CN109234048A - A kind of stainless steel cleanser compositions and its application - Google Patents
A kind of stainless steel cleanser compositions and its application Download PDFInfo
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- CN109234048A CN109234048A CN201811032650.9A CN201811032650A CN109234048A CN 109234048 A CN109234048 A CN 109234048A CN 201811032650 A CN201811032650 A CN 201811032650A CN 109234048 A CN109234048 A CN 109234048A
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- cleanser compositions
- polyoxyethylene ether
- clinoptilolite
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/122—Sulfur-containing, e.g. sulfates, sulfites or gypsum
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The invention discloses a kind of stainless steel cleanser compositions and its applications, it is related to metal cleaner technical field, this kind of detergent includes following raw material: aliphatic amine polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, diethylene glycol ether, 1,3- dimethyl urea, zinc sulfate, Lotus Root Starch, glucolactone, coconut diethanolamide, clinoptilolite, α-sodium olefin sulfonate, snail mucus, chlorogenic acid, wetting dispersing agent, Compounded Antifoamer, compounding corrosion inhibitor, water.Stainless steel detergent of the invention is environmentally protective, cleaning effect is good, washing ability is strong, it not will cause secondary pollution after use, any corrosion will not be more caused to stainless steel products, the rustproof property and glossiness for greatly increasing surface of stainless steel product are remarkably improved the antibacterial ability and Durability of antimicrobial effect of stainless steel products.
Description
Technical field
The present invention relates to metal cleaner technical fields, and in particular to a kind of stainless steel cleanser compositions and its application.
Background technique
With the development of modern society, steel industry has become the pillar industry of country, the processing industries such as lathe, workpiece
It constantly rises, the material of many workpiece has been changed to stainless steel products by plastic products.Present stainless steel products has also goed deep into house
The various aspects of front yard life, stainless steel tableware, stainless steel ornament, stainless steel bathhouse article, stainless steel household electrical appliances etc..Stainless steel watch
Face is beautiful, smooth and corrosion-resistant, very popular, but on the other hand, forms heavily fortified point just because of its corrosion resistance face
Strong oxidation film, therefore, fingerprint, hand dirt are all easily adhered.In fingerprint containing human sebaceous glands generate secretion, mainly at
Dividing is sodium chloride, lactic acid, urea, ammonium chloride and fatty acid etc..This substance, which is attached to stainless steel surface, will play corrosive agent
Effect, so that stainless steel surface is tarnished, or even stain occur, influence the beauty of product.Presently commercially available stainless steel cleaning
Agent usually contains alcohol equal solvent, the secondary pollutions such as fingerprint, hand dirt is often generated in use process, and after cleaning cleaning, no
Steel part antibacterial surface effect of becoming rusty is poor, and washing power is more insufficient.
The patent application of Publication No. CN106702412A discloses a kind of new type stainless steel. corrosion resistance cleaning agent, according to parts by volume
Number meter includes following components: 65% 4-10 parts of n-Propyl Bromide, 78% 8-15 parts of triethanolamine, 70% nonylphenol polyoxyethylene ether 3-
9 parts, 54% 10-15 parts of sodium metasilicate, 65% 2.4-5.3 parts of tributyl phosphate, 80% 12-16 parts of calgon, 50% hydroxyl
3.2-4.5 parts of base ethylidene diphosphonic acid, 95% 1.8-3.6 parts of citric acid.This kind of stainless steel cleaner safety and environmental protection, cost compared with
It is low, but its washing power is not good enough, application is poor.
The patent application of Publication No. CN104402494A discloses a kind of stainless steel detergent, by following mass fraction
Formula components composition: 15-17 parts of mono laurate propylene glycol ester, 11-13 parts of both sexes sodium salt, 22-24 parts of sodium tripolyphosphate, white oil
11-13 parts, 15-25 parts of sodium hydroxide, 16-18 parts of glycerol caprylate, 7-9 parts of tetrafluorodichloroethane, ricinoleate zinc 11-13
Part, 20-40 parts of distilled water, this kind of stainless steel detergent has detergency well, but its anti-microbial property is insufficient, and application is not
It reaches.
Summary of the invention
The purpose of the present invention is to provide a kind of stainless steel cleanser compositions and its application, this kind of stainless steel detergent systems
Standby simple and convenient, environmentally protective, application is good.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of stainless steel cleanser compositions are made of following raw material according to parts by weight:
12.5-15 parts of aliphatic amine polyoxyethylene ether；
7-8 parts of isomery undecyl alcohol polyoxyethylene ether；
8-9 parts of diethylene glycol ether；
3-4 parts of 1,3- dimethyl urea；
2-2.5 parts of zinc sulfate；
15-20 parts of Lotus Root Starch；
4-5 parts of glucolactone；
6-7 parts of coconut diethanolamide；
10-12 parts of clinoptilolite；
α -8-10 parts of sodium olefin sulfonate；
2.5-3.5 parts of snail mucus；
1.5-2 parts of chlorogenic acid；
2.5-3 parts of wetting dispersing agent；
1.5-2 parts of Compounded Antifoamer；
Corrosion inhibitor 2-2.5 parts of compounding；
140-160 parts of magnetized water；
Above-mentioned wetting dispersing agent is three kinds of Aerosol OT, calcium lignosulfonate, Nekal BX ingredients
Composition.
Further, above-mentioned Compounded Antifoamer is dimethyl silicone polymer, polyoxyethylene polyoxypropylene propylene glycol, dioxy
Three kinds of ingredients of SiClx are according to mass ratio (4-5): (2.5-3): (1.5-2) merging obtains.
Further, above-mentioned compounding corrosion inhibitor is inositol hexaphosphate, methylbenzotriazole, three kinds of poly-epoxy succinic acid
Ingredient is according to mass ratio (5-6): (3-4): (4-5) merging obtains.
Further, above-mentioned stainless steel cleanser compositions are made of following raw material according to parts by weight:
15 parts of aliphatic amine polyoxyethylene ether；
8 parts of isomery undecyl alcohol polyoxyethylene ether；
9 parts of diethylene glycol ether；
4 parts of 1,3- dimethyl urea；
2.5 parts of zinc sulfate；
20 parts of Lotus Root Starch；
5 parts of glucolactone；
7 parts of coconut diethanolamide；
12 parts of clinoptilolite；
10 parts of α-sodium olefin sulfonate；
3.5 parts of snail mucus；
2 parts of chlorogenic acid；
3 parts of wetting dispersing agent；
2 parts of Compounded Antifoamer；
2.5 parts of corrosion inhibitor of compounding；
160 parts of magnetized water.
Further, above-mentioned wetting dispersing agent is Aerosol OT, calcium lignosulfonate, Nekal BX three
Kind ingredient is what 2:2:3 merged according to mass ratio.
Further, above-mentioned Compounded Antifoamer is dimethyl silicone polymer, polyoxyethylene polyoxypropylene propylene glycol, dioxy
Three kinds of ingredients of SiClx are what 5:3:2 merged according to mass ratio.
Further, above-mentioned compounding corrosion inhibitor is inositol hexaphosphate, methylbenzotriazole, three kinds of poly-epoxy succinic acid
Ingredient is what 6:4:5 merged according to mass ratio.
Further, above-mentioned detergent the preparation method is as follows:
Step 1: weighing raw material by the parts by weight；
Step 2: taking clinoptilolite milling drying, cross 400 meshes and be placed on calcination process 40min in roaster, roasting temperature
Degree is 380 DEG C, obtains clinoptilolite powder after cooling；
Step 3: aliphatic amine polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, Lotus Root Starch, magnetized water being taken to be added jointly
Into blender, 10min is stirred under the conditions of temperature is 62 DEG C, speed of agitator is 800r/min, obtains mixing A；
Step 4: 1,3- dimethyl urea, zinc sulfate, glucolactone, chlorogenic acid being taken to be added in blender and mix jointly
Expect A mixing, and stir 8min under the conditions of temperature is 50 DEG C, speed of agitator is 500r/min, obtains mixed material B；
Step 5: under stirring condition, taking diethylene glycol ether, coconut diethanolamide, α-sodium olefin sulfonate, snail mucus
It is added sequentially to mix in blender with mixed material B, and is persistently stirred under the conditions of temperature is 65 DEG C, speed of agitator is 1000r/min
6min is mixed, mixing C is obtained；
Step 6: under stirring condition, taking wetting dispersing agent, clinoptilolite powder, compounding corrosion inhibitor, Compounded Antifoamer successively
It is added in blender and is mixed sufficiently with mixing C, finally by the material after puddling through ultrasonic vibration.
Further, above-mentioned ultrasonic vibration temperature is 58 DEG C, frequency 70KHz, time 45min.
Further, above-mentioned stainless steel cleanser compositions are in stainless steel tableware, stainless steel medical instrument, stainless steel man
Application in tool, hardware building materials field.
The present invention has following the utility model has the advantages that the present invention passes through to stainless steel detergent raw materials for production and preparation method
Explore and improve, using magnetized water as base-material, select aliphatic amine polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, Lotus Root Starch,
Clinoptilolite, α-sodium olefin sulfonate, snail mucus are added, the cooperative interaction of the outer adding assistant of compatibility, so that finished product stainless steel
Detergent has reached following characteristics:
(1) stainless steel detergent of the invention is environmentally protective, has no irritating odor, and nonhazardous effect can be recycled after use
Filtration cycle utilizes；
(2) stainless steel detergent of the invention is remarkably improved the antibacterial ability and Durability of antimicrobial effect of stainless steel products,
Ensure the safety and sanitation of stainless steel products；
(3) stainless steel detergent apparent condition of the invention it is uniform, it is not stratified, without precipitating, product is stablized, heat resistance
It is good, it is not volatile, easily store；
(4) stainless steel cleaner cleaning effect of the invention is good, and washing ability is strong, not will cause secondary pollution after use,
Any corrosion will not be more caused to stainless steel products, greatly increase the rustproof property and gloss of surface of stainless steel product
Degree.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
It all raw materials in embodiment and its produces composition and can be obtained by disclosed commercially available channel；
Embodiment 1
The present embodiment is related to a kind of stainless steel cleanser compositions, this kind of detergent is by following raw material according to parts by weight
Composition:
10 parts of aliphatic amine polyoxyethylene ether；
6 parts of isomery undecyl alcohol polyoxyethylene ether；
7 parts of diethylene glycol ether；
2.5 parts of 1,3- dimethyl urea；
1.5 parts of zinc sulfate；
10 parts of Lotus Root Starch；
3 parts of glucolactone；
5 parts of coconut diethanolamide；
8 parts of clinoptilolite；
6 parts of α-sodium olefin sulfonate；
2 parts of snail mucus；
1 part of chlorogenic acid；
2 parts of wetting dispersing agent；
1 part of Compounded Antifoamer；
1.5 parts of corrosion inhibitor of compounding；
120 parts of magnetized water.
It wetting dispersing agent in the present embodiment, Compounded Antifoamer and compounds the selection of corrosion inhibitor and produces as shown in table 1 below:
Table 1
The preparation method of stainless steel detergent substantially follows the steps below in the present embodiment:
Step 1: weighing raw material by above-mentioned parts by weight；
Step 2: taking clinoptilolite milling drying, cross 300 meshes and be placed on calcination process 30min in roaster, roasting temperature
Degree is 400 DEG C, obtains clinoptilolite powder after cooling；
Step 3: aliphatic amine polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, Lotus Root Starch, magnetized water being taken to be added jointly
Into blender, 15min is stirred under the conditions of temperature is 58 DEG C, speed of agitator is 700r/min, obtains mixing A；
Step 4: 1,3- dimethyl urea, zinc sulfate, glucolactone, chlorogenic acid being taken to be added in blender and mix jointly
Expect A mixing, and stir 10min under the conditions of temperature is 46 DEG C, speed of agitator is 400r/min, obtains mixed material B；
Step 5: under stirring condition, taking diethylene glycol ether, coconut diethanolamide, α-sodium olefin sulfonate, snail mucus
It is added sequentially to mix in blender with mixed material B, and is persistently stirred under the conditions of temperature is 60 DEG C, speed of agitator is 800r/min
8min obtains mixing C；
Step 6: under stirring condition, taking wetting dispersing agent, clinoptilolite powder, compounding corrosion inhibitor, Compounded Antifoamer successively
It is added in blender and is mixed sufficiently with mixing C, finally by the material after puddling through ultrasonic vibration, ultrasonic vibration temperature is
54 DEG C, frequency 50KHz, time 55min；
Embodiment 2
The present embodiment is related to a kind of stainless steel cleanser compositions, this kind of detergent is by following raw material according to parts by weight
Composition:
12.5 parts of aliphatic amine polyoxyethylene ether；
7 parts of isomery undecyl alcohol polyoxyethylene ether；
8 parts of diethylene glycol ether；
3 parts of 1,3- dimethyl urea；
2 parts of zinc sulfate；
15 parts of Lotus Root Starch；
4 parts of glucolactone；
6 parts of coconut diethanolamide；
10 parts of clinoptilolite；
8 parts of α-sodium olefin sulfonate；
2.5 parts of snail mucus；
1.5 parts of chlorogenic acid；
2.5 parts of wetting dispersing agent；
1.5 parts of Compounded Antifoamer；
2 parts of corrosion inhibitor of compounding；
140 parts of magnetized water.
It wetting dispersing agent in the present embodiment, Compounded Antifoamer and compounds the selection of corrosion inhibitor and produces as shown in table 2 below:
Table 2
The preparation method of stainless steel detergent substantially follows the steps below in the present embodiment:
Step 1: weighing raw material by above-mentioned parts by weight；
Step 2: taking clinoptilolite milling drying, cross 350 meshes and be placed on calcination process 35min in roaster, roasting temperature
Degree is 390 DEG C, obtains clinoptilolite powder after cooling；
Step 3: aliphatic amine polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, Lotus Root Starch, magnetized water being taken to be added jointly
Into blender, 12min is stirred under the conditions of temperature is 60 DEG C, speed of agitator is 750r/min, obtains mixing A；
Step 4: 1,3- dimethyl urea, zinc sulfate, glucolactone, chlorogenic acid being taken to be added in blender and mix jointly
Expect A mixing, and stir 9min under the conditions of temperature is 48 DEG C, speed of agitator is 450r/min, obtains mixed material B；
Step 5: under stirring condition, taking diethylene glycol ether, coconut diethanolamide, α-sodium olefin sulfonate, snail mucus
It is added sequentially to mix in blender with mixed material B, and is persistently stirred under the conditions of temperature is 63 DEG C, speed of agitator is 900r/min
7min obtains mixing C；
Step 6: under stirring condition, taking wetting dispersing agent, clinoptilolite powder, compounding corrosion inhibitor, Compounded Antifoamer successively
It is added in blender and is mixed sufficiently with mixing C, finally by the material after puddling through ultrasonic vibration, ultrasonic vibration temperature is
56 DEG C, frequency 60KHz, time 50min；
Embodiment 3
The present embodiment is related to a kind of stainless steel cleanser compositions, this kind of detergent is by following raw material according to parts by weight
Composition:
15 parts of aliphatic amine polyoxyethylene ether；
8 parts of isomery undecyl alcohol polyoxyethylene ether；
9 parts of diethylene glycol ether；
4 parts of 1,3- dimethyl urea；
2.5 parts of zinc sulfate；
20 parts of Lotus Root Starch；
5 parts of glucolactone；
7 parts of coconut diethanolamide；
12 parts of clinoptilolite；
10 parts of α-sodium olefin sulfonate；
3.5 parts of snail mucus；
2 parts of chlorogenic acid；
3 parts of wetting dispersing agent；
2 parts of Compounded Antifoamer；
2.5 parts of corrosion inhibitor of compounding；
160 parts of magnetized water.
It wetting dispersing agent in the present embodiment, Compounded Antifoamer and compounds the selection of corrosion inhibitor and produces as shown in table 3 below:
Table 3
The preparation method of stainless steel detergent substantially follows the steps below in the present embodiment:
Step 1: weighing raw material by above-mentioned parts by weight；
Step 2: taking clinoptilolite milling drying, cross 400 meshes and be placed on calcination process 40min in roaster, roasting temperature
Degree is 380 DEG C, obtains clinoptilolite powder after cooling；
Step 3: aliphatic amine polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, Lotus Root Starch, magnetized water being taken to be added jointly
Into blender, 10min is stirred under the conditions of temperature is 62 DEG C, speed of agitator is 800r/min, obtains mixing A；
Step 4: 1,3- dimethyl urea, zinc sulfate, glucolactone, chlorogenic acid being taken to be added in blender and mix jointly
Expect A mixing, and stir 8min under the conditions of temperature is 50 DEG C, speed of agitator is 500r/min, obtains mixed material B；
Step 5: under stirring condition, taking diethylene glycol ether, coconut diethanolamide, α-sodium olefin sulfonate, snail mucus
It is added sequentially to mix in blender with mixed material B, and is persistently stirred under the conditions of temperature is 65 DEG C, speed of agitator is 1000r/min
6min is mixed, mixing C is obtained；
Step 6: under stirring condition, taking wetting dispersing agent, clinoptilolite powder, compounding corrosion inhibitor, Compounded Antifoamer successively
It is added in blender and is mixed sufficiently with mixing C, finally by the material after puddling through ultrasonic vibration, ultrasonic vibration temperature is
58 DEG C, frequency 70KHz, time 45min；
The magnetic agitation that blender in above-described embodiment is produced using Weihai southern exposure chemical machinery Co., Ltd is anti-
Answer kettle.
Comparative example group
"-" indicates that the reduction of certain ingredient in embodiment uses in the following table 4；
Table 4
Comparative example 6
This comparative example is related to a kind of stainless steel detergent, relative to above-described embodiment 3, there is only Compounded Antifoamer at
Divide difference；
The ingredient of defoaming agent in this comparative example are as follows: dimethyl silicone polymer.
Comparative example 7
This comparative example is related to a kind of stainless steel detergent, relative to above-described embodiment 1, there is only compounding corrosion inhibitor respectively at
Divide the difference of mass ratio；
Corrosion inhibitor mass ratio of each component is compounded in this comparative example are as follows: inositol hexaphosphate: methylbenzotriazole: polycyclic oxygen
Succinic acid=1:1:1.
Comparative example 8
This comparative example is related to a kind of stainless steel detergent, relative to above-described embodiment 2, only by magnetized water change into it is common from
Water.
Comparative example 9
This comparative example is related to a kind of stainless steel detergent, and relative to above-described embodiment 3, there is only preparation methods not
Together.
In this comparative example stainless steel detergent the preparation method is as follows:
Step 1: weighing raw material by parts by weight listed by above-described embodiment 3；
Step 2: taking clinoptilolite milling drying, cross 400 meshes and be placed on calcination process 80min in roaster, roasting temperature
Degree is 380 DEG C, obtains clinoptilolite powder after cooling；
Step 3: clinoptilolite powder obtained and other all raw materials being added in blender jointly, are 56 in temperature
DEG C, speed of agitator be 800r/min under the conditions of stir 2h, finally by the material after puddling through ultrasonic vibration, ultrasonic vibration temperature
Degree is 58 DEG C, frequency 70KHz, time 45min.
Comparative example 10
A kind of stainless steel detergent is made of following mass fraction formula components: 15-17 parts of mono laurate propylene glycol ester,
11-13 parts of both sexes sodium salt, 22-24 parts of sodium tripolyphosphate, 11-13 parts of white oil, 15-25 parts of sodium hydroxide, glycerol caprylate 16-18
Part, 7-9 parts of tetrafluorodichloroethane, 11-13 parts of ricinoleate zinc, 20-40 parts of distilled water.
Implementation result
One, the appropriate test product of the stainless steel detergent of above-described embodiment 1-5 and comparative example 1-10 is taken to carry out performance in the following table 5
Indexs measure；
Detect test specimen: 304 model stainless steels；Specification: 50mm × 25mm × 3mm；
Test reference standard: the national standard file " GB/T 35759-2017 " newly issued.
Table 5
5 partial content of table explanation:
1. washing power: record each group detergent is configured to the washing power that the aqueous solution of mass concentration 3% shows at 40 DEG C.
2. corrosivity: experimental condition is (80 ± 2) DEG C, 2h.
3. rust-preventing characteristic: experimental condition be (35 ± 2) DEG C, RH (90 ± 2) %, for 24 hours.
Rank setting: 0 grade: surface is rustless；1 grade: surface is rustless, light discolouration or loss of gloss；2 grades: surface is gently become rusty or unevenness
Even discoloration；3 grades: the corrosion of surface large area,
4. high-temperature stability: experimental condition is (60 ± 2) DEG C, 6h；
Whether meet uniformly, not stratified situation.
5. low-temperature stability: experimental condition is (- 5 ± 2) DEG C, for 24 hours；
Whether meet uniformly, it is not stratified, the case where nodeless mesh or Precipitation.
Two, anti-microbial property detects
Test strain: staphylococcus aureus, Escherichia coli；
Big body detecting method is as follows:
(1) 304 stainless steel test specimens are equally taken, specification is in 50mm × 25mm × 3mm；
(2) several milliliters of bacterium solutions are added dropwise on test specimen, clump count is made to maintain 105CFU/ml；
(3) plastic film is covered on surface of test piece, be then placed in sterilized petri dishes, in 36 ± 1 DEG C of constant incubators
After culture 24 hours, viable bacteria is counted, antibiotic rate A1 and B1 are obtained；
(4) each group stainless steel detergent rinses test specimen, viable bacteria is counted again after rinsing, obtain antibiotic rate A2
And B2；
(5) it will be stood for 24 hours under the test specimen natural conditions after rinsing, viable bacteria counted, antibiotic rate A3 and B3 are obtained；
The testing result of anti-microbial property is shown in Table 6.
Table 6
By upper table 5 and table 6, it can be concluded that, stainless steel detergent of the invention is to have in the selection and production preparation of raw material
Exquisite, the cooperative interaction between ingredient makes detergent of the invention have excellent physicochemical property, antibiotic property and durable
Property, application performance are obviously improved, wide market.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of stainless steel cleanser compositions, which is characterized in that be made of following raw material according to parts by weight:
12.5-15 parts of aliphatic amine polyoxyethylene ether；
7-8 parts of isomery undecyl alcohol polyoxyethylene ether；
8-9 parts of diethylene glycol ether；
3-4 parts of 1,3- dimethyl urea；
2-2.5 parts of zinc sulfate；
15-20 parts of Lotus Root Starch；
4-5 parts of glucolactone；
6-7 parts of coconut diethanolamide；
10-12 parts of clinoptilolite；
α -8-10 parts of sodium olefin sulfonate；
2.5-3.5 parts of snail mucus；
1.5-2 parts of chlorogenic acid；
2.5-3 parts of wetting dispersing agent；
1.5-2 parts of Compounded Antifoamer；
Corrosion inhibitor 2-2.5 parts of compounding；
140-160 parts of magnetized water；
The wetting dispersing agent is the combination of Aerosol OT, three kinds of calcium lignosulfonate, Nekal BX ingredients
Object.
2. a kind of stainless steel cleanser compositions according to claim 1, which is characterized in that the Compounded Antifoamer is poly-
Three kinds of dimethyl siloxane, polyoxyethylene polyoxypropylene propylene glycol, silica ingredients are (4-5): (2.5- according to mass ratio
3): what (1.5-2) merging obtained.
3. a kind of stainless steel cleanser compositions according to claim 1, which is characterized in that the compounding corrosion inhibitor is flesh
Three kinds of six phosphate of alcohol, methylbenzotriazole, poly-epoxy succinic acid ingredients are (5-6): (3-4) according to mass ratio: (4-5) is closed
And obtain.
4. a kind of stainless steel cleanser compositions according to claim 1, which is characterized in that by it is following according to parts by weight
Raw material composition:
15 parts of aliphatic amine polyoxyethylene ether；
8 parts of isomery undecyl alcohol polyoxyethylene ether；
9 parts of diethylene glycol ether；
4 parts of 1,3- dimethyl urea；
2.5 parts of zinc sulfate；
20 parts of Lotus Root Starch；
5 parts of glucolactone；
7 parts of coconut diethanolamide；
12 parts of clinoptilolite；
10 parts of α-sodium olefin sulfonate；
3.5 parts of snail mucus；
2 parts of chlorogenic acid；
3 parts of wetting dispersing agent；
2 parts of Compounded Antifoamer；
2.5 parts of corrosion inhibitor of compounding；
160 parts of magnetized water.
5. a kind of stainless steel cleanser compositions according to claim 4, which is characterized in that the wetting dispersing agent is amber
Three kinds of amber acid di-isooctyl sodium sulfonate, calcium lignosulfonate, Nekal BX ingredients are what 2:2:3 merged according to mass ratio.
6. a kind of stainless steel cleanser compositions according to claim 5, which is characterized in that the Compounded Antifoamer is poly-
Three kinds of dimethyl siloxane, polyoxyethylene polyoxypropylene propylene glycol, silica ingredients are that 5:3:2 merges according to mass ratio
It arrives.
7. a kind of stainless steel cleanser compositions according to claim 6, which is characterized in that the compounding corrosion inhibitor is flesh
Three kinds of six phosphate of alcohol, methylbenzotriazole, poly-epoxy succinic acid ingredients are what 6:4:5 merged according to mass ratio.
8. a kind of stainless steel cleanser compositions according to claim 7, which is characterized in that the preparation side of the detergent
Method is as follows:
Step 1: weighing raw material by the parts by weight；
Step 2: taking clinoptilolite milling drying, cross 400 meshes and be placed on calcination process 40min in roaster, maturing temperature is
380 DEG C, clinoptilolite powder is obtained after cooling；
Step 3: aliphatic amine polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, Lotus Root Starch, magnetized water being taken to be added to and stir jointly
It mixes in machine, stirs 10min under the conditions of temperature is 62 DEG C, speed of agitator is 800r/min, obtain mixing A；
Step 4: 1,3- dimethyl urea, zinc sulfate, glucolactone, chlorogenic acid being taken to be added in blender jointly and mixing A
Mixing, and 8min is stirred under the conditions of temperature is 50 DEG C, speed of agitator is 500r/min, obtain mixed material B；
Step 5: under stirring condition, taking diethylene glycol ether, coconut diethanolamide, α-sodium olefin sulfonate, snail mucus successively
It is added in blender and is mixed with mixed material B, and persistently stirred under the conditions of temperature is 65 DEG C, speed of agitator is 1000r/min
6min obtains mixing C；
Step 6: under stirring condition, wetting dispersing agent, clinoptilolite powder, compounding corrosion inhibitor, Compounded Antifoamer being taken to sequentially add
It is mixed sufficiently into blender with mixing C, finally by the material after puddling through ultrasonic vibration.
9. a kind of stainless steel cleanser compositions according to claim 8, which is characterized in that the ultrasonic vibration temperature is
58 DEG C, frequency 70KHz, time 45min.
10. a kind of -9 any stainless steel cleanser compositions according to claim 1 are in stainless steel tableware, stainless steel medical treatment
Instrument, stainless furniture of steel, the application in hardware building materials field.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101013273A (en) * | 2006-01-30 | 2007-08-08 | 气体产品与化学公司 | Cleaning formulations |
| CN102560515A (en) * | 2012-03-12 | 2012-07-11 | 海门市森达装饰材料有限公司 | Efficient low-foam special cleaning agent for stainless steel plate |
| CN104278287A (en) * | 2014-09-25 | 2015-01-14 | 巢湖广丰金属制品有限公司 | Corrosion-inhibition type water-based metal cleaner |
-
2018
- 2018-09-05 CN CN201811032650.9A patent/CN109234048A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101013273A (en) * | 2006-01-30 | 2007-08-08 | 气体产品与化学公司 | Cleaning formulations |
| CN102560515A (en) * | 2012-03-12 | 2012-07-11 | 海门市森达装饰材料有限公司 | Efficient low-foam special cleaning agent for stainless steel plate |
| CN104278287A (en) * | 2014-09-25 | 2015-01-14 | 巢湖广丰金属制品有限公司 | Corrosion-inhibition type water-based metal cleaner |
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