CN109206807A - A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong - Google Patents
A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong Download PDFInfo
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- CN109206807A CN109206807A CN201811094638.0A CN201811094638A CN109206807A CN 109206807 A CN109206807 A CN 109206807A CN 201811094638 A CN201811094638 A CN 201811094638A CN 109206807 A CN109206807 A CN 109206807A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/448—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from other vinyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of cable materials that ageing-resistant heat-resistant fireproof performance is strong, it is formed according to the parts by weight of following raw material: 74-83 parts of polyvinyl alcohol resin, 51-59 parts of neoprene, 34-39 parts of phenolic resin, 8-12 parts of dioctyl terephthalate, 6-14 parts of polylactic acid, 5-9 parts of span acid imide, 2-5 parts of sodium pyrosulfite, 0.6-1 parts of trimethylol-propane trimethacrylate, 8-10 parts of nanometer silicon carbide, 1-6 parts of nano-titanium dioxide, 0.5-0.9 parts of propyl alcohol amidogen ether of polyoxyethylene polyoxy, 2-5 parts of titanate esters, 1-4 parts of phthalic acid n-octyl, 1-5 parts of dodecyl benzene sulfonic acid, α -1-3 parts of sodium olefin sulfonate, 1-4 parts of carbon black, 7-15 parts of glass fibre, 1-4 parts of talcum powder, 1-4 parts of fire retardant , 1-4 parts of vulcanization accelerator, 14-18 parts of deionized water.Cable material of the invention, intensity height and ageing resistance good advantage strong with high temperature resistant, flame retardant property, and have the advantages that fire resistance is good, corrosion resistance is good and chemical property is stable, it can satisfy a variety of user demands.
Description
Technical field
The present invention relates to cable material technical field more particularly to a kind of cable materials that ageing-resistant heat-resistant fireproof performance is strong
Material.
Background technique
With the growth of China's economic continuously and healthily, the huge market space, wire and cable row are provided for cable products
Industry is the second largest industry that China is only second to automobile industry, and product variety satisfaction rate and domestic market share are more than 90%.?
It reforms and opens up to the outside world short decades, Chinese cable manufacturing industry, which is formed by huge production capacity, allows the world to regard with special esteem.In the world
In range, Chinese gross output value of wire and cable has been more than the U.S., becomes the first big countries producing electric wires and cables in the world.Along with China
Wires and cables industry high speed development, creation of new enterprise quantity constantly rise, and industry overall technology level is largely increased.
Simultaneously with economic rapid development, wire and cable is widely used in various industries field.But
With the frequent generation of electrical fire accident, the fire-retardant problem of wire and cable gradually causes the attention of countries in the world.Cable fire
When release a large amount of toxic smogs and corrosive gas, hamper safe escape and the fire-fighting work of people, suffer lives and properties
To heavy losses.
Summary of the invention
The object of the invention is that solve the above-mentioned problems and to provide a kind of ageing-resistant heat-resistant fireproof performance strong
Cable material.
To achieve the goals above, the present invention is achieved by the following technical solutions: a kind of ageing-resistant heat-resistant fireproof
The strong cable material of performance forms: 74-83 parts of polyvinyl alcohol resin, neoprene 51-59 according to the parts by weight of following raw material
Part, 34-39 parts of phenolic resin, 8-12 parts of dioctyl terephthalate, 6-14 parts of polylactic acid, 5-9 parts of span acid imide, burnt sulfurous
Sour sodium 2-5 parts, 0.6-1 parts of trimethylol-propane trimethacrylate, 8-10 parts of nanometer silicon carbide, nano-titanium dioxide 1-6
Part, 0.5-0.9 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 2-5 parts of titanate esters, 1-4 parts of phthalic acid n-octyl, detergent alkylate
1-5 parts of sulfonic acid, α -1-3 parts of sodium olefin sulfonate, 1-4 parts of carbon black, 7-15 parts of glass fibre, 1-4 parts of talcum powder, 1-4 parts of fire retardant,
1-4 parts of vulcanization accelerator, 14-18 parts of deionized water.
The strong cable material of above-mentioned a kind of ageing-resistant heat-resistant fireproof performance, according to the parts by weight array of following raw material
At: 74-79 parts of polyvinyl alcohol resin, 51-56 parts of neoprene, 34-37 parts of phenolic resin, dioctyl terephthalate 8-10
Part, 6-13 parts of polylactic acid, 5-8 parts of span acid imide, 2-4 parts of sodium pyrosulfite, trimethylol-propane trimethacrylate
0.6-0.9 parts, 8-9 parts of nanometer silicon carbide, 1-4 parts of nano-titanium dioxide, 0.5-0.7 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, titanium
2-4 parts of acid esters, 1-3 parts of phthalic acid n-octyl, 1-4 parts of dodecyl benzene sulfonic acid, α -1-3 parts of sodium olefin sulfonate, carbon black 1-3
Part, 7-12 parts of glass fibre, 1-3 parts of talcum powder, 1-3 parts of fire retardant, 1-3 parts of vulcanization accelerator, 14-16 parts of deionized water.
The strong cable material of above-mentioned a kind of ageing-resistant heat-resistant fireproof performance, according to the parts by weight array of following raw material
At: 76 parts of polyvinyl alcohol resin, 53 parts of neoprene, 35 parts of phenolic resin, 9 parts of dioctyl terephthalate, 8 parts of polylactic acid,
7 parts of span acid imide, 0.8 part of trimethylol-propane trimethacrylate, 9 parts of nanometer silicon carbide, is received 3 parts of sodium pyrosulfite
Rice 3 parts of titanium dioxide, 0.6 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 3 parts of titanate esters, 2 parts of phthalic acid n-octyl, dodecane
3 parts of base benzene sulfonic acid, 2 parts of α-sodium olefin sulfonate, 2 parts of carbon black, 9 parts of glass fibre, 2 parts of talcum powder, 2 parts of fire retardant, vulcanization promote
2 parts of agent, 15 parts of deionized water.
A kind of strong cable material of above-mentioned ageing-resistant heat-resistant fireproof performance, the vulcanization accelerator select vulcanization to promote
Agent TMTD, accelerator NA-22, accelerator CZ and two kinds or three kinds therein of accelerator H.
A kind of strong cable material of above-mentioned ageing-resistant heat-resistant fireproof performance, the fire retardant are ammonium polyphosphate and hydrogen-oxygen
Change one or both of magnesium fire retardant.
In summary the invention has the following advantages: cable material of the invention, with high temperature resistant, flame retardant property
By force, intensity height and the good advantage of ageing resistance, and have the advantages that fire resistance is good, corrosion resistance is good and chemical property is stable,
It can satisfy a variety of user demands.Cable material raw material of the present invention is easy to get, simple process, is suitable for heavy industrialization and uses, real
It is strong with property.The normal use for protecting people, reduces peril.
Specific embodiment
Specific embodiment 1:
A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong forms: polyethylene according to the parts by weight of following raw material
79 parts of alcohol resin, 56 parts of neoprene, 37 parts of phenolic resin, 10 parts of dioctyl terephthalate, 13 parts of polylactic acid, span acyl are sub-
8 parts of amine, 4 parts of sodium pyrosulfite, 0.9 part of trimethylol-propane trimethacrylate, 9 parts of nanometer silicon carbide, nanometer titanium dioxide
4 parts of titanium, 0.7 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 4 parts of titanate esters, 3 parts of phthalic acid n-octyl, dodecyl benzene sulfonic acid 4
Part, 3 parts of vulcanization accelerator, is gone 3 parts of α-sodium olefin sulfonate, 3 parts of carbon black, 12 parts of glass fibre, 3 parts of talcum powder, 3 parts of fire retardant
16 parts of ionized water.
Vulcanization accelerator selects vulcanization accelerator TMTD, accelerator NA-22, accelerator CZ and vulcanization accelerator
Two kinds or three kinds therein of H；Fire retardant is one or both of ammonium polyphosphate and flame retardant of magnesium hydroxide.
Specific embodiment 2:
A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong forms: polyethylene according to the parts by weight of following raw material
76 parts of alcohol resin, 53 parts of neoprene, 35 parts of phenolic resin, 9 parts of dioctyl terephthalate, 8 parts of polylactic acid, span acid imide
7 parts, 3 parts of sodium pyrosulfite, 0.8 part of trimethylol-propane trimethacrylate, 9 parts of nanometer silicon carbide, nano-titanium dioxide 3
Part, 0.6 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 3 parts of titanate esters, 2 parts of phthalic acid n-octyl, 3 parts of dodecyl benzene sulfonic acid,
2 parts of α-sodium olefin sulfonate, 2 parts of carbon black, 9 parts of glass fibre, 2 parts of talcum powder, 2 parts of fire retardant, 2 parts of vulcanization accelerator, deionization
15 parts of water.
Vulcanization accelerator selects vulcanization accelerator TMTD, accelerator NA-22, accelerator CZ and vulcanization accelerator
Two kinds or three kinds therein of H；Fire retardant is one or both of ammonium polyphosphate and flame retardant of magnesium hydroxide.
Specific embodiment 3:
A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong forms: polyethylene according to the parts by weight of following raw material
74 parts of alcohol resin, 51 parts of neoprene, 34 parts of phenolic resin, 8 parts of dioctyl terephthalate, 6 parts of polylactic acid, span acid imide
5 parts, 2 parts of sodium pyrosulfite, 0.6 part of trimethylol-propane trimethacrylate, 8 parts of nanometer silicon carbide, nano-titanium dioxide 1
Part, 0.5 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 2 parts of titanate esters, 1 part of phthalic acid n-octyl, 1 part of dodecyl benzene sulfonic acid,
1 part of α-sodium olefin sulfonate, 1 part of carbon black, 7 parts of glass fibre, 1 part of talcum powder, 1 part of fire retardant, 1 part of vulcanization accelerator, deionization
14 parts of water.
Vulcanization accelerator selects vulcanization accelerator TMTD, accelerator NA-22, accelerator CZ and vulcanization accelerator
Two kinds or three kinds therein of H；Fire retardant is one or both of ammonium polyphosphate and flame retardant of magnesium hydroxide.
Embodiment provided above is better embodiment of the invention, only is used to facilitate to illustrate the present invention, not to this hair
It is bright to make any form of restriction, any those of ordinary skill in the art, if not departing from the proposed skill of the present invention
In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and
Without departing from technical feature content of the invention, in the range of still falling within the technology of the present invention feature.
Claims (5)
1. a kind of cable material that ageing-resistant heat-resistant fireproof performance is strong, which is characterized in that according to the parts by weight of following raw material
Composition: 74-83 parts of polyvinyl alcohol resin, 51-59 parts of neoprene, 34-39 parts of phenolic resin, dioctyl terephthalate 8-12
Part, 6-14 parts of polylactic acid, 5-9 parts of span acid imide, 2-5 parts of sodium pyrosulfite, trimethylol-propane trimethacrylate
0.6-1 parts, 8-10 parts of nanometer silicon carbide, 1-6 parts of nano-titanium dioxide, 0.5-0.9 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, metatitanic acid
2-5 parts of ester, 1-4 parts of phthalic acid n-octyl, 1-5 parts of dodecyl benzene sulfonic acid, α -1-3 parts of sodium olefin sulfonate, carbon black 1-4
Part, 7-15 parts of glass fibre, 1-4 parts of talcum powder, 1-4 parts of fire retardant, 1-4 parts of vulcanization accelerator, 14-18 parts of deionized water.
2. a kind of strong cable material of ageing-resistant heat-resistant fireproof performance according to claim 1, which is characterized in that according to
The parts by weight of following raw material form: 74-79 parts of polyvinyl alcohol resin, 51-56 parts of neoprene, 34-37 parts of phenolic resin, right
8-10 parts of dioctyl phthalate, 6-13 parts of polylactic acid, 5-8 parts of span acid imide, 2-4 parts of sodium pyrosulfite, trihydroxy methyl third
0.6-0.9 parts of alkane trimethyl acrylic ester, 8-9 parts of nanometer silicon carbide, 1-4 parts of nano-titanium dioxide, polyoxyethylene polyoxy propyl alcohol
0.5-0.7 parts of amidogen ether, 2-4 parts of titanate esters, 1-3 parts of phthalic acid n-octyl, 1-4 parts of dodecyl benzene sulfonic acid, α-alkenyl sulphur
Sour sodium 1-3 parts, 1-3 parts of carbon black, 7-12 parts of glass fibre, 1-3 parts of talcum powder, 1-3 parts of fire retardant, 1-3 parts of vulcanization accelerator, go
14-16 parts of ionized water.
3. a kind of strong cable material of ageing-resistant heat-resistant fireproof performance according to claim 1, which is characterized in that according to
The parts by weight of following raw material form: 76 parts of polyvinyl alcohol resin, 53 parts of neoprene, 35 parts of phenolic resin, terephthalic acid (TPA)
9 parts of dioctyl ester, 8 parts of polylactic acid, 7 parts of span acid imide, 3 parts of sodium pyrosulfite, trimethylol-propane trimethacrylate 0.8
Part, 9 parts of nanometer silicon carbide, 3 parts of nano-titanium dioxide, 0.6 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 3 parts of titanate esters, O-phthalic
2 parts of sour n-octyl, 3 parts of dodecyl benzene sulfonic acid, 2 parts of α-sodium olefin sulfonate, 2 parts of carbon black, 9 parts of glass fibre, 2 parts of talcum powder,
2 parts of fire retardant, 2 parts of vulcanization accelerator, 15 parts of deionized water.
4. a kind of strong cable material of ageing-resistant heat-resistant fireproof performance according to claim 1 to 3, feature exist
In: the vulcanization accelerator selects vulcanization accelerator TMTD, accelerator NA-22, accelerator CZ and accelerator H
Two kinds therein or three kinds.
5. a kind of strong cable material of ageing-resistant heat-resistant fireproof performance according to claim 1 to 3, feature exist
In: the fire retardant is one or both of ammonium polyphosphate and flame retardant of magnesium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811094638.0A CN109206807A (en) | 2018-09-19 | 2018-09-19 | A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811094638.0A CN109206807A (en) | 2018-09-19 | 2018-09-19 | A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong |
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| CN109206807A true CN109206807A (en) | 2019-01-15 |
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| CN201811094638.0A Pending CN109206807A (en) | 2018-09-19 | 2018-09-19 | A kind of cable material that ageing-resistant heat-resistant fireproof performance is strong |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110330707A (en) * | 2019-07-16 | 2019-10-15 | 安徽升隆电气有限公司 | A kind of fire hazard monitoring equipment connection ageing-resistant CABLE MATERIALS and preparation method thereof |
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2018
- 2018-09-19 CN CN201811094638.0A patent/CN109206807A/en active Pending
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Cited By (1)
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|---|---|---|---|---|
| CN110330707A (en) * | 2019-07-16 | 2019-10-15 | 安徽升隆电气有限公司 | A kind of fire hazard monitoring equipment connection ageing-resistant CABLE MATERIALS and preparation method thereof |
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