using vacuum pump
Preparing tank internal vacuum, while by flow valve to injection sodium cellulosate salt water inside batch tank, to Mitouer and to benzene two
Phenol is diluted, after the dilution by the way that the good protective agent of quantitative measurment, promotor, inhibitor are passed through configuration according to mass ratio
In tank, ultrasonic wave mixing is carried out, and developer solution finished product is obtained by filtration.
Preferably, it after being passed through protective agent, promotor, inhibitor, needs that defoaming agent (fatty alcohol is added in configuration liquid
Substance), dispersing agent (styrylphenol polyoxyethylene ether), carry out secondary agitation, eliminate foam in preparing tank and anti-
Only expect and agglomerates.
Preferably, the processing temperature of the sodium cellulosate salt water is 30 DEG C~55 DEG C；The cellulose sodium salt water quality
Amount is than being 750ml-1000ml.
Preferably, the protective agent, promotor, inhibitor be passed through total amount be 0.1%-0.3%, final developer solution
Concentration is 2.0%-2.35%, and then preparing tank side walls are being communicated with probe tube and are being extended to inside Concentration Modulation slot, right
Solution level pH value is debugged.
Compared with prior art, there are following the utility model has the advantages that the present invention mainly during the preparation process can be effective by the present invention
Liquid is dispersed, and then prevents the boring cohesion in liquid from agglomerating, so that the aobvious fixing bath liquid of environmental protection has good point
Property and mobility are dissipated, and fabrication processing is simplified, Concentration Testing can be carried out to configuration liquid after the completion of primary configuration,
By using vacuum processing method, configuration liquid can be effectively prevent to be contaminated, energy different by the mass ratio of formulation ratio
Enough prepare the developer solution flushing liquor of different degrees of performance.
Specific embodiment
The present invention is described in further details below with reference to embodiment.
Embodiment 1:
Mitouer 2g, hydroquinone mass ratio be respectively 5g, protective agent 45g, promotor 2g, inhibitor 2g, defoaming agent
3g, dispersing agent 1g and sodium cellulosate salt water 750ml.
Method when making rigid developer solution flushing liquor are as follows: distinguish the mass ratio of above-mentioned material Mitouer 2g, hydroquinone
It is measured according to the ratio for 5g, protective agent 45g, promotor 2g, inhibitor 2g, defoaming agent 3g, dispersing agent 1g and sodium cellulosate salt water 750ml
It is configured, wherein the mass ratio of hydroquinone is greater than the mass ratio in Mitouer, then by Mitouer and hydroquinone or general
It is individually delivered in batch tank using hydroquinone by delivery pipe, and batch tank uses vacuum processing method, utilizes vacuum pump
Batch tank inner vacuum extracted to and kept preparing tank internal vacuum out, while by flow valve to injecting fiber inside batch tank
Plain natrium brine, is diluted Mitouer and hydroquinone, after the dilution by by the good protective agent of quantitative measurment, promote
Agent, inhibitor are passed through in batch tank according to mass ratio, carry out ultrasonic wave mixing, and developer solution finished product is obtained by filtration,
After being passed through protective agent, promotor, inhibitor, need that defoaming agent (fatty alcohols substance), dispersing agent is added in configuration liquid
(styrylphenol polyoxyethylene ether) carries out secondary agitation, eliminates the foam in preparing tank and prevents from expecting and agglomerate, is matching
During setting, the processing temperature of sodium cellulosate salt water is 30 DEG C~55 DEG C；The sodium cellulosate brine quality ratio is 750ml-
1000ml, protective agent, promotor, inhibitor the total amount that is passed through be 0.1%-0.3%, the concentration of final developer solution is 2.0%-
2.35%, preparing tank side walls are finally communicated with probe tube and are extended to inside Concentration Modulation slot, to solution level pH value
It is debugged, in preparation hardness development flushing liquor: generally all using the stronger sodium carbonate of alkalinity or sodium hydroxide as development
The promotor of agent, and dosage is more.Can accelerate developing powder in this way, but after developing image particle it is thicker, inhibitor is bromine
Change potassium, the generation of film fog density can be prevented in this way, to can get the image of high contrast.
Embodiment 2:
Mitouer 2.5g, hydroquinone mass ratio be respectively 1g, protective agent 70g, promotor 4g, inhibitor 3.5g, disappear
Infusion 5.5g, dispersing agent 1.5g and sodium cellulosate salt water 900ml.
Liquid making method is rinsed preparing soft development are as follows: by above-mentioned material Mitouer 2.5g, the mass ratio of hydroquinone
Respectively 1g, protective agent 70g, promotor 4g, inhibitor 3.5g, defoaming agent 5.5g, dispersing agent 1.5g and sodium cellulosate salt water
900ml is measured configured according to the ratio, and wherein the mass ratio of hydroquinone is less than the mass ratio in Mitouer, then by Mitouer and
Hydroquinone will be individually delivered in batch tank using hydroquinone by delivery pipe, and batch tank uses vacuum processing side
Batch tank inner vacuum is extracted using vacuum pump and is kept out preparing tank internal vacuum by formula, while passing through flow valve to configuration
Sodium cellulosate salt water is injected inside tank, Mitouer and hydroquinone is diluted, after the dilution by the way that quantitative measurment is good
Protective agent, promotor, inhibitor be passed through in batch tank according to mass ratio, carry out ultrasonic wave mixing, and filter
To developer solution finished product, after being passed through protective agent, promotor, inhibitor, need that defoaming agent (fatty alcohols is added in configuration liquid
Substance), dispersing agent (styrylphenol polyoxyethylene ether), carry out secondary agitation, eliminate preparing tank in foam and prevent
Material and agglomeration, in configuration process, the processing temperature of sodium cellulosate salt water is 30 DEG C~55 DEG C；The cellulose sodium salt water quality
Amount than be 750ml-1000ml, protective agent, promotor, inhibitor be passed through total amount be 0.1%-0.3%, final developer solution it is dense
Degree is 2.0%-2.35%, and preparing tank side walls are finally communicated with probe tube and are extended to inside Concentration Modulation slot, to development
Liquid concentration pH value is debugged, when preparing soft developer solution flushing liquor: the content of formula sulfite sodium is more, is conducive to micro-
Grain development obtains level and enriches, the image of particle exquisiteness, using the weaker promotor of alkalinity, such as borax, kodalk.Development
The pH value of liquid is lower, generally between 7.5-9.0.Developing powder is slower, and be easy to get thin silver granuel, inhibitor-potassium bromide use
Measure it is less, in order to avoid loss image thin portion.
Embodiment 3:
Mitouer 2g, hydroquinone mass ratio be respectively 6g, protective agent 80g, promotor 3g, inhibitor 3g, defoaming agent
6g, dispersing agent 2g and sodium cellulosate salt water 850ml
Developer solution rinse liquid making method are as follows: Mitouer 2g, hydroquinone mass ratio be respectively 6g, protective agent 80g, promote
It measures sieved according to the ratio into agent 3g, inhibitor 3g, defoaming agent 6g, dispersing agent 2g and sodium cellulosate salt water 850ml, then by rice
Tu Er and hydroquinone will be individually delivered in batch tank using hydroquinone by delivery pipe, and batch tank is added using vacuum
Batch tank inner vacuum, is extracted using vacuum pump and is kept out preparing tank internal vacuum by work mode, at the same by flow valve to
Sodium cellulosate salt water is injected inside batch tank, Mitouer and hydroquinone are diluted, after the dilution by will quantitatively survey
Measured protective agent, promotor, inhibitor are passed through in batch tank according to mass ratio, carry out ultrasonic wave mixing, and passed through
Filter obtains developer solution finished product, after being passed through protective agent, promotor, inhibitor, needs (fatty to defoaming agent is added in configuration liquid
Alcohols material), dispersing agent (styrylphenol polyoxyethylene ether), carry out secondary agitation, eliminate preparing tank in foam and
It prevents from expecting and agglomerate, in configuration process, the processing temperature of sodium cellulosate salt water is 30 DEG C~55 DEG C；The cellulose sodium salt
Water quality ratio be 750ml-1000ml, protective agent, promotor, inhibitor be passed through total amount be 0.1%-0.3%, final developer solution
Concentration be 2.0%-2.35%, preparing tank side walls are finally communicated with probe tube and are extended to inside Concentration Modulation slot, it is right
Solution level pH value is debugged.
Embodiment 4:
Mitouer 3g, hydroquinone mass ratio be respectively 12g, protective agent 100g, promotor 4g, inhibitor 5g, defoaming
Agent 7.5g, dispersing agent 3g and sodium cellulosate salt water 1000ml.
Developer solution rinse liquid making method are as follows: the mass ratio by above-mentioned material Mitouer 3g, hydroquinone be respectively 12g,
Protective agent 100g, promotor 4g, inhibitor 5g, defoaming agent 7.5g, dispersing agent 3g and sodium cellulosate salt water 1000ml are measured according to the ratio
It is sieved, then by Mitouer and hydroquinone or will be individually delivered in batch tank using hydroquinone by delivery pipe,
And batch tank uses vacuum processing method, extracts batch tank inner vacuum out using vacuum pump and keeps preparing tank inner vacuum
Degree, while Mitouer and hydroquinone are diluted, to injection sodium cellulosate salt water inside batch tank dilute by flow valve
By the way that the good protective agent of quantitative measurment, promotor, inhibitor to be passed through in batch tank according to mass ratio after releasing, ultrasonic wave is carried out
It is mixed, and developer solution finished product is obtained by filtration, after being passed through protective agent, promotor, inhibitor, need to configuration liquid
Middle addition defoaming agent (fatty alcohols substance), dispersing agent (styrylphenol polyoxyethylene ether), carry out secondary agitation, and elimination is matched
It foam in tank processed and prevents from expecting and agglomerate, in configuration process, the processing temperature of sodium cellulosate salt water is 30 DEG C~55 DEG C；
The sodium cellulosate brine quality ratio be 750ml-1000ml, protective agent, promotor, inhibitor be passed through total amount be 0.1%-
0.3%, the concentration of final developer solution is 2.0%-2.35%, and preparing tank side walls are finally communicated with probe tube and are extended to dense
It spends inside preparation vessel, solution level pH value is debugged.
The present embodiment can effectively be dispersed liquid, Jin Erfang during the preparation process by the aobvious fixing bath liquid of environmental protection
The only boring cohesion agglomeration in liquid so that the aobvious fixing bath liquid of environmental protection has good dispersibility and mobility, and makes
Process flow is simplified, and can carry out Concentration Testing to configuration liquid after the completion of primary configuration, by using vacuum processing method,
Configuration liquid can be effectively prevent to be contaminated, it is different by the mass ratio of formulation ratio, different degrees of performance can be prepared
Developer solution flushing liquor.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and is modified.Therefore, the invention is not limited to the specific embodiments disclosed and described above, to the one of invention
A little modifications and changes should also be as falling into the scope of the claims of the present invention.
Claims (10)
1. a kind of aobvious fixing bath liquid of environmental protection, it is characterised in that: developer solution flushing liquor is by developer, protective agent, promotor and suppression
Preparation composition, wherein the environmental protection shows fixing bath liquid also packet defoaming agent, dispersing agent and sodium cellulosate salt water, the developer
It is that by Mitouer and hydroquinone or individually will be made by mixing to obtain developer using hydroquinone, wherein Mitouer and right
The mass ratio of benzenediol is respectively 2-3g, and hydroquinone uses 5-12g.
2. the aobvious fixing bath liquid of environmental protection as described in claim 1, it is characterised in that: the promotor usually selects it is alkaline compared with
Perhaps sodium hydroxide sodium carbonate or sodium hydroxide use mass ratio to strong sodium carbonate is 45-70PH value 9.0 or more；Alkalinity
Weaker promotor, such as borax, kodalk, the mass ratio of borax or kodalk is 2-6g；PH value is between 7.5-9.0.
3. the aobvious fixing bath liquid of environmental protection as claimed in claim 2, it is characterised in that: the inhibitor is potassium bromide, bromination
The mass ratio 2-5g of potassium.
4. the aobvious fixing bath liquid of environmental protection as described in claim 1, it is characterised in that: the protective agent of the developer solution is a kind of
More active reducing agent, common protective agent have sodium sulfite in black-and-white developer and therewith and for the azanol in colour display screen,
Wherein the mass ratio of sodium sulfite and azanol is 45-100g.
5. the aobvious fixing bath liquid of environmental protection as described in claim 1, it is characterised in that: the defoaming agent is gathered by fatty alcohol
Ether, hydro carbons composition.
6. the aobvious fixing bath liquid of environmental protection as described in claim 1, it is characterised in that: the dispersing agent is styrylphenol
Polyoxyethylene ether, diphenylethyllene phenol polyoxyethylene ether, styrylphenol polyoxyethylene ether sulfonate, naphthols polyoxyethylene
Ether sulfonate, styrylphenol polyoxyethylene ether sulfate etc. are one such or several.
7. the manufacturing method that environmental protection described in one kind shows fixing bath liquid, it is characterised in that: include the following steps: Mitouer and
Hydroquinone will be individually delivered in batch tank using hydroquinone by delivery pipe, and batch tank uses vacuum processing side
Batch tank inner vacuum is extracted using vacuum pump and is kept out preparing tank internal vacuum by formula, while passing through flow valve to configuration
Sodium cellulosate salt water is injected inside tank, Mitouer and hydroquinone is diluted, after the dilution by the way that quantitative measurment is good
Protective agent, promotor, inhibitor be passed through in batch tank according to mass ratio, carry out ultrasonic wave mixing, and filter
To developer solution finished product.
8. the manufacturing method of the aobvious fixing bath liquid of environmental protection as claimed in claim 7, it is characterised in that: be passed through protective agent, promoting
Into after agent, inhibitor, need to defoaming agent (fatty alcohols substance) is added in configuration liquid, (styrylphenol is poly- for dispersing agent
Ethylene oxide ether), secondary agitation is carried out, the foam in preparing tank is eliminated and prevents from expecting and agglomerate.
9. the manufacturing method of the aobvious fixing bath liquid of environmental protection as claimed in claim 7, it is characterised in that: the cellulose sodium salt
The processing temperature of water is 30 DEG C~55 DEG C；The sodium cellulosate brine quality ratio is 750ml-1000ml.
10. the manufacturing method of the aobvious fixing bath liquid of environmental protection as claimed in claim 7, it is characterised in that: the protective agent promotees
The total amount that is passed through into agent, inhibitor is 0.1%-0.3%, and the concentration of final developer solution is 2.0%-2.35%, then will matched
Tank side walls processed are communicated with probe tube and extend to inside Concentration Modulation slot, debug to solution level pH value.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811316813.6A CN109240037A (en) | 2018-11-07 | 2018-11-07 | A kind of aobvious fixing bath liquid of environmental protection |
| PCT/CN2018/115597 WO2020093430A1 (en) | 2018-11-07 | 2018-11-15 | Environmental-friendly developing and fixing washing liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811316813.6A CN109240037A (en) | 2018-11-07 | 2018-11-07 | A kind of aobvious fixing bath liquid of environmental protection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109240037A true CN109240037A (en) | 2019-01-18 |
Family
ID=65076980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811316813.6A Pending CN109240037A (en) | 2018-11-07 | 2018-11-07 | A kind of aobvious fixing bath liquid of environmental protection |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN109240037A (en) |
| WO (1) | WO2020093430A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116393070A (en) * | 2023-04-11 | 2023-07-07 | 昆山欣谷微电子材料有限公司 | Copolymer for preparing developing solution by slowly releasing dissolved oxygen and use method thereof |
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|---|---|
| WO2020093430A1 (en) | 2020-05-14 |
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