CN109181139A - Plate fitment special PVC offset plate and preparation method thereof - Google Patents

Plate fitment special PVC offset plate and preparation method thereof Download PDF

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Publication number
CN109181139A
CN109181139A CN201810690708.2A CN201810690708A CN109181139A CN 109181139 A CN109181139 A CN 109181139A CN 201810690708 A CN201810690708 A CN 201810690708A CN 109181139 A CN109181139 A CN 109181139A
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parts
plate
offset plate
fitment
pvc offset
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邹飞廷
邹飞航
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Xinhua Zhong Pi Integrated Furniture Co Ltd
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Xinhua Zhong Pi Integrated Furniture Co Ltd
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Priority to CN201810690708.2A priority Critical patent/CN109181139A/en
Publication of CN109181139A publication Critical patent/CN109181139A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0033Use of organic additives containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0028Use of organic additives containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0085Use of fibrous compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2445/00Characterised by the use of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Derivatives of such polymers
    • C08J2445/02Characterised by the use of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Derivatives of such polymers of coumarone-indene polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/04Linoxyn
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2497/00Characterised by the use of lignin-containing materials
    • C08J2497/02Lignocellulosic material, e.g. wood, straw or bagasse

Abstract

The invention discloses a kind of plate fitment special PVC offset plates and preparation method thereof, with PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent is raw material, any aldehyde material is free of in raw material, to avoid plate release free formaldehyde in face from destroying human health and environment, plate fitment special PVC offset plate obtained, it can be improved the hardness of PVC offset plate, compression strength, impact strength, dimensional stability and antiseptic property, it is big to solve abscess-size difference in existing offset plate, the problems such as being unevenly distributed, improve the waterproof and dampproof performance of imitated wood material, reduce the brittleness of PVC offset plate, it improves plate fitment special PVC offset plate intensity and extends use Service life.

Description

Plate fitment special PVC offset plate and preparation method thereof
Technical field
The present invention relates to plate fitment field, especially a kind of plate fitment special PVC offset plate and preparation method thereof.
Background technique
It is main substrate, using plate as the assembling-disassembling furniture of basic structure that plate fitment, which is using wood-based plate,.Wood-based plate Including standing grain perfume (or spice) plate, glued board, core-board, particieboard, medium density fiberboard.Current imitation wood substantially uses timber, such as glue Plywood, fiberboard, particieboard, core-board, wood wool board and timber lamination material etc..Since timber needs disafforestation, the earth Ecological environment seriously destroyed.For this purpose, people seek other natural fiber materials substitute timber manufacture fiberboard, but by In there is still a need for the binders using traditional urine aldehyde glue or phenol glue or directly synthesized by formaldehyde and different acetate hydrogen.These are with first Binder based on aldehyde can discharge free formaldehyde, and become the pollution sources of new influence human health and welding.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of plate fitment special PVC offset plates and preparation method thereof, in raw material Without any aldehyde material, so that plate release free formaldehyde in face be avoided to destroy human health and environment.
To achieve the goals above, the invention provides the following technical scheme:
A kind of plate fitment special PVC offset plate, the raw material including following parts by weight:
Preferably, the wood powder by sawdust, wood shavings, sawdust after crushed, be sieved, be dried to obtain;The mesh number of the wood powder For 80~150 mesh.
Preferably, the inorganic filler include sepiolite, glass microballoon, glass fibre, asbestos, attapulgite, titanium dioxide, Mica powder and feldspar.
Preferably, the foaming agent is lauryl sodium sulfate or ethoxylated alkyl sulfate.
Preferably, the reinforcing agent includes rosin resin, Ben-zylphenol Polyoxyethyl Ether, cocoyl diethanol amine, γ-contracting Water glycerol ether oxygen propyl trimethoxy silicane, pyrophyllite and soap city powder.
The present invention also provides a kind of above-mentioned preparation methods of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Preferably, the temperature of the internal mixing and plasticizing is 110~130 DEG C, and the temperature of the twin-roll mixing is 80~120 DEG C, The blowing temperature of the one-step mould is 150~170 DEG C, and the blowing temperature of the secondary mould pressing is 170~190 DEG C.
The present invention provides a kind of plate fitment special PVC offset plate and preparation method thereof, with PVC, polysulfide rubber, wood powder, Coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, lauryl methacrylate, sucrose, hydroxyl Methacrylamide, foaming agent, reinforcing agent are raw material, any aldehyde material are free of in raw material, to avoid face plate release Free formaldehyde destroys human health and environment, plate fitment special PVC offset plate obtained, can be improved the hardness of PVC offset plate, resists Compressive Strength, impact strength, dimensional stability and antiseptic property, solve in existing offset plate that abscess-size difference is big, and distribution is not The problems such as equal, improves the waterproof and dampproof performance of imitated wood material, reduces the brittleness of PVC offset plate, improves plate fitment special PVC Offset plate intensity simultaneously prolongs the service life.In addition preparation method is simple, easy to produce, and product has preferable appearance, and The abscess-size of lower production costs, PVC offset plate obtained is small and uniform, greatly improve plate fitment special PVC offset plate every Thermal effect, anti-deformation ability, improve the stability of plate fitment special PVC offset plate.
Specific embodiment
A kind of plate fitment special PVC offset plate provided by the invention, the raw material including following parts by weight:
Above-mentioned technical proposal, with PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, Cellulose polylactic acid, lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are raw material, former Any aldehyde material is free of in material, so that plate release free formaldehyde in face be avoided to destroy human health and environment, plate obtained Formula furniture special PVC offset plate, can be improved hardness, compression strength, impact strength, dimensional stability and the anti-corrosion of PVC offset plate Performance, solves in existing offset plate that abscess-size difference is big, the problems such as being unevenly distributed, improves the waterproof and dampproof property of imitated wood material Can, the brittleness of PVC offset plate is reduced, plate fitment special PVC offset plate intensity is improved and prolongs the service life.
PVC enables to PVC plastic offset plate to have excellent ageing-resistant performance, hardness, intensity.In the present invention, the weight of PVC Measuring number is 80~120 parts;In an embodiment of the present invention, the parts by weight of PVC are 90~110 parts;In other embodiments, The parts by weight of PVC are 95~105 parts.
Polysulfide rubber is used to improve the compression strength of plate fitment special PVC offset plate.In the present invention, the weight of polysulfide rubber Measuring number is 10~20 parts;In an embodiment of the present invention, the parts by weight of polysulfide rubber are 12~18 parts;In other embodiments In, the parts by weight of polysulfide rubber are 14~16 parts.
Wood powder is used to improve the hardness of plate fitment special PVC offset plate.In an embodiment of the present invention, wood powder by sawdust, Wood shavings, sawdust after crushed, are sieved, are dried to obtain;The mesh number of wood powder is 80~150 mesh.
In the present invention, the parts by weight of wood powder are 20~30 parts;In an embodiment of the present invention, the parts by weight of wood powder It is 22~28 parts;In other embodiments, the parts by weight of wood powder are 24~26 parts.
Coumarone indene resin for reducing plate fitment special PVC offset plate surface roughness.In the present invention, coumarone tree The parts by weight of rouge are 5~10 parts;In an embodiment of the present invention, the parts by weight of coumarone indene resin are 6~9 parts;At other In embodiment, the parts by weight of coumarone indene resin are 7~8 parts.
Sodium pyrophosphate is used to improve the wearability for improving plate fitment special PVC offset plate.In the present invention, sodium pyrophosphate Parts by weight are 3~5 parts;In an embodiment of the present invention, the parts by weight of sodium pyrophosphate are 3.4~4.8 parts;In other implementations In example, the parts by weight of sodium pyrophosphate are 3.7~4.3 parts.
Inorganic filler is used to improve the impact strength of plate fitment special PVC offset plate.In an embodiment of the present invention, inorganic Filler includes sepiolite, glass microballoon, glass fibre, asbestos, attapulgite, titanium dioxide, mica powder and feldspar.
In the present invention, the parts by weight of inorganic filler are 20~30 parts;In an embodiment of the present invention, inorganic filler Parts by weight are 22~28 parts;In other embodiments, the parts by weight of inorganic filler are 24~26 parts.
Castor oil is used for the antiseptic property of plate fitment special PVC offset plate.In the present invention, the parts by weight of castor oil are 4~8 parts;In an embodiment of the present invention, the parts by weight of castor oil are 5~7 parts;In other embodiments, the weight of castor oil Measuring number is 5.5~6.5 parts.
Cellulose polylactic acid is used to improve the foam performance of plate fitment special PVC offset plate, improves plate fitment special PVC The cell density of offset plate.In the present invention, the parts by weight of cellulose polylactic acid are 3~7 parts;In an embodiment of the present invention, The parts by weight of cellulose polylactic acid are 4~6 parts;In other embodiments, the parts by weight of cellulose polylactic acid be 4.5~ 5.5 part.
Lauryl methacrylate can be avoided the deformation of plate fitment special PVC offset plate.In the present invention, methyl-prop The parts by weight of olefin(e) acid dodecyl ester are 4~6 parts;In an embodiment of the present invention, the weight of lauryl methacrylate Measuring number is 4.3~5.6 parts;In other embodiments, the parts by weight of lauryl methacrylate are 4.7~5.2 parts.
Sucrose is used to improve the dimensional stability of plate fitment special PVC offset plate.In the present invention, the parts by weight of sucrose It is 6~10 parts;In an embodiment of the present invention, the parts by weight of sucrose are 7~9 parts;In other embodiments, the weight of sucrose Number is 7.5~8.5 parts.
Hydroxymethyl acrylamide is in addition to solidification, additionally it is possible to improve the waterproofness of plate fitment special PVC offset plate Energy.In the present invention, the parts by weight of hydroxymethyl acrylamide are 1~2 part;In an embodiment of the present invention, methylol propylene The parts by weight of amide are 1.2~1.7 parts;In other embodiments, the parts by weight of hydroxymethyl acrylamide are 1.3~1.6 Part.
Foaming agent enables to plate fitment special PVC offset plate to generate fine and closely woven stable a large amount of foams.In reality of the invention It applies in example, foaming agent is lauryl sodium sulfate or ethoxylated alkyl sulfate.
In the present invention, the parts by weight of foaming agent are 3~7 parts;In an embodiment of the present invention, the parts by weight of foaming agent Number is 4~6.4 parts;In other embodiments, the parts by weight of foaming agent are 4.5~6 parts.
Reinforcing agent is used to improve the bending strength of plate fitment special PVC offset plate.In an embodiment of the present invention, reinforcing agent Including rosin resin, Ben-zylphenol Polyoxyethyl Ether, cocoyl diethanol amine, γ-glycidyl ether oxygen propyl trimethoxy silicon Alkane, pyrophyllite and soap city powder.In other embodiments, rosin resin, Ben-zylphenol Polyoxyethyl Ether, cocoyl diethanol amine, The mass ratio of γ-glycidyl ether oxygen propyl trimethoxy silicane, pyrophyllite and soap city powder is
In the present invention, the parts by weight of reinforcing agent are 2~4 parts;In an embodiment of the present invention, the parts by weight of reinforcing agent Number is 2.4~3.6 parts;In other embodiments, the parts by weight of reinforcing agent are 2.7~3.2 parts.
The present invention also provides a kind of above-mentioned preparation methods of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Wherein, PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, the poly- cream of cellulose Acid, lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are same as above, herein no longer It repeats.
In an embodiment of the present invention, the temperature of internal mixing and plasticizing is 110~130 DEG C, and the temperature of twin-roll mixing is 80~120 DEG C, the blowing temperature of one-step mould is 150~170 DEG C, and the blowing temperature of secondary mould pressing is 170~190 DEG C.
Among the above, preparation method is simple, easy to produce, and product has preferable appearance, and lower production costs, The abscess-size of PVC offset plate obtained is small and uniform, greatly improves heat insulation, the anti-deformation of plate fitment special PVC offset plate Ability improves the stability of plate fitment special PVC offset plate.
In order to further illustrate the present invention, below with reference to embodiment to a kind of plate fitment special PVC provided by the invention Offset plate and preparation method thereof is described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
Plate fitment special PVC offset plate, the raw material including following parts by weight:
95 parts of PVC, 18 parts of polysulfide rubber, 26 parts of wood powders, 7 parts of coumarone indene resins, 4.3 parts of sodium pyrophosphates, 24 parts inorganic fill out Material, 5.5 parts of castor oil, 5.5 parts of cellulose polylactic acid, 4 parts of lauryl methacrylates, 7 portions of sucrose, 1.3 parts of methylols Acrylamide, 4.5 parts of foaming agents, 2.7 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 2
Plate fitment special PVC offset plate, the raw material including following parts by weight:
110 parts of PVC, 14 parts of polysulfide rubber, 28 parts of wood powders, 8 parts of coumarone indene resins, 3 parts of sodium pyrophosphates, 28 parts inorganic fill out Material, 5 parts of castor oil, 3 parts of cellulose polylactic acid, 6 parts of lauryl methacrylates, 9 portions of sucrose, 1.2 parts of methylol propylene Amide, 6.4 parts of foaming agents, 3.2 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 3
Plate fitment special PVC offset plate, the raw material including following parts by weight:
120 parts of PVC, 10 parts of polysulfide rubber, 20 parts of wood powders, 5 parts of coumarone indene resins, 5 parts of sodium pyrophosphates, 22 parts inorganic fill out Material, 4 parts of castor oil, 7 parts of cellulose polylactic acid, 4.3 parts of lauryl methacrylates, 6 portions of sucrose, 1.7 parts of methylols third Acrylamide, 3 parts of foaming agents, 2.4 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 4
Plate fitment special PVC offset plate, the raw material including following parts by weight:
80 parts of PVC, 20 parts of polysulfide rubber, 30 parts of wood powders, 10 parts of coumarone indene resins, 4.8 parts of sodium pyrophosphates, 26 parts inorganic fill out Material, 8 parts of castor oil, 4 parts of cellulose polylactic acid, 5.6 parts of lauryl methacrylates, 10 portions of sucrose, 1 part of methylol propylene Amide, 7 parts of foaming agents, 3.6 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 5
Plate fitment special PVC offset plate, the raw material including following parts by weight:
105 parts of PVC, 16 parts of polysulfide rubber, 24 parts of wood powders, 6 parts of coumarone indene resins, 3.4 parts of sodium pyrophosphates, 20 parts inorganic fill out Material, 6.5 parts of castor oil, 6 parts of cellulose polylactic acid, 5.2 parts of lauryl methacrylates, 7.5 portions of sucrose, 2 parts of methylols Acrylamide, 6 parts of foaming agents, 2 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 6
Plate fitment special PVC offset plate, the raw material including following parts by weight:
90 parts of PVC, 12 parts of polysulfide rubber, 26 parts of wood powders, 9 parts of coumarone indene resins, 3.7 parts of sodium pyrophosphates, 30 parts inorganic fill out Material, 7 parts of castor oil, 4.5 parts of cellulose polylactic acid, 4.7 parts of lauryl methacrylates, 8.5 portions of sucrose, 1.6 parts of hydroxyl first Base acrylamide, 4 parts of foaming agents, 4 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 7
Plate fitment special PVC offset plate, the raw material including following parts by weight:
100 parts of PVC, 15 parts of polysulfide rubber, 25 parts of wood powders, 7.5 parts of coumarone indene resins, 4 parts of sodium pyrophosphates, 25 parts inorganic fill out Material, 6 parts of castor oil, 5 parts of cellulose polylactic acid, 5 parts of lauryl methacrylates, 8 portions of sucrose, 1.4 parts of methylol propylene Amide, 5 parts of foaming agents, 3 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 8
Plate fitment special PVC offset plate, the raw material including following parts by weight:
98 parts of PVC, 14 parts of polysulfide rubber, 26 parts of wood powders, 8 parts of coumarone indene resins, 4 parts of sodium pyrophosphates, 26 parts of inorganic fillers, 5.8 parts of castor oil, 4.5 parts of cellulose polylactic acid, 4.7 parts of lauryl methacrylates, 7.5 portions of sucrose, 1.4 parts of methylols Acrylamide, 4.5 parts of foaming agents, 2.7 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 9
Plate fitment special PVC offset plate, the raw material including following parts by weight:
102 parts of PVC, 16 parts of polysulfide rubber, 24 parts of wood powders, 7.5 parts of coumarone indene resins, 3.7 parts of sodium pyrophosphates, 25 parts it is inorganic Filler, 6 parts of castor oil, 5 parts of cellulose polylactic acid, 5.2 parts of lauryl methacrylates, 8.5 portions of sucrose, 1.5 parts of hydroxyl first Base acrylamide, 6 parts of foaming agents, 3.2 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
Embodiment 10
Plate fitment special PVC offset plate, the raw material including following parts by weight:
100 parts of PVC, 15 parts of polysulfide rubber, 25 parts of wood powders, 7 parts of coumarone indene resins, 4.3 parts of sodium pyrophosphates, 24 parts inorganic fill out Material, 6.2 parts of castor oil, 5.5 parts of cellulose polylactic acid, 5 parts of lauryl methacrylates, 7 portions of sucrose, 1.6 parts of methylols Acrylamide, 5.5 parts of foaming agents, 3 parts of reinforcing agents;
The preparation method of plate fitment special PVC offset plate, comprising the following steps:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, Lauryl methacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, mixing It is plasticized 10~15min;It is put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine In, one-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC Offset plate.
The surface roughness, hardness of plate fitment special PVC offset plate made from testing example 1~10, are torn at tensile strength Resistance to spalling, impact strength and bending strength.
Above description can be realized professional and technical personnel in the field or using this to stating in the disclosed embodiments It is bright, it enables those skilled in the art to implement or use the present invention.Various modifications to these embodiments are to this field It will be apparent for professional technician, the general principles defined herein can not depart from spirit of the invention Or in the case where range, realize in other embodiments.Therefore, the present invention is not intended to be limited to these implementations shown in this article Example, and it is to fit to the widest scope consistent with principles disclosed herein and novel features.

Claims (7)

1. a kind of plate fitment special PVC offset plate, which is characterized in that the raw material including following parts by weight:
2. plate fitment special PVC offset plate as described in claim 1, which is characterized in that the wood powder is by sawdust, wood shavings, saw It after crushed, is sieved, is dried to obtain in end;The mesh number of the wood powder is 80~150 mesh.
3. plate fitment special PVC offset plate as described in claim 1, which is characterized in that the inorganic filler include sepiolite, Glass microballoon, glass fibre, asbestos, attapulgite, titanium dioxide, mica powder and feldspar.
4. plate fitment special PVC offset plate as described in claim 1, which is characterized in that the foaming agent is dodecyl sulphur Sour sodium or ethoxylated alkyl sulfate.
5. plate fitment special PVC offset plate as described in claim 1, which is characterized in that the reinforcing agent include rosin resin, Ben-zylphenol Polyoxyethyl Ether, cocoyl diethanol amine, γ-glycidyl ether oxygen propyl trimethoxy silicane, pyrophyllite and soap City's powder.
6. a kind of preparation method of plate fitment special PVC offset plate as claimed in any one of claims 1 to 5, which is characterized in that The following steps are included:
By PVC, polysulfide rubber, wood powder, coumarone indene resin, sodium pyrophosphate, inorganic filler, castor oil, cellulose polylactic acid, methyl Dodecylacrylate, sucrose, hydroxymethyl acrylamide, foaming agent, reinforcing agent are put into adding pressure type mixer, internal mixing and plasticizing 10~15min;It being put into twin-screw extruder, after twin-roll mixing 6min, horizontal drawing slice is placed in First moulded from foam machine, One-step mould foaming 8min;After 120~150min of room temperature natural cooling, it is placed in second moulded from foam machine, secondary mould pressing Foam 10min;Finally, after 150~200min of room temperature natural cooling, punching at different size plate fitment special PVC glue Plate.
7. preparation method as claimed in claim 6, which is characterized in that the temperature of the internal mixing and plasticizing is 110~130 DEG C, institute The temperature for stating twin-roll mixing is 80~120 DEG C, and the blowing temperature of the one-step mould is 150~170 DEG C, the secondary mould pressing Blowing temperature is 170~190 DEG C.
CN201810690708.2A 2018-06-28 2018-06-28 Plate fitment special PVC offset plate and preparation method thereof Pending CN109181139A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070405A (en) * 2007-05-23 2007-11-14 福建师范大学 Method for preparing anti-bacterial anti-mildew styrene-butadiene rubber foamed plate
CN107130731A (en) * 2017-06-03 2017-09-05 合肥慧林建材有限公司 Wood plastic boards with moisture-keeping functions and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070405A (en) * 2007-05-23 2007-11-14 福建师范大学 Method for preparing anti-bacterial anti-mildew styrene-butadiene rubber foamed plate
CN107130731A (en) * 2017-06-03 2017-09-05 合肥慧林建材有限公司 Wood plastic boards with moisture-keeping functions and preparation method thereof

Non-Patent Citations (1)

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Application publication date: 20190111