CN109208339A - A kind of heat-resisting emulational leather material - Google Patents
A kind of heat-resisting emulational leather material Download PDFInfo
- Publication number
- CN109208339A CN109208339A CN201810942512.8A CN201810942512A CN109208339A CN 109208339 A CN109208339 A CN 109208339A CN 201810942512 A CN201810942512 A CN 201810942512A CN 109208339 A CN109208339 A CN 109208339A
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- CN
- China
- Prior art keywords
- parts
- resisting
- heat
- tetrabromobisphenol
- molybdenum trioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1628—Dimensional stability
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1685—Wear resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of heat-resisting emulational leather material, contains the following parts by weight: 20-50 parts of matrix resin SEBS, 20-40 parts of tetrabromobisphenol A, 2-20 parts of molybdenum trioxide, 0.3-1.5 parts of antioxidant, 60-80 parts of polyvinyl chloride, 2-4 parts of melamine, 9-15 parts of tetrabromobisphenol A, 1-3 parts of molybdenum trioxide, 10-15 parts of hexabromocyclododecane, 15-20 parts of zinc borate, 2-5 parts of plasticizer, 6-10 parts of expansible graphite, 2-5 parts of cosolvent, 15-19 parts of flame retarding polyether, 7-9 parts of brominated epoxy resin, 0.1-0.3 parts of coupling agent.The heat-resisting fire-retardant emulational leather material of emulation provided by the invention, handsome in appearance, environmental protection and energy saving, do not absorb water, be non-ignitable, is wear-resisting, simple process, dimensional stability are good, compressive creep resistance can be good, adapt to mechanized production line, it is cheap, pattern according to demand can watermark can also use coating technique.
Description
Technical field
The present invention relates to a kind of processing and fabricating fields of leather substance, and in particular to a kind of heat-resisting emulational leather material.
Background technique
The leather substance of Vehicles Collected from Market is only made of a kind of material of leather mostly, and effect is relatively simple, with the warp of science and technology
The method cane of Ji, there has been proposed more demands.Emulational leather is on woven fabric base or nonwoven fabric base, by various different formulations
The foaming such as PVC, PU and PU or overlay film processing and fabricating form, can be according to varying strength, wear resistance, cold-resistant degree and color, light
The requirements such as pool, floral designs are processed into, with designs and varieties are various, waterproof performance is good, not care about one's appearance is neat, utilization rate is high and price
The opposite cheap feature of corium.It is early stage a kind of material all extremely popular till now always, and it is various to be commonly used production
Leather and fur products or partial leather material.Surface is very fine and smooth, can be indefective, and more durable.Automobile,
It is widely used in furniture, household.
Because its material is mostly inflammable thing, scene of fire becomes the occurring source of flue gas poison gas and thermal energy.The people are not only given in this way
Safe quality of life and property bring great fire hazard also to strongly limit in the more demanding special dimension of fire-protection rating
Application.
Summary of the invention
A kind of heat-resisting emulational leather material is provided it is an object of the invention to overcome above-mentioned the deficiencies in the prior art place.
To achieve the above object, the technical solution adopted by the present invention are as follows: a kind of heat-resisting emulational leather material, comprising following heavy
Measure the component of part: 20-50 parts of matrix resin SEBS, 20-40 parts of tetrabromobisphenol A, 2-20 parts of molybdenum trioxide, antioxidant 0.3-
1.5 parts, 60-80 parts of polyvinyl chloride, 2-4 parts of melamine, 9-15 parts of tetrabromobisphenol A, 1-3 parts of molybdenum trioxide, hexabromo ring 12
10-15 parts of alkane, 15-20 parts of zinc borate, 2-5 parts of plasticizer, 6-10 parts of expansible graphite, 2-5 parts of cosolvent, flame retarding polyether 15-
19 parts, 7-9 parts of brominated epoxy resin, 0.1-0.3 parts of coupling agent.
Preferably, the heat-resisting emulational leather material, contains the following parts by weight: 40 parts of matrix resin SEBS, four
30 parts of bromine bisphenol-A, 15 parts of molybdenum trioxide, 0.7 part of antioxidant, 70 parts of polyvinyl chloride, 3 parts of melamine, tetrabromobisphenol A 10
Part, 2 parts of molybdenum trioxide, 12 parts of hexabromocyclododecane, 18 parts of zinc borate, 3 parts of plasticizer, 8 parts of expansible graphite, 4 parts of cosolvent,
18 parts of flame retarding polyether, 8 parts of brominated epoxy resin, 0.2 part of coupling agent.
The beneficial effects of the present invention are: the heat-resisting fire-retardant emulational leather material of emulation provided by the invention, handsome in appearance, ring
Guarantor is energy saving, do not absorb water, is non-ignitable, is wear-resisting, simple process, dimensional stability are good, compressive creep resistance energy is good, adapts to mechanical metaplasia
Produce assembly line, it is cheap, pattern according to demand can watermark can also use coating technique.
Specific embodiment
For more concise displaying technical solution of the present invention, objects and advantages, combined with specific embodiments below
The present invention is described in further detail.
Embodiment 1
The heat-resisting emulational leather material of this implementation contains the following parts by weight: 20 parts of matrix resin SEBS, tetrabromo are double
A20 parts of phenol, 2 parts of molybdenum trioxide, 0.3 part of antioxidant, 60 parts of polyvinyl chloride, 2 parts of melamine, 9 parts of tetrabromobisphenol A, three oxygen
Change 1 part of molybdenum, 10 parts of hexabromocyclododecane, 15 parts of zinc borate, 2 parts of plasticizer, 6 parts of expansible graphite, 2 parts of cosolvent, fire-retardant poly-
15 parts of ether, 7 parts of brominated epoxy resin, 0.1 part of coupling agent.
Embodiment 2
The heat-resisting emulational leather material of this implementation contains the following parts by weight: 50 parts of matrix resin SEBS, tetrabromo are double
A40 parts of phenol, 20 parts of molybdenum trioxide, 1.5 parts of antioxidant, 80 parts of polyvinyl chloride, 4 parts of melamine, 15 parts of tetrabromobisphenol A, three
It is 3 parts of molybdenum oxide, 15 parts of hexabromocyclododecane, 20 parts of zinc borate, 5 parts of plasticizer, 10 parts of expansible graphite, 5 parts of cosolvent, fire-retardant
19 parts of polyethers, 9 parts of brominated epoxy resin, 0.3 part of coupling agent.
Embodiment 3
The heat-resisting emulational leather material of this implementation contains the following parts by weight: 40 parts of matrix resin SEBS, tetrabromo are double
A30 parts of phenol, 15 parts of molybdenum trioxide, 0.7 part of antioxidant, 70 parts of polyvinyl chloride, 3 parts of melamine, 10 parts of tetrabromobisphenol A, three
It is 2 parts of molybdenum oxide, 12 parts of hexabromocyclododecane, 18 parts of zinc borate, 3 parts of plasticizer, 8 parts of expansible graphite, 4 parts of cosolvent, fire-retardant
18 parts of polyethers, 8 parts of brominated epoxy resin, 0.2 part of coupling agent.
Comparative example 1
The heat-resisting emulational leather material of comparative example 1 contains the following parts by weight: 15 parts of molybdenum trioxide, antioxidant
0.7 part, 70 parts of polyvinyl chloride, 3 parts of melamine, 10 parts of tetrabromobisphenol A, 2 parts of molybdenum trioxide, 12 parts of hexabromocyclododecane, boron
18 parts of sour zinc, 3 parts of plasticizer, 8 parts of expansible graphite, 4 parts of cosolvent, 18 parts of flame retarding polyether, 8 parts of brominated epoxy resin, coupling
0.2 part of agent.
Comparative example 2
The heat-resisting emulational leather material of comparative example 2 contains the following parts by weight: 40 parts of matrix resin SEBS, tetrabromo
30 parts of bisphenol-A, 15 parts of molybdenum trioxide, 0.7 part of antioxidant, 70 parts of polyvinyl chloride, 3 parts of melamine, 10 parts of tetrabromobisphenol A,
2 parts of molybdenum trioxide, 18 parts of zinc borate, 3 parts of plasticizer, 8 parts of expansible graphite, 4 parts of cosolvent, is incited somebody to action at 12 parts of hexabromocyclododecane
Embodiment 1-3 and comparative example 1-2 is respectively formulated composite leather obtained and carries out the dedicated performance detection of leather, the results are shown in Table 1.
As seen from the above table, the performance indexes of the embodiment of the present invention 1-3 than comparative example 1,2 than get well, and implement
Example 3 is highly preferred embodiment of the present invention.And comparative example 1,2 is due to lacking raw material of the invention, in the effect of the above aspect of performance
It is poorer than embodiment 1-3, illustrate that the formula of leather substance of the invention is obtained not by the simple combination of each raw material, into one
Step illustrates there is synergistic effect between inventive formulation each component.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (2)
1. a kind of heat-resisting emulational leather material, which is characterized in that contain the following parts by weight: matrix resin SEBS 20-50
Part, 20-40 parts of tetrabromobisphenol A, 2-20 parts of molybdenum trioxide, 0.3-1.5 parts of antioxidant, 60-80 parts of polyvinyl chloride, melamine
2-4 parts, 9-15 parts of tetrabromobisphenol A, 1-3 parts of molybdenum trioxide, 10-15 parts of hexabromocyclododecane, 15-20 parts of zinc borate, plasticizer
2-5 parts, 6-10 parts of expansible graphite, 2-5 parts of cosolvent, 15-19 parts of flame retarding polyether, 7-9 parts of brominated epoxy resin, coupling agent
0.1-0.3 parts.
2. heat-resisting emulational leather material as described in claim 1, which is characterized in that contain the following parts by weight: matrix
40 parts of resin SEBS, 30 parts of tetrabromobisphenol A, 15 parts of molybdenum trioxide, 0.7 part of antioxidant, 70 parts of polyvinyl chloride, melamine 3
Part, 10 parts of tetrabromobisphenol A, 2 parts of molybdenum trioxide, 12 parts of hexabromocyclododecane, 18 parts of zinc borate, 3 parts of plasticizer, inflatable stone
Black 8 parts, 4 parts of cosolvent, 18 parts of flame retarding polyether, brominated epoxy resin part, 0.2 part of coupling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810942512.8A CN109208339A (en) | 2018-08-17 | 2018-08-17 | A kind of heat-resisting emulational leather material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810942512.8A CN109208339A (en) | 2018-08-17 | 2018-08-17 | A kind of heat-resisting emulational leather material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109208339A true CN109208339A (en) | 2019-01-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810942512.8A Pending CN109208339A (en) | 2018-08-17 | 2018-08-17 | A kind of heat-resisting emulational leather material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108978243A (en) * | 2018-08-17 | 2018-12-11 | 广州龙戈皮创文化有限公司 | A kind of complex leather material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592674A (en) * | 2014-12-26 | 2015-05-06 | 神盾防火科技有限公司 | Polyvinyl chloride A-grade fire-retardant interior decoration material |
| CN104611941A (en) * | 2014-12-26 | 2015-05-13 | 神盾防火科技有限公司 | Polyvinyl chloride flame-retardant artificial leather material |
| CN105860329A (en) * | 2016-04-22 | 2016-08-17 | 上海大学 | Bacterial inhibition type flexible polyvinyl chloride artificial leather foaming layer material and preparation method thereof |
| CN107142745A (en) * | 2017-06-03 | 2017-09-08 | 东莞市良展有机硅科技有限公司 | High abrasion silica gel synthetic leather and preparation method thereof |
| CN107476077A (en) * | 2017-08-10 | 2017-12-15 | 丁彬彬 | A kind of preparation technology of ultra-fine velvet surface synthetic leather |
-
2018
- 2018-08-17 CN CN201810942512.8A patent/CN109208339A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592674A (en) * | 2014-12-26 | 2015-05-06 | 神盾防火科技有限公司 | Polyvinyl chloride A-grade fire-retardant interior decoration material |
| CN104611941A (en) * | 2014-12-26 | 2015-05-13 | 神盾防火科技有限公司 | Polyvinyl chloride flame-retardant artificial leather material |
| CN105860329A (en) * | 2016-04-22 | 2016-08-17 | 上海大学 | Bacterial inhibition type flexible polyvinyl chloride artificial leather foaming layer material and preparation method thereof |
| CN107142745A (en) * | 2017-06-03 | 2017-09-08 | 东莞市良展有机硅科技有限公司 | High abrasion silica gel synthetic leather and preparation method thereof |
| CN107476077A (en) * | 2017-08-10 | 2017-12-15 | 丁彬彬 | A kind of preparation technology of ultra-fine velvet surface synthetic leather |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108978243A (en) * | 2018-08-17 | 2018-12-11 | 广州龙戈皮创文化有限公司 | A kind of complex leather material |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190115 |
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