CN109161409A - A kind of methanol gasoline and preparation method thereof - Google Patents
A kind of methanol gasoline and preparation method thereof Download PDFInfo
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- CN109161409A CN109161409A CN201811079711.7A CN201811079711A CN109161409A CN 109161409 A CN109161409 A CN 109161409A CN 201811079711 A CN201811079711 A CN 201811079711A CN 109161409 A CN109161409 A CN 109161409A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
- C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention belongs to technical field of fuel, specially a kind of methanol gasoline and preparation method thereof.Methanol gasoline of the invention is according to parts by weight comprising following component: 55-75 parts of methanol, 45-58 parts of gasoline, 0.14-0.29 parts of preservative, 10.97-11.22 parts of cosolvent, 1.19-1.37 parts of surfactant, 7.99-10.28 parts of methanol gasoline heat value modifier, 3-4 parts of octane enhancing additive.Preparation process of the present invention is simple, and raw material is easy to get, and production cost is low, the research octane number and calorific value of fuel oil can be effectively improved, and the Routine purges substance such as CO, HC is greatly reduced, pollution of the fuel burning to environment is effectively reduced, alleviate petroleum fuel resource anxiety problem, is suitable for wide popularization and application.
Description
Technical field
The present invention relates to technical field of fuel, and in particular to a kind of Novel methanol gasoline and preparation method thereof.
Background technique
Along with the high speed development of national economy, demand of the people to petroleum resources is higher and higher, to cause a series of
The problem of, CO, unburned hydrocarbon are caused due to the imperfect combustion of gasoline for gasoline-fueled vehicle
(HC) and nitrogen oxides (NOx=NO, NO2And N2) etc. O discharge, CO prevent O in conjunction with the hemoglobin in blood2It arrives
Up to heart, so as to cause heart attack and apoplexy, to generate murder by poisoning to human body.NOx is also the component part of acid rain, because
It will form nitric acid with reaction of moisture.Therefore, in order to preferably develop, problem of environmental pollution is further severe, and government implements necessary
The discharge standard met, to ensure that the masses obtain the air of high quality.Demand with the world to clean air is more and more sensitive,
With the continuous improvement of catalysis technique, these standards become more stringent, and longer service life is needed effectively to be subtracted
Row.
Methanol gasoline is as a kind of new energy, and methanol has the characteristics that boiling point low octane rating height etc., since methanol is oxygen-containing
Atom makes gasoline full combustion, and 50% or more of motor vehicle exhaust emission pernicious gas total amount can be effectively reduced, and it is big to be conducive to protection
Compression ring border.In-engine carbon distribution can be cleared up simultaneously, improved engine efficiency, the cleaning of engine is kept, to reduce carbon
The discharge of the pollutants such as hydrogen, nitrogen oxides, pellet, carbon monoxide.
Summary of the invention
The present invention provides a kind of preparation method of Novel methanol gasoline, can effectively improve gasoline research octane number and
Calorific value, and the Routine purges substance such as CO, HC is greatly reduced.
The present invention is achieved through the following technical solutions:
The present invention provides a kind of methanol gasoline, according to parts by weight comprising following component: 55-75 parts of methanol, gasoline
45-58 parts, 0.14-0.29 parts of preservative, 10.97-11.22 parts of cosolvent, 1.19-1.37 parts of surfactant, methanol gasoline
7.99-10.28 parts of calorific value modifier, 3-4 parts of octane enhancing additive.
In the present invention, the preservative is 2,4,6- tri-butyl-phenols.
In the present invention, the cosolvent is that diethylene glycol monobutyl ether, isoamyl alcohol and the acetone that quality proportioning is 3:1:8 are formed
Mixture.
In the present invention, the surfactant is the S-80 that mass ratio is 1:1 and the mixture of anthracene formation.
In the present invention, the methanol gasoline heat value modifier be mass ratio be 3:1:1:1 n,N-Dimethylaniline, second
The mixture of alcohol, normal octane and fatty acid distribution of coconut oil diacetayl amide composition.
In the present invention, octane enhancing additive is the methyl tertiary butyl ether(MTBE) and xylene mixture that mass ratio is 1:1.5.
The present invention also provides a kind of preparation methods of above-mentioned methanol gasoline, comprising the following steps:
Step 1: by the cosolvent of the parts by weight, surfactant, octane enhancing additive is mixed evenly；
Step 2: by the methanol of the parts by weight, preservative, methanol gasoline heat value modifier is mixed evenly；
Step 3: it is stirred evenly after step 1 is mixed with mixture obtained by step 2；
Step 4: mixture obtained by step 3 is uniformly mixed with the gasoline of the parts by weight to get product.
Compared to the prior art, the beneficial effects of the present invention are:
A kind of Novel methanol gasoline provided by the invention, hence it is evident that improve the research octane number and calorific value of gasoline, and big
Amplitude reduces the Routine purges substances such as CO, HC.In the present invention, the cosolvent, surfactant, methanol gasoline heat value are improved
Agent and octane enhancing additive exist as a mixture, can overcome and not filled using the burning being easy to produce using single agents
Point, the problem of flame color is abnormal, and residue remains.
Specific embodiment
Technical solution of the present invention will be clearly and completely described by embodiment below, it is clear that described reality
Applying example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field skill
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The raw materials used in the present invention can be bought on the market, without being further processed, can be used directly, wherein used 92#
Gasoline provides vehicle fuel oil, preservative used, i.e., 2 for Sinopec, and 4,6- tri-butyl-phenols are purchased from the spacious pavilion in Guangzhou
Work Co., Ltd.
In embodiment, preservative 2,4,6- tri-butyl-phenol.Cosolvent is the diethylene glycol list that mass ratio is 3:1:8
The mixture that butyl ether, isoamyl alcohol and acetone are formed.The mixture that surfactant is the S-80 that mass ratio is 1:1 and anthracene is formed.
Methanol gasoline heat value modifier is the N that mass ratio is 3:1:1:1, accelerine, ethyl alcohol, normal octane and fatty acid distribution of coconut oil two
The mixture of acetamide composition.Octane enhancing additive is the methyl tertiary butyl ether(MTBE) and xylene mixture that mass ratio is 1:1.5.
Embodiment 1
Step 1: in parts by weight, by 10.97 parts of cosolvents, 1.19 parts of surfactants, 3 portions of octane enhancing additives are mixed
It closes, it is uniform with 88-1 magnetic stirrer；
Step 2: in parts by weight, by 55 parts of methanol, 0.14 portion of preservative, 7.99 parts of methanol gasoline heat value modifiers are mixed
Merge uniform with 88-1 magnetic stirrer；
Step 3: uniform with 88-1 magnetic stirrer after step 1 is mixed with mixture obtained by step 2；
Step 4: by mixture obtained by step 3 and 45 part 92#Gasoline is uniformly mixed to get product.
It is 4.89 × 10 by the calorific value that ZDHW-300T touch screen calorimeter analyzer measures product7J/kg uses FLA-502
Vehicle exhaust exhaust gas analyzer method detects the lower Routine purges object burst size that runs at high speed, pungent using GBT5487-2015 measurement research
Alkane value, the results are shown in Table 1.
Embodiment 2
Step 1: in parts by weight, by 11.22 parts of cosolvents, 1.37 parts of surfactants, 4 portions of octane enhancing additives are mixed
It closes, it is uniform with 88-1 magnetic stirrer；
Step 2: score by weight is by 75 parts of methanol, 0.29 portion of preservative, and 10.28 parts of methanol gasoline heat value modifiers are mixed
Merge uniform with 88-1 magnetic stirrer；
Step 3: uniform with 88-1 magnetic stirrer after step 1 is mixed with mixture obtained by step 2；
Step 4: by mixture obtained by step 3 and 58 part 92#Gasoline is uniformly mixed to get product.
It is 4.91 × 10 by the calorific value that ZDHW-300T touch screen calorimeter measures product7J/kg, with FLA-502 car tail
Gas exhaust gas analyzer detects the lower Routine purges object burst size that runs at high speed, and measures research octane number result using GBT5487-2015
As shown in table 1.
Table 1: methanol gasoline basic physical properties and conventional exhaust emission detection limit
Claims (7)
1. a kind of methanol gasoline, which is characterized in that according to parts by weight comprising following component: 55-75 parts of methanol, gasoline 45-
58 parts, 0.14-0.29 parts of preservative, 10.97-11.22 parts of cosolvent, 1.19-1.37 parts of surfactant, methanol gasoline heat value
7.99-10.28 parts of modifier, 3-4 parts of octane enhancing additive.
2. methanol gasoline according to claim 1, which is characterized in that the preservative is 2,4,6- tri-butyl-phenols.
3. methanol gasoline according to claim 1, which is characterized in that the cosolvent is the diethyl that mass ratio is 3:1:8
The mixture that glycol monobutyl ether, isoamyl alcohol and acetone are formed.
4. methanol gasoline according to claim 1, which is characterized in that the surfactant is the S- that mass ratio is 1:1
80 and anthracene formed mixture.
5. methanol gasoline according to claim 1, which is characterized in that the methanol gasoline heat value modifier is that mass ratio is
The N of 3:1:1:1, the mixture that accelerine, ethyl alcohol, normal octane and fatty acid distribution of coconut oil diacetayl amide form.
6. methanol gasoline according to claim 1, which is characterized in that octane enhancing additive is the first that mass ratio is 1:1.5
Base tertbutyl ether and xylene mixture.
7. it is a kind of according to claim 1~one of 6 described in methanol gasoline preparation method, which is characterized in that including following step
It is rapid:
Step 1: by the cosolvent of the parts by weight, surfactant and octane enhancing additive are mixed evenly；
Step 2: by the methanol of the parts by weight, preservative and methanol gasoline heat value modifier are mixed evenly；
Step 3: it is stirred evenly after step 1 is mixed with mixture obtained by step 2；
Step 4: mixture obtained by step 3 is uniformly mixed with the gasoline of the parts by weight to get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811079711.7A CN109161409A (en) | 2018-09-17 | 2018-09-17 | A kind of methanol gasoline and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811079711.7A CN109161409A (en) | 2018-09-17 | 2018-09-17 | A kind of methanol gasoline and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109161409A true CN109161409A (en) | 2019-01-08 |
Family
ID=64879339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811079711.7A Pending CN109161409A (en) | 2018-09-17 | 2018-09-17 | A kind of methanol gasoline and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115232656A (en) * | 2022-08-05 | 2022-10-25 | 中国石油大学(华东) | Preparation method of alcohol-based gasoline fuel |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724474A (en) * | 2008-10-14 | 2010-06-09 | 陈若歆 | Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology |
| CN101914396A (en) * | 2010-08-18 | 2010-12-15 | 上海化工研究院 | Automobile methanol gasoline microemulsion and preparation method thereof |
| CN104263427A (en) * | 2014-10-17 | 2015-01-07 | 广西丰泰能源防爆科技有限公司 | Alcohol ether petrol for vehicles |
-
2018
- 2018-09-17 CN CN201811079711.7A patent/CN109161409A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724474A (en) * | 2008-10-14 | 2010-06-09 | 陈若歆 | Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology |
| CN101914396A (en) * | 2010-08-18 | 2010-12-15 | 上海化工研究院 | Automobile methanol gasoline microemulsion and preparation method thereof |
| CN104263427A (en) * | 2014-10-17 | 2015-01-07 | 广西丰泰能源防爆科技有限公司 | Alcohol ether petrol for vehicles |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115232656A (en) * | 2022-08-05 | 2022-10-25 | 中国石油大学(华东) | Preparation method of alcohol-based gasoline fuel |
| CN115232656B (en) * | 2022-08-05 | 2024-02-09 | 中国石油大学(华东) | Preparation method of alcohol-based gasoline fuel |
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Application publication date: 20190108 |
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