CN109161074A - A kind of antibacterial engineering plastic and preparation method thereof - Google Patents

A kind of antibacterial engineering plastic and preparation method thereof Download PDF

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Publication number
CN109161074A
CN109161074A CN201810719407.8A CN201810719407A CN109161074A CN 109161074 A CN109161074 A CN 109161074A CN 201810719407 A CN201810719407 A CN 201810719407A CN 109161074 A CN109161074 A CN 109161074A
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CN
China
Prior art keywords
parts
antibacterial
engineering plastic
raw material
agent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810719407.8A
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Chinese (zh)
Inventor
毕力
高敏
陈鹏
刘勇
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Tongcheng He Yi Plastic Industry Co Ltd
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Tongcheng He Yi Plastic Industry Co Ltd
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Publication date
Application filed by Tongcheng He Yi Plastic Industry Co Ltd filed Critical Tongcheng He Yi Plastic Industry Co Ltd
Priority to CN201810719407.8A priority Critical patent/CN109161074A/en
Publication of CN109161074A publication Critical patent/CN109161074A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a kind of antibacterial engineering plastics and preparation method thereof.One of antibacterial engineering plastic, raw material are formed by following parts by weight: 40-50 parts of high density polyethylene (HDPE), 30-40 parts of thermoplastic resin masterbatch, 20-40 parts of polyethylene terephthalate, 10-20 parts of polytetrafluoroethylene (PTFE), 10-20 parts of polypropylene, 10-20 parts of natural rubber, 5-8 parts of magnesia, 6-8 parts of graphite fibre, 5-7 parts of diatomite, 2-4 parts of antibacterial agent, 2-4 parts of lubricant, 1-3 parts of antioxidant, 1-3 parts of plasticizer.Engineering plastics prepared by the present invention have good mechanical performance, and the performance with good resistance bacteria breed, and light-weight, and intensity is high, has extensive market prospects on applying and popularizing.

Description

A kind of antibacterial engineering plastic and preparation method thereof
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of antibacterial engineering plastic and preparation method thereof.
Background technique
Engineering plastics are the plastics of engineering material and replacement metal manufacture element part etc..Engineering plastics have excellent Comprehensive performance, rigidity is big, and creep is small, high mechanical strength, and heat-resist, electrical insulating property is good, can be in harsher chemistry, physical rings It is used for a long time in border, alternative metal is used as structural timber, but price is more expensive, and yield is smaller.With general-purpose plastics phase Than, engineering plastics mechanical performance, durability, corrosion resistance, in terms of can reach higher requirement, and process more Convenient and alternative metal material.Engineering plastics are widely used in electric, automobile, building, office equipment, machinery, boat The industries such as empty space flight, to mould Dai Gang, have become international popular trend to mould Dai Mu, engineering plastics have become world today's plastics work The most fast field of growth rate in industry.But in life there are ponding discharges to be not thorough, easily breeds for common various engineering plastics The shortcomings that bacterium.
Summary of the invention
The present invention provides a kind of antibacterial engineering plastics and preparation method thereof, to solve the above technical problems.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is that:
A kind of antibacterial engineering plastic is made of by weight following raw material: 40-50 parts of high density polyethylene (HDPE), thermoplastic resin It is 30-40 parts of rouge masterbatch, 20-40 parts of polyethylene terephthalate, 10-20 parts of polytetrafluoroethylene (PTFE), 10-20 parts of polypropylene, natural 10-20 parts of rubber, 6-8 parts of graphite fibre, 5-7 parts of diatomite, 2-4 parts of antibacterial agent, 2-4 parts of lubricant, resists 5-8 parts of magnesia 1-3 parts of oxidant, 1-3 parts of plasticizer.
Preferably, a kind of antibacterial engineering plastic is made of by weight following raw material: 40 parts of high density polyethylene (HDPE), thermoplastic 30 parts of resin concentrates of property, 20 parts of polyethylene terephthalate, 10 parts of polytetrafluoroethylene (PTFE), 10 parts of polypropylene, 10 parts of natural rubber, 5 parts of magnesia, 6 parts of graphite fibre, 5 parts of diatomite, 2 parts of antibacterial agent, 2 parts of lubricant, 1 part of antioxidant, 1 part of plasticizer.
Preferably, a kind of antibacterial engineering plastic is made of by weight following raw material: 45 parts of high density polyethylene (HDPE), thermoplastic 35 parts of resin concentrates of property, 30 parts of polyethylene terephthalate, 15 parts of polytetrafluoroethylene (PTFE), 15 parts of polypropylene, 15 parts of natural rubber, 6.5 parts of magnesia, 7 parts of graphite fibre, 6 parts of diatomite, 3 parts of antibacterial agent, 3 parts of lubricant, 2 parts of antioxidant, 2 parts of plasticizer.
Preferably, a kind of antibacterial engineering plastic is made of by weight following raw material: 50 parts of high density polyethylene (HDPE), thermoplastic 40 parts of resin concentrates of property, 40 parts of polyethylene terephthalate, 20 parts of polytetrafluoroethylene (PTFE), 20 parts of polypropylene, 20 parts of natural rubber, 8 parts of magnesia, 8 parts of graphite fibre, 7 parts of diatomite, 4 parts of antibacterial agent, 4 parts of lubricant, 3 parts of antioxidant, 3 parts of plasticizer.
Preferably, the lubricant is microcrystalline wax.
Preferably, the plasticizer phthalic acid two (2- ethyl hexyl) ester.
Preferably, the antioxidant chooses hindered phenol antioxidant.
A kind of preparation method of antibacterial engineering plastic, which comprises the following steps:
(1) each component in above-mentioned raw materials is taken by weight, and is uniformly mixed and heated to molten condition;
(2) raw material obtained in step (1) is handled by kneader kneading;
(3) the investment double screw extruder of raw material obtained in step (2) is subjected to extruding pelletization;
(4) it will be granulated obtained in step (3) through air-cooled, screening magnetic separation, metering, packaging to get required antibacterial engineering Plastics.
Beneficial effects of the present invention:
Engineering plastics prepared by the present invention have good mechanical performance, and have the good performance for resisting bacteria breed, And light-weight, intensity is high, has extensive market prospects on applying and popularizing.
Specific embodiment
The embodiment of the present invention is described in detail below, but what the present invention can be defined by the claims and cover Multitude of different ways is implemented.
Embodiment 1
A kind of antibacterial engineering plastic is made of by weight following raw material:
40 parts of high density polyethylene (HDPE), 30 parts of thermoplastic resin masterbatch, 20 parts of polyethylene terephthalate, polytetrafluoroethylene (PTFE) 10 parts, 10 parts of polypropylene, 10 parts of natural rubber, 5 parts of magnesia, 6 parts of graphite fibre, 5 parts of diatomite, 2 parts of antibacterial agent, lubrication 2 parts of agent, 1 part of antioxidant, 1 part of plasticizer.
A kind of preparation method of antibacterial engineering plastic, comprising the following steps:
(1) each component in above-mentioned raw materials is taken by weight, and is uniformly mixed and heated to molten condition;
(2) raw material obtained in step (1) is handled by kneader kneading;
(3) the investment double screw extruder of raw material obtained in step (2) is subjected to extruding pelletization;
(4) it will be granulated obtained in step (3) through air-cooled, screening magnetic separation, metering, packaging to get required antibacterial engineering Plastics.
Above-mentioned lubricant is microcrystalline wax.
Above-mentioned plasticizer phthalic acid two (2- ethyl hexyl) ester.
Above-mentioned antioxidant chooses hindered phenol antioxidant.
The difference of following embodiment and embodiment 1 is only that:
Embodiment 2
A kind of antibacterial engineering plastic is made of by weight following raw material:
45 parts of high density polyethylene (HDPE), 35 parts of thermoplastic resin masterbatch, 30 parts of polyethylene terephthalate, polytetrafluoroethylene (PTFE) 15 parts, 15 parts of polypropylene, 15 parts of natural rubber, 6.5 parts of magnesia, 7 parts of graphite fibre, 6 parts of diatomite, 3 parts of antibacterial agent, profit 3 parts of lubrication prescription, 2 parts of antioxidant, 2 parts of plasticizer.
Embodiment 3
A kind of antibacterial engineering plastic is made of by weight following raw material:
50 parts of high density polyethylene (HDPE), 40 parts of thermoplastic resin masterbatch, 40 parts of polyethylene terephthalate, polytetrafluoroethylene (PTFE) 20 parts, 20 parts of polypropylene, 20 parts of natural rubber, 8 parts of magnesia, 8 parts of graphite fibre, 7 parts of diatomite, 4 parts of antibacterial agent, lubrication 4 parts of agent, 3 parts of antioxidant, 3 parts of plasticizer.
The embodiments of the present invention described above are not intended to limit the scope of the present invention, any in the present invention Spirit and principle within made modifications, equivalent substitutions and improvements etc., should be included in claim protection model of the invention Within enclosing.

Claims (8)

1. a kind of antibacterial engineering plastic, which is characterized in that be made of by weight following raw material: 40-50 parts of high density polyethylene (HDPE), 30-40 parts of thermoplastic resin masterbatch, 20-40 parts of polyethylene terephthalate, 10-20 parts of polytetrafluoroethylene (PTFE), polypropylene 10-20 Part, 10-20 parts of natural rubber, 5-8 parts of magnesia, 6-8 parts of graphite fibre, 5-7 parts of diatomite, 2-4 parts of antibacterial agent, lubricant 2- 4 parts, 1-3 parts of antioxidant, 1-3 parts of plasticizer.
2. antibacterial engineering plastic according to claim 1, which is characterized in that be made of by weight following raw material: highly dense Spend 40 parts of polyethylene, 30 parts of thermoplastic resin masterbatch, 20 parts of polyethylene terephthalate, 10 parts of polytetrafluoroethylene (PTFE), polypropylene 10 parts, it is 10 parts of natural rubber, 5 parts of magnesia, 6 parts of graphite fibre, 5 parts of diatomite, 2 parts of antibacterial agent, 2 parts of lubricant, anti-oxidant 1 part of agent, 1 part of plasticizer.
3. antibacterial engineering plastic according to claim 1, which is characterized in that be made of by weight following raw material: highly dense Spend 45 parts of polyethylene, 35 parts of thermoplastic resin masterbatch, 30 parts of polyethylene terephthalate, 15 parts of polytetrafluoroethylene (PTFE), polypropylene 15 parts, 15 parts of natural rubber, 6.5 parts of magnesia, 7 parts of graphite fibre, 6 parts of diatomite, 3 parts of antibacterial agent, 3 parts of lubricant, antioxygen 2 parts of agent, 2 parts of plasticizer.
4. antibacterial engineering plastic according to claim 1, which is characterized in that be made of by weight following raw material: highly dense Spend 50 parts of polyethylene, 40 parts of thermoplastic resin masterbatch, 40 parts of polyethylene terephthalate, 20 parts of polytetrafluoroethylene (PTFE), polypropylene 20 parts, it is 20 parts of natural rubber, 8 parts of magnesia, 8 parts of graphite fibre, 7 parts of diatomite, 4 parts of antibacterial agent, 4 parts of lubricant, anti-oxidant 3 parts of agent, 3 parts of plasticizer.
5. antibacterial engineering plastic according to claim 1, which is characterized in that the lubricant is microcrystalline wax.
6. antibacterial engineering plastic according to claim 1, which is characterized in that the plasticizer is two (2- of phthalic acid Ethyl hexyl) ester.
7. antibacterial engineering plastic according to claim 1, which is characterized in that it is anti-oxidant that the antioxidant chooses hindered phenol Agent.
8. the preparation method of the antibacterial engineering plastic as described in claim 1-4 any one, which is characterized in that including following step It is rapid:
(1) each component in above-mentioned raw materials is taken by weight, and is uniformly mixed and heated to molten condition;
(2) raw material obtained in step (1) is handled by kneader kneading;
(3) the investment double screw extruder of raw material obtained in step (2) is subjected to extruding pelletization;
(4) it will be granulated obtained in step (3) through air-cooled, screening magnetic separation, metering, packaging to get required antibacterial engineering plastic.
CN201810719407.8A 2018-07-02 2018-07-02 A kind of antibacterial engineering plastic and preparation method thereof Withdrawn CN109161074A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810719407.8A CN109161074A (en) 2018-07-02 2018-07-02 A kind of antibacterial engineering plastic and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810719407.8A CN109161074A (en) 2018-07-02 2018-07-02 A kind of antibacterial engineering plastic and preparation method thereof

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CN109161074A true CN109161074A (en) 2019-01-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317440A (en) * 2019-08-07 2019-10-11 贵阳伟佳塑料有限公司 Section material synthesized winding pipe of modified polyurethane and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189341A (en) * 2017-07-11 2017-09-22 合肥康之恒机械科技有限公司 It is a kind of for flame-proof antibiotic plastics of dustbin and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189341A (en) * 2017-07-11 2017-09-22 合肥康之恒机械科技有限公司 It is a kind of for flame-proof antibiotic plastics of dustbin and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317440A (en) * 2019-08-07 2019-10-11 贵阳伟佳塑料有限公司 Section material synthesized winding pipe of modified polyurethane and preparation method thereof

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Application publication date: 20190108

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