CN109179563A - A kind of light intensity chemical algae removing agent - Google Patents
A kind of light intensity chemical algae removing agent Download PDFInfo
- Publication number
- CN109179563A CN109179563A CN201811200268.4A CN201811200268A CN109179563A CN 109179563 A CN109179563 A CN 109179563A CN 201811200268 A CN201811200268 A CN 201811200268A CN 109179563 A CN109179563 A CN 109179563A
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- China
- Prior art keywords
- algae
- light intensity
- removing agent
- intensity chemical
- algae removing
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
Abstract
The invention discloses a kind of light intensity chemical algae removing agent, the light intensity chemical algae removing agent is that allelochemical is dissolved in dimethyl sulfoxide and is obtained, there is remarkable result under illumination condition, wherein, the allelochemical is P-hydroxybenzoic acid, parahydroxyben-zaldehyde it is a kind of or their mixture, wherein allelochemical concentration range in dimethyl sulfoxide is 0.2%-50%, for in the application of algae and water bioscrubbing, additional amount in algae solution per ton is 0.05-10kg, in the case where natural outdoor optical photograph or light intensity are 500-30000Lux artificial light sources irradiation condition, it can make algae in water body that bleaching and lethal occur.Through the above way, the present invention can effectively be directed to the Different Waters algae such as cytoalgae, Dunaliella salina, hair-like nostoc, chlorella, anabena and microcystic aeruginosa, have the advantages that quickly to remove algae, long action time, prevent algicide dependence and pollution-free, odorlessness, environment will not be polluted, be a kind of green algicide.
Description
Technical field
The present invention relates to algicide fields, are a kind of light intensity chemical algae removing agent specifically.
Background technique
In recent years, since the eutrophication of water body is got worse, water bloom of water body outburst in part is raw to the ecological balance and the mankind
Safety living causes great threat, it has also become environmental area a great problem to be solved.How to effectively control wawter blooms, eliminate rich battalion
Explosive increase of feedingization harmful algae in water body is current water environment area research hot spot and forward position.
Currently, algae and water controls and the major technique removed mainly has: physical method, bioanalysis and chemical method.
Physical method includes machinery, filtering, air bearing, shading technology, encloses barrier, ultrasonic method etc., these can directly be removed
Algae in water body not will cause secondary pollution, but its input cost is excessively high and is unfavorable for large area except algae operation, Er Qiewei
Water eutrophication can fundamentally be solved.
Bioanalysis between biology including the use of interacting, put aquatile control algae, microbial flocculation in a suitable place to breed except algae etc., bioanalysis
Except algae has many advantages, such as pollution-free, low consumption, sustainability, but slow effect, period are long, and be affected by the external environment compared with
Greatly, being not suitable for breaking out in algae influences to use under the serious state of emergency.
Chemical rule is to be carried out using various chemical algae removing agent except algae, is at present using most, with fastest developing speed one kind sides
Method, have many advantages, such as it is relatively easy, can large area operation, but existing algicide exists and is not thorough except algae effect, uses
After the problem of being easy to produce harmful by-products, leading to secondary pollution of water.
It is concerned in recent years using allelopathy algal control as a kind of biological algal control technology of new type of safe, allelochemical
For botanical secondary metabolite, such as pyrogallic acid, diallyl disulfide, vanillic aldehyde, usually easily drop under field conditions (factors)
Solution, will not accumulate in the ecosystem, there is the features such as ecological security is preferable.Now about the research of this respect, such as
The prior art such as Authorization Notice No. is the Chinese invention patent of CN104782626A, disclose a kind of allelochemical algae-inhibiting agent and its
Method for extraction and purification；Authorization Notice No. is the Chinese invention patent of CN104326515A, discloses a kind of utilize from Eucalyptus APMP
The method that the allelochemical extracted in pulp-making waste-water inhibits microcystic aeruginosa；Authorization Notice No. is the middle promulgated by the State Council of CN102125066B
Bright patent discloses a kind of preparation method of sustained-release composite biological algicide.Above-mentioned three kinds of algicide mainly utilize medicament
Inhibition to algae or killing effect in itself.
We have discovered that some compounds such as P-hydroxybenzoic acid, parahydroxyben-zaldehyde etc. have photobleaching work to algae
With, in daylight or under being aided with artificial light sources irradiation, strong blanching effect can be generated to microalgae in water body and kill algae, and
In itself to algae killing effect very little under no illumination condition.Therefore, the present invention is that a kind of strengthened by illumination reaches except Cutleriales
Light intensity chemical algae removing agent.
Summary of the invention
The purpose of the present invention is to provide a kind of light intensity chemical algae removing agent.
The present invention in background technique aiming at the problem that mentioning, the technical solution taken are as follows: provides a kind of by illumination reinforcing
Light intensity chemical algae removing agent, which is characterized in that the light intensity chemical algae removing agent is that one or more compounds are dissolved in diformazan
Base sulfoxide and obtain, one or more of them compound be one or both of P-hydroxybenzoic acid, parahydroxyben-zaldehyde and
Itself and salicylic mixture, wherein P-hydroxybenzoic acid and parahydroxyben-zaldehyde are the required chemical combination of light intensity chemical algae removing agent
Object, salicylic acid are auxiliary compounds.
Above-mentioned one or more compounds solution concentration range in dimethyl sulfoxide is 0.2%-50% (W/V), for
In the application of algae and water bioscrubbing, the light intensity chemical algae removing agent additional amount in algae solution per ton is 0.005~10kg, wherein light
The artificial light sources for being 500-30000Lux according to condition outdoor natural light or light intensity can make the algae in water body that photobleaching occur and cause
Extremely.
One or more compounds are as the mechanism of action of algicide in the present invention: frond itself are acted on, in illumination
Under the action of, make frond generation photobleaching and death removes to reach biology and go out.
The present invention also provides such as above-mentioned light intensity chemical algae removing agent to inhibit and kill cytoalgae, Dunaliella salina, hair-like
Application in nostoc, chlorella, anabena and microcystic aeruginosa.
Through the above technical solutions, the present invention provides a kind of light intensity chemical algae removing agent and application, wherein light intensity
Learning algicide is that one or more compounds are dissolved in dimethyl sulfoxide and are obtained, and one or more compounds are para hydroxybenzene first
Acid, one or both of parahydroxyben-zaldehyde and its with salicylic mixture, wherein P-hydroxybenzoic acid and para hydroxybenzene
Formaldehyde is the required compound of light intensity chemical algae removing agent, and salicylic acid is auxiliary compounds.
Specific embodiment:
Below with reference to embodiment, the present invention is further described, following embodiments be it is illustrative, be not restrictive,
It cannot be limited the scope of protection of the present invention with following embodiments.
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
A kind of light intensity chemical algae removing agent, feature include: that the light intensity chemical algae removing agent is by one or more chemical combination
Object is dissolved in dimethyl sulfoxide and obtains, and has under illumination condition and significantly removes algae effect.One or more compounds
For one or both of P-hydroxybenzoic acid, parahydroxyben-zaldehyde and its with salicylic mixture, wherein para hydroxybenzene first
Acid is the required compound of light intensity chemical algae removing agent with parahydroxyben-zaldehyde, and salicylic acid is auxiliary compounds.One or moreization
Close object in dimethyl sulfoxide solution concentration range be 10%-50% (W/V), for algae and water bioscrubbing application in, often
Light intensity chemical algae removing agent additional amount in ton algae solution is 0.005~10kg, and wherein illumination condition is outdoor natural light or light intensity
For the artificial light sources of 500-30000Lux.
Embodiment 1
In a preferred embodiment of the present invention, compound P-hydroxybenzoic acid described in the agent of light intensity chemical algae removing
Solution concentration is 50% (W/V) in dimethyl sulfoxide, takes light intensity chemical algae removing agent 10kg, and being added to 1 ton of OD value is 0.6
In cytoalgae algae solution, the Continuous irradiation 4d in the case where light intensity is the artificial light sources of 700Lux, it is found that cytoalgae is irradiating in algae solution later
2d start to occur dead, cytoalgae content is precipitated in light blue and gradually fade, in 4d cytoalgae it is all dead and
Algae solution is colorless and transparent.
Embodiment 2
In the present embodiment, compound P-hydroxybenzoic acid solution in dimethyl sulfoxide described in light intensity chemical algae removing agent
Concentration is 50% (W/V), takes light intensity chemical algae removing agent 2kg to be added in the cytoalgae algae solution that 1 ton of OD value is 0.6, later
The Continuous irradiation 6d in the case where light intensity is the artificial light sources of 700Lux has found that cytoalgae starts to occur dead in the 3d of irradiation in water body
It dies, cytoalgae content, which is precipitated, to be in light blue and gradually fade, and the cytoalgae death rate reaches 80% in 6d, dead cytoalgae
Algae solution is colorless and transparent.
Embodiment 3
In a comparative examples of the invention, compound P-hydroxybenzoic acid described in light intensity chemical algae removing agent exists
Solution concentration is 50% (W/V) in dimethyl sulfoxide, and the light intensity chemical algae removing agent is taken to be added to the cytoalgae algae that OD value is 0.6
In liquid, the light intensity chemical algae removing agent additional amount in algae solution per ton is 8kg, later in the case where light intensity is the artificial light sources of 3000Lux
Continuous irradiation 4d has found in algae solution that cytoalgae starts significant death the of irradiation for 24 hours, and cytoalgae content is precipitated in light blue
And gradually fade, the cytoalgae death rate reaches 80% in 2d, and cytoalgae is all dead in the 4d of irradiation, and algae solution is in colourless
Bright shape.
Embodiment 4
In a comparative examples of the invention, the compound P-hydroxybenzoic acid in light intensity chemical algae removing agent exists
Solution concentration is 50% (W/V) in dimethyl sulfoxide, and the light intensity chemical algae removing agent is taken to be added to the cytoalgae algae that OD value is 0.6
In liquid, the light intensity chemical algae removing agent additional amount in algae solution per ton is 8kg, continuously cultivates 4d in the condition that is protected from light later, discovery exists
Cytoalgae does not occur the apparent phenomena of mortality in water body in the 4d being protected from light, and cytoalgae is green in pale blue, the death of cytoalgae in 4d
Rate is only 2%, comparative example 3, the algicide is found under the conditions of light intensity, except algae efficiency improves 50 times.
Embodiment 5
In an embodiment of the invention, compound parahydroxyben-zaldehyde described in the agent of light intensity chemical algae removing is in diformazan
Solution concentration is 50% (W/V) in base sulfoxide, and algae used is Dunaliella salina algae, and the light intensity chemical algae removing agent in algae solution per ton adds
Entering amount is 10kg, and algae solution initial OD values are 0.6, irradiate 5d in outdoor optical later, it is found that cytoalgae is in the 2d of irradiation in algae solution
Start death occur, algae content, which is precipitated, to be in light blue and gradually fade, and algae is completely dead in 5d, dead Dunaliella salina algae
Liquid is colorless and transparent.
Embodiment 6
In a preferred embodiment of the present invention, by compound P-hydroxybenzoic acid described in light intensity chemical algae removing agent and
Parahydroxyben-zaldehyde mass ratio 1: 1 is dissolved in the solution that total soluble matters content 50% is made in dimethyl sulfoxide, in algae solution per ton
Light intensity chemical algae removing agent additional amount is 8kg, when algae solution initial OD values are 0.6, later in the artificial light sources that light intensity is 2000Lux
Lower Continuous irradiation 5d has found that cytoalgae starts to occur dead in the 2d of irradiation in water body, and it is in pale blue that cytoalgae content, which is precipitated,
Color simultaneously gradually fades, and the 4d cytoalgae death rate reaches 85%, and all dead and algae solution is in nothing to cytoalgae in the 5d of irradiation
Color transparence.
Embodiment 7
In an embodiment of the invention, compound described in the agent of light intensity chemical algae removing is P-hydroxybenzoic acid and water
Poplar acid, this two kinds of compounds of mass ratio 1: 1 solution total concentration in dimethyl sulfoxide are 50% (W/V), and algae used is small
Ball algae, the light intensity chemical algae removing agent additional amount in algae solution per ton are 7kg, and algae solution initial OD values are 0.6, are in light intensity later
Continuous irradiation 5d under the artificial light sources of 2000Lux has found that algae starts to occur dead, algae content analysis in the 2d of irradiation in algae solution
Out it is in light blue and gradually fades, the 4d chlorella death rate reaches 80%, the whole dead and algae solutions of algae in the 5d of irradiation
It is colorless and transparent.
Embodiment 8
In an embodiment of the invention, compound described in the agent of light intensity chemical algae removing is parahydroxyben-zaldehyde and water
Poplar acid, this two kinds of compounds of mass ratio 1: 1 are dissolved in be made in dimethyl sulfoxide 50% solution, algae used be cytoalgae,
Light intensity chemical algae removing agent additional amount in algae solution per ton is 10kg, and algae solution initial OD values are 0.6, is in light intensity later
Continuous irradiation 5d under the artificial light sources of 2000Lux has found that cytoalgae starts death, cytoalgae occur in the 2d of irradiation in algae solution
Content, which is precipitated, to be in light blue and gradually fades, and the 4d cytoalgae death rate reaches 80%, and cytoalgae is whole in the 5d of irradiation
It is dead and colorless and transparent.
Embodiment 9
In an embodiment of the invention, compound P-hydroxybenzoic acid described in the agent of light intensity chemical algae removing is in diformazan
Solution concentration is 50% in base sulfoxide, and the light intensity chemical algae removing agent additional amount in algae solution per ton is 10kg, algae solution initial OD values
It is 0.6, irradiates 5d under the conditions of outdoor natural light later, it is found that cytoalgae starts to occur dead in the 2d of irradiation in water body,
Cytoalgae content, which is precipitated, to be in light blue and gradually fades, and the cytoalgae death rate reaches 75% in 3d, and dead cytoalgae is in nothing
Color transparence.
Embodiment 10
In an embodiment of the invention, compound P-hydroxybenzoic acid described in the agent of light intensity chemical algae removing is in diformazan
Solution concentration is 50% in base sulfoxide, and the light intensity chemical algae removing agent additional amount in algae solution per ton is 10kg, and algae used is verdigris
Microcystis aeruginosa, algae solution OD value are 0.6, irradiate 6d in outdoor natural light later, it is found that microcystic aeruginosa is in the 3d of irradiation in water body
Starting death occur, microcystic aeruginosa is faded by blue-green into light green, and the death rate of 4d microcystic aeruginosa only has 45%,
5d microcystic aeruginosa discolouration phenomena is obvious, and the death rate reaches 80%, and 6d microcystic aeruginosa is all dead, and algae solution is in colourless
Bright shape.
Embodiment 11
In an embodiment of the invention, compound P-hydroxybenzoic acid solution concentration in dimethyl sulfoxide is
50% (W/V), algae used are anabena, and the light intensity chemical algae removing agent additional amount in algae solution per ton is 10kg, and algae solution is initial
OD value is 0.6, and outdoor natural light irradiates 5d later, it is found that anabena starts death, fish raw meat occur in the 2d of irradiation in algae solution
Algae is faded by blue-green at light blue, and the death rate of 3d anabena reaches 60%, and frond discolouration phenomena is obvious, 5d anabena
All dead, algae solution is finally colorless and transparent.
Embodiment 12
In an embodiment of the invention, compound P-hydroxybenzoic acid solution concentration in dimethyl sulfoxide is
50% (W/V), algae used are hair-like nostoc, and the light intensity chemical algae removing agent additional amount in algae solution per ton is 10kg, algae solution
Initial OD values are 0.6, and the Continuous irradiation 5d in the case where light intensity is the artificial light sources of 1500Lux, has found hair-like nostoc in algae solution later
Start death occur in the 3d of irradiation, hair-like nostoc content, which is precipitated, to be in light blue and gradually fade, and hair-like is read in 6d
Pearl algae is all dead, and dead hair-like nostoc algae solution is colorless and transparent.
Claims (7)
1. the present invention relates to a kind of light intensity chemical algae removing agent, it is characterised in that: the light intensity chemical algae removing agent be by a kind of or
Multiple compounds are dissolved in dimethyl sulfoxide and obtain, and there is significant remove to imitate various water bodies algae under illumination condition
Fruit.
2. one or more compounds according to claim 1 are one of P-hydroxybenzoic acid, parahydroxyben-zaldehyde
Or two kinds and its with salicylic mixture, wherein P-hydroxybenzoic acid and parahydroxyben-zaldehyde are that the agent of light intensity chemical algae removing must
Compound is needed, salicylic acid is auxiliary compounds.
3. a kind of light intensity chemical algae removing agent according to claim 1, contained by one or more compounds in hydroxyl
Yl benzoic acid and parahydroxyben-zaldehyde can be any mass ratio, but the ratio between salicylic acid and the above two gross masses are no more than 70%.
4. a kind of light intensity chemical algae removing agent according to claim 1, it is characterised in that: one or more compounds are two
Total concentration range in methyl sulfoxide is 0.2%-50% (W/V).
5. a kind of light intensity chemical algae removing agent according to claim 1, it is characterised in that: various water bodies algae is removed
In, light intensity chemical algae removing agent additional amount is 0.005~10kg in algae solution per ton.
6. illumination condition according to claim 1, it is characterised in that: its illumination is outdoor natural light or light intensity is 500-
The artificial light sources of 30000Lux.
7. various water bodies algae according to claim 1 is cytoalgae, Dunaliella salina, hair-like nostoc, chlorella, fish raw meat
Algae and microcystic aeruginosa.
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| CN201811200268.4A CN109179563A (en) | 2018-10-16 | 2018-10-16 | A kind of light intensity chemical algae removing agent |
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| CN201811200268.4A CN109179563A (en) | 2018-10-16 | 2018-10-16 | A kind of light intensity chemical algae removing agent |
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