CN109161194A - A kind of fishing rod high-strength tenacity composite material - Google Patents
A kind of fishing rod high-strength tenacity composite material Download PDFInfo
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- CN109161194A CN109161194A CN201810938046.6A CN201810938046A CN109161194A CN 109161194 A CN109161194 A CN 109161194A CN 201810938046 A CN201810938046 A CN 201810938046A CN 109161194 A CN109161194 A CN 109161194A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F132/00—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
- C08F132/08—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of fishing rod high-strength tenacity composite materials, its parts by weight composition are as follows: 85 ~ 115 parts of benzoxazine, 40 ~ 67 parts of dicyclopentadiene, hold 10 ~ 15 parts of amido liquid nitrile rubber, 5 ~ 6 parts of liquid nbr carboxyl terminal, 8 ~ 10 parts of plasticizer, 2 ~ 3 parts of fire retardant, 0.5 ~ 1 part of stabilizer, 5 ~ 6 parts of terpene resin, 3 ~ 6 parts of curing agent, 1 ~ 2 part of release agent, 0.5 ~ 1 part of curing accelerator.In the case where open loop shifts catalyst system, the blend alloy of polydicyclopentadiene and benzoxazine is prepared with the means of simultaneous polymerization, and using reaction press moulding mode straight forming fishing rod material.Fishing rod provided by the invention has good intensity and toughness with high-strength tenacity composite material, and light ageing-resistant fire prevention, preparation manipulation method is simple, is able to satisfy the requirement of high-performance fishing rod material.
Description
Technical field
The invention belongs to fishing gear fields, and in particular to a kind of fishing rod high-strength tenacity composite material.
Background technique
Fishing pole is commonly called as " fishing rod ".Fishing casting rod loads in mixture one kind of fishing group tool.It is mostly bamboo in the past, now it is mostly used glass reinforced plastic, carbon
Fiber, aluminium alloy etc. are made.Length is generally 2-8 meters.Front fine and rear thick, preceding light rear weight, it is flexible, it is more tough and tensile.It can divide by shape
To prolong pole, taking out pole three classes after pole；Hand pole, extra large pole and three kinds of rock pole can be divided by waters use；By the function of gone fishing class, have soft
Pole, hard pole and neutral three kinds of pole.It as the extension of arm, protrudes into the water of distant place, fishing takes various fish and aquatic animal.Fishing rod is pressed
Material is divided into the big series of bamboo and wood, glass reinforced plastic (glass fiber compound material) fishing rod, carbon fishing rod three.Wherein, carbon fishing rod according to
The difference of phosphorus content is divided into low-carbon fishing rod, high-carbon fishing rod and Super High Carbon fishing rod, in addition, current Britain is proposed and joined nanometer
The high-carbon fishing rod of boron fibre.Bamboo and wood pole has many advantages, such as that superior materials, technique are fastidious, cheap, easy to use, belongs to biography
System fishing rod.Hollow glass rod is also known as glass reinforced plastic pole, glass fiber resin pole, using glass fibre satin, soaks ring through bath
Oxygen resin hot setting shapes (hollow pipe or solid rod body), has preferable toughness and elasticity, is to fish fishing pole production trend
The first generation product of modern composite materials, the factorial production.Carbon fibre rod is also known as carbon pole, is using carbon dimension material manufacture
Made of, conductive and extraordinary tensile strength spins carbon fiber longitudinal direction cloth tubulation using no shuttle, through resin pickup solidification
At.Recently nanometer boron fibre fishing rod very popular also belongs to carbon fishing rod in fact, only in order to which Ameliorative character is in material
It is added to a kind of material for being called nanometer boron fibre.Currently, pure carbon, high carbon fishing rod have arrived the pole of intensity and weight
Limit, carbon is too low then too heavy, and carbon is too high, makes fishing rod embrittlement.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of fishing rod high-strength tenacity composite material is provided.
The invention is realized by the following technical scheme:
A kind of fishing rod high-strength tenacity composite material, parts by weight composition are as follows: 149 ~ 189 parts of benzoxazine monomer, bicyclic penta 2
84 ~ 130 parts of alkene monomer, 3 ~ 24 parts of basalt fibre hold 10 ~ 15 parts of amido liquid nitrile rubber, liquid nbr carboxyl terminal 5
~ 6 parts, 2 ~ 3 parts of fire retardant, 1 ~ 3 part of stabilizer, 5 ~ 6 parts of terpene resin, 3 ~ 6 parts of curing agent, 1 ~ 2 part of release agent, solidification promotes
0.5 ~ 1 part of agent, 0.05 ~ 0.1 part of major catalyst, 1 ~ 2 part of co-catalyst, 1 ~ 2 part of polymerization reaction time regulator；
The fire retardant is phosphorus flame retardant；The stabilizer is organic tin stabilizer；The release agent is dimethicone；
The curing agent be diaminodiphenylmethane, diaminodiphenylsulfone, hexamethylene tetramine and diaminodiphenyl ether in extremely
Few one kind；The curing accelerator is 2-methylimidazole, 2-ethyl-4-methylimidazole, benzene sulfonyl chloride, 2- methyl 4-phenyl miaow
At least one of azoles and 2- phenylimidazole；
A kind of fishing rod high-strength tenacity composite material, which is characterized in that preparation method includes the following steps:
Step 1 weighs the raw material for standby of following corresponding parts by weight:
A liquid: 63 ~ 87 parts of dicyclopentadiene monomer, 98 ~ 117 parts of benzoxazine monomer, 10 ~ 15 parts of amido liquid nitrile rubber of end,
5 ~ 6 parts of liquid nbr carboxyl terminal, 0.05 ~ 0.1 part of major catalyst, 1 ~ 2 part of stabilizer；
B liquid: 21 ~ 43 parts of dicyclopentadiene monomer, 51 ~ 72 parts of benzoxazine monomer, 1 ~ 2 part of co-catalyst, polymerization reaction time
1 ~ 2 part of regulator, 2 ~ 3 parts of fire retardant, 0.5 ~ 1 part of stabilizer, 3 ~ 24 parts of basalt fibre, 5 ~ 6 parts of terpene resin, curing agent 3
~ 6 parts, 1 ~ 2 part of release agent, 0.5 ~ 1 part of curing accelerator；
Reaction compression molding: step 2 A liquid, B liquid is uniformly mixed, under low temperature and low pressure, according to set polymerization technique item
Part injects in closed fishing rod mold, generates rapid polymerization reaction and therewith curing molding in a mold, is full of after mold about
The completion polymerization forming in 10 ~ 20s, rear curing process 1min, after solidification, after curing materials are naturally cooled to room temperature,
Obtain fishing rod high-strength tenacity composite material.
Further, the benzoxazine monomer is Bisphenol F/aniline type benzoxazine monomer, bisphenol-A/aniline type benzene
And oxazines monomer, thiodiphenol/aniline type benzoxazine monomer, bisphenol-A/propylene amine type benzoxazine monomer, Bisphenol F/the third
One of enamine type benzoxazine monomer or bisphenol-A/benzidine benzoxazine monomer.
Further, the basalt fibre is that silane coupling agent is added after dehydrated alcohol is uniformly dispersed and quality point is made
The coupling agent solution that number is 2% will be added coupling agent solution after basalt fibre drying, take after being stirred by ultrasonic 2 hours at 100 DEG C
Out, filtering, which is placed at 100 DEG C of vacuum oven, dries, and benzoxazine resin pre-preg 2h after drying is spare after cooling；
Further, the major catalyst is the one or more of the WCl6 and TiCl4 toluene solution containing nonylbenzene phenol；It is described
Co-catalyst be Et2AlCl, Et2Zn and EtAlCl2 it is one or more.
Further, polymerization time regulator described in step 1 is butyl cellosolve, acetylacetone,2,4-pentanedione, tetrahydrofuran
It is one or more.
Further, polymerization process condition described in step 2,75 ~ 80 DEG C of material temperature, 180 DEG C of polymerization temperature, injection pressure
0.4 ~ 0.6MPa, 0 ~ 0.3MPa of mold clamping force.
Further, the stabilizer is irgasfos 168, antioxidant 264, antioxidant 1076, in antioxidant 1010
It is one or more.
Beneficial effects of the present invention:
Polydicyclopentadiene is a kind of polymer few in number of dual mechanical property with higher toughness and rigidity.Polyphenyl
And oxazines cure shrinkage is low, volume is hardly shunk after benzoxazine resin solidification, and benzoxazine resin is unique due to its
Structure is released without low-molecular material when solidification, and solidfied material volume contraction very little, obtained product internal stress is small, porosity is low, property
Can be excellent, it is simple to create product producing process, production, the significantly reduced excellent characteristics of die cost.Using liquid butyronitrile rubber
Glue component modification benzoxazine, has obtained preferable effect.Adding liquid nitrile rubber, dissolubility are promoted, dispersibility is more preferable, phase
Size tends to the uniformly toughening effect to promote co-mixing system.Transparency is higher, good toughness, and damage is hardly galled in corner, durable
Degree is high, resistance to fall.Benzoxazine has the characteristics that ring-opening polymerisation, and when solidification discharges without small molecule, and similar phenolic aldehyde tree is formed after solidification
The cure shrinkage of the reticular structure of rouge, product is small, and porosity is low, has excellent mechanical property, high heat resistance and flame retardant property,
It is particularly suitable as the matrix resin of high-performance fiber enhancing composite material.Dicyclopentadiene is being blended with double benzoxazine resins
It further reduced its required solidification temperature and longer curing time in polymerization process and further to improve its tough
Property is easier in technique.
Compared with the prior art the present invention, has the advantage that
(1) fishing rod provided by the invention high-strength tenacity composite material, fracture toughness, tensile strength and Young's modulus can be very big
Meet the requirement of athletic type fishing rod in degree.
(2) it is provided by the invention can fishing rod high-strength tenacity composite material, benzoxazine, dicyclopentadiene and liquid butyronitrile
There is very strong hydrogen bonding active force between rubber, promote the two to be uniformly dispersed in benzoxazine matrix, and then play coordination plasticizing
Effect.
(3) product properties is excellent: high impact-resistant and it is heat-resisting, do not have to release agent or it is a small amount of use, rear curing time is extremely short, or
Solidify after being not necessarily to, molded article surface is smooth, and coating adhesion is excellent；It is easy to react molding: conventional equipment is slightly transformed just
It can be used, can form at room temperature, the mixing ratio of A liquid and B liquid does not need to accurately control, and equipment is simple, and polymerization time is short, productivity
It is high；Processing conditions is easily controllable: low pressure molding, and energy consumption is few, and cost of equipment is general injection molding 15% or so, die cost
Injection molding 10% or so for as, deformation is small, and flash is few, the products such as easily fabricated fishing rod.It is light-weight, so fishing fan
Fishing when can use for a long time, even if in streams using will not feel fatigue；Rigidity is big, is easy to squeeze into target；It can
To feel the sound of fish, it is easy to be captured；Rigidity is big, recuperability is big, when a fish snapped at the bait, is easy volume setline；Because of weight
It gently, can be farther when far throw；Vibration aftershock is small, and fishing rod is static to be wanted early.
Specific embodiment
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A kind of fishing rod high-strength tenacity composite material, parts by weight composition are as follows: 156 parts of benzoxazine monomer, dicyclopentadiene list
111 parts of body, 17 parts of basalt fibre, 13 parts of amido liquid nitrile rubber of end, 6 parts of liquid nbr carboxyl terminal, fire retardant 3
Part, 2 parts of stabilizer, 6 parts of terpene resin, 4 parts of curing agent, 2 parts of release agent, 1 part of curing accelerator, is stablized 0.1 part of major catalyst
2 parts of agent, 2 parts of co-catalyst, 1.5 parts of polymerization reaction time regulator；
The fire retardant is phosphorus flame retardant；The stabilizer is organic tin stabilizer；The release agent is dimethicone；
The curing agent be diaminodiphenylmethane, diaminodiphenylsulfone, hexamethylene tetramine and diaminodiphenyl ether in extremely
Few one kind；The curing accelerator is 2-methylimidazole, 2-ethyl-4-methylimidazole, benzene sulfonyl chloride, 2- methyl 4-phenyl miaow
At least one of azoles and 2- phenylimidazole；
A kind of fishing rod high-strength tenacity composite material, which is characterized in that preparation method includes the following steps:
Step 1 weighs the raw material for standby of following corresponding parts by weight:
A liquid: 70 parts of dicyclopentadiene monomer, 100 parts of benzoxazine monomer, 13 parts of amido liquid nitrile rubber of end, liquid end carboxylic
6 parts of base nitrile rubber, 0.1 part of major catalyst, 1 part of stabilizer；
B liquid: 41 parts of dicyclopentadiene monomer, 56 parts of benzoxazine monomer, 2 parts of co-catalyst, polymerization reaction time regulator 1.5
Part, 3 parts of fire retardant, 1 part of stabilizer, 13 parts of basalt fibre, 6 parts of terpene resin, 4 parts of curing agent, 2 parts of release agent, solidification promotees
Into 1 part of agent；
Reaction compression molding: step 2 A liquid, B liquid is uniformly mixed, under low temperature and low pressure, according to set polymerization technique item
Part injects in closed fishing rod mold, generates rapid polymerization reaction and therewith curing molding in a mold, is full of after mold about
The completion polymerization forming in 10 ~ 20s, rear curing process 1min, after solidification, after curing materials are naturally cooled to room temperature,
Obtain fishing rod high-strength tenacity composite material.
Further, the benzoxazine monomer is Bisphenol F/aniline type benzoxazine monomer, bisphenol-A/aniline type benzene
And oxazines monomer, thiodiphenol/aniline type benzoxazine monomer, bisphenol-A/propylene amine type benzoxazine monomer, Bisphenol F/the third
One of enamine type benzoxazine monomer or bisphenol-A/benzidine benzoxazine monomer.
Further, the basalt fibre is that silane coupling agent is added after dehydrated alcohol is uniformly dispersed and quality point is made
The coupling agent solution that number is 2% will be added coupling agent solution after basalt fibre drying, take after being stirred by ultrasonic 2 hours at 100 DEG C
Out, filtering, which is placed at 100 DEG C of vacuum oven, dries, and benzoxazine resin pre-preg 2h after drying is spare after cooling；
Further, the major catalyst is the one or more of the WCl6 and TiCl4 toluene solution containing nonylbenzene phenol；It is described
Co-catalyst be Et2AlCl, Et2Zn and EtAlCl2 it is one or more.
Further, polymerization time regulator described in step 1 is butyl cellosolve, acetylacetone,2,4-pentanedione, tetrahydrofuran
It is one or more.
Further, polymerization process condition described in step 2,75 ~ 80 DEG C of material temperature, 180 DEG C of polymerization temperature, injection pressure
0.4 ~ 0.6MPa, 0 ~ 0.3MPa of mold clamping force.
Further, the stabilizer is irgasfos 168, antioxidant 264, antioxidant 1076, in antioxidant 1010
It is one or more.
Embodiment 2
A kind of fishing rod high-strength tenacity composite material, parts by weight composition are as follows: 157 parts of benzoxazine monomer, dicyclopentadiene list
113 parts of body, 23 parts of basalt fibre, 13 parts of amido liquid nitrile rubber of end, 6 parts of liquid nbr carboxyl terminal, fire retardant 3
Part, 2 parts of stabilizer, 6 parts of terpene resin, 4 parts of curing agent, 2 parts of release agent, 1 part of curing accelerator, is stablized 0.1 part of major catalyst
2 parts of agent, 2 parts of co-catalyst, 1.5 parts of polymerization reaction time regulator；
The fire retardant is phosphorus flame retardant；The stabilizer is organic tin stabilizer；The release agent is dimethicone；
The curing agent be diaminodiphenylmethane, diaminodiphenylsulfone, hexamethylene tetramine and diaminodiphenyl ether in extremely
Few one kind；The curing accelerator is 2-methylimidazole, 2-ethyl-4-methylimidazole, benzene sulfonyl chloride, 2- methyl 4-phenyl miaow
At least one of azoles and 2- phenylimidazole；
A kind of fishing rod high-strength tenacity composite material, which is characterized in that preparation method includes the following steps:
Step 1 weighs the raw material for standby of following corresponding parts by weight:
A liquid: 72 parts of dicyclopentadiene monomer, 100 parts of benzoxazine monomer, 13 parts of amido liquid nitrile rubber of end, liquid end carboxylic
6 parts of base nitrile rubber, 0.1 part of major catalyst, 1 part of stabilizer；
B liquid: 41 parts of dicyclopentadiene monomer, 57 parts of benzoxazine monomer, 2 parts of co-catalyst, polymerization reaction time regulator 1.5
Part, 3 parts of fire retardant, 1 part of stabilizer, 23 parts of basalt fibre, 6 parts of terpene resin, 4 parts of curing agent, 2 parts of release agent, solidification promotees
Into 1 part of agent；
Reaction compression molding: step 2 A liquid, B liquid is uniformly mixed, under low temperature and low pressure, according to set polymerization technique item
Part injects in closed fishing rod mold, generates rapid polymerization reaction and therewith curing molding in a mold, is full of after mold about
The completion polymerization forming in 10 ~ 20s, rear curing process 1min, after solidification, after curing materials are naturally cooled to room temperature,
Obtain fishing rod high-strength tenacity composite material.
Further, the benzoxazine monomer is Bisphenol F/aniline type benzoxazine monomer, bisphenol-A/aniline type benzene
And oxazines monomer, thiodiphenol/aniline type benzoxazine monomer, bisphenol-A/propylene amine type benzoxazine monomer, Bisphenol F/the third
One of enamine type benzoxazine monomer or bisphenol-A/benzidine benzoxazine monomer.
Further, the basalt fibre is that silane coupling agent is added after dehydrated alcohol is uniformly dispersed and quality point is made
The coupling agent solution that number is 2% will be added coupling agent solution after basalt fibre drying, take after being stirred by ultrasonic 2 hours at 100 DEG C
Out, filtering, which is placed at 100 DEG C of vacuum oven, dries, and benzoxazine resin pre-preg 2h after drying is spare after cooling；
Further, the major catalyst is the one or more of the WCl6 and TiCl4 toluene solution containing nonylbenzene phenol；It is described
Co-catalyst be Et2AlCl, Et2Zn and EtAlCl2 it is one or more.
Further, polymerization time regulator described in step 1 is butyl cellosolve, acetylacetone,2,4-pentanedione, tetrahydrofuran
It is one or more.
Further, polymerization process condition described in step 2,75 ~ 80 DEG C of material temperature, 180 DEG C of polymerization temperature, injection pressure
0.4 ~ 0.6MPa, 0 ~ 0.3MPa of mold clamping force.
Further, the stabilizer is irgasfos 168, antioxidant 264, antioxidant 1076, in antioxidant 1010
It is one or more.
Comparative example 1
This comparative example compared with Example 2, weighs in step in raw material, saves basalt fibre ingredient, method step in addition to this
It is rapid all the same.
Comparative example 2
This comparative example compared with Example 2, weighs in step in raw material, saves liquid nbr carboxyl terminal ingredient, in addition to this
Method and step it is all the same.
Comparative example 3
This comparative example compared with Example 2, weighs in step in raw material, saves end amido liquid nitrile rubber ingredient, in addition to this
Method and step it is all the same.
The performance test results of fishing rod material prepared by each embodiment and comparative example of table 1
Claims (8)
1. a kind of fishing rod high-strength tenacity composite material, it is characterised in that: its parts by weight composition are as follows: benzoxazine monomer 149 ~
189 parts, 84 ~ 130 parts of dicyclopentadiene monomer, 3 ~ 24 parts of basalt fibre hold 10 ~ 15 parts of amido liquid nitrile rubber, liquid
5 ~ 6 parts of nbr carboxyl terminal, 2 ~ 3 parts of fire retardant, 1 ~ 2 part of stabilizer, 5 ~ 6 parts of terpene resin, 3 ~ 6 parts of curing agent, release agent
1 ~ 2 part, 0.5 ~ 1 part of curing accelerator, 0.05 ~ 0.1 part of major catalyst, 1 ~ 2 part of co-catalyst, polymerization reaction time regulator 1
~ 2 parts；
The fire retardant is phosphorus flame retardant；The stabilizer is organic tin stabilizer；The release agent is dimethicone；
The curing agent be diaminodiphenylmethane, diaminodiphenylsulfone, hexamethylene tetramine and diaminodiphenyl ether in extremely
Few one kind；The curing accelerator is 2-methylimidazole, 2-ethyl-4-methylimidazole, benzene sulfonyl chloride, 2- methyl 4-phenyl miaow
At least one of azoles and 2- phenylimidazole.
2. a kind of fishing rod high-strength tenacity composite material according to claim 1, which is characterized in that preparation method includes
Following steps:
Step 1 weighs the raw material for standby of following corresponding parts by weight:
A liquid: 63 ~ 87 parts of dicyclopentadiene monomer, 98 ~ 117 parts of benzoxazine monomer, 10 ~ 15 parts of amido liquid nitrile rubber of end,
5 ~ 6 parts of liquid nbr carboxyl terminal, 0.05 ~ 0.1 part of major catalyst, 1 ~ 2 part of stabilizer；
B liquid: 21 ~ 43 parts of dicyclopentadiene monomer, 51 ~ 72 parts of benzoxazine monomer, 1 ~ 2 part of co-catalyst, polymerization reaction time
1 ~ 2 part of regulator, 2 ~ 3 parts of fire retardant, 0.5 ~ 1 part of stabilizer, 3 ~ 24 parts of basalt fibre, 5 ~ 6 parts of terpene resin, curing agent 3
~ 6 parts, 1 ~ 2 part of release agent, 0.5 ~ 1 part of curing accelerator；
Reaction compression molding: step 2 A liquid, B liquid is uniformly mixed, under low temperature and low pressure, according to set polymerization technique item
Part injects in closed fishing rod mold, generates rapid polymerization reaction and therewith curing molding in a mold, is full of after mold about
The completion polymerization forming in 10 ~ 20s, rear curing process 1min, after solidification, after curing materials are naturally cooled to room temperature,
Obtain fishing rod high-strength tenacity composite material.
3. a kind of fishing rod high-strength tenacity composite material according to claim 1, which is characterized in that the benzoxazine
Monomer is Bisphenol F/aniline type benzoxazine monomer, bisphenol-A/aniline type benzoxazine monomer, thiodiphenol/aniline type benzo
Oxazines monomer, bisphenol-A/propylene amine type benzoxazine monomer, Bisphenol F/propylene amine type benzoxazine monomer or bisphenol-A/benzidine
One of benzoxazine monomer.
4. a kind of fishing rod high-strength tenacity composite material according to claim 1, which is characterized in that the basalt fibre
For silane coupling agent, which is added after dehydrated alcohol is uniformly dispersed, is made the coupling agent solution that mass fraction is 2%, by basalt fibre
Coupling agent solution is added after drying, is taken out after being stirred by ultrasonic 2 hours at 100 DEG C, filtering is placed at 100 DEG C of vacuum oven
Drying, benzoxazine resin pre-preg 2h after drying are spare after cooling.
5. a kind of fishing rod high-strength tenacity composite material according to claim 1, which is characterized in that the major catalyst
For the one or more of the WCl6 and TiCl4 toluene solution containing nonylbenzene phenol；The co-catalyst be Et2AlCl, Et2Zn and
EtAlCl2's is one or more.
6. a kind of fishing rod high-strength tenacity composite material according to claim 1, which is characterized in that the polymerization time
Regulator be butyl cellosolve, acetylacetone,2,4-pentanedione, tetrahydrofuran it is one or more.
7. a kind of fishing rod high-strength tenacity composite material according to claim 1, which is characterized in that polymerization described in step 2
Process conditions, 75 ~ 80 DEG C of material temperature, 180 DEG C of polymerization temperature, 0.4 ~ 0.6MPa of injection pressure, 0 ~ 0.3MPa of mold clamping force.
8. a kind of fishing rod high-strength tenacity composite material according to claim 1, which is characterized in that the stabilizer is
Irgasfos 168, antioxidant 264, antioxidant 1076, one of antioxidant 1010 or a variety of.
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| CN201810938046.6A CN109161194A (en) | 2018-08-17 | 2018-08-17 | A kind of fishing rod high-strength tenacity composite material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110435069A (en) * | 2019-08-06 | 2019-11-12 | 合肥东胜新能源汽车股份有限公司 | A kind of processing technology of PDCPD pick up rear cabinet cap assembly |
| CN112143170A (en) * | 2020-10-14 | 2020-12-29 | 安徽宏翔农业机械有限公司 | Preparation method of high-strength toughened plastic shovel for grain piling and winnowing |
| CN117551294A (en) * | 2024-01-11 | 2024-02-13 | 汕头市雅仕达包装材料有限公司 | High-strength PE film and preparation method thereof |
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| CN117551294A (en) * | 2024-01-11 | 2024-02-13 | 汕头市雅仕达包装材料有限公司 | High-strength PE film and preparation method thereof |
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