CN109173722A - A kind of SCR system sectional precisely sprays ammonia method - Google Patents

A kind of SCR system sectional precisely sprays ammonia method Download PDF

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Publication number
CN109173722A
CN109173722A CN201811223447.XA CN201811223447A CN109173722A CN 109173722 A CN109173722 A CN 109173722A CN 201811223447 A CN201811223447 A CN 201811223447A CN 109173722 A CN109173722 A CN 109173722A
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load
rated load
ammonia
scr system
rated
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CN201811223447.XA
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荣幸
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Zhongke Runeng (beijing) Technology Co Ltd
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Zhongke Runeng (beijing) Technology Co Ltd
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Priority to CN201811223447.XA priority Critical patent/CN109173722A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Chimneys And Flues (AREA)

Abstract

The present invention relates to a kind of SCR system sectionals precisely to spray ammonia method, it is characterized by: it includes acquisition module, database and output module, acquisition module acquires unit load and operation coal pulverizer combined command, database is to pass through field test, the different unit loads of determining correspondence and all branch pipe spray ammonia of the SCR system ammonia-spraying grid of different coal pulverizers combination automatically adjust valve opening database, and output module exports all branch pipe spray ammonia automatic regulating valve opening degree instructions of real-time SCR system ammonia-spraying grid.The advantages of the present invention over the prior art are that: can sectional precisely spray ammonia, improve denitration efficiency and simultaneously reduce the escaping of ammonia.

Description

A kind of SCR system sectional precisely sprays ammonia method
Technical field
The present invention relates to the technical fields of coal fired power generation environment protection field, in particular to a kind of SCR system sectional precisely to spray Ammonia method.
Background technique
With the worsening of ecological environment, Environmental protection is increasingly paid attention to.In recent years, country's dispatch in succession, It is required that Air Pollutant Emission of keeping under strict control, makes every effort to implement in full coal fired power plant minimum discharge transformation in the year two thousand twenty.And SCR system mainstream Minimum discharge modification measures be to increase one layer of denitrating catalyst, at this time SO newly2/SO3Conversion ratio will increase, while spray ammonia in tradition Under mode, spray ammonia total amount can also be significantly improved when system is run, and the ammonia slip levels that this is bound to cause SCR system exhaust pass are aobvious It writes and increases.Back-end ductwork escape ammonia easily with the SO in flue gas3Generating has very strong sticky ammonium hydrogen sulfate (ABS), and ABS is easy Absorption dust directly contributes the blocking of downstream air preheater, makes changing for the reduction of air preheater flow area, resistance increase and heat exchange element Thermal efficiency decline, jeopardizes unit safety stable operation.
Unit varying duty or become coal pulverizer combined running during, the flow field characteristic of each subregion in the section SCR system AIG and NOxCharacteristic can constantly change, and unit load and coal pulverizer combination variation are two influence flow field characteristics and NOxDistribution character is most Principal element.Under tradition spray ammonia mode, it is hand-operated valve that spray ammonia, which adjusts branch pipe valve,.Ammonia efficiency is sprayed in order to improve, reduces the escaping of ammonia, Many power plant also carried out the optimization of spray ammonia, but since regulating valve is hand-operated valve, therefore this optimization is also just for specific load Operating condition, after adjustment, spray ammonia branch pipe valve opening immobilizes, the spray ammonia demand after not being able to satisfy load, operating condition variation, Therefore, spray ammonia effect of optimization is limited.Ammonia nitrogen is easy to cause biggish the escaping of ammonia than higher region, and ammonia nitrogen holds than relatively low region It is not up to standard to easily lead to minimum discharge, brings dilemma to power plant.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the above technological deficiency, a kind of sectional is provided and precisely sprays ammonia, is improved The denitration efficiency and SCR system sectional for reducing the escaping of ammonia precisely sprays ammonia method.
In order to solve the above technical problems, technical solution provided by the invention are as follows: a kind of SCR system sectional precisely sprays ammonia side Method, it includes acquisition module, database and output module, and acquisition module acquires unit load and operation coal pulverizer combined command, Database is by field test, the SCR system ammonia-spraying grid of the different unit loads of determining correspondence and the combination of different coal pulverizers All branch pipe spray ammonia automatically adjust valve opening database, and all branch pipes of real-time SCR system ammonia-spraying grid are sprayed ammonia by output module The output of automatic regulating valve opening degree instruction.
As an improvement, all branch pipe spray ammonia regulating valves of SCR system ammonia-spraying grid are automatic regulating valve.
As an improvement, determining that corresponding different load and the SCR system of different coal pulverizers combination spray ammonia lattice by field test All branch pipe spray ammonia of grid automatically adjust valve opening database.
As an improvement, according to unit load and coal pulverizer combined command, can be chosen in the database simultaneously in actual motion Corresponding ammonia-spraying grid branch pipe spray ammonia automatic adjustment valve opening is adjusted in time.
As an improvement, the test load changes in rated load and minimum Peak Load section, each amplitude of variation is 5% rated load, for example, 100% rated load, 95% rated load, 90% rated load, 85% rated load ..., 50% rated load, 45% rated load, 40% rated load, 35% rated load, 30% rated load.For different machines Group, minimum Peak Load is not identical, and usual minimum Peak Load has 40% rated load, 35% rated load, 30% specified Three kinds of loads of load.
As an improvement, the different load is adapted to the load in ± 2.5% rated load section of test load, wherein 100% rated load data are adapted to " being more than or equal to " 97.5% rated load, and minimum Peak Load data are adapted to " being less than " Minimum Peak Load, other load test data are adapted to ± 2.5% rated load load in section of test load, under section includes Limit is without including the upper limit, such as 95% rated load data are adapted to " being less than " 97.5% rated load but " being more than or equal to " The load of 92.5% rated load, 90% rated load data are adapted to " being less than " 92.5% rated load but " being more than or equal to " The load of 87.5% rated load, 85% rated load data are adapted to " being less than " 87.5% rated load but " being more than or equal to " The load of 82.5% rated load, 80% rated load data are adapted to " being less than " 82.5% rated load but " being more than or equal to " The load of 77.5% rated load ... etc..
After using the above structure, the present invention has the advantage that sectional precisely sprays ammonia, improves denitration efficiency and reduce ammonia Escape, in use, SCR system spray ammonia branch pipe, which is first adjusted hand-operated valve, is all changed to automatic regulating valve, and to various loads and The flow field in each region under coal pulverizer composite condition and NOxDistribution character is tested, and NO is analyzedxThe uniformity of distribution, adjustment is certainly Dynamic valve to optimum state makes NOx distribution become more uniform, then establishes various unit loads and coal pulverizer composite condition is corresponding Optimal branch pipe regulating valve database.In actual moving process, it is right in database to be chosen according to different load and coal pulverizer combination Valve opening is answered, to realize that sectional precisely sprays ammonia, improve denitration efficiency and reduce the escaping of ammonia.
Detailed description of the invention
Fig. 1 is the process flow chart that a kind of SCR system sectional of the invention patent precisely sprays ammonia method.
Specific embodiment
Present invention will be described in further detail below with reference to the accompanying drawings.
In conjunction with attached drawing 1.
In the specific implementation, a kind of SCR system sectional precisely sprays ammonia method to the present invention, it includes acquisition module, data Library and output module, acquisition module acquire unit load and operation coal pulverizer combined command, and database is by field test, really The different unit loads of fixed correspondence and all branch pipe spray ammonia automatic regulating valves of the SCR system ammonia-spraying grid of different coal pulverizers combination are opened Database is spent, output module exports all branch pipe spray ammonia automatic regulating valve opening degree instructions of real-time SCR system ammonia-spraying grid.
All branch pipe spray ammonia regulating valves of SCR system ammonia-spraying grid are automatic regulating valve.
By field test, SCR system ammonia-spraying grid all of corresponding different load and the combination of different coal pulverizers are determined Pipe sprays ammonia and automatically adjusts valve opening database.
In actual motion, according to unit load and coal pulverizer combined command, it can choose and adjust in time in the database Corresponding ammonia-spraying grid branch pipe spray ammonia automatically adjusts valve opening.
The test load changes in rated load and minimum Peak Load section, and each amplitude of variation is 5% specified negative Lotus, such as 100% rated load, 95% rated load, 90% rated load, 85% rated load, 50% rated load, 45% Rated load, 40% rated load, 35% rated load, 30% rated load.For different units, minimum Peak Load is not Identical, usual minimum Peak Load has 40% rated load, 35% rated load, 30% rated load, three kinds of loads.
The different load is adapted to the load in ± 2.5% rated load section of test load, wherein 100% rated load Data are adapted to " being more than or equal to " 97.5% rated load, and minimum Peak Load data are adapted to " being less than " minimum Peak Load, Other load test data are adapted to ± 2.5% rated load load in section of test load, and section includes lower limit without including upper Limit, such as 95% rated load data are adapted to " being less than " 97.5% rated load but " being more than or equal to " 92.5% rated load Load, 90% rated load data are adapted to the negative of " being less than " 92.5% rated load but " being more than or equal to " 87.5% rated load Lotus, 85% rated load data are adapted to the negative of " being less than " 87.5% rated load but " being more than or equal to " 82.5% rated load Lotus, 80% rated load data are adapted to the load of " being less than " 82.5% rated load but " being more than or equal to " 77.5% rated load Deng.
The working principle of the invention: firstly, SCR system spray ammonia branch pipe, which is adjusted hand-operated valve, is all changed to automatic adjustment Valve, and flow field and NO to each region under various loads and coal pulverizer composite conditionxDistribution character is tested, and NO is analyzedxPoint The uniformity of cloth, adjustment automatic valve to optimum state make NOx distribution become more uniform, then establish various loads and coal pulverizer The corresponding optimal branch pipe regulating valve database of composite condition, i.e., the NO under different unit loads and coal pulverizer composite conditionxDistribution Most uniform different branch valve openings, then the corresponding each branch valve opening typing number of these different loads and coal pulverizer composite condition According to library, by adjusting determination.In actual moving process, chosen according to different unit loads and coal pulverizer combination corresponding in database Valve opening, to realize that sectional precisely sprays ammonia, improve denitration efficiency and reduce the escaping of ammonia.
The present invention and its embodiments have been described above, this description is no restricted, shown in the drawings Only one of embodiments of the present invention, actual structure is not limited to this.All in all if the ordinary skill of this field Personnel are enlightened by it, without departing from the spirit of the invention, are not inventively designed and the technical solution phase As frame mode and embodiment, be within the scope of protection of the invention.

Claims (6)

1. a kind of SCR system sectional precisely sprays ammonia method, it is characterised in that: it includes acquisition module, database and output mould Block, acquisition module acquire unit load and operation coal pulverizer combined command, and database is by field test, and determining correspondence is not Valve opening database is automatically adjusted with all branch pipe spray ammonia of SCR system ammonia-spraying grid that unit load and different coal pulverizers combine, Output module exports all branch pipe spray ammonia automatic regulating valve opening degree instructions of real-time SCR system ammonia-spraying grid.
2. a kind of SCR system sectional according to claim 1 precisely sprays ammonia method, it is characterised in that: the SCR system All branch pipe spray ammonia regulating valves of ammonia-spraying grid are automatic regulating valve.
3. a kind of SCR system sectional according to claim 1 precisely sprays ammonia method, it is characterised in that: tried by scene It tests, determines that all branch pipe spray ammonia automatic regulating valves of the SCR system ammonia-spraying grid of corresponding different load and the combination of different coal pulverizers are opened Spend database.
4. a kind of SCR system sectional according to claim 1 precisely sprays ammonia method, it is characterised in that: in actual motion, According to unit load and coal pulverizer combined command, it can choose in the database and adjust corresponding ammonia-spraying grid branch pipe spray in time Ammonia automatically adjusts valve opening.
5. a kind of SCR system sectional according to claim 1 precisely sprays ammonia method, it is characterised in that: the test is negative Lotus changes in rated load and minimum Peak Load section, and each amplitude of variation is 5% rated load, such as 100% specified negative It is lotus, 95% rated load, 90% rated load, 85% rated load, 50% rated load, 45% rated load, 40% specified Load, 35% rated load, 30% rated load.For different units, minimum Peak Load is not identical, usual minimum peak regulation Load has 40% rated load, 35% rated load, 30% rated load, three kinds of loads.
6. a kind of SCR system sectional according to claim 1 precisely sprays ammonia method, it is characterised in that: described different negative Lotus is adapted to the load in ± 2.5% rated load section of test load, wherein 100% rated load data be adapted to " be greater than etc. In " 97.5% rated load, minimum Peak Load data are adapted to " being less than " minimum Peak Load, other load test data are suitable It should include lower limit without including the upper limit, such as 95% rated load in ± 2.5% rated load load in section of test load, section Data are adapted to the load of " being less than " 97.5% rated load but " being more than or equal to " 92.5% rated load, 90% rated load number According to load, the 85% rated load data for being adapted to " being less than " 92.5% rated load but " being more than or equal to " 87.5% rated load Load, the 80% rated load data for being adapted to " being less than " 87.5% rated load but " being more than or equal to " 82.5% rated load are suitable The load etc. of 82.5% rated load of Ying Yu " being less than " but " being more than or equal to " 77.5% rated load.
CN201811223447.XA 2018-10-19 2018-10-19 A kind of SCR system sectional precisely sprays ammonia method Pending CN109173722A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112717670A (en) * 2020-12-18 2021-04-30 华能陇东能源有限责任公司 Control device and control method for ammonia injection grid of denitration system

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11179155A (en) * 1997-12-19 1999-07-06 Babcock Hitachi Kk Apparatus and method for feeding ammonia in denitrification reactor
CN104102138A (en) * 2014-07-16 2014-10-15 北京中合实创电力科技有限公司 Soft measurement based ammonia injection grid partition control method
CN105700504A (en) * 2016-02-24 2016-06-22 东南大学 SCR system automatic control method based on ammonia spraying sensitive valve locking
CN106237850A (en) * 2016-07-28 2016-12-21 浙江浙能技术研究院有限公司 A kind of it is applicable to the denitration Precise control method to stamp coal-burning boiler
CN107243257A (en) * 2017-05-08 2017-10-13 浙江大学 It is adapted to the intelligence spray ammonia control system of full load
CN108404661A (en) * 2018-04-28 2018-08-17 南京新瓦特智控科技有限公司 The full load of a kind of leveling of on-line velocity field and concentration field measurement precisely sprays ammonia system
CN207929006U (en) * 2017-12-30 2018-10-02 光力科技股份有限公司 A kind of SCR denitration spray ammonia regulator control system
CN108607358A (en) * 2018-05-08 2018-10-02 湖南大唐节能科技有限公司 A kind of full load denitrification apparatus having urea smoke gas pyrolysis function

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11179155A (en) * 1997-12-19 1999-07-06 Babcock Hitachi Kk Apparatus and method for feeding ammonia in denitrification reactor
CN104102138A (en) * 2014-07-16 2014-10-15 北京中合实创电力科技有限公司 Soft measurement based ammonia injection grid partition control method
CN105700504A (en) * 2016-02-24 2016-06-22 东南大学 SCR system automatic control method based on ammonia spraying sensitive valve locking
CN106237850A (en) * 2016-07-28 2016-12-21 浙江浙能技术研究院有限公司 A kind of it is applicable to the denitration Precise control method to stamp coal-burning boiler
CN107243257A (en) * 2017-05-08 2017-10-13 浙江大学 It is adapted to the intelligence spray ammonia control system of full load
CN207929006U (en) * 2017-12-30 2018-10-02 光力科技股份有限公司 A kind of SCR denitration spray ammonia regulator control system
CN108404661A (en) * 2018-04-28 2018-08-17 南京新瓦特智控科技有限公司 The full load of a kind of leveling of on-line velocity field and concentration field measurement precisely sprays ammonia system
CN108607358A (en) * 2018-05-08 2018-10-02 湖南大唐节能科技有限公司 A kind of full load denitrification apparatus having urea smoke gas pyrolysis function

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112717670A (en) * 2020-12-18 2021-04-30 华能陇东能源有限责任公司 Control device and control method for ammonia injection grid of denitration system

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