CN109160845A - The agriculture compound trace element fertilizer that agriculture and industry waste is produced - Google Patents
The agriculture compound trace element fertilizer that agriculture and industry waste is produced Download PDFInfo
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- CN109160845A CN109160845A CN201811112525.9A CN201811112525A CN109160845A CN 109160845 A CN109160845 A CN 109160845A CN 201811112525 A CN201811112525 A CN 201811112525A CN 109160845 A CN109160845 A CN 109160845A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Abstract
It is to belong to the agriculture compound trace element fertilizer of Huinong's science and technology to prepare production technical field the invention discloses the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced.The industrial or agricultural salkali waste slag straw powdered rice hulls environmental protection ferment, the leftover bits and pieces boron mud soybean stalks ferment powder for producing borax, oil refinery waste cobalt molybdate and useless nickel molybdate waste liquid corn stover aethiops vegetabilis zeolite Os Sus domestica powder compound trace element fertilizer, rich selenium germanium animal hair produce the compound trace element fertilizer composition of amino acid.Human health and environmental area, dietary factor are closely related, the earth's crust, air, water quality, crops, food fruit constituent content lack or insufficient, lead to a variety of chronic diseases of modern humans, ciril disease, even cancer.China is an industrial or agricultural big country, Industry Waste slag, waste liquid, agricultural wastes, stalk again, environment is polluted, therefore agriculture and industry waste production is made full use of to produce agriculture compound trace element fertilizer, is turned waste into wealth, it promotes the well-being of mankind, increasing both production and income, making one's country rich and powerful so that its people can enjoy a prosperous life is the purpose of the present invention.
Description
Technical field:
It is to belong to Huinong's science and technology nutrient agricultural the invention discloses the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced
Compound trace element fertilizer prepares production technical field.
Background technique:
The so more industrial alkali waste slag waste liquids of agriculture and industry waste, containing microelement necessary to two or more crops, for
If this waste residue and liquid is free of to the harmful heavy metal of crops and other harmful compounds, separating treatment need not be made,
Production cost can be substantially reduced in this way.The waste soda residue clinker of smelting industry: such as with smelting industry clinker (such as blast furnace slag, Yellow phosphorus furnace
Slag, ferro-manganese slag, carbonated coal balls slag etc.) it is slag class siliceous fertilizer made of raw material, this kind of siliceous fertilizer, which removes, contains solubility in citric acid silica
Outside, also containing micro- fertilizer in calcium, magnesium and iron, molybdenum, manganese, zinc, boron etc., the activated processing of these waste residues, be well in micro- fertilizer, one
As arable land usage amount be 225-750kg/hm2.This be at present promote the use of a large area both at home and abroad based on siliceous fertilizer in micro- fertilizer.
Human health and environmental area factor, dietary factor have substantial connection.Crustal elements are unevenly distributed, and lead to crops
The micronutrient levels of fruit has very big difference.Microelement deficiencies and food are inferior related in human body.It is micro- to obtain people
Secondary element food abundant, the present invention produce novel agricultural compound trace element fertilizer from agriculture and industry waste alkali-activated slag stalk, to make up ground
Shell Elemental redistribution unevenness is on the insufficient influence of cereal crops fruit micronutrient levels.To promote agriculture volume increase, agricultural production is improved
Quality meets the needs that people absorb microelement from food.The element for knowing from experience people reaches adjusting, supplement, antagonism,
Make one in-vivo element balance, health.
Summary of the invention:
The purpose of the present invention is to provide the agriculture compound trace element fertilizers that a kind of agriculture and industry waste is produced.
Technical Solving of the invention:
1, the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: the industrial or agricultural salkali waste slag powder waste liquid and
Straw powdered rice hulls environmental protection ferment forms % by following quality proportioning
Slag powders 10-30；Calcium superphosphate 2-6；
Powdered rice hulls 2-6；Potassium nitrate 0.5-1.5；
Beancake powder 1-3；Boron 0.1-0.3；
Bagasse powder 1-3；Rice straw powder 5-15；
Urea 2-6；Alkaline residue 5-15；
Environmental protection ferment adds to 100.
Preparation method:
It by above-mentioned each crushing material and is ground into fine powder, crosses 1200 meshes, be then uniformly mixed to obtain the final product.
In use, being used as low fertilizer, dose is 10-15kg per acre.Also visual soil quality situation, increases and decreases dosage as one sees fit.
Increasing soil fertility using micro- fertilizer is the task of top priority, and microelement is essential in China's fertile soil engineering construction
Fertilizer.The problem of China's soil lacks element, and especially middle microelement is generally existing shortage, fertilization compositions based on earth measurement is complete
Carry out within the scope of state.The dosage of middle microelement is increasing, and the research of the micro- fertilizer in China is started late with application, but develops fast
Speed, single inorganic micro- fertilizer have become the leading role in micro- fertilizer, and the dosage of organic trace element fertilizer is also gradually increasing, but due to this slightly fertile valence
Lattice are high, are subject to certain restrictions the application and popularizations of large area.Therefore, development and application industrial or agricultural " three wastes " is effectively dropped as raw material
The low production cost of micro- fertilizer, has also administered industrial or agricultural " three wastes ", has been the important channel of " turning harm into good ".
Crop growth needs various nutrient elements, contains various nutrient elements, element simultaneously in many industrial or agricultural " three wastes "
It may not necessarily separate in production.This makes its production cost well below single inorganic micro- fertilizer and organic trace element fertilizer, so, micro- fertilizer
Production can produce compound trace element fertilizer using local resource with adaptation to local conditions.Such as contain industrial residue, the waste liquid of middle microelement, agricultural
The many kinds of enormous amount of waste especially solids in production can be generally divided into following a few classes by its ingredient:
The primary produces waste, is primarily referred to as vegetative fiber waste, remains from farmland and orchard, such as stalk, fruit
Shell etc..
Secondary production waste, be primarily referred to as fowl and animal excrement and column circle underbed etc. and animal kill after hair.
Third produces waste, the residue after being primarily referred to as agricultural byproducts processing, shell, clast etc..
4th property produces waste, is primarily referred to as rural resident's domestic refuse and township industry waste etc..
It is sufficiently effective to utilize agriculture and industry waste, not only by its process change at useful agricultural products, and reduce
Environmental pollution, improves Ecological Environment.
Agriculture and industry waste is stepping into the scientific new stage, is rationally utilizing and promote this as a kind of energy
A little technologies will generate good economic benefit, ecological benefits and social benefit.
2, the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: the leftover bits and pieces boron of the production borax
Mud soybean stalks element powder forms % by following quality proportioning
Boron mud 5-15；Ferrous sulfate 0.5-1.5；
Urea 5-15；Soybean stalks powder 5-15；
Potassium nitrate 5-15；Ferric sulfate 0.5-1.5；
Calcium superphosphate 2-6；Borax 0.2-0.6；
Calcium nitrate 1-3；Zinc sulfate 0.1-0.3；
Magnesium sulfate 0.5-1.5；Copper sulphate 0.1-0.3；
Ammonium molybdate 0.2-0.6；Water adds to 100.
Preparation method:
Above-mentioned each component is added in 100mL water, stirring dissolves solids all, shake up.
National main production borax producer is 23, and annual practical total output is more than 10 ten thousand tons, the composition group of various regions boron mud
At %:B2O 2.4,2.19,2.75；CaO 4.0,3.11,1.69,0.70；MgO 40.5,33.9,42.9,42.6；Fe2O3
9.1,12.6,2.98,3.14；FeO 1.3,1.07,0.58；Al2O32.5,6.53；Na2O30.5,0.84；Acid non-soluble substance
26.7,22.6,21.1；Burning decrement 16.9,25.3,21.6.
Boron mud can be applied directly as boron fertilizer, and can be used as the micro-fertilizer raw materials such as boric magnesium fertilizer, boron magnesium-phosphorus fertilizer and boron magnesium nitrogenous fertilizer.
3, the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: the oil refinery waste cobalt molybdate and useless
Nickel molybdate waste liquid corn stover aethiops vegetabilis zeolite Os Sus domestica powder compound trace element fertilizer forms % by following quality proportioning
Useless cobalt molybdate catalyst 1-3；Useless nikel molybdate 1-3；
Corn stalk powder 3-9；Seaweed powdered carbon 2-6；
Peat 2-6；Zeolite powder 2-6；
Bentonite 1.5-4.5；Os Sus domestica powder 0.5-1.5；
Garden mould 1-3；Animal blood meal 0.2-0.6；
River sand 1-3；White clouds matter stone 1-3；
Cake fertilizer slag 1-3；Potassium nitrate 0.2-0.6；
Calcium superphosphate 1-3；Medical stone powder 0.5-1.5；
Potassium sulfate 0.2-0.6；Leaf mould adds to 100.
Preparation method:
Various elements material in formula is uniformly mixed.
The every production 1t ammonium paramolybdate of molybdenum-containing waste slag just has 0.403t molybdenum-containing waste slag, and untreated waste residue contains molybdenum 10% or so,
Water-soluble state molybdenum 1% -5%, available state molybdenum 1.3% -6.0%.Waste residue can be used as molydbenum fertilizer application.
Cobalt molybdate catalyst its at being grouped as %:MoO311.5—15.0；Co 1.7—2.3；Fe2O3< 0.07；Na2O
< 0.07；Al2O3> 83.
Nikel molybdate is at being grouped as %:MoO312—15；Ni 2—3；Al2O3 82—85。
Dead catalyst passes through Detoxified treatment, removes harmful element, then makees molydbenum fertilizer application, also can be used as production ammonium paramolybdate
Raw material.
In addition to useless cobalt molybdate, useless nickel molybdate, there are also the tungsten mixing leftover bits and pieces of tungsten wire factory, and give up tungsten mixing leftover bits and pieces, give up
Contain molybdenum 10% -15% in tungsten mixture, molydbenum fertilizer can be produced through processing.It or a kind of sterilization filter poison release are micro simultaneously
The compound trace element fertilizer of element anion fresh air.
4, the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: described with rich selenium germanium and animal hair
Amino Acid Chelated Mineral Fertilizer is produced, by following sour water Jie alkali neutralisation process flow:
Using protein fertilizer as raw material, the HCL that 30% concentration is added is hydrolyzed, and NaOH is then added and is neutralized, selenium is added
The microelements such as germanium are chelated, and are finally concentrated, are dried, finished product.
Amino acid be constitute protein basis can not only increase the fertilizer efficiency of micro- fertilizer with aminoacid chelated trace fertilizer, and
And amino acid itself can also promote plant growth.Chelated trace fertilizer obtained in this way, 1/2 of price less than general chelated trace fertilizer.
Moreover chelating amino acids zinc fertilizer or copper fertilizer, iron fertilizer, molydbenum fertilizer can promote plant growth, and have very well to the disease of certain crops
Preventive and therapeutic effect.
Production method is with animal hair (hair, pig hair, feather stem etc.) for raw material, and amino acid, then chela is made through hydrolyzing
Trace elements of selenium and germanium are closed, the Amino Acid Chelated Mineral Fertilizer of germanium containing selenium is made.
Wherein with sour water solution, alkali neutralisation, rich selenium germanium Amino Acid Chelated Mineral Fertilizer technique is prepared, is to use salt with keratoprotein is discarded
Sour (or sulfuric acid) hydrolyzes and generates compound amino acid, then with after alkali neutralization, with trace elements of selenium germanium chelating, concentrated, drying is
Obtain finished product.
In order to avoid the inhomogeneities of crustal elements distribution causes different influences to the health of different geographical different crowd,
Beneficial element is set in soil to cannot get due supplement and strong to crowd also for the chemical fertilizer such as wide nitrogen fertilizer application in the last hundred years are overcome
It is damaged caused by health, should be under Equilibrium of Trace Elements health care theoretical direction, nature remodeling cannot leave it to chance.By developing member
Element balance fertilizer etc. of improving the soil makees base manure and the high foliar fertilizer of " volume increase essence " element balance three makees top dressing, plants the various farmings of element balance
Object, it is edible for numerous residents.
Agriculture and industry waste mine alkali residue waste liquid agricultural stalk and animal wool etc. is used to be developed into as the agriculture micro- fertilizer of elements compounding
Function, industrial residue waste liquid contain various elements necessary to human body, can effectively increase agri-foodstuffs as agricultural micro fertilizer and make
The element balance of object, such as in abandoned mine alkaline residue liquid, wherein alkaline residue is through repeated detection experimental study, in alkaline residue not only containing nitrogen,
The conventional fertilizers such as phosphorus, potassium, also containing the macroelements such as calcium and magnesium chlorine sodium, also containing iron, zinc, manganese, titanium, vanadium, chromium, nickel, strontium, boron, beryllium,
The microelement that the plants such as copper, cobalt, silicon and human body require, and harmful element lead content is less than earth's crust Clarke value 13mg/kg,
Other some elements also belong to normal background level.So with alkaline residue base-material prepare various elements balance improve the soil fertilizer just have it is good
After good material base not only increases beneficiating ingredient in soil, but also crops absorb these beneficial elements, to the health of human body
Wholesome effect can be generated.
The preparation method of the environmental protection ferment:
Make the percentage of environmental protection ferment, sugared (brown sugar, brown sugar): fresh food garbage (vegetable leaf, fruit peel etc.): water=1:3:10.
Container: there is the plastic bottle of sealing cover mouth.Plastic bottle is optimal selection, avoids selecting glass or metal etc. can not be swollen
Swollen container.Because environmental protection ferment has bulk gas generation during fermentation, can be swollen.Select glassware can be fragile.
Production method:
1. plastic bottle to be filled to sixty percent unboiled water.(such as five liters of slack tank puts into three liters of water.Container must screw lid.)
2. 1/10th amount of water is exactly the amount of required brown sugar or brown sugar.(1 liter of water is equivalent to one kilogram of weight.
So three liters of water will match 300 g of brown sugar or brown sugar.) be poured into water sugar, it gently stirs evenly, makes to melt.It (can
It goes to stir with hand).
3. 3/10ths amount of water is exactly the amount of required fresh vegetables and fruits food waste.Three liters of water will match 900 g of vegetable
Fruit rubbish.Vegetables and fruits food waste is put into water, is gently stirred evenly.All vegetables and fruits food wastes of make suring all are dipped in water.
4. plastic bottle lid is screwed, and date in body.It is placed in place of shady and cool ventilation.Some spaces are stayed in I container,
It is overflowed outside container when preventing ferment from fermenting.
5. the first month in manufacturing process has gas generation, bottle cap is unscrewed once daily, and fastens at once.Release
The gas expanded out by fermentation is all right.
6. would not should have again the gas of expansion after one month (plastic bottle is no longer heaved).Continue to stand to three months
Expire.
7. the rubbish floated on liquid level is pressed down frequently, impregnate it in a liquid.
Manufacturing process:
1. avoiding the container for selecting glass or metal etc. that can not expand.
2. ferment raw material (such as: dish slag, pericarp) can be sliced, cut smaller, more facilitate to decompose.
3. ferment raw material avoids having putrefactive odor using fish, meat or greasy food waste (but can be used as compost).
4. orange peel, lemon peel and Ban Lanye etc., which can be added, to be had if it is desired to which the ferment made has the smell of faint scent
The vegetables pericarp of fragrance.
5. the container of installation ferment need to possess 20% fermenting space.
6. fresh food garbage can be added successively, 3 months time limits are by last if the fresh food garbage of enough deals can not be collected for the moment
It is counted on the day of secondary addition.
7. indicating making date on container.Ferment raw material decomposes and fermentation last 3 months, and patience is asked to make whole process complete
Whole progress.
8. make ferment, pleasant mood please be keep, love is cherished and does, the quality of ferment can be more preferable.
9. environmental protection ferment should be placed in air circulation, shady place, sunlight direct irradiation is avoided.It is sure not to be placed in refrigerator
Interior, low temperature can reduce the activity of ferment.
Fermentation process:
1. brown sugar water need to cover the ferment raw material such as dish slag, pericarp.If raw material floats on the surface of the water, need to stir makes it be immersed in brown sugar
In water.
2. making initial stage, need to open bottle cap daily, the gas of fermentation is allowed to circulate outward, " taste " can be heard when uncapping
Sound, here it is the sound of fermentation.
3. bottle can be stretched if being not turned on bottleneck, gas is overflowed when can not discharge, or even can explode, and please notices more.
4. can be used after 3 months phases of fermenting.6 months or more preferably, and the fermentation phase is more long, and effect is better, more Chen Yue alcohol.
Rice field application of zinc fertilizer can increase production, experiments have shown that, increasing production of rice 10% or so can be used in application of zinc fertilizer, can also improve grain of rice matter
Amount.The corn not only needs the macronutrients such as nitrogen, phosphorus, potassium in growth and development process.And need zinc, boron, manganese, copper, iron,
The various trace elements such as molybdenum.If lacking these microelements, corn is unable to normal growth, and leads to Severe Reduction.What they used
Micro- fertilizer mainly has: zinc sulfate, borax, boric acid, manganese sulfate, copper sulphate, ferrous sulfate, ammonium molybdate solution etc., carries out foliage-spray.
Using micro- fertilizer it should be noted that item:
1. paying attention to the quantity for determining the type of application according to the needs of soil: microelement generally has certain contain in the soil
Amount, but its validity is very big by Influence To Soil, and under different soil, microelement is rich scarce also inconsistent.It therefore, should be in line with scarce
What principle what mend, and on the basis of carrying out assay or single experiment to soil, determines the application type and amount of application of micro- fertilizer.
2. paying attention to micro- fertilizer of mixing, element species should not be excessive；Various micro- fertilizer competence exertions when concentration is suitable for act on, if
Mixing excessively is difficult to guarantee various micro optium concentrations and amount of application, not only cannot preferably play a role in this way, but also
It is unfavorable to crop.
3. paying attention to understanding fully between micro- fertilizer, the correlation between micro- fertilizer and soil: crop absorbs various nutritional ingredients, is all
It is absorbed with the ionic condition in aqueous solution.By different different, the interionic meetings with the electrically charged and valence mumber of micro- fertilizer of pH value in soil
Phenomena such as appearance attracts each other, fights mutually, inhibiting mutually.Influence being absorbed and utilized for crop.So to master it is micro- fertilizer between, it is micro-
Correlation between fertilizer and soil.In general, molydbenum fertilizer and nitrogen, phosphorus, potash fertilizer mixing application effect are good.Zinc fertilizer and ammonium sulfate,
Ammonium chloride can mix application, cannot mix application with urea, ammonium hydrogen carbonate, ammonium hydroxide.Boron fertilizer can mix application with nitrogen, phosphate fertilizer.Copper
Class mixes application in proportion under certain condition for fertilizer, manganese fertilizer, boron fertilizer.
Result of study is generally investigated according to epidemiology, selenium deficiency germanium is a Factors during liver cancer occurrence and development.Molybdenum
Related with the cancer of the esophagus, scarce molybdenum may be the Factors of the cancer of the esophagus.Manganese content and onset of liver cancer rate are in negative in internal external environment
It closes.Therefore, appropriate application selenium fertilizer, germanium fertilizer and manganese fertilizer can be considered for High Phc Incidence Area crops, it is suitable to esophagus high cancer incidence area
When application selenium germanium molydbenum fertilizer and manganese fertilizer, to improve the content of grain microelement, cure the disease to play the role of aspect.
It is described that zeolite micro mist is immersed in the aqueous solution or dissolved salt of metal soluble-salt, make sodium ion therein by copper, silver, zinc etc.
Metal ion displacement, can be obtained the zeolite with antibacterial functions, and have functions that take drugs potently, filter poison.
Bentonite in clay antibacterial agent because it is with very strong adsorption capacity and ion-exchange capacity, and becomes inorganic
The ideal carrier of antibacterial agent.With broad spectrum antibacterial, all there is ideal inhibitory effect to Glan negative bacterium, fungal mold etc..
Antimicrobial fluid prepared by the nano silver antimicrobials is detected through China Preventive Medicial Science Institute, to Escherichia coli and golden yellow grape
The antibiotic rate of coccus is up to 99.9%, the effectively bacterium in killing off plant, virus, and antibacterial agent property safe to the human body without
Poison is non-stimulated, and antibacterial is lasting.
Aluminum oxide Al in the medical stone ingredient203Content accounts for 16.5%, has far infrared radiation bactericidal effect, also
Titanium dioxide TiO2It is the representative of photocatalysis formula sterilization, there is degradable organic pollutant, its catalytic activity is high, chemically
Matter is stable, without secondary pollution, improvement water pollution purifies air, has extremely strong oxidation-reduction quality, can pass through the strong of transmitting light
Degree improves the decomposition rate of pollutant to enhance dissolved oxygen content, shortens the pollution reaction time, strengthens reaction, so medical stone has
Magical water purification deodorization functions, at the same also containing a variety of required trace elements irons of human body, calcium, nickel, zinc, molybdenum, cobalt, silicon, copper,
The harmful elements content such as tin, vanadium, selenium, germanium, fluorine, iodine, potassium, magnesium, sodium, chromium, lithium, strontium is low, will not damage to human body.Especially mention
The two kinds of elements of selenium, germanium arrived, a large amount of medical researches prove in recent years, they can enhance immune, anti-cancer, anticancer, promote longevity.
Germanium has the function of promoting plant growth, also can guarantee that rice seedling grows vigorously in cold ice environment, test card
Bright germanium can promote the growth of ginseng and improve its quality, and the disease-resistant cold tolerance of ginseng cultivated with organic germanium is reinforced, and find in recent years
Wild ganoderma, wild wild ginseng are germanic to be up to 2000*10 respectively-6And 4000*10-6No wonder the mankind are since ancient times ganoderma lucidum, people
Ginseng is described as elixir, mesona, help medicine, miraculous cure, it can promote human health, regulation of physiological functions, anti-inflammatory, antibacterial, anticancer,
It is anti-aging.Selenium germanium conjunctive use, can effectively clear human free radical, and organic germanium pharmacological action is mainly manifested in its uniqueness having
There are three the key with oxygen in molecular structure, oral absorption can provide a large amount of oxygen to systemic cell, improve metabolism, and enhancing is thin
Intracellular activity promotes regeneration, strengthen immunity and the ability resisted the disease, and anti-cancer, inhibits cancer cell to be formed at anticancer, reduces
Blood viscosity increases blood flow, improves blood circulation and organ dysfunction, increases blood vessel elasticity, reduces blood pressure, prevent heart and brain blood
Pipe disease and cerebral thrombosis, headstroke are formed.Germanium is widely distributed in living organism, the skin of many enzymes, human brain in organism
All contain Germanium in matter and grey matter, in the subcellulars composition such as cell wall, mitochondria, chromosome, lysosome, due to the biology of germanium
Activity and its risen special medical health-care effect in human body, cause chemist, pharmacologist and nutrition in the world
Family greatly interest and concern, referred to as " jinx of human diseases ", " the help germanium of 21st century ", " 21st century is raw
The good names such as the source of life ", the nova of the world " vibration ", " bodyguard of human health ", due to germanium and the regulator of plant growth,
It can promote the growth and improvement quality of cereal, veterinary antibiotics etc., the agriculture compound trace element fertilizer produced with a kind of agriculture and industry waste.
It is applied in the soil of crop growth, the soil is made to become the natural treasure-house of microelement required for plant growth.Plant
Nutritional ingredient necessary to the numerous elements of these germanium containing selenium is absorbed from soil and compound nutritional fertilizer, maintains and promote its growth and development
Life movement process, and turn waste into wealth, make one's country rich and powerful so that its people can enjoy a prosperous life.
The present invention is furtherd elucidate below with reference to embodiment
Specific embodiment:
Embodiment 1: a kind of agriculture compound trace element fertilizer that agriculture and industry waste is produced, it is characterized in that: the industrial or agricultural salkali waste slag powders
Waste liquid and straw powdered rice hulls environmental protection ferment form % by following quality proportioning
Slag powders 10-30；Calcium superphosphate 2-6；
Powdered rice hulls 2-6；Potassium nitrate 0.5-1.5；
Beancake powder 1-3；Boron 0.1-0.3；
Bagasse powder 1-3；Rice straw powder 5-15；
Urea 2-6；Alkaline residue 5-15；
Environmental protection ferment adds to 100.
Embodiment 2: a kind of agriculture compound trace element fertilizer that agriculture and industry waste is produced, it is characterized in that: under the production borax
Heel boron mud soybean stalks element powder forms % by following quality proportioning
Boron mud 5-15；Ferrous sulfate 0.5-1.5；
Urea 5-15；Soybean stalks powder 5-15；
Potassium nitrate 5-15；Ferric sulfate 0.5-1.5；
Calcium superphosphate 2-6；Borax 0.2-0.6；
Calcium nitrate 1-3；Zinc sulfate 0.1-0.3；
Magnesium sulfate 0.5-1.5；Copper sulphate 0.1-0.3；
Ammonium molybdate 0.2-0.6；Water adds to 100.
Embodiment 3: a kind of agriculture compound trace element fertilizer that agriculture and industry waste is produced, it is characterized in that: the oil refinery waste molybdic acid
Cobalt and useless nickel molybdate waste liquid corn stover aethiops vegetabilis zeolite Os Sus domestica powder compound trace element fertilizer form % by following quality proportioning
Useless cobalt molybdate catalyst 1-3；Useless nikel molybdate 1-3；
Corn stalk powder 3-9；Seaweed powdered carbon 2-6；
Peat 2-6；Zeolite powder 2-6；
Bentonite 1.5-4.5；Os Sus domestica powder 0.5-1.5；
Garden mould 1-3；Animal blood meal 0.2-0.6；
River sand 1-3；White clouds matter stone 1-3；
Cake fertilizer slag 1-3；Potassium nitrate 0.2-0.6；
Calcium superphosphate 1-3；Medical stone powder 0.5-1.5；
Potassium sulfate 0.2-0.6；Leaf mould adds to 100.
Embodiment 4: a kind of agriculture compound trace element fertilizer that agriculture and industry waste is produced, it is characterized in that: described with rich selenium germanium and dynamic
Object hair produces Amino Acid Chelated Mineral Fertilizer, by following sour water Jie alkali neutralisation process flow:
Using protein fertilizer as raw material, the HCL that 30% concentration is added is hydrolyzed, and NaOH is then added and is neutralized, selenium is added
The microelements such as germanium are chelated, and are finally concentrated, are dried, finished product.
Claims (4)
1. the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: the industrial or agricultural salkali waste slag powder waste liquid and
Straw powdered rice hulls environmental protection ferment forms % by following quality proportioning
Slag powders 10-30；Calcium superphosphate 2-6；
Powdered rice hulls 2-6；Potassium nitrate 0.5-1.5；
Beancake powder 1-3；Boron 0.1-0.3；
Bagasse powder 1-3；Rice straw powder 5-15；
Urea 2-6；Alkaline residue 5-15；
Environmental protection ferment adds to 100.
2. the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: the leftover bits and pieces boron mud of the production borax is yellow
Beanstalk stalk element powder forms % by following quality proportioning
Boron mud 5-15；Ferrous sulfate 0.5-1.5；
Urea 5-15；Soybean stalks powder 5-15；
Potassium nitrate 5-15；Ferric sulfate 0.5-1.5；
Calcium superphosphate 2-6；Borax 0.2-0.6；
Calcium nitrate 1-3；Zinc sulfate 0.1-0.3；
Magnesium sulfate 0.5-1.5；Copper sulphate 0.1-0.3；
Ammonium molybdate 0.2-0.6；Water adds to 100.
3. the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: the oil refinery waste cobalt molybdate and useless molybdic acid
Nickel waste liquid corn stover aethiops vegetabilis zeolite Os Sus domestica powder compound trace element fertilizer forms % by following quality proportioning
Useless cobalt molybdate catalyst 1-3；Useless nikel molybdate 1-3；
Corn stalk powder 3-9；Seaweed powdered carbon 2-6；
Peat 2-6；Zeolite powder 2-6；
Bentonite 1.5-4.5；Os Sus domestica powder 0.5-1.5；
Garden mould 1-3；Animal blood meal 0.2-0.6；
River sand 1-3；White clouds matter stone 1-3；
Cake fertilizer slag 1-3；Potassium nitrate 0.2-0.6；
Calcium superphosphate 1-3；Medical stone powder 0.5-1.5；
Potassium sulfate 0.2-0.6；Leaf mould adds to 100.
4. the agriculture compound trace element fertilizer that a kind of agriculture and industry waste is produced, it is characterized in that: described produced with rich selenium germanium and animal hair
Amino Acid Chelated Mineral Fertilizer, by following sour water Jie alkali neutralisation process flow:
Using protein fertilizer as raw material, the HCL that 30% concentration is added is hydrolyzed, and NaOH is then added and is neutralized, selenium is added
The microelements such as germanium are chelated, and are finally concentrated, are dried, finished product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111333434A (en) * | 2020-04-24 | 2020-06-26 | 北京光明橡塑制品厂 | Method for preparing fertilizer from metallurgical steel slag material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060580A (en) * | 2009-11-17 | 2011-05-18 | 四川新绿盛生物工程技术有限公司 | Preparation of humic acid biological organic fertilizer from composite biological fungi |
| CN105541448A (en) * | 2015-11-09 | 2016-05-04 | 南通蛇类治疗研究所 | Fertilizer powder for cultivating high-selenium and germanium, cancer prevention and life prolongation broccoli |
| CN106946621A (en) * | 2017-05-21 | 2017-07-14 | 南通蛇类治疗研究所 | Cultivate rich selenium germanium multielement watermelon nutrition fertilizer |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060580A (en) * | 2009-11-17 | 2011-05-18 | 四川新绿盛生物工程技术有限公司 | Preparation of humic acid biological organic fertilizer from composite biological fungi |
| CN105541448A (en) * | 2015-11-09 | 2016-05-04 | 南通蛇类治疗研究所 | Fertilizer powder for cultivating high-selenium and germanium, cancer prevention and life prolongation broccoli |
| CN106946621A (en) * | 2017-05-21 | 2017-07-14 | 南通蛇类治疗研究所 | Cultivate rich selenium germanium multielement watermelon nutrition fertilizer |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111333434A (en) * | 2020-04-24 | 2020-06-26 | 北京光明橡塑制品厂 | Method for preparing fertilizer from metallurgical steel slag material |
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