CN109181100A - The production method and its application of stone paper masterbatch composition, master batch - Google Patents
The production method and its application of stone paper masterbatch composition, master batch Download PDFInfo
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- CN109181100A CN109181100A CN201810815948.0A CN201810815948A CN109181100A CN 109181100 A CN109181100 A CN 109181100A CN 201810815948 A CN201810815948 A CN 201810815948A CN 109181100 A CN109181100 A CN 109181100A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses the production methods and its application of a kind of stone paper masterbatch composition, master batch, the composition is made of the components of following parts: 20~90 parts of polypropylene, inorganic 10~80 parts of water suction filler material, 1~2 part of interfacial agent SBW-111,1~2 part and 0.1 part of antioxidant of printing auxiliary agent B -903；And the application of master batch made of disclosing；Preparation method simple process of the invention, easily operated, raw material mixing condition is mild, high production efficiency；The stone paper produced using product of the present invention low, good product quality, recoverable with production cost, especially suitable for the chromatography color printing of water-based ink, printing quality is good, improves the class of product, can be applied to packaging field.
Description
Technical field
The invention belongs to pulp technology for making paper more particularly to a kind of stone paper masterbatch composition, master batch production method and
It is applied.
Background technique
Currently, stone paper as one kind using inorganic mineral as primary raw material, by physics, chemical method is modified and high score
The environment-friendly products that sub- polymer Compound Machining is molded with have the characteristics that cheap, production technology is easy.With traditional papermaking
It compares, stone paper does not need felling timber, protect a large amount of vegetation resources, enhance atmosphere indirectly using natural minerals as raw material
Detergent power.Meanwhile compared with traditional paper-making industry, stone paper production process does not need boiling separation fiber, washing, bleaching etc.
Process flow, because not discharging waste liquid, waste residue and toxic gas without using the industrial chemicals such as strong acid, highly basic, bleaching agent,
It is basic to belong to green product up to zero-emission, thus it is widely used in the fields such as packaging, decoration, decoration.
But the stone paper produced at present is made of largely with polypropylene, calcium carbonate etc. for main material, this stone
The problems such as how generally existing paper printing adaptability be poor, stiffness is poor, shielding is poor, intensity is low, causes manufactured goods to generally use oiliness
Ink prints, and color is single, and smell is big, it is difficult to solve the environmental issue of ink, problem above be also that stone paper is difficult to advise greatly
The bottleneck problem that mould promotes and applies.
Summary of the invention:
The first purpose of this invention is: providing a kind of stone paper masterbatch composition, uses master batch made of the composition
Carry out stone paper production, product low, good product quality, recoverable with production cost, especially suitable for water-based ink
Chromatography color printing.
Second object of the present invention is: providing a kind of production method of stone paper master batch, this method simple process is easy to
It operates, raw material mixing condition is mild, high production efficiency.
Third object of the present invention is: providing the practical application of the stone paper master batch.
In order to solve the above technical problems, the technical scheme is that
A kind of stone paper masterbatch composition, is made of the components of following parts: 20~90 parts of polypropylene, inorganic water suction is filled out
10~80 parts of charge, 1~2 part of interfacial agent SBW-111,1~2 part and 0.1 part of antioxidant of printing auxiliary agent B -903.
Preferably, the composition is made of the components of following parts: 35~40 parts of polypropylene, inorganic water suction filling
50~60 parts of material, 1.5 parts of interfacial agent SBW-111,1.5 parts and 0.1 part of antioxidant of printing auxiliary agent B -903.
Preferably, the inorganic water suction filler material is powdered whiting, precipitated calcium carbonate, kaolin, talcum powder and hydrogen
The mixture of one or more of magnesia；Antioxidant is phenolic antioxidant 1010, (the thiodipropionic acid dilauryl osmanthus DLTDP
Ester), DSTDP (thio-2 acid two (18) ester), TNPP (phosphorous acid three (nonyl phenyl ester)), in acrylic functional group 168
One or more of mixtures.Preferably phenolic antioxidant 1010 (buying from Guangzhou Hao Su Chemical Co., Ltd.).
Interfacial agent SBW- III (is bought from Qingdao Siwei Chemical Co., Ltd.), and main component is chelating-coordinating
Borate is a kind of parental type interfacial agent, the polar group generation coupling reaction of hydrophilic radical and inorganic filler surface
It is lipophilic group on the surface grafting of filler in turn, and with high molecular material phase can occur for the lipophilic group for being grafted on filler surface
Mutually winding, improves the binding force of inorganic filler and high molecular material, ensure that the mechanical property of this product.
- 903 composition of auxiliary agent B (buying from Qingdao Siwei Chemical Co., Ltd.) is printed, main component is semi-polarity boric acid
Ester is a kind of interfacial agent containing multiple polar groups and a lipophilic group, during processing of high molecular material
The compatibility of its lipophilic group and high molecular material is good, finely dispersed to enter in material, and a large amount of polar group dispersion
On the surface of material, when water-based ink printing, the polar group on surface and the polar group compatibility of ink are good, ink
And the combination of substrate is all right, and then just improves the adhesive force of ink and high molecular material.
A kind of production method of stone paper master batch, comprising the following steps:
A. mixing one: first weighing each raw material respectively by weight, and inorganic 10~80 parts of water suction filler material, interface is living
Property 1~2 part of SBW-111 of agent be added in batch mixer, 80~90 DEG C, mixing speed be 50~100rpm under the conditions of, stirring 10
~20 minutes；
B. 20~90 parts of polypropylene, 1~2 part of auxiliary agent B -903 of printing, 0.1 part of antioxidant mixing two: are continuously added extremely
Stirred in batch mixer, 80~90 DEG C, mixing speed be 50~100rpm under the conditions of, stir 10~20 minutes；
C. it manufactures master batch: the obtained material of step b being placed in pelletizer and carries out water ring pelletizing, and is screened, it is qualified
Product are stone paper master batch；
D. recycle: the product that step c is obtained is secondary back to carrying out in step c by rejected product after screening
Mixing recycles.
Preferably, the batch mixer in the step a and step b is high speed mixer.
Preferably, pelletizer is Bitruder, operating condition setting are as follows: screw slenderness ratio in the step c
45:1~55:1, operation temperature parameter are set by feed end to discharge end are as follows: feeding section is controlled at 150~165 DEG C, closes section control
At 165~175 DEG C, discharge zone is controlled at 165~150 DEG C, then carries out water ring pelletizing.
The application of stone paper masterbatch composition: with the composition stone paper master batch.
The application of stone paper master batch: stone paper plate is made with the stone paper master batch.
The application of stone paper plate: packing case is made with the stone paper plate.
By adopting the above-described technical solution, the beneficial effects of the present invention are:
1, raw material ratio of the present invention is simple and easy to get, especially largely uses inorganic water suction filler material, therefore can reduce life
Cost is produced, and simplifies production technology.
2, the addition of interfacial agent SBW-111 and printing auxiliary agent B -903 can change inorganic water suction filler material and poly- third
The problems such as alkene mixture printing adaptability is poor, stiffness is poor, shielding is poor, intensity is low, allows product to carry out process printing, mentions
The high quality of product.
3, mixing mild condition in production process, and increase and process is utilized using waste recovery, therefore is more energy efficient, environmentally friendly
And safety.
In short, preparation method simple process of the present invention, easily operated, raw material mixing condition are mild, high production efficiency；It utilizes
The stone paper of product of the present invention production low, good product quality, recoverable with production cost, especially suitable for water-based ink
Chromatography color printing, printing quality is good, improves the class of product, can be applied to packaging field.
Detailed description of the invention
Fig. 1 is instance graph after stone paper product printing produced by the present invention；
Fig. 2 is instance graph after existing stone paper product printing currently on the market；
Fig. 3 is example details figure after stone paper product printing produced by the present invention；
Fig. 4 is example details figure after existing stone paper product printing currently on the market.
Specific embodiment
Technical solution of the present invention is further described with reference to the accompanying drawings and examples:
Embodiment one:The production one of stone paper master batch
A. mixing one: each raw material is weighed respectively first, and according to parts by weight, by 50 parts of inorganic water suction filler material (heavys
Calcium carbonate and precipitated calcium carbonate are mixed with arbitrary proportion), 2.0 parts of interfacial agent SBW-111 be added in high speed mixer,
80 DEG C, mixing speed be 100rpm under the conditions of, stir 10 minutes；
B. 40 parts of polypropylene, 1.0 parts of printing auxiliary agent Bs -903,0.1 part of antioxidant (phenols antioxygen mixing two: are continuously added
Agent 1010 and DLTDP are mixed with arbitrary proportion) stirred into high speed mixer, 80 DEG C, mixing speed be 100rpm under the conditions of,
Stirring 10 minutes；
C. it manufactures master batch: the obtained material of step b being placed in pelletizer and carries out water ring pelletizing, and is screened, it is qualified
Product are stone paper master batch；
D. recycle: the product that step c is obtained is secondary back to carrying out in step c by rejected product after screening
Mixing recycles.
Embodiment two:The production two of stone paper master batch
A. mixing one: each raw material is weighed respectively first, and according to parts by weight, by 80 parts of inorganic water suction filler material (kaolinites
Soil, talcum powder and magnesium hydroxide are mixed with arbitrary proportion), 1.0 parts of interfacial agent SBW-111 be added in high speed mixer,
90 DEG C, mixing speed be 50rpm under the conditions of, stir 20 minutes；
B. mixing two: continuously add 20 parts of polypropylene, 2.0 parts of printing auxiliary agent Bs -903,0.1 part of antioxidant (DSTDP,
TNPP and acrylic functional group 168 are mixed with arbitrary proportion) it is stirred into high speed mixer, in 90 DEG C, mixing speed 50rpm
Under the conditions of, it stirs 20 minutes；
C. it manufactures master batch: the obtained material of step b being placed in pelletizer and carries out water ring pelletizing, and is screened, it is qualified
Product are stone paper master batch；
D. recycle: the product that step c is obtained is secondary back to carrying out in step c by rejected product after screening
Mixing recycles.
Embodiment three:The production three of stone paper master batch
A. mixing one: each raw material is weighed respectively first, and according to parts by weight, by 65 parts of inorganic water suction filler material (talcums
Powder and precipitated calcium carbonate are mixed with arbitrary proportion), 1.5 parts of interfacial agent SBW-111 be added in high speed mixer, 85
DEG C, mixing speed be 75rpm under the conditions of, stir 15 minutes；
B. mixing two: continuously add 30 parts of polypropylene, 1.5 parts of printing auxiliary agent Bs -903,0.1 part of antioxidant (DLTDP and
TNPP is mixed with arbitrary proportion) stirred into high speed mixer, 85 DEG C, mixing speed be 75rpm under the conditions of, stir 15 points
Clock；
C. it manufactures master batch: the obtained material of step b being placed in pelletizer and carries out water ring pelletizing, and is screened, it is qualified
Product are stone paper master batch；
D. recycle: the product that step c is obtained is secondary back to carrying out in step c by rejected product after screening
Mixing recycles.
Example IV:The production four of stone paper master batch
A. mixing one: each raw material is weighed respectively first, and according to parts by weight, by 60 parts of inorganic water suction filler material (heavys
Calcium carbonate, talcum powder and magnesium hydroxide are mixed with arbitrary proportion), 1.5 parts of interfacial agent SBW-111 be added to high speed mixer
In, 85 DEG C, mixing speed be 75rpm under the conditions of, stir 15 minutes；
B. 35 parts of polypropylene, 0.1 part of 1.5 parts of printing auxiliary agent Bs -903, antioxidant (phenols antioxygen mixing two: are continuously added
Agent 1010, DLTDP and TNPP are mixed with arbitrary proportion) it is stirred into high speed mixer, it is 75rpm item in 85 DEG C, mixing speed
Under part, stir 15 minutes；
C. it manufactures master batch: the obtained material of step b being placed in pelletizer and carries out water ring pelletizing, and is screened, it is qualified
Product are stone paper master batch；
D. recycle: the product that step c is obtained is secondary back to carrying out in step c by rejected product after screening
Mixing recycles.
Embodiment five:The production five of stone paper master batch
A. mixing one: each raw material is weighed respectively first, and according to parts by weight, by 55 parts of inorganic water suction filler material (heavys
Calcium carbonate), 1.8 parts of interfacial agent SBW-111 be added in high speed mixer, 85 DEG C, mixing speed be 75rpm condition
Under, it stirs 15 minutes；
B. 39 parts of polypropylene, 0.1 part of 1.2 parts of printing auxiliary agent Bs -903, antioxidant (phenols antioxygen mixing two: are continuously added
Agent 1010) stirred into high speed mixer, 85 DEG C, mixing speed be 75rpm under the conditions of, stir 15 minutes；
C. it manufactures master batch: the obtained material of step b being placed in pelletizer and carries out water ring pelletizing, and is screened, it is qualified
Product are stone paper master batch；
D. recycle: the product that step c is obtained is secondary back to carrying out in step c by rejected product after screening
Mixing recycles.
Embodiment six:Concrete application of the present invention
It the composite can be widely applied to the stone paper plate manufactured with stone paper master batch and the thus first pass of plate manufacture
Product, such as packing case have good product quality, recoverable using the packing case of this stone paper board making, especially suitable
For the chromatography color printing of water-based ink, printing quality is good, from attached drawing 1 to attached drawing 4 as can be seen that being produced by the present composition
The carton that does of stone paper on printing quality be apparently higher than similar product in the market.
Claims (9)
1. a kind of stone paper masterbatch composition, which is characterized in that be made of the components of following parts: 20~90 parts of polypropylene,
Inorganic 10~80 parts of water suction filler material, 1~2 part of interfacial agent SBW-111,1~2 part of auxiliary agent B -903 of printing and anti-oxidant
0.1 part of agent.
2. stone paper masterbatch composition as described in claim 1, it is characterised in that: the composition by following parts by weight group
Part is made: 35~40 parts of polypropylene, inorganic 50~60 parts of water suction filler material, 1.5 parts of interfacial agent SBW-111, printing auxiliary agent
1.5 parts and 0.1 part of antioxidant of B-903.
3. stone paper masterbatch composition as claimed in claim 1 or 2, it is characterised in that: the inorganic water suction filler material is attached most importance to
The mixture of one or more of matter calcium carbonate, precipitated calcium carbonate, kaolin, talcum powder and magnesium hydroxide；It is described anti-oxidant
Agent is the mixture of one or more of phenolic antioxidant 1010, DLTDP, DSTDP, TNPP, acrylic functional group 168.
4. a kind of method using composition production stone paper master batch described in claim 1, it is characterised in that: including following step
It is rapid:
A. mixing one: each raw material is weighed respectively by weight, by inorganic 10~80 parts of water suction filler material, interfacial agent SBW-
111 1~2 parts are added in batch mixer, 80~90 DEG C, mixing speed be 50~100rpm under the conditions of, stir 10~20 points
Clock；
B. 20~90 parts of polypropylene, 1~2 part of auxiliary agent B -903 of printing, 0.1 part of antioxidant to mixing mixing two: are continuously added
Stirred in machine, 80~90 DEG C, mixing speed be 50~100rpm under the conditions of, stir 10~20 minutes；
C. it manufactures master batch: the obtained material of step b being placed in pelletizer and carries out water ring pelletizing, and is screened, qualified product is
For stone paper master batch；
D. recycle: rejected product is returned in step c after screening and carries out secondary mixing by the product that step c is obtained,
It recycles.
5. the method for production stone paper master batch as claimed in claim 4, it is characterised in that: mixed in the step a and step b
Material machine is high speed mixer.
6. the method for production stone paper master batch as claimed in claim 4, it is characterised in that: pelletizer is double in the step c
Multiple screw extruder, operating condition setting are as follows: screw slenderness ratio 45:1~55:1, operation temperature parameter is by feed end to discharge end
Setting are as follows: feeding section is controlled at 150~165 DEG C, closes section control at 165~175 DEG C, and discharge zone is controlled at 165~150 DEG C, then
Carry out water ring pelletizing.
7. the application of stone paper masterbatch composition described in a kind of claim 1, it is characterised in that: with the composition stone paper
Master batch.
8. the application of stone paper master batch described in a kind of claim 7, it is characterised in that: stone paper is made with the stone paper master batch
Plate.
9. the application of stone paper plate described in a kind of claim 8, it is characterised in that: be made and packed of the stone paper plate
Case.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810815948.0A CN109181100A (en) | 2018-07-24 | 2018-07-24 | The production method and its application of stone paper masterbatch composition, master batch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810815948.0A CN109181100A (en) | 2018-07-24 | 2018-07-24 | The production method and its application of stone paper masterbatch composition, master batch |
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Family
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| CN201810815948.0A Pending CN109181100A (en) | 2018-07-24 | 2018-07-24 | The production method and its application of stone paper masterbatch composition, master batch |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110372945A (en) * | 2019-08-26 | 2019-10-25 | 淮安禾邦工贸有限公司 | A kind of manufacturing process and formula of mother of pearl paper |
| CN110803882A (en) * | 2019-11-13 | 2020-02-18 | 山西宇皓环保纸业有限公司 | Method for producing stone paper by using stone paper leftover material and regenerated stone paper |
| CN111944238A (en) * | 2020-09-08 | 2020-11-17 | 烟台融晟新材料有限公司 | PP calcium plastic material for improving printing suitability of packaging box and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110372945A (en) * | 2019-08-26 | 2019-10-25 | 淮安禾邦工贸有限公司 | A kind of manufacturing process and formula of mother of pearl paper |
| CN110803882A (en) * | 2019-11-13 | 2020-02-18 | 山西宇皓环保纸业有限公司 | Method for producing stone paper by using stone paper leftover material and regenerated stone paper |
| CN110803882B (en) * | 2019-11-13 | 2021-11-09 | 山西宇皓环保纸业有限公司 | Method for producing stone paper by using stone paper leftover material and regenerated stone paper |
| CN111944238A (en) * | 2020-09-08 | 2020-11-17 | 烟台融晟新材料有限公司 | PP calcium plastic material for improving printing suitability of packaging box and preparation method thereof |
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