CN109180069A - A kind of noise reducing type glass fiber compound material - Google Patents
A kind of noise reducing type glass fiber compound material Download PDFInfo
- Publication number
- CN109180069A CN109180069A CN201811011645.XA CN201811011645A CN109180069A CN 109180069 A CN109180069 A CN 109180069A CN 201811011645 A CN201811011645 A CN 201811011645A CN 109180069 A CN109180069 A CN 109180069A
- Authority
- CN
- China
- Prior art keywords
- glass fiber
- parts
- noise reducing
- powder
- reducing type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/34—Metals, e.g. ferro-silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/38—Fibrous materials; Whiskers
- C04B14/42—Glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/10—Acids or salts thereof containing carbon in the anion
- C04B22/106—Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of noise reducing type glass fiber compound materials, belong to building material technical field.The present invention is by glass fibre ball milling, sieving, obtain glass fiber powder, glass fiber powder is mixed into immersion with sodium hydroxide solution, filtering, washing, obtain single treatment glass fiber powder, by single treatment glass fiber powder, biogas slurry, sucrose, sodium alginate solution mixed fermentation, it is subsequently added into ferric chloride solution and Fluorinse, it is stirred, filtering, washing, charing, it heats up step by step, pyroreaction, cooling, up to modified glass-fiber powder by epoxy resin, diluent, modified glass-fiber powder, low-melting alloy powder, saltcake, odium stearate, modified micro-capsule, calcium bicarbonate and phosphatide are stirred, injection molding, it is hot-forming, demoulding, up to noise reducing type glass fiber compound material.Noise reducing type glass fiber compound material sound insulation value and mechanical property provided by the invention have obtained effective promotion simultaneously.
Description
Technical field
The invention discloses a kind of noise reducing type glass fiber compound materials, belong to building material technical field.
Background technique
In a broad sense, noise, which refers to, allows the uncomfortable sound of the mankind, belongs to a major class of environmental pollution, with air
Pollution, water pollution together, are listed in the three overall situation pollution sources in the present age.With modern industry, construction industry and transportation
Deng development, the problem of noise pollution also becomes increasingly conspicuous, it has also become influences people's quality of life and is detrimental to health main
One of factor.Therefore, the noise pollution for how reducing environment, arouses widespread concern.
Make a general survey of the work done in terms of reducing pollution from environmental noise, it can be seen that mainly at two aspects: being on the one hand
Noise source is controlled and is administered, i.e., the big scrap build of noise is become into the small or even mute equipment of noise;Second is that making an uproar
Noise reduction is carried out in the Acoustic Wave Propagation approach of sound, mainly develops various partitions or the sound insulation of absorption noise or sound-absorbing material.
In order to effectively separate noise, traditional acoustic material is mostly thick and heavy type, the range limited its application.With room rate rising and
Increase of the people to space requirement, the requirement to thin light Acoustic barrier plate are higher and higher.Xin Feng is first equal theoretically to be had studied
The sound insulation property of light-weight metal sandwich boards shows that the plate of sandwich structure has good sound insulation value.Yu Laiming etc. is ground
Influence of the spread pattern of reinforcing material to composite material sound insulation value is studied carefully.Yang Tianbing etc. has studied honeycomb weave fabric enhancing polychlorostyrene
The sound insulation value of ethylene composite material.There is a company, has developed a kind of novel soundproof construction composition, this soundproof construction
Material is and the fire-retardant soundproof plate enhanced with glass fibre foaming body using the old glass of recycling as foaming body.Though
These right acoustic materials have good sound insulation value, but are difficult to meet the multiple requirements that people separate premises.It passes at present
System noise reducing type glass fiber compound material the problem of can not being promoted simultaneously there is also sound insulation value and mechanical property, therefore also need pair
It is studied.
Summary of the invention
The present invention solves the technical problem of: for traditional noise reducing type glass fiber compound material sound insulation value and power
The problem of performance can not be promoted simultaneously is learned, a kind of noise reducing type glass fiber compound material is provided.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of noise reducing type glass fiber compound material, is made of the raw material of following parts by weight:
40~60 parts of epoxy resin
20~30 parts of diluent
20~30 parts of modified glass-fiber powder
10~20 parts of low-melting alloy powder
8~10 parts of saltcake
3~5 parts of odium stearate
Modified 8~10 parts of micro-capsule
3~5 parts of calcium bicarbonate
Phosphatidase 3~5 part
The preparation process of the noise reducing type glass fiber compound material are as follows: each raw material is weighed by raw material composition, it is dilute by epoxy resin
Agent is released, modified glass-fiber powder, low-melting alloy powder, saltcake, odium stearate, modified micro-capsule, calcium bicarbonate and phosphatide stirring are mixed
It closes, injection molding is hot-forming, demoulds to get noise reducing type glass fiber compound material.
The epoxy resin is any one in epoxy resin E51, epoxy resin E44 or epoxy resin E20.
The diluent is dimethylbenzene, any one in acetone or alcohol.
The preparation process of the modified glass-fiber powder are as follows: by glass fibre ball milling, cross the sieve of 100 mesh, obtain glass fibre
Glass fiber powder is mixed immersion with sodium hydroxide solution 1:10~1:20 in mass ratio by powder, is filtered, and washing obtains single treatment
Glass fiber powder, according to parts by weight, by 20~30 parts of single treatment glass fiber powders, 2~3 parts of biogas slurries, 1~2 portion of sucrose, 30
~40 parts of sodium alginate solution mixed fermentations are subsequently added into the ferric chloride solution of 0.1~0.2 times of single treatment glass fiber powder quality
It with 0.1~0.2 times of Fluorinse of single treatment glass fiber powder quality, is stirred, filters, wash, charing rises step by step
Temperature, pyroreaction cool down to get modified glass-fiber powder.
The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%(ω), tin accounts for 31%(ω), lead accounts for 10%(ω),
Indium accounts for 9%(ω).
The preparation process of the modified micro-capsule are as follows: by linseed oil and gelatin solution be in mass ratio 1:10~1:15 mix point
It dissipates, obtains lotion, add the metabisulfite solution of quality of the emulsion 8~10%, after heating stirring mixing, cooling, and quality of the emulsion is added dropwise
5~7% formalin, then pH to 9.6~9.8 is adjusted, it is then cured, it filters, washing and drying are to get modified micro-capsule.
The phosphatide is soybean lecithin, any one in yolk phospholipid or milk phosphatide.
The beneficial effects of the present invention are:
The present invention is by addition modified glass-fiber powder, calcium bicarbonate and low-melting alloy, during the preparation process, firstly, glass
Fiber powder is impregnated by sodium hydroxide solution, using sodium hydroxide etching glass fiber, so that the roughness of fiberglass surfacing
It is promoted, then by fermentation, bacterium is enabled to adhere to and breed in fiberglass surfacing, then pass through addition iron chloride
Solution, bacterial cell wall surface is negatively charged, and the iron ion in system can be adsorbed by bacteria cell wall, so that a large amount of iron ion
It is enriched in bacterium surface, then, in carbonization process, the organic matter of fiberglass surfacing is carbonized, meanwhile, iron ion is reduced into
Fe, and fiberglass surfacing is fixed on by carbonaceous layer, in high-temperature reaction process, make in the catalysis of fe and sodium fluoride
Under, the silica of fiberglass surfacing and the charcoal qualitative response on its surface generate silicon carbide, so that the mechanical property of system obtains
To promotion, in use, calcium bicarbonate is thermally decomposed, and generates a large amount of carbon dioxide gas, so that being formed in system big
The through-hole of amount has just melted, alloy simultaneously as low-melting alloy has lower fusing point before branch is fully cured
It can be very good to disperse and surround fe after ion fusing, after alloy graining, may make and form metallurgical bonding between glass fibre,
So that the mechanical property of system gets a promotion, meanwhile, the formation of metallurgical bonding is formed a large amount of so that the through-hole in system separates
Closed pore so that the sound insulation value of system is further promoted.
Specific embodiment
Sodium alginate and water 1:50~1:100 in mass ratio are placed in No. 1 beaker, stir 10~20min with glass bar,
After standing 3~5h of swelling, No. 1 beaker is placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 80~85 DEG C in temperature, revolving speed is
Under the conditions of 300~500r/min, heating stirring dissolves 40~60min to get sodium alginate solution;Glass fibre is placed in ball mill
Middle ball milling crosses the sieve of 100 mesh, obtains glass fiber powder, the sodium hydroxide solution for being 30~37% by glass fiber powder and mass fraction
1:10~1:20 is placed in reaction kettle in mass ratio, is 40~60 DEG C in temperature, under the conditions of revolving speed is 300~500r/min, is mixed
It closes and impregnates 1~2h, obtain soak, then soak is filtered, obtain No. 1 filter cake, then spend glacial acetic acid for No. 1 Washing of Filter Cake to washing
Liquid is washed as neutrality, obtains single treatment glass fiber powder, according to parts by weight, by 20~30 parts of single treatment glass fiber powders, 2~
3 parts of biogas slurries, 1~2 portion of sucrose, 30~40 parts of sodium alginate solutions are placed in mixed fermentation 5~8 days in fermentation cauldron, then to fermentation cauldron
It is middle that ferric chloride solution and the single treatment that 0.1~0.2 times of mass fraction of single treatment glass fiber powder quality is 10~20% is added
0.1~0.2 times of mass fraction of glass fiber powder quality be 3~5% Fluorinse, in revolving speed be 400~600r/min condition
Under, it is stirred 40~60min, mixed serum is obtained, then mixed serum is filtered, obtains filter residue, then with deionized water by filter residue
Washing to cleaning solution is neutrality, obtains dry filter residue, and then dry filter residue is placed in tube furnace, and with 100~120mL/min speed
Rate is filled with nitrogen into furnace, under the conditions of temperature is 750~1000 DEG C, after carbonizing 1~2h, with the heating speed of 8~15 DEG C/min
In-furnace temperature is risen to 1400~1550 DEG C by rate, after 3~5h of pyroreaction, is down to room temperature with furnace to get modified glass-fiber powder;
It is in mass ratio that 1:10~1:15 pours into the gelatin solution mixing that linseed oil and mass fraction are 4~6% in No. 2 beakers, and incites somebody to action
No. 2 beakers move into ultrasonic disperse instrument, in supersonic frequency be 55~65kHz, under the conditions of temperature is 45~50 DEG C, ultrasonic disperse 45~
60min obtains lotion, then the metabisulfite solution that the mass fraction of quality of the emulsion 8~10% is 10~20% is added into No. 2 beakers,
It is then 80~90 DEG C in temperature, under the conditions of revolving speed is 400~500r/min, heating stirring mixes 2~4h, stop heating, to
55~60 DEG C are cooled to, adds the formalin that the mass fraction of quality of the emulsion 5~7% in No. 2 beakers is 37%, and adjust 2
Material pH to 9.6~9.8 in number beaker after being stirred 10~15min with glass bar, stands 45~60min of solidification, then through taking out
Filter, obtains No. 2 filter cakes, and No. 2 filter cakes are washed with deionized 3~5 times, then No. 2 filter cakes after washing are freeze-dried to get changing
Property micro-capsule;According to parts by weight, by 40~60 parts of epoxy resin, 20~30 parts of diluents, 20~30 parts of modified glass-fibers
Powder, 10~20 parts of low-melting alloy powder, 8~10 parts of saltcake, 3~5 parts of odium stearate, 8~10 parts of modified micro-capsules, 3~5 parts of carbonic acid
Hydrogen calcium and 3~5 parts of phosphatide are placed in batch mixer, under the conditions of revolving speed is 1000~1200r/min, high-speed stirred mixing 40~
60min obtains mixed slurry, by mixed slurry inject mold in, then mold is placed in molding machine, in temperature be 130~160
DEG C, under the conditions of pressure is 10~15MPa, after hot-forming, demould to get noise reducing type glass fiber compound material.The epoxy
Resin is any one in epoxy resin E51, epoxy resin E44 or epoxy resin E20.The diluent is dimethylbenzene, acetone
Or any one in ethyl alcohol.The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%(ω), tin accounts for 31%(ω),
Lead accounts for 10%(ω), indium accounts for 9%(ω).The phosphatide is soybean lecithin, any one in yolk phospholipid or milk phosphatide.
Sodium alginate and water 1:100 in mass ratio are placed in No. 1 beaker, stir 20min with glass bar, stands swelling 5h
Afterwards, No. 1 beaker is placed in digital display to test the speed in constant temperature blender with magnetic force, is 85 DEG C in temperature, under the conditions of revolving speed is 500r/min, adds
Thermal agitation dissolves 60min to get sodium alginate solution;Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass
The sodium hydroxide solution 1:20 in mass ratio that glass fiber powder and mass fraction are 37% is placed in reaction kettle, Yu Wen by fiber powder
Degree is 60 DEG C, and under the conditions of revolving speed is 500r/min, 2h is impregnated in mixing, obtains soak, then soak is filtered, obtains No. 1 filter cake, connect
Spend glacial acetic acid by No. 1 Washing of Filter Cake to cleaning solution for neutrality, obtain single treatment glass fiber powder, according to parts by weight, will
30 parts of single treatment glass fiber powders, 3 parts of biogas slurries, 2 portions of sucrose, 40 parts of sodium alginate solutions are placed in mixed fermentation 8 days in fermentation cauldron,
Then ferric chloride solution that 0.2 times of mass fraction of single treatment glass fiber powder quality is 20% and primary is added into fermentation cauldron
The Fluorinse that 0.2 times of mass fraction of glass fiber powder quality is 5% is handled, under the conditions of revolving speed is 600r/min, stirring is mixed
60min is closed, mixed serum is obtained, then mixed serum is filtered, obtains filter residue, be then by residue washing to cleaning solution with deionized water
Neutrality obtains dry filter residue, then dry filter residue is placed in tube furnace, and nitrogen is filled with into furnace with 120mL/min rate, in
Under the conditions of temperature is 1000 DEG C, after carbonizing 2h, in-furnace temperature is risen to 1550 DEG C with the heating rate of 15 DEG C/min, pyroreaction
After 5h, room temperature is down to get modified glass-fiber powder with furnace;In mass ratio be 1:15 by linseed oil and mass fraction be 6% it is bright
Sol solution mixing is poured into No. 2 beakers, and No. 2 beakers are moved into ultrasonic disperse instrument, in supersonic frequency be 65kHz, temperature 50
Under the conditions of DEG C, ultrasonic disperse 60min obtains lotion, then the sulphur that the mass fraction of quality of the emulsion 10% is 20% is added into No. 2 beakers
Acid sodium solution is then 90 DEG C in temperature, and under the conditions of revolving speed is 500r/min, heating stirring mixes 4h, stops heating, wait cool down
To 60 DEG C, the formalin that the mass fraction of quality of the emulsion 7% in No. 2 beakers is 37% is added, and adjust material in No. 2 beakers
PH to 9.8 after being stirred 15min with glass bar, stands solidification 60min, then filtered, obtains No. 2 filter cakes, and use deionized water
Wash No. 2 filter cakes 5 times, then by No. 2 filter cakes freeze-drying after washing to get modified micro-capsule;According to parts by weight, by 60 parts of rings
Oxygen resin, 30 parts of diluents, 30 parts of modified glass-fiber powder, 20 parts of low-melting alloy powder, 10 parts of saltcake, 5 parts of odium stearate,
10 parts of modified micro-capsules, 5 parts of calcium bicarbonates and 5 parts of phosphatide are placed in batch mixer, under the conditions of revolving speed is 1200r/min, high-speed stirring
Mixing 60min is mixed, mixed slurry is obtained, mixed slurry is injected in mold, then mold is placed in molding machine, is in temperature
It 160 DEG C, under the conditions of pressure is 15MPa, after hot-forming, demoulds to get noise reducing type glass fiber compound material.The asphalt mixtures modified by epoxy resin
Rouge is epoxy resin E51.The diluent is dimethylbenzene.The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%
(ω), tin account for 31%(ω), lead accounts for 10%(ω), indium accounts for 9%(ω).The phosphatide is soybean lecithin.
Sodium alginate and water 1:100 in mass ratio are placed in No. 1 beaker, stir 20min with glass bar, stands swelling 5h
Afterwards, No. 1 beaker is placed in digital display to test the speed in constant temperature blender with magnetic force, is 85 DEG C in temperature, under the conditions of revolving speed is 500r/min, adds
Thermal agitation dissolves 60min to get sodium alginate solution;Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass
Fiber powder;In mass ratio to be 1:15, which mix the gelatin solution that linseed oil and mass fraction are 6%, pours into No. 2 beakers, and by 2
Number beaker moves into ultrasonic disperse instrument, is 65kHz in supersonic frequency, and under the conditions of temperature is 50 DEG C, ultrasonic disperse 60min obtains lotion,
Again into No. 2 beakers be added quality of the emulsion 10% mass fraction be 20% metabisulfite solution, then in temperature be 90 DEG C, revolving speed
Under the conditions of 500r/min, heating stirring mixes 4h, stops heating, wait be cooled to 60 DEG C, adds quality of the emulsion in No. 2 beakers
The formalin that 7% mass fraction is 37%, and material pH to 9.8 in No. 2 beakers is adjusted, 15min is stirred with glass bar
Afterwards, solidification 60min is stood, then is filtered, obtains No. 2 filter cakes, and No. 2 filter cakes are washed with deionized 5 times, then by 2 after washing
The freeze-drying of number filter cake is to get modified micro-capsule;According to parts by weight, by 60 parts of epoxy resin, 30 parts of diluents, 30 parts of glass
Fiber powder, 20 parts of low-melting alloy powder, 10 parts of saltcake, 5 parts of odium stearate, 10 parts of modified micro-capsules, 5 parts of calcium bicarbonates and 5 parts of phosphorus
Rouge is placed in batch mixer, and under the conditions of revolving speed is 1200r/min, high-speed stirred mixes 60min, mixed slurry is obtained, by mixing slurry
Material injection mold in, then mold is placed in molding machine, in temperature be 160 DEG C, pressure be 15MPa under the conditions of, it is hot-forming
Afterwards, demoulding is to get noise reducing type glass fiber compound material.The epoxy resin is epoxy resin E51.The diluent is diformazan
Benzene.The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%(ω), tin accounts for 31%(ω), lead accounts for 10%(ω), indium accounts for
9%(ω).The phosphatide is soybean lecithin.
Sodium alginate and water 1:100 in mass ratio are placed in No. 1 beaker, stir 20min with glass bar, stands swelling 5h
Afterwards, No. 1 beaker is placed in digital display to test the speed in constant temperature blender with magnetic force, is 85 DEG C in temperature, under the conditions of revolving speed is 500r/min, adds
Thermal agitation dissolves 60min to get sodium alginate solution;Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass
The sodium hydroxide solution 1:20 in mass ratio that glass fiber powder and mass fraction are 37% is placed in reaction kettle, Yu Wen by fiber powder
Degree is 60 DEG C, and under the conditions of revolving speed is 500r/min, 2h is impregnated in mixing, obtains soak, then soak is filtered, obtains No. 1 filter cake, connect
Spend glacial acetic acid by No. 1 Washing of Filter Cake to cleaning solution for neutrality, obtain single treatment glass fiber powder, according to parts by weight, will
30 parts of single treatment glass fiber powders, 3 parts of biogas slurries, 2 portions of sucrose, 40 parts of sodium alginate solutions are placed in mixed fermentation 8 days in fermentation cauldron,
Then ferric chloride solution that 0.2 times of mass fraction of single treatment glass fiber powder quality is 20% and primary is added into fermentation cauldron
The Fluorinse that 0.2 times of mass fraction of glass fiber powder quality is 5% is handled, under the conditions of revolving speed is 600r/min, stirring is mixed
60min is closed, mixed serum is obtained, then mixed serum is filtered, obtains filter residue, be then by residue washing to cleaning solution with deionized water
Neutrality obtains dry filter residue, then dry filter residue is placed in tube furnace, and nitrogen is filled with into furnace with 120mL/min rate, in
Under the conditions of temperature is 1000 DEG C, after carbonizing 2h, in-furnace temperature is risen to 1550 DEG C with the heating rate of 15 DEG C/min, pyroreaction
After 5h, room temperature is down to get modified glass-fiber powder with furnace;In mass ratio be 1:15 by linseed oil and mass fraction be 6% it is bright
Sol solution mixing is poured into No. 2 beakers, and No. 2 beakers are moved into ultrasonic disperse instrument, in supersonic frequency be 65kHz, temperature 50
Under the conditions of DEG C, ultrasonic disperse 60min obtains lotion, then the sulphur that the mass fraction of quality of the emulsion 10% is 20% is added into No. 2 beakers
Acid sodium solution is then 90 DEG C in temperature, and under the conditions of revolving speed is 500r/min, heating stirring mixes 4h, stops heating, wait cool down
To 60 DEG C, the formalin that the mass fraction of quality of the emulsion 7% in No. 2 beakers is 37% is added, and adjust material in No. 2 beakers
PH to 9.8 after being stirred 15min with glass bar, stands solidification 60min, then filtered, obtains No. 2 filter cakes, and use deionized water
Wash No. 2 filter cakes 5 times, then by No. 2 filter cakes freeze-drying after washing to get modified micro-capsule;According to parts by weight, by 60 parts of rings
Oxygen resin, 30 parts of diluents, 30 parts of modified glass-fiber powder, 10 parts of saltcake, 5 parts of odium stearate, 10 parts of modified micro-capsules, 5 parts of carbon
Sour hydrogen calcium and 5 parts of phosphatide are placed in batch mixer, and under the conditions of revolving speed is 1200r/min, high-speed stirred mixes 60min, must be mixed
Mixed slurry is injected in mold, then mold is placed in molding machine by slurry, is 160 DEG C in temperature, pressure is 15MPa item
Under part, after hot-forming, demould to get noise reducing type glass fiber compound material.The epoxy resin is epoxy resin E51.Institute
Stating diluent is dimethylbenzene.The phosphatide is soybean lecithin.
Sodium alginate and water 1:100 in mass ratio are placed in No. 1 beaker, stir 20min with glass bar, stands swelling 5h
Afterwards, No. 1 beaker is placed in digital display to test the speed in constant temperature blender with magnetic force, is 85 DEG C in temperature, under the conditions of revolving speed is 500r/min, adds
Thermal agitation dissolves 60min to get sodium alginate solution;Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass
The sodium hydroxide solution 1:20 in mass ratio that glass fiber powder and mass fraction are 37% is placed in reaction kettle, Yu Wen by fiber powder
Degree is 60 DEG C, and under the conditions of revolving speed is 500r/min, 2h is impregnated in mixing, obtains soak, then soak is filtered, obtains No. 1 filter cake, connect
Spend glacial acetic acid by No. 1 Washing of Filter Cake to cleaning solution for neutrality, obtain single treatment glass fiber powder, according to parts by weight, will
30 parts of single treatment glass fiber powders, 3 parts of biogas slurries, 2 portions of sucrose, 40 parts of sodium alginate solutions are placed in mixed fermentation 8 days in fermentation cauldron,
Then ferric chloride solution that 0.2 times of mass fraction of single treatment glass fiber powder quality is 20% and primary is added into fermentation cauldron
The Fluorinse that 0.2 times of mass fraction of glass fiber powder quality is 5% is handled, under the conditions of revolving speed is 600r/min, stirring is mixed
60min is closed, mixed serum is obtained, then mixed serum is filtered, obtains filter residue, be then by residue washing to cleaning solution with deionized water
Neutrality obtains dry filter residue, then dry filter residue is placed in tube furnace, and nitrogen is filled with into furnace with 120mL/min rate, in
Under the conditions of temperature is 1000 DEG C, after carbonizing 2h, in-furnace temperature is risen to 1550 DEG C with the heating rate of 15 DEG C/min, pyroreaction
After 5h, room temperature is down to get modified glass-fiber powder with furnace;In mass ratio be 1:15 by linseed oil and mass fraction be 6% it is bright
Sol solution mixing is poured into No. 2 beakers, and No. 2 beakers are moved into ultrasonic disperse instrument, in supersonic frequency be 65kHz, temperature 50
Under the conditions of DEG C, ultrasonic disperse 60min obtains lotion, then the sulphur that the mass fraction of quality of the emulsion 10% is 20% is added into No. 2 beakers
Acid sodium solution is then 90 DEG C in temperature, and under the conditions of revolving speed is 500r/min, heating stirring mixes 4h, stops heating, wait cool down
To 60 DEG C, the formalin that the mass fraction of quality of the emulsion 7% in No. 2 beakers is 37% is added, and adjust material in No. 2 beakers
PH to 9.8 after being stirred 15min with glass bar, stands solidification 60min, then filtered, obtains No. 2 filter cakes, and use deionized water
Wash No. 2 filter cakes 5 times, then by No. 2 filter cakes freeze-drying after washing to get modified micro-capsule;According to parts by weight, by 60 parts of rings
Oxygen resin, 30 parts of diluents, 30 parts of modified glass-fiber powder, 20 parts of low-melting alloy powder, 5 parts of odium stearate, 10 parts of modifications are micro-
Capsule, 5 parts of calcium bicarbonates and 5 parts of phosphatide are placed in batch mixer, under the conditions of revolving speed is 1200r/min, high-speed stirred mixing
60min obtains mixed slurry, and mixed slurry is injected in mold, then mold is placed in molding machine, is 160 DEG C in temperature, presses
Under the conditions of power is 15MPa, after hot-forming, demould to get noise reducing type glass fiber compound material.The epoxy resin is epoxy
Resin E51.The diluent is dimethylbenzene.The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%(ω), tin accounts for
31%(ω), lead accounts for 10%(ω), indium accounts for 9%(ω).The phosphatide is soybean lecithin.
Sodium alginate and water 1:100 in mass ratio are placed in No. 1 beaker, stir 20min with glass bar, stands swelling 5h
Afterwards, No. 1 beaker is placed in digital display to test the speed in constant temperature blender with magnetic force, is 85 DEG C in temperature, under the conditions of revolving speed is 500r/min, adds
Thermal agitation dissolves 60min to get sodium alginate solution;Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass
The sodium hydroxide solution 1:20 in mass ratio that glass fiber powder and mass fraction are 37% is placed in reaction kettle, Yu Wen by fiber powder
Degree is 60 DEG C, and under the conditions of revolving speed is 500r/min, 2h is impregnated in mixing, obtains soak, then soak is filtered, obtains No. 1 filter cake, connect
Spend glacial acetic acid by No. 1 Washing of Filter Cake to cleaning solution for neutrality, obtain single treatment glass fiber powder, according to parts by weight, will
30 parts of single treatment glass fiber powders, 3 parts of biogas slurries, 2 portions of sucrose, 40 parts of sodium alginate solutions are placed in mixed fermentation 8 days in fermentation cauldron,
Then ferric chloride solution that 0.2 times of mass fraction of single treatment glass fiber powder quality is 20% and primary is added into fermentation cauldron
The Fluorinse that 0.2 times of mass fraction of glass fiber powder quality is 5% is handled, under the conditions of revolving speed is 600r/min, stirring is mixed
60min is closed, mixed serum is obtained, then mixed serum is filtered, obtains filter residue, be then by residue washing to cleaning solution with deionized water
Neutrality obtains dry filter residue, then dry filter residue is placed in tube furnace, and nitrogen is filled with into furnace with 120mL/min rate, in
Under the conditions of temperature is 1000 DEG C, after carbonizing 2h, in-furnace temperature is risen to 1550 DEG C with the heating rate of 15 DEG C/min, pyroreaction
After 5h, room temperature is down to get modified glass-fiber powder with furnace;According to parts by weight, by 60 parts of epoxy resin, 30 parts of diluents,
30 parts of modified glass-fiber powder, 20 parts of low-melting alloy powder, 10 parts of saltcake, 5 parts of odium stearate, 5 parts of calcium bicarbonates and 5 parts of phosphatide
It is placed in batch mixer, under the conditions of revolving speed is 1200r/min, high-speed stirred mixes 60min, mixed slurry is obtained, by mixed slurry
Inject mold in, then mold is placed in molding machine, in temperature be 160 DEG C, pressure be 15MPa under the conditions of, after hot-forming,
Demoulding is to get noise reducing type glass fiber compound material.The epoxy resin is epoxy resin E51.The diluent is dimethylbenzene.
The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%(ω), tin accounts for 31%(ω), lead accounts for 10%(ω), indium accounts for 9%
(ω).The phosphatide is soybean lecithin.
Sodium alginate and water 1:100 in mass ratio are placed in No. 1 beaker, stir 20min with glass bar, stands swelling 5h
Afterwards, No. 1 beaker is placed in digital display to test the speed in constant temperature blender with magnetic force, is 85 DEG C in temperature, under the conditions of revolving speed is 500r/min, adds
Thermal agitation dissolves 60min to get sodium alginate solution;Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass
The sodium hydroxide solution 1:20 in mass ratio that glass fiber powder and mass fraction are 37% is placed in reaction kettle, Yu Wen by fiber powder
Degree is 60 DEG C, and under the conditions of revolving speed is 500r/min, 2h is impregnated in mixing, obtains soak, then soak is filtered, obtains No. 1 filter cake, connect
Spend glacial acetic acid by No. 1 Washing of Filter Cake to cleaning solution for neutrality, obtain single treatment glass fiber powder, according to parts by weight, will
30 parts of single treatment glass fiber powders, 3 parts of biogas slurries, 2 portions of sucrose, 40 parts of sodium alginate solutions are placed in mixed fermentation 8 days in fermentation cauldron,
Then ferric chloride solution that 0.2 times of mass fraction of single treatment glass fiber powder quality is 20% and primary is added into fermentation cauldron
The Fluorinse that 0.2 times of mass fraction of glass fiber powder quality is 5% is handled, under the conditions of revolving speed is 600r/min, stirring is mixed
60min is closed, mixed serum is obtained, then mixed serum is filtered, obtains filter residue, be then by residue washing to cleaning solution with deionized water
Neutrality obtains dry filter residue, then dry filter residue is placed in tube furnace, and nitrogen is filled with into furnace with 120mL/min rate, in
Under the conditions of temperature is 1000 DEG C, after carbonizing 2h, in-furnace temperature is risen to 1550 DEG C with the heating rate of 15 DEG C/min, pyroreaction
After 5h, room temperature is down to get modified glass-fiber powder with furnace;In mass ratio be 1:15 by linseed oil and mass fraction be 6% it is bright
Sol solution mixing is poured into No. 2 beakers, and No. 2 beakers are moved into ultrasonic disperse instrument, in supersonic frequency be 65kHz, temperature 50
Under the conditions of DEG C, ultrasonic disperse 60min obtains lotion, then the sulphur that the mass fraction of quality of the emulsion 10% is 20% is added into No. 2 beakers
Acid sodium solution is then 90 DEG C in temperature, and under the conditions of revolving speed is 500r/min, heating stirring mixes 4h, stops heating, wait cool down
To 60 DEG C, the formalin that the mass fraction of quality of the emulsion 7% in No. 2 beakers is 37% is added, and adjust material in No. 2 beakers
PH to 9.8 after being stirred 15min with glass bar, stands solidification 60min, then filtered, obtains No. 2 filter cakes, and use deionized water
Wash No. 2 filter cakes 5 times, then by No. 2 filter cakes freeze-drying after washing to get modified micro-capsule;According to parts by weight, by 60 parts of rings
Oxygen resin, 30 parts of diluents, 30 parts of modified glass-fiber powder, 20 parts of low-melting alloy powder, 10 parts of saltcake, 5 parts of odium stearate,
10 parts of modified micro-capsules and 5 parts of phosphatide are placed in batch mixer, and under the conditions of revolving speed is 1200r/min, high-speed stirred mixes 60min,
Mixed slurry is obtained, mixed slurry is injected in mold, then mold is placed in molding machine, is 160 DEG C in temperature, pressure is
Under the conditions of 15MPa, after hot-forming, demould to get noise reducing type glass fiber compound material.The epoxy resin is epoxy resin
E51.The diluent is dimethylbenzene.The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%(ω), tin accounts for 31%
(ω), lead account for 10%(ω), indium accounts for 9%(ω).The phosphatide is soybean lecithin.
Sodium alginate and water 1:100 in mass ratio are placed in No. 1 beaker, stir 20min with glass bar, stands swelling 5h
Afterwards, No. 1 beaker is placed in digital display to test the speed in constant temperature blender with magnetic force, is 85 DEG C in temperature, under the conditions of revolving speed is 500r/min, adds
Thermal agitation dissolves 60min to get sodium alginate solution;Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass
The sodium hydroxide solution 1:20 in mass ratio that glass fiber powder and mass fraction are 37% is placed in reaction kettle, Yu Wen by fiber powder
Degree is 60 DEG C, and under the conditions of revolving speed is 500r/min, 2h is impregnated in mixing, obtains soak, then soak is filtered, obtains No. 1 filter cake, connect
Spend glacial acetic acid by No. 1 Washing of Filter Cake to cleaning solution for neutrality, obtain single treatment glass fiber powder, according to parts by weight, will
30 parts of single treatment glass fiber powders, 3 parts of biogas slurries, 2 portions of sucrose, 40 parts of sodium alginate solutions are placed in mixed fermentation 8 days in fermentation cauldron,
Then ferric chloride solution that 0.2 times of mass fraction of single treatment glass fiber powder quality is 20% and primary is added into fermentation cauldron
The Fluorinse that 0.2 times of mass fraction of glass fiber powder quality is 5% is handled, under the conditions of revolving speed is 600r/min, stirring is mixed
60min is closed, mixed serum is obtained, then mixed serum is filtered, obtains filter residue, be then by residue washing to cleaning solution with deionized water
Neutrality obtains dry filter residue, then dry filter residue is placed in tube furnace, and nitrogen is filled with into furnace with 120mL/min rate, in
Under the conditions of temperature is 1000 DEG C, after carbonizing 2h, in-furnace temperature is risen to 1550 DEG C with the heating rate of 15 DEG C/min, pyroreaction
After 5h, room temperature is down to get modified glass-fiber powder with furnace;In mass ratio be 1:15 by linseed oil and mass fraction be 6% it is bright
Sol solution mixing is poured into No. 2 beakers, and No. 2 beakers are moved into ultrasonic disperse instrument, in supersonic frequency be 65kHz, temperature 50
Under the conditions of DEG C, ultrasonic disperse 60min obtains lotion, then the sulphur that the mass fraction of quality of the emulsion 10% is 20% is added into No. 2 beakers
Acid sodium solution is then 90 DEG C in temperature, and under the conditions of revolving speed is 500r/min, heating stirring mixes 4h, stops heating, wait cool down
To 60 DEG C, the formalin that the mass fraction of quality of the emulsion 7% in No. 2 beakers is 37% is added, and adjust material in No. 2 beakers
PH to 9.8 after being stirred 15min with glass bar, stands solidification 60min, then filtered, obtains No. 2 filter cakes, and use deionized water
Wash No. 2 filter cakes 5 times, then by No. 2 filter cakes freeze-drying after washing to get modified micro-capsule;According to parts by weight, by 60 parts of rings
Oxygen resin, 30 parts of diluents, 30 parts of modified glass-fiber powder, 20 parts of low-melting alloy powder, 10 parts of saltcake, 5 parts of odium stearate,
10 parts of modified micro-capsules, 5 parts of calcium bicarbonates are placed in batch mixer, under the conditions of revolving speed is 1200r/min, high-speed stirred mixing
60min obtains mixed slurry, and mixed slurry is injected in mold, then mold is placed in molding machine, is 160 DEG C in temperature, presses
Under the conditions of power is 15MPa, after hot-forming, demould to get noise reducing type glass fiber compound material.The epoxy resin is epoxy
Resin E51.The diluent is dimethylbenzene.The low-melting alloy powder is bismuth tin alloy powder, and wherein bismuth accounts for 50%(ω), tin accounts for
31%(ω), lead accounts for 10%(ω), indium accounts for 9%(ω).
Comparative example: the glass fiber compound material of Dongguan fiberglass products Co., Ltd production.
1 to 7 gained glass fiber compound material of example and comparative example product are subjected to performance detection, specific detection method is such as
Under:
Bending strength is tested by GB1449;Sound insulation value uses two-channel acoustic analysis test macro.
Specific testing result is as shown in table 1:
Table 1: performance detection table
By 1 testing result of table it is found that the present invention gained noise reducing type glass fiber compound material sound insulation value and mechanical property simultaneously
Effective promotion is obtained.
Claims (7)
1. a kind of noise reducing type glass fiber compound material, it is characterised in that: be made of the raw material of following parts by weight:
40~60 parts of epoxy resin
20~30 parts of diluent
20~30 parts of modified glass-fiber powder
10~20 parts of low-melting alloy powder
8~10 parts of saltcake
3~5 parts of odium stearate
Modified 8~10 parts of micro-capsule
3~5 parts of calcium bicarbonate
Phosphatidase 3~5 part
The preparation process of the noise reducing type glass fiber compound material are as follows: each raw material is weighed by raw material composition, it is dilute by epoxy resin
Agent is released, modified glass-fiber powder, low-melting alloy powder, saltcake, odium stearate, modified micro-capsule, calcium bicarbonate and phosphatide stirring are mixed
It closes, injection molding is hot-forming, demoulds to get noise reducing type glass fiber compound material.
2. a kind of noise reducing type glass fiber compound material according to claim 1, it is characterised in that: the epoxy resin is ring
Any one in oxygen resin E51, epoxy resin E44 or epoxy resin E20.
3. a kind of noise reducing type glass fiber compound material according to claim 1, it is characterised in that: the diluent is diformazan
Benzene, any one in acetone or alcohol.
4. a kind of noise reducing type glass fiber compound material according to claim 1, it is characterised in that: the modified glass-fiber
The preparation process of powder are as follows: by glass fibre ball milling, cross the sieve of 100 mesh, glass fiber powder is obtained, by glass fiber powder and sodium hydroxide
Solution 1:10~1:20 in mass ratio mixing is impregnated, and is filtered, and washing obtains single treatment glass fiber powder, according to parts by weight, will
20~30 parts of single treatment glass fiber powders, 2~3 parts of biogas slurries, 1~2 portion of sucrose, 30~40 parts of sodium alginate solution mixed fermentations,
It is subsequently added into the ferric chloride solution and single treatment glass fiber powder quality of 0.1~0.2 times of single treatment glass fiber powder quality
0.1~0.2 times of Fluorinse, is stirred, and filters, and washs, and charing heats up step by step, and pyroreaction cools down to get changing
Property glass fiber powder.
5. a kind of noise reducing type glass fiber compound material according to claim 1, it is characterised in that: the low-melting alloy powder
For bismuth tin alloy powder, wherein bismuth accounts for 50%(ω), tin accounts for 31%(ω), lead accounts for 10%(ω), indium accounts for 9%(ω).
6. a kind of noise reducing type glass fiber compound material according to claim 1, it is characterised in that: the system of the modified micro-capsule
Standby process are as follows: by linseed oil and gelatin solution be in mass ratio that 1:10~1:15 mixes dispersion, obtain lotion, add quality of the emulsion
8~10% metabisulfite solution, after heating stirring mixing, cooling, and the formalin of quality of the emulsion 5~7% is added dropwise, then adjust pH
To 9.6~9.8, then cured, suction filtration, washing and drying are to get modified micro-capsule.
7. a kind of noise reducing type glass fiber compound material according to claim 1, it is characterised in that: the phosphatide is soybean phosphorus
Any one in rouge, yolk phospholipid or milk phosphatide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811011645.XA CN109180069A (en) | 2018-08-31 | 2018-08-31 | A kind of noise reducing type glass fiber compound material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811011645.XA CN109180069A (en) | 2018-08-31 | 2018-08-31 | A kind of noise reducing type glass fiber compound material |
Publications (1)
Publication Number | Publication Date |
---|---|
CN109180069A true CN109180069A (en) | 2019-01-11 |
Family
ID=64917761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811011645.XA Withdrawn CN109180069A (en) | 2018-08-31 | 2018-08-31 | A kind of noise reducing type glass fiber compound material |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109180069A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110156328A (en) * | 2019-04-28 | 2019-08-23 | 江苏华鸥玻璃有限公司 | A kind of novel fire resistant glass tube and its processing technology |
CN114316519A (en) * | 2022-01-05 | 2022-04-12 | 泰山玻璃纤维有限公司 | Carbon-glass mixed pulling plate and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1730527A (en) * | 2005-09-12 | 2006-02-08 | 上海汽车集团股份有限公司 | Fiber reinforcement composite material used for car shrouding parts and back holding door produced therefrom |
CN108314985A (en) * | 2018-02-10 | 2018-07-24 | 汪逸凡 | A kind of water-fast building adhesive of two-part room temperature curing type |
-
2018
- 2018-08-31 CN CN201811011645.XA patent/CN109180069A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1730527A (en) * | 2005-09-12 | 2006-02-08 | 上海汽车集团股份有限公司 | Fiber reinforcement composite material used for car shrouding parts and back holding door produced therefrom |
CN108314985A (en) * | 2018-02-10 | 2018-07-24 | 汪逸凡 | A kind of water-fast building adhesive of two-part room temperature curing type |
Non-Patent Citations (3)
Title |
---|
邹宗柏等: "减振降噪功能材料的研制", 《环境科学》 * |
陈袁曦: "细菌纤维素对玻璃纤维/环氧树脂的界面改性", 《中国博士学位论文全文数据库 工程科技I辑》 * |
高红霞: "《工程材料》", 30 September 2009, 中国轻工业出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110156328A (en) * | 2019-04-28 | 2019-08-23 | 江苏华鸥玻璃有限公司 | A kind of novel fire resistant glass tube and its processing technology |
CN114316519A (en) * | 2022-01-05 | 2022-04-12 | 泰山玻璃纤维有限公司 | Carbon-glass mixed pulling plate and preparation method thereof |
CN114316519B (en) * | 2022-01-05 | 2024-03-22 | 泰山玻璃纤维有限公司 | Carbon-glass mixed pulling plate and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2021008194A1 (en) | Nano-modified material for cavity wall with insulation for prefabricated building, and preparation method and use thereof | |
CN109180069A (en) | A kind of noise reducing type glass fiber compound material | |
CN106365544A (en) | Fiber-reinforced concrete | |
CN109809776A (en) | A kind of lightweight wall plate and its production technology of fire-proof and thermal-insulation | |
CN108585659A (en) | A kind of wall heat insulation plank and preparation method thereof | |
CN103467016B (en) | Preparation method for preparing low-density oil well cement test block from composite ceramic microbeads | |
CN112441780A (en) | Method for preparing baking-free geopolymer material by utilizing spodumene flotation tailings | |
CN110204291A (en) | A kind of building exterior wall heat preserving plate and preparation method thereof | |
CN106739397A (en) | The preparation method of high-orientation absorbing material | |
CN103483001A (en) | Manufacturing method of halogen-resistant-strengthened lightweight composite wallboard and building block made of light magnesium powder | |
CN108117364A (en) | A kind of preparation method of high crack resistance type rock cotton board | |
CN108314368A (en) | A kind of environment-friendly light decorative insulation board and preparation method thereof | |
CN107523023A (en) | A kind of graphene polyester sound-absorbing material and preparation method thereof | |
CN108975797A (en) | A kind of preparation method of ultralight foam concrete | |
CN109250950A (en) | A kind of distress in concrete repairs the preparation method of special microorganism carrier material | |
CN115974477B (en) | Ultra-high performance concrete containing rare earth polishing powder waste and preparation method thereof | |
CN108929072B (en) | Method for preparing ferric oxide and nano composite heat insulation material from iron tailings | |
CN115259823B (en) | Lightweight high-strength low-thermal-conductivity aerated concrete and preparation method thereof | |
CN111018480A (en) | Fiber-reinforced inorganic composite insulation board | |
CN105541381A (en) | Environment-friendly high-strength inorganic heat-insulating material and preparation method therefor | |
CN107244845A (en) | A kind of heat insulation decoration integrated composite plate and its production technology | |
CN108558308A (en) | A kind of insulating light wall slab and preparation method thereof | |
CN114714691A (en) | Novel ceramic integrated plate and processing technology thereof | |
CN108222401B (en) | Composite insulation board integrated board and preparation process | |
CN111875410A (en) | Light magnesium slag building material and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190111 |