CN109231880A - A kind of preparation method of concrete foamer - Google Patents

A kind of preparation method of concrete foamer Download PDF

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Publication number
CN109231880A
CN109231880A CN201811327851.1A CN201811327851A CN109231880A CN 109231880 A CN109231880 A CN 109231880A CN 201811327851 A CN201811327851 A CN 201811327851A CN 109231880 A CN109231880 A CN 109231880A
Authority
CN
China
Prior art keywords
parts
concrete
concrete foamer
surfactant
dibutyl tin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811327851.1A
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Chinese (zh)
Inventor
姚海港
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Pizhou Tiefu Kowloon Public Service Co Ltd
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Pizhou Tiefu Kowloon Public Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pizhou Tiefu Kowloon Public Service Co Ltd filed Critical Pizhou Tiefu Kowloon Public Service Co Ltd
Priority to CN201811327851.1A priority Critical patent/CN109231880A/en
Publication of CN109231880A publication Critical patent/CN109231880A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/42Pore formers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention belongs to building material technical fields, and in particular to a kind of preparation method of concrete foamer.Concrete foamer, the following raw material the following steps are included: will be uniformly mixed by preparation method in parts by weight: 40~50 parts of sorbierite, 2~3 parts of potassium phosphate, 2~3 parts of polyglyceryl fatty acid ester, 1~2 part of polylactic acid, 3~5 parts of chitosan, 3~5 parts of benzyltriethylammoinium chloride, 3~7 parts of dibutyl tin laurate, 6~12 parts of triethylsilane, 3~5 parts of dibutyl tin laurate, 2~4 parts of acrylic acid, 1~2 part of boron nitride, 1~3 part of diethanol amine, 5~8 parts of chitin, 10~15 parts of polyethylene glycol, 5~9 parts of sodium tripolyphosphate, 4~7 parts of the tert-butyl alcohol, 3~6 parts of dimethyl carbonate, 2~5 parts of silica white, 1~2 part of choline chloride, 5~8 parts of hydrochloric acid, 5~8 parts of diatomite, 2~8 parts of wheat bran, 3~6 parts of calcium monohydrogen phosphate, surfactant 1~ 2 parts, 20~30 parts of water.

Description

A kind of preparation method of concrete foamer
Technical field
The invention belongs to building material technical fields, and in particular to a kind of preparation method of concrete foamer.
Background technique
Foamed concrete also known as foam concrete or lightweight concrete, foamed concrete are the foaming systems by foaming machine System mechanically sufficiently foams foaming agent, and foam is uniformly mixed with cement slurry, then passes through the pumping system of foaming machine System carries out cast-in-place construction or mold molding, is formed by a kind of novel light quality guarantee containing a large amount of sealed porositys through natural curing Adiabator;Foamed concrete is double set continuous structures that organic binder is stirred into foaming agent, cement, flyash, mountain flour etc. Polymer, include uniform stomata;Foamed concrete is to look for slope, ground insulating bed course for roof heat insulation, turn over beam foundation pit and fill out It fills, the energy-saving materials such as wall pouring.Foaming agent aqueous solution is usually mechanically prepared into foam by foamed concrete, then Foam is added in the slurry containing compositions such as siliceous material, calcareous material, water and various additives, is mixed, is poured A kind of porous material made of molding, maintenance.Due to, containing a large amount of closed holes, being made it have following in foamed concrete Good physical and mechanical property.1, the density of lightweight, foamed concrete is small, and density rating is generally 300-1800kg/m3, often It is 300-1200kg/m3 with the density rating of foamed concrete.Since the density of foam concrete is small, it can generally make building Self weight reduces by 25% or so, therefore, has significant economic benefit using foamed concrete in construction projects.2, thermal insulation separation Good in thermal property, it is due to, containing a large amount of closed tiny holes, there is good thermal property in foamed concrete, i.e., good Good thermal and insulating performance, this is not available for normal concrete.Usual density rating is in 300-1200kg/m3 range Foamed concrete, for thermal coefficient between 0.08-0.3w/ (mK), thermal resistance is about 10-20 times of normal concrete.Using hair Concrete is steeped as building masonry wall and roofing, and there is good energy-saving effect.3, sound-proof refractory performance is good, and foaming is mixed Solidifying penus porous material, therefore it is also a kind of good acoustic material, in the sound insulation of the floor and highway of building The material can be used as puigging in plate, top layer of underground structure etc..Foam concrete is inorganic material, will not be burnt, from And there is good fire resistance, it is used on building, the fire protecting performance of building can be improved.
CN102276290A provides a kind of concrete foamer, includes in parts by weight: starch 40-60, surface-active Agent 32-47, laruyl alcohol 3-8, the alkali metal salt 2-5 of carboxymethyl cellulose.It is solid that CN103922635A discloses a kind of foam concrete Body powdery foaming agent and its application method, weight part ratio composition are as follows: anionic surfactant: lauryl sodium sulfate 20~ 40 parts, 20~40 parts of α-sodium olefin sulfonate, 5~15 parts of dodecyl polyoxyethylene ether sodium sulphate, sodium lauroyl sarcosine 3~10 Part;Nonionic surfactant: 1~5 part of fatty acid alkanol amides;Chelating: 1~5 part of triethanolamine;Foam stabilizer: polypropylene One of alkene crosslinked resin, polyacrylamide, hydroxyethyl cellulose are 1~5 part several.CN101654345A provides one kind Compound type concrete foaming agent and its preparation method and application is combined by first component and second component, the first component are as follows: 10-20 parts of polyvinyl alcohol, 15-25 parts of rosin, 1.5-2.5 parts of natrium carbonicum calcinatum, 3.5-4.5 parts of industrial caustic soda, triethanolamine 3-5 Part, 0.2-0.5 parts of technical-grade hydrochloric acid, 53.5-55.8 parts of water;The second component are as follows: 0.2-0.5 parts of triethanolamine, sodium sulphate 8- 10 parts, 12-15 parts of sodium nitrite, 10-25 parts of calcium chloride, 54.7-64.5 parts of water.
But above-mentioned foaming agent has that concrete strength is not high.
Summary of the invention
The technical issues of present invention actually solves is: providing the concrete foamer that a kind of foaming effect is good, intensity is high.
The technical solution adopted by the invention is as follows:
A kind of concrete foamer, preparation method the following steps are included:
The following raw material will be uniformly mixed in parts by weight: 40~50 parts of sorbierite, 2~3 parts of potassium phosphate, polyglycereol fat 2~3 parts of acid esters, 1~2 part of polylactic acid, 3~5 parts of chitosan, 3~5 parts of benzyltriethylammoinium chloride, dibutyl tin laurate 3~ 7 parts, 6~12 parts of triethylsilane, 3~5 parts of dibutyl tin laurate, 2~4 parts of acrylic acid, 1~2 part of boron nitride, diethanol amine 1~3 part, 5~8 parts of chitin, 10~15 parts of polyethylene glycol, 5~9 parts of sodium tripolyphosphate, 4~7 parts of the tert-butyl alcohol, dimethyl carbonate 3~6 parts, 2~5 parts of silica white, 1~2 part of choline chloride, 5~8 parts of hydrochloric acid, 5~8 parts of diatomite, 2~8 parts of wheat bran, phosphoric acid hydrogen 3~6 parts of calcium, 1~2 part of surfactant, 20~30 parts of water.
The surfactant is cationic surfactant.
The cationic surfactant is quaternary ammonium salt system.
The molecular weight of the polyethylene glycol is 400.
The mass concentration of the hydrochloric acid is 20%.
The utility model has the advantages that concrete foamer provided by the invention has foaming effect good, the high advantage of concrete strength.
Specific embodiment
The present invention is further described in detail below by specific embodiment, but not limited to this.
Embodiment 1
A kind of concrete foamer, preparation method the following steps are included:
The following raw material will be uniformly mixed in parts by weight: 40 parts of sorbierite, 2 parts of potassium phosphate, 2 parts of polyglyceryl fatty acid ester, 1 part of polylactic acid, 3 parts of chitosan, 3 parts of benzyltriethylammoinium chloride, 3 parts of dibutyl tin laurate, 6 parts of triethylsilane, laurel 3 parts of sour dibutyl tin, 2 parts of acrylic acid, 1 part of boron nitride, 1 part of diethanol amine, 5 parts of chitin, 10 parts of polyethylene glycol, tripolyphosphate 5 parts of sodium, 4 parts of the tert-butyl alcohol, 3 parts of dimethyl carbonate, 2 parts of silica white, 1 part of choline chloride, 5 parts of hydrochloric acid, 5 parts of diatomite, wheat bran 2 Part, 3 parts of calcium monohydrogen phosphate, 1 part of surfactant, 20 parts of water.
Ionic surface active agent is quaternary ammonium salt system, and the molecular weight of the polyethylene glycol is 400, the quality of the hydrochloric acid Concentration is 20%.
Embodiment 2
A kind of concrete foamer, preparation method the following steps are included:
The following raw material will be uniformly mixed in parts by weight: 50 parts of sorbierite, 3 parts of potassium phosphate, 3 parts of polyglyceryl fatty acid ester, 2 parts of polylactic acid, 5 parts of chitosan, 5 parts of benzyltriethylammoinium chloride, 7 parts of dibutyl tin laurate, 12 parts of triethylsilane, laurel 5 parts of sour dibutyl tin, 4 parts of acrylic acid, 2 parts of boron nitride, 3 parts of diethanol amine, 8 parts of chitin, 15 parts of polyethylene glycol, tripolyphosphate 9 parts of sodium, 7 parts of the tert-butyl alcohol, 6 parts of dimethyl carbonate, 5 parts of silica white, 2 parts of choline chloride, 8 parts of hydrochloric acid, 8 parts of diatomite, wheat bran 8 Part, 6 parts of calcium monohydrogen phosphate, 2 parts of surfactant, 30 parts of water.
Ionic surface active agent is quaternary ammonium salt system, and the molecular weight of the polyethylene glycol is 400, the quality of the hydrochloric acid Concentration is 20%.
Embodiment 3
A kind of concrete foamer, preparation method the following steps are included:
The following raw material will be uniformly mixed in parts by weight: 40 parts of sorbierite, 3 parts of potassium phosphate, 2 parts of polyglyceryl fatty acid ester, 1 part of polylactic acid, 5 parts of chitosan, 4 parts of benzyltriethylammoinium chloride, 4 parts of dibutyl tin laurate, 8 parts of triethylsilane, laurel 4 parts of sour dibutyl tin, acrylic acid 3,1 part of boron nitride, 2 parts of diethanol amine, 5 parts of chitin, 15 parts of polyethylene glycol, sodium tripolyphosphate 5 parts, 5 parts of the tert-butyl alcohol, 5 parts of dimethyl carbonate, 3 parts of silica white, 1 part of choline chloride, 5 parts of hydrochloric acid, 8 parts of diatomite, 8 parts of wheat bran, 6 parts of calcium monohydrogen phosphate, 1 part of surfactant, 24 parts of water.
Ionic surface active agent is quaternary ammonium salt system, and the molecular weight of the polyethylene glycol is 400, the quality of the hydrochloric acid Concentration is 20%.
In order to illustrate foaming agent of the invention foaminess and in terms of performance, in above-described embodiment The foaming agent of synthesis carries out foaming experiment, according to the test method in standard JG/T266-2011 " foam concrete " and requires to survey Coefficient of foaming, foam stabilizing time and the sedimentation of foaming agent are determined away from test result is as follows shown in table:
Project Embodiment 1 Embodiment 2 Embodiment 3
Coefficient of foaming 32 31 35
The foam stabilizing time/h 32 23 26
1h is settled away from/mm 1.1 1.4 1.3
Concrete strength Mpa 139 129 119
Can be seen that concrete foamer provided by the invention from above-mentioned test result has foaming effect good, concrete strength High advantage.

Claims (5)

1. a kind of concrete foamer, which is characterized in that preparation method will be the following steps are included: will in parts by weight will be following former Material is uniformly mixed: 40~50 parts of sorbierite, 2~3 parts of potassium phosphate, 2~3 parts of polyglyceryl fatty acid ester, 1~2 part of polylactic acid, shell 3~5 parts of glycan, 3~5 parts of benzyltriethylammoinium chloride, 3~7 parts of dibutyl tin laurate, 6~12 parts of triethylsilane, laurel 3~5 parts of sour dibutyl tin, 2~4 parts of acrylic acid, 1~2 part of boron nitride, 1~3 part of diethanol amine, 5~8 parts of chitin, poly- second two 10~15 parts of alcohol, 5~9 parts of sodium tripolyphosphate, 4~7 parts of the tert-butyl alcohol, 3~6 parts of dimethyl carbonate, 2~5 parts of silica white, chlorination gallbladder 1~2 part of alkali, 5~8 parts of hydrochloric acid, 5~8 parts of diatomite, 2~8 parts of wheat bran, 3~6 parts of calcium monohydrogen phosphate, 1~2 part of surfactant, 20~30 parts of water.
2. concrete foamer according to claim 1, which is characterized in that the surfactant is cationic surface Activating agent.
3. concrete foamer according to claim 1, which is characterized in that the cationic surfactant is quaternary ammonium Salt system.
4. concrete foamer according to claim 1, which is characterized in that the molecular weight of the polyethylene glycol is 400.
5. concrete foamer according to claim 1, which is characterized in that the mass concentration of the hydrochloric acid is 20%.
CN201811327851.1A 2018-11-09 2018-11-09 A kind of preparation method of concrete foamer Pending CN109231880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811327851.1A CN109231880A (en) 2018-11-09 2018-11-09 A kind of preparation method of concrete foamer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811327851.1A CN109231880A (en) 2018-11-09 2018-11-09 A kind of preparation method of concrete foamer

Publications (1)

Publication Number Publication Date
CN109231880A true CN109231880A (en) 2019-01-18

Family

ID=65077367

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811327851.1A Pending CN109231880A (en) 2018-11-09 2018-11-09 A kind of preparation method of concrete foamer

Country Status (1)

Country Link
CN (1) CN109231880A (en)

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Application publication date: 20190118

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