CN109207231A - A kind of coal-saving comburant improving efficiency of fire coal - Google Patents

A kind of coal-saving comburant improving efficiency of fire coal Download PDF

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Publication number
CN109207231A
CN109207231A CN201811340631.2A CN201811340631A CN109207231A CN 109207231 A CN109207231 A CN 109207231A CN 201811340631 A CN201811340631 A CN 201811340631A CN 109207231 A CN109207231 A CN 109207231A
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Prior art keywords
coal
agent
minutes
saving
raw material
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CN201811340631.2A
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Inventor
黄勇
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Shandong East Aronsheng Adhesive Co Ltd
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Shandong East Aronsheng Adhesive Co Ltd
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Priority to CN201811340631.2A priority Critical patent/CN109207231A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives
    • C10L9/12Oxidation means, e.g. oxygen-generating compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a kind of coal-saving comburants for improving efficiency of fire coal, including oxygenation agent, curing agent, catalyst and primary raw material, the coal-saving comburant to be prepared by the component of following parts by weight: oxygenation agent: sodium chloride 10%;Curing agent: epoxy resin 10%;Catalyst: calcium carbonate 5%;Primary raw material: miberal powder 60%;Synergist: gas synergist 5%;Hardening agent: stearic acid 10%, raw material is placed on the stirring of blender internal mix, mixture after mixing is ground into powder using grinder, it is matched in the present invention by plurality of raw materials, it is mixed according to different proportion, 1% coal-saving comburant, which is added, can save 10% fire coal, reduce economic cost, coal-fired resource has been saved, coal-fired utilization efficiency is improved;The design of reversible type and multiple grinding process is rotated forward by paddle, so that the mixing of various raw materials is more abundant, ensure that mixture homogenization and powdered, to reach good combustion efficiency.

Description

A kind of coal-saving comburant improving efficiency of fire coal
Technical field
The present invention relates to Hazards in Power Plant field, specifically a kind of coal-saving comburant for improving efficiency of fire coal.
Background technique
Coal is a kind of flammable black or brownish black sedimentary rock, such sedimentary rock be commonly done in referred to as coal bed or In the lithostratigraphy in coal seam or in mineral ore, because being exposed under raised temperature and pressure later, the coal of harder form can be with It is considered as metamorphic rock, such as anthracite, coal mainly consist of carbon, constitutes together with by other elements of different number, mainly Hydrogen, sulphur, oxygen and nitrogen, with the rapid development of society so that raw material of the coal mine as development, but present coal due to it is long when Between use so that coal resource is greatly reduced, and burning of coal efficiency is lower, so that the utilization rate of coal reduces, greatly Waste resource.Therefore, those skilled in the art provide a kind of coal-saving comburant for improving efficiency of fire coal, to solve above-mentioned back The problem of being proposed in scape technology.
Summary of the invention
The purpose of the present invention is to provide a kind of coal-saving comburants for improving efficiency of fire coal, to solve in above-mentioned background technique The problem of proposition.
To achieve the above object, the invention provides the following technical scheme:
It is a kind of improve efficiency of fire coal coal-saving comburant, including oxygenation agent, curing agent, catalyst, primary raw material, synergist and Hardening agent, the coal-saving comburant are prepared by the component of following parts by weight: oxygenation agent: sodium chloride 10%;Curing agent: epoxy Resin 10%;Catalyst: calcium carbonate 5%;Primary raw material: miberal powder 60%;Synergist: gas synergist 5%;Hardening agent: stearic acid 10%, raw material is placed on the stirring of blender internal mix, mixture after mixing is ground using grinder, is ground At powdered.
As further scheme of the invention: the primary raw material miberal powder pours into inside blender, successively internally falls Enter oxygenation agent, synergist, curing agent and catalyst, is first stirred after pouring into the clockwise direction of 500~600rd/h of agitating paddle It mixes 5~10 minutes, then stops 5~10 minutes, then stir 5~10 points counterclockwise again with the speed of 500~600rd/h of agitating paddle Clock, then stop stirring 5~10 minutes, hardening agent is poured into, internally again finally with the speed up time of 700~800rd/h of agitating paddle Needle stirs 5~10 minutes, then stops 5~10 minutes, then stir 5 counterclockwise again with the speed of 700~800rd/h of agitating paddle~ 10 minutes, then stop stirring 5~10 minutes, it is uniformly mixed and forms mixture.
As further scheme of the invention: the mixture is poured into inside grinder and is once ground, ground Mixture afterwards continues through secondary grinding, it is secondary it is ground after mixture continue through and grind three times, by grinding three times Mixture could be ground to powdered by process.
As further scheme of the invention: the coal-saving comburant is with the component of raw coal proportion when in use 1:100。
As further scheme of the invention: containing inside the primary raw material has a small amount of active carbon.
Compared with prior art, mixed according to different proportion the beneficial effects of the present invention are: being matched by plurality of raw materials Close, be added 1% coal-saving comburant can save 10% or so fire coal, economic cost greatly reduces, has saved coal-fired resource, Improve coal-fired utilization efficiency;The design that reversible type and multiple grinding process are rotated forward by paddle, so that various raw materials What is mixed is more abundant, ensure that mixture homogenization and powdered, to reach good combustion efficiency.
Specific embodiment
In the embodiment of the present invention, it is a kind of improve efficiency of fire coal coal-saving comburant, including oxygenation agent, curing agent, catalyst, Primary raw material, synergist and hardening agent, coal-saving comburant are prepared by the component of following parts by weight: oxygenation agent: sodium chloride 10%;Curing agent: epoxy resin 10%;Catalyst: calcium carbonate 5%;Primary raw material: miberal powder 60%;Synergist: gas synergist 5%; Hardening agent: raw material is placed on the stirring of blender internal mix by stearic acid 10%, and mixture after mixing uses grinder It is ground, is ground into powder, coal-saving comburant is when in use 1:100, primary raw material with the component of raw coal proportion Inside, which is contained, a small amount of active carbon.
Primary raw material miberal powder pours into inside blender, successively internally pours into oxygenation agent, synergist, curing agent and catalysis Agent is first stirred 5~10 minutes with the clockwise direction of 500~600rd/h of agitating paddle after pouring into, then stops 5~10 minutes, so It is stirred counterclockwise 5~10 minutes with the speed of 500~600rd/h of agitating paddle again afterwards, then stops stirring 5~10 minutes, finally again Hardening agent is internally poured into, is stirred 5~10 minutes with the clockwise direction of 700~800rd/h of agitating paddle, then stop 5~10 points Then clock is stirred 5~10 minutes counterclockwise with the speed of 700~800rd/h of agitating paddle again, then stops stirring 5~10 minutes, mix Conjunction is formed uniformly mixture, and mixture is poured into inside grinder and once ground, it is ground after mixture continue through two Secondary grinding, it is secondary it is ground after mixture continue through and grind three times, could will mix abrasive lapping by grinding process three times It is extremely powdered.
It carries out two groups of data comparisons using coal-saving comburant to test, first group of comparative test:
Started to be added #2 furnace coal-saving comburant January 3, before point of addition is located at #2 furnace weighing belt, addition manner is The adding proportion of artificial addition, frequency conversion batcher control feeding coal, coal and combustion adjuvant is 100:1, causes combustion adjuvant within 5 to 8 Fugitive dust loss is larger, and adding proportion is abnormal not to be calculated, and adds combustion adjuvant according to normal rates within 10 to 13;
Then stop addition combustion adjuvant, is used as within 24 to 27 and is not added with combustion adjuvant calculating data;
#2 furnace adds fire retardant situation:
Time Steam production T Coal consumption T As-fired coal Calorific value T Combustion adjuvant Measure T Combustion adjuvant Account for coal ratio Example % Ton raw coal Steam production T Ton mark coal Steam production T Flying dust contains Carbon amounts % Clinker contains Carbon amounts %
1.10 3330 415 5005 5.03 1.21 8.02 11.22 4.30 13.83
1.11 3282 426 5025 4.9 1.15 7.70 10.73 5.63 7.13
1.12 3184 409 4927 4.7 1.15 7.78 11.06 4.20 11.89
1.13 3295 455 5096 4.88 1.07 7.24 9.95 3.94 18.47
Average value 3273 426.25 5016 4.88 1.15 7.69 10.74 4.52 12.83
#2 furnace is not added with fire retardant situation:
Time Steam production T Coal consumption T As-fired coal Calorific value T Combustion adjuvant Measure T Combustion adjuvant Account for coal ratio Example % Ton raw coal Steam production T Ton mark coal Steam production T Flying dust contains Carbon amounts % Clinker contains Carbon amounts %
1.24 3249 470 5085 6.91 9.52 5.94 35.72
1.25 3348 457 5137 7.33 9.98 5.72 17.07
1.26 3322 483 5207 6.88 9.25 6.79 25.18
1.27 3316 479 5014 6.92 9.66 5.47 38.97
Average value 3309 47.25 5111 7.01 9.60 5.98 29.24
By comparing above, it is preferable that ton mark coal steam production, flying dust and clinker combustible ratio are not added with corresponding index when combustion adjuvant, The reduction of flying dust and clinker combustible is eventually exhibited as the rising of ton mark coal steam production, and specific energy-saving effect is as follows:
When adding combustion adjuvant: ton mark coal steam production is 10.74 tons, is equivalent to 1 ton of steam consumption, 0.093 ton of mark coal;
When being not added with combustion adjuvant: ton mark coal steam production is 9.6 tons, is equivalent to and produces 1 ton of steam consumption, 0.104 ton of mark coal;
Coal conservation: 0.093-0.104=- 0.011(tons of mark coal);
According to above averagely 3309 tons of steam production, coal 3309*0.011=36.4(tons of mark can be saved daily);
Daily coal money of saving: 36.4*700=25480(member);
Mark coal price lattice per ton are 700 yuan, are added coal-saving comburant according to coal and combustion adjuvant ratio 100:1, every to add day by day 4.8 tons, auxiliary agent price per ton of economizing on coal is 3000 yuan, per coal-saving agent 4.8*3000=14400 yuan day by day;
Combustion adjuvant is such as added, can be saved daily: 25480-14400=11080 yuan;
By specifically adding combustion adjuvant combustion test, 11080 yuan of coal money can be saved daily, is run every year according to boiler 8000 hours It calculates, can save every year: 8000/24*11080=3,690,000 yuan.
Second group of comparative test:
Start to be added #2 furnace combustion adjuvant in August morning 9:30 on the 27th, before point of addition is located at #2 furnace weighing belt, addition side Formula is manually to add, frequency conversion batcher control feeding coal, and the adding proportion of coal and combustion adjuvant is 100:1, and August 27th start to put into Coal-saving comburant makes system run all right, and record and data in the meantime belongs to the transitional period, not in comparing calculation, to protect Confirmatory test is accurate;Start within August 29 days to compare experimental stage, and August 29 days is reduced because of outer net steam consumption, boiler is crack outward Exhaust, influences Experimental comparison, removes this day parameter, and August 30 days to September 7th are addition flame retardant run data;
Wherein combustion adjuvant is added in September stopping on the 7th, and to guarantee data accuracy, 8 days and 9 days parameters are not compare the transitional period Data, September Boiler Operation on the 9th change, and need boiler to be down to medium temperature and medium pressure (pressure 4.5MP, 480 DEG C of temperature) according to outer net Operation, theoretically according to enthalpy entropy table: 9.8MP, 540 DEG C of steam enthalpies are 3478.95KJ/kg;4MP, 480 DEG C of steam enthalpies For 3400KJ/kg, i.e., every kilogram of steam absorbs energy 79KJ less after cooling decompression, by can be calculated: the few mark of a steam 2.7 kilograms of coal, so the ton steam consumption mark coal amount when adding combustion adjuvant test should reduce 2.7 thousand for the accuracy for guaranteeing experiment Gram.
#2 furnace adds fire retardant situation:
Time Steam production T Coal consumption T As-fired coal Calorific value T Combustion adjuvant Measure T Combustion adjuvant Account for coal ratio Example % Ton raw coal Steam production T Ton mark coal Steam production T Flying dust contains Carbon amounts % Clinker contains Carbon amounts %
8.30 2419 368 5061 4.1 1.08 6.57 9.1978 10.13 22.14
8.31 2487 374 5097 4.02 1.12 6.65 9.3098 9.07 35.04
9.1 2666 388 5058 4.19 1.08 6.87 9.6178 9.84 27.6
9.2 2567 411 5198 3.93 1.02 6.25 8.7498 5.72 23.18
9.3 2580 412 5183 4.09 1.04 6.26 8.7638 8.21 18.85
9.4 2382 366 5171 3.93 1.03 6.51 9.1138 7.82 14.51
9.5 2583 417 4922 4.29 1.06 6.19 8.6658 7.37 18.1
9.6 2612 413 4889 4.48 1.11 6.32 8.8478 9.03 26.52
9.7 2582 403 4962 4.16 1.12 6.41 8.9738 8.27 21.72
Average value 2542 394 5.60 4.13 1.07 6.44 9.0267 8.3 23
#2 furnace is not added with fire retardant situation:
Time Steam production T Coal consumption T As-fired coal Calorific value T Combustion adjuvant Measure T Combustion adjuvant Account for coal ratio Example % Ton raw coal Steam production T Ton mark coal Steam production T Flying dust contains Carbon amounts % Clinker contains Carbon amounts %
9.10 2776 481 4984 5.77 8.0775 9.33 16.11
9.11 2780 447 4974 6.22 8.7178 7.06 31.11
9.12 2663 422 5159 6.31 8.8338 7.38 36.19
9.13 2714 417 5247 6.51 9.1138 5.67 21.85
9.14 2387 392 5110 6.09 8.5258 8.01 26.23
9.15 2754 434 5148 6.35 8.8898 10.89 31.26
Average value 2679 432 5103 6.20 8.691 8.05 27.12
By comparing above:
After boiler decrease temperature and pressure, steam production increase certainly will be will cause, coal consumption will not increase too much under normal circumstances, add combustion-supporting Comparison before and after agent adds average 432-394=38 ton of economizing on coal daily when combustion adjuvant;
When adding combustion adjuvant: ton mark coal steam production is 9.026 tons, is equivalent to 1 ton of steam consumption, 0.11 ton of mark coal;
When being not added with combustion adjuvant: ton mark coal steam production is 8.691 tons, is equivalent to and produces 1 ton of steam consumption, 0.115 ton of mark coal;
Steam saving mark coal amount=0.115-0.11+0.0027=0.0077 ton=7.7 kilogram per ton;
According to specified steam production 130*24=3120 ton of boiler, mark coal 3120*0.0077=24.024 ton can be saved daily;
Daily coal money of saving: 24.024*700=16816.8(member);
4.1 tons of combustion adjuvant are averagely used daily, is calculated according to 3000 yuan per ton, and combustion adjuvant spends 12300 yuan daily, final section daily About coal money: 16816.8-12300=4516.8 yuan;
In summary: theoretically, by calculating current heaven combustion adjuvant combustion experiment, 24 tons of coal of mark, coal money can be saved daily 4516.8 yuan, 1,620,000 yuan of coal money can be saved every year;
In fact, calculated according to 5T/H according to test card it is found that boiler decrease temperature and pressure afterload can increase 5T/H to 10T/H, Increase load 24*5=120 ton daily, the boiler load that is averaged daily after decompression is 2542+120=2660, substantially close to practical decompression 2679 tons of steam production afterwards, so 30/0.7143=42 ton of coal is marked with actually can averagely save 30 tons of raw coal after combustion adjuvant daily, Coal money 42*700=29400 yuan, then daily combustion adjuvant amount of money 29400-12300=17100 are subtracted, mark coal 17100 can be saved daily Member can save 6,150,000 yuan of coal of mark every year.
It is above-described, it is merely preferred embodiments of the present invention, but protection scope of the present invention is not limited to This, anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention And its inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. it is a kind of improve efficiency of fire coal coal-saving comburant, including oxygenation agent, curing agent, catalyst, primary raw material, synergist with And hardening agent, which is characterized in that the coal-saving comburant is prepared by the component of following parts by weight: oxygenation agent: sodium chloride 10%;Curing agent: epoxy resin 10%;Catalyst: calcium carbonate 5%;Primary raw material: miberal powder 60%;Synergist: gas synergist 5%; Hardening agent: raw material is placed on the stirring of blender internal mix by stearic acid 10%, and mixture after mixing uses grinder It is ground, is ground into powder.
2. a kind of coal-saving comburant for improving efficiency of fire coal according to claim 1, which is characterized in that the primary raw material Miberal powder pours into inside blender, successively internally pours into oxygenation agent, synergist, curing agent and catalyst, pour into after first with The clockwise direction of 500~600rd/h of agitating paddle stirs 5~10 minutes, then stops 5~10 minutes, then again with agitating paddle 500 The speed of~600rd/h stirs 5~10 minutes counterclockwise, then stops stirring 5~10 minutes, finally internally pours into reinforcing again Agent is stirred 5~10 minutes with the clockwise direction of 700~800rd/h of agitating paddle, then stops 5~10 minutes, then again with stirring The speed of 700~800rd/h of paddle stirs 5~10 minutes counterclockwise, then stops stirring 5~10 minutes, is uniformly mixed and forms mixing Material.
3. a kind of coal-saving comburant for improving efficiency of fire coal according to claim 1, which is characterized in that the mixture falls Enter and once ground inside grinder, it is ground after mixture continue through secondary grinding, it is secondary it is ground after mixing Material continues through to be ground three times, could be ground to mixture by grinding process three times powdered.
4. a kind of coal-saving comburant for improving efficiency of fire coal according to claim 1, which is characterized in that the coal-saving burning Agent is when in use 1:100 with the component of raw coal proportion.
5. a kind of coal-saving comburant for improving efficiency of fire coal according to claim 1, which is characterized in that the primary raw material Inside, which is contained, a small amount of active carbon.
CN201811340631.2A 2018-11-12 2018-11-12 A kind of coal-saving comburant improving efficiency of fire coal Pending CN109207231A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115044277A (en) * 2022-07-26 2022-09-13 厦门国丽静电粉末有限公司 Application of powder coating as combustion improver and use method of powder coating as flame retardant

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Publication number Priority date Publication date Assignee Title
CN115044277A (en) * 2022-07-26 2022-09-13 厦门国丽静电粉末有限公司 Application of powder coating as combustion improver and use method of powder coating as flame retardant

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