CN109234837A - A kind of composite plastic woven material - Google Patents
A kind of composite plastic woven material Download PDFInfo
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- CN109234837A CN109234837A CN201811075755.2A CN201811075755A CN109234837A CN 109234837 A CN109234837 A CN 109234837A CN 201811075755 A CN201811075755 A CN 201811075755A CN 109234837 A CN109234837 A CN 109234837A
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- plastic woven
- woven material
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- composite plastic
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composite plastic woven materials, its is composed of the following components by weight: 100-150 parts of polypropylene, 50-60 parts of polymethyl methacrylate, 10-15 parts of toluene sulfonyl semicarbazide, 1-1.5 parts of butanone, 13-15 parts of carbon fiber, 4-6 parts of aniline, 5-6 parts of white oil, 1-2 parts of amine curing agent, 12-17 parts of ethyl silicon oil, 8-15 parts of clay, 0.2-0.4 parts of antibacterial agent, 0.2-0.4 parts of mould inhibitor, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of iron powder.Inventive formulation is simple, at low cost, and manufactured Polywoven Bag can effectively prevent oxidation reaction caused by ultraviolet illumination, solve the problems, such as that packaging bag service life is short in the prior art, and the present invention is durable, anti-skidding, not bale broken, particularly suitable long distance transportation and outlet.
Description
Technical field
The present invention relates to plastic film field, specially a kind of composite plastic woven material.
Background technique
Polywoven Bag is divided into Polypropylene Bag, Polythene Bag by main material composition；It is divided into seam bottom bag, seam by method of sewing
Side bottom bag.It is now widely used for a kind of packaging material of fertilizer, chemical products and other items.Its main production is to utilize modeling
Material raw material is flat filament through extrusion film, cutting, simple tension, by obtaining product, commonly referred to as woven bag through knitting device.Tradition
The packaging bag of the polypropylene flat-filament establishment of technology production, weatherability is poor, is easy to appear in north of china in winter and hardens, embrittlement, demoulding, rises
The problems such as skin, fracture, is easy to cause woven bag old in south since summer temperature is high, illumination is strong, ultraviolet light penetration power is strong
The problems such as change, burn into poor toughness, the short low service life of intensity, not only waste of resource but also had polluted environment.
Summary of the invention
The purpose of the present invention is to provide a kind of composite plastic woven materials.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of composite plastic woven material, its is composed of the following components by weight: 100-150 parts of polypropylene, poly- methyl
50-60 parts of methyl acrylate, 10-15 parts of toluene sulfonyl semicarbazide, 1-1.5 parts of butanone, 13-15 parts of carbon fiber, 4-6 parts of aniline,
5-6 parts of white oil, 1-2 parts of amine curing agent, antistatic lotion 12-17 parts, 8-15 parts of clay, 0.2-0.4 parts of antibacterial agent, mould inhibitor
0.2-0.4 parts, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of auxiliary agent.
A kind of composite plastic woven material, its is composed of the following components by weight: 100 parts of polypropylene, poly- methyl
50 parts of methyl acrylate, 10 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 13 parts of carbon fiber, 4 parts of aniline, 5 parts of white oil, amine-type cure
1 part of agent, 12 parts of antistatic lotion, 8 parts of clay, 0.2 part of antibacterial agent, 0.2 part of mould inhibitor, 2 parts of gelatin, 15 parts of hydroxypropul starch,
14 parts of auxiliary agent.
A kind of composite plastic woven material, its is composed of the following components by weight: 150 parts of polypropylene, poly- methyl
60 parts of methyl acrylate, 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber, 6 parts of aniline, 6 parts of white oil, amine is solid
2 parts of agent, 17 parts of antistatic lotion, 15 parts of clay, 0.4 part of antibacterial agent, 0.4 part of mould inhibitor, 3 parts of gelatin, hydroxypropul starch 20
Part, 20 parts of auxiliary agent.
A kind of composite plastic woven material, its is composed of the following components by weight: 120 parts of polypropylene, poly- methyl
55 parts of methyl acrylate, 12 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 14 parts of carbon fiber, 5 parts of aniline, 5 parts of white oil, amine-type cure
1 part of agent, 15 parts of antistatic lotion, 10 parts of clay, 0.3 part of antibacterial agent, 0.3 part of mould inhibitor, 2 parts of gelatin, 18 parts of hydroxypropul starch,
18 parts of auxiliary agent.
The antibacterial agent is vanadium diboride.
The mould inhibitor is actinolite.
The auxiliary agent is made from the following raw materials in parts by weight: clay 20-24, alum 5-6, altax 2-3, crosslinking agent
TAC2-3, antioxidant 1010 1-2, actinolite 3-4, ferrocene 2-3, morpholine 1-2,1,6 hexanediyl ester 5-7, adjacent benzene
Dicarboxylic acid esters 35-40, propylgallate 3-4, green tea powder 1-2, coix seed oil 2-3, vanadium diboride 2-3, epicatechin 1-2；System
Preparation Method is that clay, actinolite are sent into calcining furnace to calcine at 720-740 DEG C 2-3 hours, then, takes out, is sent into 10-
It is impregnated 2-3 hours in 15% hydrochloric acid solution, filters, obtain filter residue, cleaned with clear water, dry, be ground into 400-600 mesh powder；
Gained powder is mixed with other residual components, is heated to 60-70 DEG C, is stirred to react 40-50 minutes, cooling, is ground into slurry, i.e.,
?.
What the antistatic lotion was made of the raw material of following weight parts: Dodecydimethylammonium bronides 1-2, gathering
80 0.6-1 of sorb ester, tetradecane binary acid 2-3, precipitated calcium carbonate 17-20, ethyl naphthol 0.1-0.2.
The preparation method of the antistatic lotion, comprising the following steps:
(1) ethyl naphthol is taken, is added in the dehydrated alcohol of 7-9 times of its weight, stirs evenly, increasing temperature is 60-65 DEG C,
Insulated and stirred 1-2 hours, obtain ethyl naphthol alcoholic solution；
(2) precipitated calcium carbonate, the mixing of tetradecane binary acid are taken, insulated and stirred 10-20 minutes at 76-80 DEG C, is added to
In the deionized water of 13-20 times of mixture weight, polyoxyethylene sorbitan monoleate is added, it is 5-10 minutes ultrasonic, obtain calcium carbonate dispersion liquid；
(3) above-mentioned ethyl naphthol alcoholic solution, the mixing of calcium carbonate dispersion liquid are taken, is stirred evenly, increasing temperature is 90-95 DEG C, is protected
Temperature stirring 1-2 hours, is added Dodecydimethylammonium bronides, stirs evenly, obtain the antistatic lotion.
A kind of composite plastic woven material, preparation the following steps are included:
(1) polymethyl methacrylate, toluene sulfonyl semicarbazide mixing are taken, is added in polypropylene, stirs evenly, score
Dispersion liquid；
(2) clay, butanone, carbon fiber, aniline, white oil are taken, is stirred evenly, amine curing agent and hydroxypropul starch is added,
Insulated and stirred 1-2 hours at 60-65 DEG C, the dispersion liquid of mixing step (1)；
(3) mixture for taking above-mentioned steps is added in antistatic lotion, stirs evenly, and antibacterial agent, mould inhibitor is added,
It is 10-20 minutes ultrasonic, obtain mixed emulsion；
(4) it takes above-mentioned mixture to mix with remaining each raw material, stirs evenly, be sent in extruder, heating melting, by taking out
Silk machine reels off raw silk from cocoons, and through cold rinse bank cooling and shaping, winds to get the plastic woven material.
Beneficial effects of the present invention: inventive formulation is simple, at low cost, and manufactured Polywoven Bag can effectively prevent purple
Oxidation reaction caused by outside line illumination solves the problems, such as that packaging bag service life is short in the prior art, and knot of the present invention
It is real durable, anti-skidding, not bale broken, particularly suitable long distance transportation and outlet.
Specific embodiment
The present invention is described further below with reference to embodiment.
Embodiment 1
A kind of composite plastic woven material, its is composed of the following components by weight: 100 parts of polypropylene, polymethyl
50 parts of sour methyl esters, 10 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 13 parts of carbon fiber, 4 parts of aniline, 5 parts of white oil, amine curing agent 1
Part, 12 parts of antistatic lotion, 8 parts of clay, 0.2 part of antibacterial agent, 0.2 part of mould inhibitor, 2 parts of gelatin, 15 parts of hydroxypropul starch, auxiliary agent
14 parts.
Preparation the following steps are included:
(1) polymethyl methacrylate, toluene sulfonyl semicarbazide mixing are taken, is added in polypropylene, stirs evenly, score
Dispersion liquid；
(2) clay, butanone, carbon fiber, aniline, white oil are taken, is stirred evenly, amine curing agent and hydroxypropul starch is added,
Insulated and stirred 1-2 hours at 60-65 DEG C, the dispersion liquid of mixing step (1)；
(3) mixture for taking above-mentioned steps is added in antistatic lotion, stirs evenly, and antibacterial agent, mould inhibitor is added,
It is 10-20 minutes ultrasonic, obtain mixed emulsion；
(4) it takes above-mentioned mixture to mix with remaining each raw material, stirs evenly, be sent in extruder, heating melting, by taking out
Silk machine reels off raw silk from cocoons, and through cold rinse bank cooling and shaping, winds to get the plastic woven material.
Embodiment 2
A kind of composite plastic woven material, its is composed of the following components by weight: 150 parts of polypropylene, polymethyl
60 parts of sour methyl esters, 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber, 6 parts of aniline, 6 parts of white oil, amine curing agent
2 parts, 17 parts of antistatic lotion, 0.4 part of antibacterial agent, 0.4 part of mould inhibitor, 3 parts of gelatin, 20 parts of hydroxypropul starch, helps by 15 parts of clay
20 parts of agent.
Preparation the following steps are included:
(1) polymethyl methacrylate, toluene sulfonyl semicarbazide mixing are taken, is added in polypropylene, stirs evenly, score
Dispersion liquid；
(2) clay, butanone, carbon fiber, aniline, white oil are taken, is stirred evenly, amine curing agent and hydroxypropul starch is added,
Insulated and stirred 1-2 hours at 60-65 DEG C, the dispersion liquid of mixing step (1)；
(3) mixture for taking above-mentioned steps is added in antistatic lotion, stirs evenly, and antibacterial agent, mould inhibitor is added,
It is 10-20 minutes ultrasonic, obtain mixed emulsion；
(4) it takes above-mentioned mixture to mix with remaining each raw material, stirs evenly, be sent in extruder, heating melting, by taking out
Silk machine reels off raw silk from cocoons, and through cold rinse bank cooling and shaping, winds to get the plastic woven material.
Embodiment 3
A kind of composite plastic woven material, its is composed of the following components by weight: 120 parts of polypropylene, polymethyl
55 parts of sour methyl esters, 12 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 14 parts of carbon fiber, 5 parts of aniline, 5 parts of white oil, amine curing agent 1
Part, 15 parts of antistatic lotion, 0.3 part of antibacterial agent, 0.3 part of mould inhibitor, 2 parts of gelatin, 18 parts of hydroxypropul starch, helps by 10 parts of clay
18 parts of agent.
Preparation the following steps are included:
(1) polymethyl methacrylate, toluene sulfonyl semicarbazide mixing are taken, is added in polypropylene, stirs evenly, score
Dispersion liquid；
(2) clay, butanone, carbon fiber, aniline, white oil are taken, is stirred evenly, amine curing agent and hydroxypropul starch is added,
Insulated and stirred 1-2 hours at 60-65 DEG C, the dispersion liquid of mixing step (1)；
(3) mixture for taking above-mentioned steps is added in antistatic lotion, stirs evenly, and antibacterial agent, mould inhibitor is added,
It is 10-20 minutes ultrasonic, obtain mixed emulsion；
(4) it takes above-mentioned mixture to mix with remaining each raw material, stirs evenly, be sent in extruder, heating melting, by taking out
Silk machine reels off raw silk from cocoons, and through cold rinse bank cooling and shaping, winds to get the plastic woven material.
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple
Described specific example does various modifications or additions or is substituted in a similar manner, as long as wanting not past this right
Range defined in book is sought, should belong to the protection scope of invention.
Claims (8)
1. a kind of composite plastic woven material, which is characterized in that its is composed of the following components by weight: polypropylene 100-150
Part, 50-60 parts of polymethyl methacrylate, 10-15 parts of toluene sulfonyl semicarbazide, 1-1.5 parts of butanone, 13-15 parts of carbon fiber, benzene
4-6 parts of amine, 5-6 parts of white oil, 1-2 parts of amine curing agent, antistatic lotion 12-17 parts, 8-15 parts of clay, antibacterial agent 0.2-0.4
Part, 0.2-0.4 parts of mould inhibitor, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of auxiliary agent.
2. a kind of composite plastic woven material according to claim 1, which is characterized in that it is by following components group by weight
At: 150 parts of polypropylene, 60 parts of polymethyl methacrylate, 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber,
6 parts of aniline, 6 parts of white oil, 2 parts of amine curing agent, 17 parts of antistatic lotion, 15 parts of clay, 0.4 part of antibacterial agent, mould inhibitor 0.4
Part, 3 parts of gelatin, 20 parts of hydroxypropul starch, 20 parts of auxiliary agent.
3. a kind of composite plastic woven material according to claim 1, which is characterized in that the antibacterial agent is vanadium diboride.
4. a kind of composite plastic woven material according to claim 1, which is characterized in that the mould inhibitor is actinolite.
5. a kind of composite plastic woven material according to claim 1, which is characterized in that the auxiliary agent is by following parts by weight
Raw material is made: clay 20-24, alum 5-6, altax 2-3, crosslinking agent TAC2-3, antioxidant 1010 1-2, actinolite 3-4,
It is ferrocene 2-3, morpholine 1-2,1,6 hexanediyl ester 5-7, phthalic acid ester 35-40, propylgallate 3-4, green
Tea powder 1-2, coix seed oil 2-3, vanadium diboride 2-3, epicatechin 1-2；Preparation method is that clay, actinolite are sent into calcining furnace
It is calcined at 720-740 DEG C 2-3 hours, then, takes out, be sent into the hydrochloric acid solution of 10-15% and impregnate 2-3 hours, filter, obtain
Filter residue is cleaned with clear water, dries, is ground into 400-600 mesh powder；Gained powder is mixed with other residual components, is heated to 60-
70 DEG C, be stirred to react 40-50 minutes, it is cooling, be ground into slurry to get.
6. a kind of composite plastic woven material according to claim 1, which is characterized in that the antistatic lotion is under
State the raw material composition of parts by weight: Dodecydimethylammonium bronides 1-2, polyoxyethylene sorbitan monoleate 0.6-1, tetradecane binary acid 2-
3, precipitated calcium carbonate 17-20, ethyl naphthol 0.1-0.2.
7. a kind of composite plastic woven material according to claim 5, which is characterized in that the preparation side of the antistatic lotion
Method, comprising the following steps:
(1) ethyl naphthol is taken, is added in the dehydrated alcohol of 7-9 times of its weight, stirs evenly, increasing temperature is 60-65 DEG C, heat preservation
Stirring 1-2 hours, obtains ethyl naphthol alcoholic solution；
(2) precipitated calcium carbonate, the mixing of tetradecane binary acid are taken, insulated and stirred 10-20 minutes at 76-80 DEG C, is added to mixing
In the deionized water of 13-20 times of weight of material, polyoxyethylene sorbitan monoleate is added, it is 5-10 minutes ultrasonic, obtain calcium carbonate dispersion liquid；
(3) above-mentioned ethyl naphthol alcoholic solution, the mixing of calcium carbonate dispersion liquid are taken, is stirred evenly, increasing temperature is 90-95 DEG C, and heat preservation is stirred
It mixes 1-2 hours, Dodecydimethylammonium bronides is added, stirs evenly, obtains the antistatic lotion.
8. a kind of composite plastic woven material according to claim 1, preparation the following steps are included:
(1) polymethyl methacrylate, toluene sulfonyl semicarbazide mixing are taken, is added in polypropylene, stirs evenly, must disperse
Liquid；
(2) clay, butanone, carbon fiber, aniline, white oil are taken, is stirred evenly, amine curing agent and hydroxypropul starch is added, in 60-
Insulated and stirred 1-2 hours at 65 DEG C, the dispersion liquid of mixing step (1)；
(3) mixture for taking above-mentioned steps is added in antistatic lotion, stirs evenly, and antibacterial agent, mould inhibitor, ultrasound is added
10-20 minutes, obtain mixed emulsion；
(4) it takes above-mentioned mixture to mix with remaining each raw material, stirs evenly, be sent in extruder, heating melting, by spinning machine
It reels off raw silk from cocoons, through cold rinse bank cooling and shaping, winds to get the plastic woven material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811075755.2A CN109234837A (en) | 2018-09-14 | 2018-09-14 | A kind of composite plastic woven material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811075755.2A CN109234837A (en) | 2018-09-14 | 2018-09-14 | A kind of composite plastic woven material |
Publications (1)
| Publication Number | Publication Date |
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| CN109234837A true CN109234837A (en) | 2019-01-18 |
Family
ID=65058546
Family Applications (1)
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| CN201811075755.2A Pending CN109234837A (en) | 2018-09-14 | 2018-09-14 | A kind of composite plastic woven material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111748867A (en) * | 2019-03-28 | 2020-10-09 | 安庆市康明纳包装有限公司 | Composite plastic woven packaging bag |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614802A (en) * | 2013-11-28 | 2014-03-05 | 安徽安远塑胶股份有限公司 | Filament for thermal insulating plastic woven bags |
| CN103710787A (en) * | 2013-11-28 | 2014-04-09 | 安徽安远塑胶股份有限公司 | Anti-ultraviolet plastic woven-bag filament |
| CN107474392A (en) * | 2017-09-29 | 2017-12-15 | 安徽明诚塑业有限公司 | A kind of composite plastic woven material |
| CN108130622A (en) * | 2017-12-25 | 2018-06-08 | 桐城市祥泰塑业有限公司 | A kind of anti-static plastic braided material and preparation method thereof |
-
2018
- 2018-09-14 CN CN201811075755.2A patent/CN109234837A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614802A (en) * | 2013-11-28 | 2014-03-05 | 安徽安远塑胶股份有限公司 | Filament for thermal insulating plastic woven bags |
| CN103710787A (en) * | 2013-11-28 | 2014-04-09 | 安徽安远塑胶股份有限公司 | Anti-ultraviolet plastic woven-bag filament |
| CN107474392A (en) * | 2017-09-29 | 2017-12-15 | 安徽明诚塑业有限公司 | A kind of composite plastic woven material |
| CN108130622A (en) * | 2017-12-25 | 2018-06-08 | 桐城市祥泰塑业有限公司 | A kind of anti-static plastic braided material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111748867A (en) * | 2019-03-28 | 2020-10-09 | 安庆市康明纳包装有限公司 | Composite plastic woven packaging bag |
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Application publication date: 20190118 |