CN109181227A - A kind of TPR footwear material transparent filler and preparation method thereof - Google Patents
A kind of TPR footwear material transparent filler and preparation method thereof Download PDFInfo
- Publication number
- CN109181227A CN109181227A CN201810956878.0A CN201810956878A CN109181227A CN 109181227 A CN109181227 A CN 109181227A CN 201810956878 A CN201810956878 A CN 201810956878A CN 109181227 A CN109181227 A CN 109181227A
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- Prior art keywords
- parts
- antioxidant
- calcium carbonate
- transparent filler
- footwear material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of TPR footwear material transparent filler and preparation method thereof, transparent filler includes the raw material of following parts by weight: 20~40 parts of talcum powder, 20~30 parts of precipitated calcium carbonate, 10~20 parts of pulverized limestone, 10~18 parts of epoxy resin, 5~15 parts of polycarbonate, 1~3 part of antioxidant, 3~7 parts of couplant, 5-10 parts of adhesive.TPR footwear material transparent filler proposed by the present invention has preferable reflective function so that the surface of TPR footwear material is in bright face, has good resilience and good wearability, skid resistance and damping performance are excellent, the method for the present invention simple process, easy to spread.
Description
Technical field
The present invention relates to TPR footwear material transparent filler technical field more particularly to a kind of TPR footwear material transparent fillers.
Background technique
TPR is a kind of thermoplastic elastomer macromolecule material being widely used with rubber and plastic properties, at present very
More rubber materials can be using thermoplastic elastomer (TPE) substitution, especially footwear material market with the continuous expansion of rubber-sole arts
Greatly, increasing to the demand of TPR sole, quality requirements are higher and higher, and existing TPR shoes materials filler is only with simple
Calcium carbonate, device transparency, low in glossiness, thus it is proposed that a kind of TPR footwear material transparent filler and preparation method thereof.
Summary of the invention
The purpose of the present invention is to solve disadvantage existing in the prior art, and a kind of TPR footwear material proposed is with transparent
Filler.
A kind of TPR footwear material transparent filler, the raw material including following parts by weight: 20~40 parts of talcum powder, precipitated calcium carbonate
20~30 parts, 10~20 parts of pulverized limestone, 10~18 parts of epoxy resin, 5~15 parts of polycarbonate, 1~3 part of antioxidant, coupling
3~7 parts of agent, 5-10 parts of adhesive.
Preferably, 25~35 parts of the talcum powder, 23~26 parts of precipitated calcium carbonate, 12~18 parts of pulverized limestone, epoxy resin
13~15 parts, 10~12 parts of polycarbonate, 1.5~2.5 parts of antioxidant, 4~6 parts of couplant, 7-9 parts of adhesive.
Preferably, 30 parts of the talcum powder, 5 parts of precipitated calcium carbonate, 15 parts of pulverized limestone, 14 parts of epoxy resin, polycarbonate
11 parts, 2 parts of antioxidant, 5 parts of couplant, 8 parts of adhesive.
Preferably, it is 1.2~2:1~1.2:1 antioxidant 1010, antioxidant that the antioxidant, which is mass ratio,
168 and antioxidant 1076 compounding agent.
A kind of preparation method of TPR footwear material transparent filler, comprising the following steps:
S1: precipitated calcium carbonate is added to the water, and after being uniformly mixed, is adjusted pH value to 6.5-7, is obtained precipitated calcium carbonate slurry
Material；
S2: in the light calcium carbonate slurry that pH is 6.5~7, talcum powder, pulverized limestone, epoxy resin are added under stiring
And polycarbonate；
S3: being added couplant and adhesive under stiring, it is made to mix adhesion glomeration；
S4: it is eventually adding antioxidant mixing, carries out anti-oxidant treatment；
S5: the filter cake by the slurries filtration after cladding to water content less than 45% is dried at 90~110 DEG C.
The present invention proposes TPR footwear material transparent filler, so that the surface of TPR footwear material is in bright face, has preferable reflective
Can, there is good resilience and good wearability, skid resistance and damping performance are excellent, the method for the present invention simple process, easily
In popularization.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment one
A kind of TPR footwear material transparent filler proposed by the present invention, the raw material including following parts by weight: 30 parts of talcum powder, light
5 parts of matter calcium carbonate, 15 parts of pulverized limestone, 14 parts of epoxy resin, 11 parts of polycarbonate, 2 parts of antioxidant, 5 parts of couplant, adhesive
8 parts.
The antioxidant is that mass ratio is 1.2~2:1~1.2:1 antioxidant 1010, antioxidant 168 and antioxygen
The compounding agent of agent 1076.
A kind of preparation method of TPR footwear material transparent filler, comprising the following steps: S1: precipitated calcium carbonate is added to the water,
After being uniformly mixed, pH value is adjusted to 6.5-7, obtains light calcium carbonate slurry
S2: in the light calcium carbonate slurry that pH is 6.5~7, talcum powder, pulverized limestone, epoxy resin are added under stiring
And polycarbonate；
S3: being added couplant and adhesive under stiring, it is made to mix adhesion glomeration；
S4: it is eventually adding antioxidant mixing, carries out anti-oxidant treatment；
S5: the filter cake by the slurries filtration after cladding to water content less than 45% is dried at 90 DEG C.
Embodiment two
A kind of TPR footwear material transparent filler proposed by the present invention, the raw material including following parts by weight: 20 parts of talcum powder, light
20 parts of matter calcium carbonate, 10 parts of pulverized limestone, 10 parts of epoxy resin, 5 parts of polycarbonate, 1 part of antioxidant, 3 parts of couplant, adhesive
5 parts.
The antioxidant is that mass ratio is 1.2~2:1~1.2:1 antioxidant 1010, antioxidant 168 and antioxygen
The compounding agent of agent 1076.
A kind of preparation method of TPR footwear material transparent filler, comprising the following steps:
S1: precipitated calcium carbonate is added to the water, and after being uniformly mixed, is adjusted pH value to 6.5-7, is obtained precipitated calcium carbonate slurry
Material
S2: in the light calcium carbonate slurry that pH is 6.5~7, talcum powder, pulverized limestone, epoxy resin are added under stiring
And polycarbonate；
S3: being added couplant and adhesive under stiring, it is made to mix adhesion glomeration；
S4: it is eventually adding antioxidant mixing, carries out anti-oxidant treatment；
S5: the filter cake by the slurries filtration after cladding to water content less than 45% is dried at 100 DEG C.
Embodiment three
A kind of TPR footwear material transparent filler proposed by the present invention, the raw material including following parts by weight: 40 parts of talcum powder, light
30 parts of matter calcium carbonate, 20 parts of pulverized limestone, 18 parts of epoxy resin, 15 parts of polycarbonate, 3 parts of antioxidant, 7 parts of couplant, bonding
10 parts of agent.
The antioxidant is that mass ratio is 1.2~2:1~1.2:1 antioxidant 1010, antioxidant 168 and antioxygen
The compounding agent of agent 1076.
A kind of preparation method of TPR footwear material transparent filler, comprising the following steps:
S1: precipitated calcium carbonate is added to the water, and after being uniformly mixed, is adjusted pH value to 6.5-7, is obtained precipitated calcium carbonate slurry
Material
S2: in the light calcium carbonate slurry that pH is 6.5~7, talcum powder, pulverized limestone, epoxy resin are added under stiring
And polycarbonate；
S3: being added couplant and adhesive under stiring, it is made to mix adhesion glomeration；
S4: it is eventually adding antioxidant mixing, carries out anti-oxidant treatment；
S5: the filter cake by the slurries filtration after cladding to water content less than 45% is dried at 110 DEG C.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (5)
1. a kind of TPR footwear material transparent filler, which is characterized in that the raw material including following parts by weight: 20~40 parts of talcum powder, light
20~30 parts of matter calcium carbonate, 10~20 parts of pulverized limestone, 10~18 parts of epoxy resin, 5~15 parts of polycarbonate, antioxidant 1~3
Part, 3~7 parts of couplant, 5-10 parts of adhesive.
2. a kind of TPR footwear material transparent filler according to claim 1, which is characterized in that 25~35 parts of the talcum powder,
23~26 parts of precipitated calcium carbonate, 12~18 parts of pulverized limestone, 13~15 parts of epoxy resin, 10~12 parts of polycarbonate, antioxidant
1.5~2.5 parts, 4~6 parts of couplant, 7-9 parts of adhesive.
3. a kind of TPR footwear material transparent filler according to claim 1, which is characterized in that 30 parts of the talcum powder, lightweight
5 parts of calcium carbonate, 15 parts of pulverized limestone, 14 parts of epoxy resin, 11 parts of polycarbonate, 2 parts of antioxidant, 5 parts of couplant, adhesive 8
Part.
4. a kind of TPR footwear material transparent filler according to claim 1, which is characterized in that the antioxidant is quality
Than the compounding agent for 1.2~2:1~1.2:1 antioxidant 1010, antioxidant 168 and antioxidant 1076.
5. a kind of preparation method of TPR footwear material transparent filler, feature described in any one of -4 exist according to claim 1
In, comprising the following steps:
S1: precipitated calcium carbonate is added to the water, and after being uniformly mixed, is adjusted pH value to 6.5-7, is obtained light calcium carbonate slurry；
S2: in the light calcium carbonate slurry that pH is 6.5~7, talcum powder, pulverized limestone, epoxy resin is added under stiring and gathers
Carbonic ester；
S3: being added couplant and adhesive under stiring, it is made to mix adhesion glomeration；
S4: it is eventually adding antioxidant mixing, carries out anti-oxidant treatment；
S5: the filter cake by the slurries filtration after cladding to water content less than 45% is dried at 90~110 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810956878.0A CN109181227A (en) | 2018-08-21 | 2018-08-21 | A kind of TPR footwear material transparent filler and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810956878.0A CN109181227A (en) | 2018-08-21 | 2018-08-21 | A kind of TPR footwear material transparent filler and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109181227A true CN109181227A (en) | 2019-01-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810956878.0A Pending CN109181227A (en) | 2018-08-21 | 2018-08-21 | A kind of TPR footwear material transparent filler and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112175353A (en) * | 2020-10-10 | 2021-01-05 | 南京和润新材料科技有限公司 | Transparent filler for TPR (thermal Plastic rubber) shoe material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006122550A (en) * | 2004-11-01 | 2006-05-18 | Makino Shoji Kk | Insole for footwear, and sandal equipped with the insole |
| CN104109260A (en) * | 2013-04-18 | 2014-10-22 | 芜湖卓越纳米新材料有限公司 | Preparation method of transparent padding functional calcium carbonate specially used for TPR shoe material |
| CN107698860A (en) * | 2017-10-30 | 2018-02-16 | 美瑞新材料股份有限公司 | A kind of sole high resilience composition expanded material and preparation method thereof |
-
2018
- 2018-08-21 CN CN201810956878.0A patent/CN109181227A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006122550A (en) * | 2004-11-01 | 2006-05-18 | Makino Shoji Kk | Insole for footwear, and sandal equipped with the insole |
| CN104109260A (en) * | 2013-04-18 | 2014-10-22 | 芜湖卓越纳米新材料有限公司 | Preparation method of transparent padding functional calcium carbonate specially used for TPR shoe material |
| CN107698860A (en) * | 2017-10-30 | 2018-02-16 | 美瑞新材料股份有限公司 | A kind of sole high resilience composition expanded material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112175353A (en) * | 2020-10-10 | 2021-01-05 | 南京和润新材料科技有限公司 | Transparent filler for TPR (thermal Plastic rubber) shoe material and preparation method thereof |
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Application publication date: 20190111 |
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