CN109207285A - Has the fabric bacteria-removing liquid and preparation method thereof of mosquito repellent function - Google Patents

Has the fabric bacteria-removing liquid and preparation method thereof of mosquito repellent function Download PDF

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Publication number
CN109207285A
CN109207285A CN201811266785.1A CN201811266785A CN109207285A CN 109207285 A CN109207285 A CN 109207285A CN 201811266785 A CN201811266785 A CN 201811266785A CN 109207285 A CN109207285 A CN 109207285A
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Prior art keywords
removing liquid
bacteria
mosquito repellent
repellent function
fabric
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CN109207285B (en
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骆建华
薛洪伟
吴鹰花
廖国栋
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Zhongshan Lanju Daily Chemical Industries Co Ltd
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Zhongshan Lanju Daily Chemical Industries Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2017Monohydric alcohols branched
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2037Terpenes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2041Dihydric alcohols
    • C11D3/2051Dihydric alcohols cyclic; polycyclic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/30Organic compounds, e.g. vitamins containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44Perfumes; Colouring materials; Brightening agents ; Bleaching agents
    • C11D9/442Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44Perfumes; Colouring materials; Brightening agents ; Bleaching agents
    • C11D9/444Dyes; Pigments

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of fabric bacteria-removing liquids and preparation method thereof for having mosquito repellent function, belong to fabric washing nursing technique field.The bacteria-removing liquid is prepared by the raw material of following mass percent: 1%-10% mosquito repellent function ingredient, 1%-20% solvent, 1%-10% surfactant, 1%-5% fungicide PCMX, auxiliary agent 0.1%-5%.Fabric bacteria-removing liquid produced by the present invention not only has preferable mosquito repellent function, but also stability is good, is suitable for that popularization and use are commercialized.

Description

Has the fabric bacteria-removing liquid and preparation method thereof of mosquito repellent function
Technical field
The present invention relates to fabric washing nursing technique field, more particularly to a kind of fabric bacteria-removing liquid for having mosquito repellent function and Preparation method.
Background technique
Currently, daily use chemicals washing industry product it is all kinds of, and toward multifunction direction develop, if any declare it is submissive, remove Bacterium, color protection etc. other than meeting daily washing demand, are also required as consumer increasingly focuses on healthy living Product can bring additional added value, can offer convenience for the life of oneself, or solve certain worries of living.
In summer, usual mosquito is relatively more, and the people for southern area of especially living often are surrounded by mosquito and bite, this It can cause the red and swollen and scratchy of human skin, can also catch when serious, to the normal life and work of people and outdoor fortune It is dynamic to bring puzzlement.Therefore exploitation has the detergent product of mosquito repellent function, washes rear fabric with repelling effect, is able to solve and disappears The daily worries of the person of expense meet the needs of consumption healthy living, have a vast market foreground.
For these problems, patent CN105671940 B discloses a kind of polyester or the long-acting mosquito-proof knitted side of blended fabric Material and preparation method, the patent provides the methods how one kind prepares mosquito-proof knitting fabric, but the emphasis of the patent exists Fabric itself, even if fabric itself has repelling effect, but mosquito-proof component content is limited in anti-mosquito cloth after all, by daily anti- After after backwashing is washed, mosquito-proof component content can be reduced, and mosquito-proof effect will appear the problem of gradually decaying.And 107012020 A of patent CN Disclose a kind of plant liquid detergent, mention a kind of antipathogenic composition containing natural anophelifuge --- chamomile, but chamomile as it is antibacterial with Mosquito-proof active constituent, effect are undesirable.
Summary of the invention
Based on this, it is necessary to which, in view of the above-mentioned problems, providing a kind of fabric bacteria-removing liquid for having mosquito repellent function, fabric passes through degerming After liquid washing by soaking, fabric can not only reach efficient bacteria-eliminating efficacy, can also achieve the effect that mosquito repellent is mosquito-proof.
A kind of fabric bacteria-removing liquid having mosquito repellent function, is prepared by the raw material of following mass percent:
The solvent is selected from alcohols and alcohol ethers solvent.
The fabric bacteria-removing liquid of above-mentioned tool mosquito repellent function makes degerming by the way that mosquito component to be added in bacteria-removing liquid to reach Liquid has the purpose of mosquito repellent function.And by test and screening repeatedly, specific raw material composition and match ratio are finally had selected Example, obtained fabric bacteria-removing liquid, after the fabric bacteria-removing liquid washing by soaking, fabric can not only reach efficient degerming effect Fruit, moreover it is possible to achieve the effect that mosquito repellent is mosquito-proof, while the fabric bacteria-removing liquid stability is good, be suitable for merchandized handling and use.
The fabric bacteria-removing liquid is prepared by the raw material of following mass percent in one of the embodiments:
The mosquito component is selected from one of the embodiments: Metadelphene, dimethyl phthalate, Icaridin, Meng's glycol, lemongrass Aldehyde, geraniol, citronellol, terpinol, citronella oil, eucalyptus citriodora oil, Permethrin, d-phenothrin, in transfluthrin extremely Few one kind.Preferably Meng's glycol, citronellol, citronella oil, terpinol, more preferably Meng's glycol.
The solvent is selected from one of the embodiments: ethyl alcohol, isopropanol, polyethylene glycol, in butyl It is at least one.Preferred alcohol, isopropanol, terpinol;More preferable ethyl alcohol, isopropanol.The ethyl alcohol, isopropanol, terpinol it is excellent Selecting weight part ratio is 2-6:6-12:1-3;Preferred weight part of the ethyl alcohol and isopropanol is compared for 1:1.
The surfactant is selected from one of the embodiments: aliphatic alcohol polyethenoxy sodium sulphate, dodecyl sulphur At least one of sour sodium, neopelex, lauric acid potash soap, oleic acid potash soap, castor oil potash soap.
The fungicide is selected from parachlorometaxylenol (PCMX) in one of the embodiments,.
The auxiliary agent is selected from least one of essence, pigment in one of the embodiments,.
The essence is selected from one of the embodiments, (can be natural suitable for the fragrance component of detergent product Source is also possible to chemically synthesized product;Such as melon and fruit perfume, the fragrance of flowers and plants perfume (or spice) class);The pigment, which is selected from, is suitable for cleaning product Dyestuff and/or pigment.
The invention also discloses the preparation methods of the fabric bacteria-removing liquid of above-mentioned tool mosquito repellent function, comprising the following steps:
The preparation pre- solution of A: the mosquito component and fungicide being dissolved in the solvent, the pre- solution of A is obtained, spare;
The preparation pre- solution of B: the surfactant being dissolved in water, the pre- solution of B is obtained, spare;
Mixing: the pre- solution of above-mentioned A and the pre- solution of above-mentioned B are mixed, stirs evenly, obtains clear liquid;
Discharging: the auxiliary agent is added, and is uniformly mixed, can be discharged, obtain the fabric bacteria-removing liquid.
The advantages of above-mentioned preparation method has simple and reliable process, is suitable for industrialized production.
In one of the embodiments, in the mixing step, by the pre- solution of the A be slowly added to the pre- solution of the B into Row is mixed.
Compared with prior art, the invention has the following advantages:
The fabric bacteria-removing liquid of tool mosquito repellent function of the invention, so that the effect that the fabric after washing has preferable mosquito repellent mosquito-proof Fruit, and pass through the type and proportion of reasonable preparation each component, a kind of bacteria-removing liquid with better stability is obtained, is suitable for commercialization Production and popularization and use.
The preparation method of the fabric bacteria-removing liquid of tool mosquito repellent function of the invention, it is by solvent that mosquito component and fungicide is pre- Dissolution, then be slowly added into the aqueous surfactant solution dissolved, after stirring is completely dissolved, it is eventually adding auxiliary agent, there is work Skill is simple, advantage convenient for production.
Specific embodiment
To facilitate the understanding of the present invention, below with reference to embodiment to invention is more fully described.But this hair It is bright to realize in many different forms, however it is not limited to embodiment described herein.On the contrary, providing these embodiments Purpose be to make the disclosure of the present invention more thorough and comprehensive.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.
Raw materials used source is as follows in following embodiment, and it is commercially available that remaining, which does not refer to raw material, yet:
Industrial alcohol: make solvent;
Isopropanol: solvent is purchased from Guangzhou Qi Shuo Chemical Co., Ltd.;
PCMX: parachlorometaxylenol, fungicide are purchased from Netchem Inc Canada company;
Terpinol: mosquito component is purchased from the single Chemical Co., Ltd. in Guangzhou;
Meng's glycol: to menthyl -3,8- glycol, mosquito component is purchased from Givaudan company;
Castor oil potash soap: surfactant is purchased from the single Chemical Co., Ltd. in Guangzhou.
Embodiment 1
A series of fabric bacteria-removing liquid of tool mosquito repellent functions is prepared, formula is as shown in the table.
The formula of the different bacteria-removing liquids of table 1.
Note :/indicate not adding the ingredient.
Above-mentioned bacteria-removing liquid is prepared by the following method:
1) the pre- solution of A is prepared:
It is calculated by mass percentage and weighs the solvent, to dissolve mosquito component and fungicide PCMX, and mixed Conjunction stirs evenly, and completely, this is the pre- solution of A for dissolution.
2) the pre- solution of B is prepared:
It is calculated by mass percentage and weighs the surfactant dissolution in deionized water, be mixed evenly, it is molten Completely, this is the pre- solution of B to solution.
3) it mixes:
The pre- solution of the A is slowly added into the pre- solution of B to be mixed, until clear.
4) it discharges:
It is eventually adding the auxiliary agent, is mixed evenly, knitting for the ingredient containing mosquito repellent function can be prepared in discharging Object bacteria-removing liquid.
Embodiment 2
A series of fabric bacteria-removing liquid of tool mosquito repellent functions is prepared, formula is as shown in the table.
The formula of the different bacteria-removing liquids of table 2.
Note :/indicate not adding the ingredient.
Above-mentioned bacteria-removing liquid is prepared by the following method:
1) the pre- solution of A is prepared:
It is calculated by mass percentage and weighs the solvent, to dissolve mosquito component and fungicide PCMX, and mixed Conjunction stirs evenly, and completely, this is the pre- solution of A for dissolution.
2) the pre- solution of B is prepared:
It is calculated by mass percentage and weighs the surfactant dissolution in deionized water, be mixed evenly, it is molten Completely, this is the pre- solution of B to solution.
3) it mixes:
The pre- solution of the A is slowly added into the pre- solution of B to be mixed, until clear.
4) it discharges:
It is eventually adding the auxiliary agent, is mixed evenly, knitting for the ingredient containing mosquito repellent function can be prepared in discharging Object bacteria-removing liquid.
Test example
One, repelling effect is tested
1, test method
(1) four clean cotta clothings (pure cotton) are taken, wherein two pieces impregnates 15min with fabric bacteria-removing liquid with 2% concentration, It is rinsed 1 time after washing, naturally dry is denoted as clothing I, III.Another two pieces impregnates 15min using clear water, it dries in the air after washing without rinsing nature It is dry, it is denoted as clothing II, IV.
(2) it is simulated in big room in 28m3, places sprout wings 3 days female sensibility aedes albopictus, Culex quinquefasciatus each 100, to Half an hour mosquito is stablized.
(3) consistent two genders, height and the similar tester's first of figure and second are looked for, puts on clothing I and II respectively, into Enter it is above be put into the above simulation room, start timing.
(4) tester is and fails, and record the time by bite by mosquitos.
(5) to exclude the interference that different human body attracts mosquito, first, second is put on clothing IV and III respectively, is swapped flat Row test.
(6) average value for testing the testing time twice is taken, is compared.
2, test result.
Repelling effect test is carried out to the bacteria-removing liquid that embodiment 1 is prepared, as a result as shown in the table.
2 bacteria-removing liquid A-G repelling effect test result of table
From the above results, the bacteria-removing liquid repelling effect for adding Meng's glycol is obviously sweeter than not adding Meng's glycol or addition ocean The bacteria-removing liquid effect of chrysanthemum is good, can be seen that from the average guard time of bacteria-removing liquid A-E and bacteria-removing liquid F, G.Bacteria-removing liquid A-E, with Meng's glycol dosage increase (bacteria-removing liquid A be 2%, bacteria-removing liquid B, D 5%, bacteria-removing liquid D, E 8%), repelling effect is further bright It is aobvious to improve.And in the degerming liquid system, Meng's glycol dosage be added to it is 8% sufficiently large, it is not larger with 5% dosage The increase of amplitude.It can be seen that introduce proper ratio (5%-8%) mosquito component Meng glycol can make bacteria-removing liquid bring compared with Has preferable repelling effect under the premise of few adverse side effect.
Two, study on the stability index test
1, test method
The specific inspection target of Dependent Stability is as follows:
Low-temperature stability: sample is placed 0 DEG C refrigerator 4 weeks, restores room temperature, observes appearance;
High-temperature stability: sample is placed 45 DEG C baking oven 4 weeks, restores room temperature, observes appearance;
Frozen-thawed cycled: sample is placed -10 to -15 DEG C refrigerator 24 hours, is restored room temperature 24 hours;Circulation 4 times restores normal Temperature observes appearance;
Cold cycling: sample is placed 45 DEG C baking oven 24 hours, places -15 DEG C refrigerator 24 hours;Circulation 4 times restores normal Temperature observes appearance.
2, test result.
Repelling effect test is carried out to the bacteria-removing liquid that embodiment 2 is prepared, as a result as shown in the table.
4 bacteria-removing liquid study on the stability result of table
Test sample title Low-temperature stability High-temperature stability Frozen-thawed cycled Cold cycling
Bacteria-removing liquid H Not stratified no precipitating Not stratified no precipitating It is normal to restore room temperature It is normal to restore room temperature
Bacteria-removing liquid I Not stratified no precipitating Not stratified no precipitating It is normal to restore room temperature It is normal to restore room temperature
Bacteria-removing liquid J Not stratified no precipitating Not stratified no precipitating It is normal to restore room temperature It is normal to restore room temperature
Bacteria-removing liquid K Not stratified no precipitating Not stratified no precipitating It is normal to restore room temperature It is normal to restore room temperature
Bacteria-removing liquid L Generate obvious sediment Generate obvious sediment It is normal to restore room temperature It is normal to restore room temperature
Bacteria-removing liquid M Generate obvious sediment Not stratified no precipitating It is normal to restore room temperature It is normal to restore room temperature
Bacteria-removing liquid N Generate obvious sediment Not stratified no precipitating It is normal to restore room temperature It is normal to restore room temperature
Bacteria-removing liquid O Generate obvious sediment Not stratified no precipitating It is normal to restore room temperature It is normal to restore room temperature
By upper table result it is found that bacteria-removing liquid H-K introducing Meng's glycol formulation stability is good, but bacteria-removing liquid L-N stability There is precipitated and separated phenomenon in investigation.The present inventor's analysis, the decline of bacteria-removing liquid L and M stability may be due to alcohols and alcohol ethers Solvent combination selects improper cause;And the stability decline of bacteria-removing liquid N may be due to dimethyl phthalate instead of Meng's glycol, due to Dimethyl phthalate amalgamation in system is poor to be caused;And the stability decline of bacteria-removing liquid O may be due to changing surfactant Cause.It can be seen that the present invention applies mosquito component in liquid detergent composition formula, should preferably be had Mosquito-expelling bactericidal effect has preferable stability again, needs that formula is screened and configured meticulously.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (10)

1. a kind of fabric bacteria-removing liquid for having mosquito repellent function, which is characterized in that be prepared by the raw material of following mass percent:
The solvent is selected from least one of alcohols or alcohol ethers solvent.
2. the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1, which is characterized in that by following mass percent Raw material is prepared:
3. the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1 or 2, which is characterized in that the mosquito component choosing From: Metadelphene, dimethyl phthalate, Icaridin, Meng's glycol, citronellal, geraniol, citronellol, terpinol, citronella oil, eucalyptus citriodora oil, chlorine At least one of pyrethroids, d-phenothrin, transfluthrin.
4. the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1 or 2, which is characterized in that the solvent is selected from: second At least one of alcohol, isopropanol, polyethylene glycol, butyl.
5. the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1 or 2, which is characterized in that the surfactant It is selected from: aliphatic alcohol polyethenoxy sodium sulphate, lauryl sodium sulfate, neopelex, lauric acid potash soap, potassium oleate At least one of soap, castor oil potash soap.
6. the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1 or 2, which is characterized in that the fungicide is selected from Parachlorometaxylenol.
7. the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1 or 2, which is characterized in that the auxiliary agent is selected from perfume At least one of essence, pigment.
8. the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 7, which is characterized in that the essence, which is selected from, to be suitable for The fragrance component of detergent product;The pigment is selected from dyestuff and/or pigment suitable for cleaning product.
9. the preparation method of the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1-8, which is characterized in that The following steps are included:
The preparation pre- solution of A: the mosquito component and fungicide being dissolved in the solvent, the pre- solution of A is obtained, spare;
The preparation pre- solution of B: the surfactant being dissolved in water, the pre- solution of B is obtained, spare;
Mixing: the pre- solution of above-mentioned A and the pre- solution of above-mentioned B are mixed, stirs evenly, obtains clear liquid;
Discharging: the auxiliary agent is added, and is uniformly mixed, can be discharged, obtain the fabric bacteria-removing liquid.
10. the preparation method of the fabric bacteria-removing liquid of tool mosquito repellent function according to claim 1, which is characterized in that described mixed It closes in step, the pre- solution of the A is slowly added to the pre- solution of the B and is mixed.
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Cited By (6)

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CN110396820A (en) * 2019-08-20 2019-11-01 广州恩沣新材料科技有限公司 A kind of mosquito-proof antibacterial finishing agent and preparation method thereof
CN112980607A (en) * 2021-02-26 2021-06-18 中山百科清洁用品制造有限公司 Long-acting mosquito-repelling laundry detergent and preparation method thereof
CN113041995A (en) * 2021-03-02 2021-06-29 王晋芳 Composite adsorbent for air purification and preparation method thereof
CN113575599A (en) * 2021-08-26 2021-11-02 中山榄菊日化实业有限公司 Mosquito-repellent incense liquid and preparation method thereof
CN113930965A (en) * 2021-11-22 2022-01-14 广州立白企业集团有限公司 Fabric sterilization composition
CN114831115A (en) * 2021-02-02 2022-08-02 浙江澳岚丁生物科技有限公司 Antimalarial, mosquito-repellent and bacteriostatic composition and preparation method thereof

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CN104673514A (en) * 2013-11-26 2015-06-03 青岛海芬海洋生物科技有限公司 A marine organism degerming mosquito-repellent laundry detergent

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110396820A (en) * 2019-08-20 2019-11-01 广州恩沣新材料科技有限公司 A kind of mosquito-proof antibacterial finishing agent and preparation method thereof
CN114831115A (en) * 2021-02-02 2022-08-02 浙江澳岚丁生物科技有限公司 Antimalarial, mosquito-repellent and bacteriostatic composition and preparation method thereof
CN112980607A (en) * 2021-02-26 2021-06-18 中山百科清洁用品制造有限公司 Long-acting mosquito-repelling laundry detergent and preparation method thereof
CN113041995A (en) * 2021-03-02 2021-06-29 王晋芳 Composite adsorbent for air purification and preparation method thereof
CN113575599A (en) * 2021-08-26 2021-11-02 中山榄菊日化实业有限公司 Mosquito-repellent incense liquid and preparation method thereof
CN113930965A (en) * 2021-11-22 2022-01-14 广州立白企业集团有限公司 Fabric sterilization composition
CN113930965B (en) * 2021-11-22 2023-08-25 广州立白企业集团有限公司 Fabric degerming composition

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