CN109141973A - The collection device and method of acid mist in stationary source atmosphere - Google Patents

The collection device and method of acid mist in stationary source atmosphere Download PDF

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Publication number
CN109141973A
CN109141973A CN201710504988.9A CN201710504988A CN109141973A CN 109141973 A CN109141973 A CN 109141973A CN 201710504988 A CN201710504988 A CN 201710504988A CN 109141973 A CN109141973 A CN 109141973A
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China
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collection
collector
resin
droplet
acid mist
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CN201710504988.9A
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CN109141973B (en
Inventor
云美峰
朱敏
熊新兴
樊苗苗
张晶晶
刘欢
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XI'AN YUCHI TESTING TECHNOLOGY Co Ltd
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XI'AN YUCHI TESTING TECHNOLOGY Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/10Devices for withdrawing samples in the liquid or fluent state
    • G01N1/14Suction devices, e.g. pumps; Ejector devices

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The present invention relates to the collection devices and method of acid mist in environment protection field more particularly to stationary source atmosphere.Collection vessel comprising top, it is placed with droplet in the collection vessel and collects disk, it is the poroid disk of resin that droplet, which collects disk, it includes multiple resin withes, multiple resin withe parallelly distribute ons, lower section is resin filter layer to reduced diameter portion below collection vessel again, it is the collector with filter layer, insulating layer below collection vessel, the collector avris with filter layer, insulating layer includes a suction filtration pump interface, it filters pump interface and connects suction filter pump, mouth should be taken comprising a collection liquid with the collector lower section of filter layer, insulating layer.Using the present invention of technical solution as above, have the advantages that compared with the existing technology: the collecting terminal of resin is more durable, and the solution acid corrosion of filament is not durable;Filter layer can make the solution collected cleaner;The bottom of inclined collector makes the solution collected be easier to pour out;Liquid level sensor can be to avoid the excessively high spilling of liquid level.

Description

The collection device and method of acid mist in stationary source atmosphere
Technical field
The present invention relates to the collection devices and method of acid mist in environment protection field more particularly to stationary source atmosphere.
Background technique
Mist is the tiny droplet swum in low latitude, is suspended in subaerial aerosol.The general journey ball-type of droplet, diameter Between 2-100 μm.Acid mist is one kind of broad sense acid rain, refers to misty acid.Forming feature: 1. due to acid solution table The evaporation in face, acid molecule enter air, absorb moisture and agglomerate and be shaped to acid mist drop;2. having chemical reaction and life in acid solution At bubble, explosion after bubble emersion liquid level takes drop into air out of.Occur mainly with chemical industry, metallurgy, light industry, plating, spinning Knit the industries such as (chemical fibre), grease, papermaking and machine-building in sour process.
Acid mist is formed since the acidic materials in atmosphere are absorbed by droplet, and acid drop is also to form the important field of acid mist Institute.With the rapid development of economy, the consumption of fossil energy rapidly increases, the occurrence frequency of acid mist is higher, the pH value of acid mist Can be down to 2.0 hereinafter, greasy weather, the exhaust gas accumulated in low latitude are not easy to dissipate, acid mist destroys Plant Cuticular wax layer, inhibits Plant Light Its growth is hindered with effect, leads to Plant death, Forest dicline;People's Long Term Contact acid mist has Atrophic nasal mucosas and with smelling Feel decline or disappear, chronic bronchitis, pulmonary edema and dental erosion, acid mist contain there are many carcinogenic factor of causing a disease, and induce A variety of diseases and cancer, damage to plant are difficult to estimate to the extent of damage of body health.
Since mist only occurs in limited when and where, collect, acquisition difficulty, collecting fog is typically all related personnel The easy device of qualification in practical study has no the molding fog collector of exploitation.Current fog collection method is divided into two Class, one is many filament grids of longitudinal pull-up, rear sets up fan and attracts air, and droplet is made to hit collection on filament;Separately One is swingle collecting method, swingle top has trap, and motor drives swingle rotation, and droplet passes through centrifugal action, Collect collection.
The processing method bulk fluid absorption process of acid mist, suspends and moulds ball cladding process or generated with fog inhibitor at electrostatic demisting method Foam method.
The detection method of acid mist, mainly there is a spectrum detection method and chromatographic detection, spectrum detection method include ultraviolet light detection, Chemical light detection, fluorimeter detection, IR, Raman etc.;Chromatography detection includes gas phase, liquid phase.
Acid mist collecting, one is droplets to be directly collected into collector, and one is lye is packed into collector for exception It collects.Collection method droplet as described in 1 hits collection either swingle collecting method on filament.We have found that collecting There is no a specific separation systems during droplet, and if the concentration of acid mist is very big, filament is not durable inevitably, and And there are other impurities in the solution collected.And if it is using lye absorbing liquid to collect, then easily freeze in winter.
Summary of the invention
The purpose of invention: in order to provide the collection device of acid mist and side in a kind of better stationary source atmosphere of effect Method, specific purposes are shown in multiple substantial technological effects of specific implementation part.
In order to reach purpose as above, the present invention is adopted the following technical scheme that:
Scheme one:
The collection device of acid mist in stationary source atmosphere, which is characterized in that the collection vessel comprising top, the collection vessel In be placed with droplet collect disk, droplet collect disk be the poroid disk of resin, it includes multiple resin withes, multiple resin thins Branch parallelly distribute on, lower section is resin filter layer again for reduced diameter portion below collection vessel, below collection vessel for filter layer, The collector of insulating layer should include a suction filtration pump interface with the collector avris of filter layer, insulating layer, and filter pump interface Suction filter pump is connected, mouth should be taken comprising a collection liquid with the collector lower section of filter layer, insulating layer.
The further technical solution of the present invention is that the oral area of the collector has card slot, and card slot can place resin mistake Filtering layer.
The further technical solution of the present invention is that the bottom wall of the collector is inclined surface, and inclined surface slope aspect collection liquid takes Mouthful.
The further technical solution of the present invention is that the collection liquid, which takes mouth and filters pump interface, respectively contains valve.
The further technical solution of the present invention is that the oral area of the collection vessel and collector docking is reduced diameter portion.
The further technical solution of the present invention is that there is one layer of heat preservation material in the outside of the collector.
The further technical solution of the present invention is that the droplet collects the plastic disc that disk is acquisition, has on disk There is aperture resin withe, having an aperture on disk is that can install sensor, which is liquid level sensor, and liquid level passes The adherent cabling of the wall of sensor, the liquid level sensor communicate to connect warning device.
The further technical solution of the present invention is that the resin filter layer can filter out organic substance.
The collection method of acid mist in stationary source atmosphere, which is characterized in that as above any collection device is utilized, It comprises the following steps,
Mist is the tiny droplet swum in low latitude, is suspended in subaerial aerosol;Collection starts, and filters pump startup.Mist During doing Brownian movement, irregular movement is collided with advanced withe, and droplet is captured, with more and more droplets Aggregation, gravity and under the action of, be deposited in discoid first time filter device i.e. droplet collection disk on, pass through this hole Diameter, droplet continue to flow down, and by filter layer, are finally collected into collector;During entire collection, if the acid solution being collected into More than liquid level, then sensor can be warned, and avoided collection liquid from excessively overflowing and caused secondary pollution.
Using the present invention of technical solution as above, have the advantages that compared with the existing technology: the collecting terminal of resin is more Durable, the solution acid corrosion of filament is not durable;Filter layer can make the solution collected cleaner;The bottom of inclined collector Portion makes the solution collected be easier to pour out;Liquid level sensor can be to avoid the excessively high spilling of liquid level.
Detailed description of the invention
In order to further illustrate the present invention, it is further illustrated with reference to the accompanying drawing:
Fig. 1 is the collection structure schematic diagram of invention;
Fig. 2 is the process flow chart of invention;
Wherein: 1. resin outer walls;2. resin withe;3 resin Round Porous plate-likes;4. resin filter layer;5. filtering pump interface;6. band There is the collector of filter layer, insulating layer;7. clip;8. collection liquid takes mouth;9. liquid level sensor;10. thermal insulation material;11. lye Absorbing liquid or acid mist drip solution;12. inclined container bottom;13. fixed side;14. glass wall.
Specific embodiment
With reference to the accompanying drawings and detailed description, the present invention is furture elucidated, it should be understood that following specific embodiments are only For illustrating the present invention rather than limiting the scope of the invention.
Scheme one:
The collection device of acid mist in stationary source atmosphere, which is characterized in that the collection vessel comprising top, the collection vessel In be placed with droplet collect disk, droplet collect disk be the poroid disk of resin, it includes multiple resin withes, multiple resin thins Branch parallelly distribute on, lower section is resin filter layer again for reduced diameter portion below collection vessel, below collection vessel for filter layer, The collector of insulating layer should include a suction filtration pump interface with the collector avris of filter layer, insulating layer, and filter pump interface Suction filter pump is connected, mouth should be taken comprising a collection liquid with the collector lower section of filter layer, insulating layer.The technical solution institute at this place The technical effect and its realization process of the essence played are as follows: mist is the tiny droplet swum in low latitude, is suspended in close The aerosol on ground;Collection starts, and filters pump startup.Mist during doing Brownian movement, irregular movement with it is advanced thin Branch collision, droplet is captured, as more and more droplets are assembled, gravity and under the action of, be deposited in discoid first Secondary filter device, that is, droplet is collected on disk, and by this aperture, droplet continues to flow down, and by filter layer, is finally collected into collection In device.The preferred diameter of resin withe at this is 0.05 centimetre to 1 centimetre, the most further preferably, moreover it is possible to which it is netted for interweaving.
It tests and analyzes:
1. if the acid mist drop being directly collected into, is analyzed with the chromatography of ions.Ion chromatograph has autosampler.Point During analysis, then first method for building up determines the retention time of nitrate ion;It is prepared and is marked according to the concentration level of actual sample Quasi- serial solution draws calibration curve;Bent appropriate amount of sample, ion chromatograph analysis.
2. if with GB/T 7480-1987, " the measurement Pbenoldisulfonic Acid of water quality nitrate is divided light collection liquid is lye Degree method " measurement nitrate nitrogen.The detection range of the nitrate nitrogen of this standard is between 0.02-2.0mg/L, so if needing to use This method, should just dilute, then be tested and analyzed according to standard, finally be converted into the concentration of the nitrate of former collection liquid.
The oral area of the collector has card slot, and card slot can place resin filter layer.The technical solution at this place is played Essence technical effect and its realize process be as follows: this place provides a kind of fixed form of specific resin filter layer, Similar fixation is in the protection scope of this patent.
The bottom wall of the collector is inclined surface, and inclined surface slope aspect collection liquid takes mouth.What the technical solution at this place was played The technical effect and its realization process of essence are as follows: liquid is conveniently gone out when pouring out, and does not have to shake whole.It collects The bottom angled of device is in order to pouring out the acid mist being collected into.
The collection liquid, which takes mouth and filters pump interface, respectively contains valve.Without using when, valve can close.Institute The oral area for stating collection vessel and collector docking is reduced diameter portion.
There is one layer of heat preservation material in the outside of the collector.It prevents from freezing.
The droplet collects the plastic disc that disk is acquisition, has aperture resin withe on disk, has on disk One aperture is can to install sensor, which is liquid level sensor, the adherent cabling of the wall of liquid level sensor, liquid level biography Sensor communicates to connect warning device.During entire collection, sensor can be sent out if the acid solution being collected into is more than liquid level Raw warning, avoids collection liquid from excessively overflowing and causes secondary pollution.
In a creative way, above each effect is individually present, moreover it is possible to the combination of the above results is completed with a nested structure.
It is clear that the technical effect that the above structure is realized is realized, if the additional technical solution is not taken into account, this patent title is also It can be a kind of environmentally friendly structure.Part details is not shown in the figure.
It should be noted that multiple schemes that this patent provides include the basic scheme of itself, independently of each other, not mutually It restricts, but it can also be combined with each other in the absence of conflict, reach multiple effects and realize jointly.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of this field Personnel should be recognized that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this hairs Bright principle, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these variations It is both fallen in claimed range with improving.

Claims (9)

1. the collection device of acid mist in stationary source atmosphere, which is characterized in that the collection vessel comprising top, the collection are held It is placed with droplet in device and collects disk, it is the poroid disk of resin that droplet, which collects disk, and it includes multiple resin withes, multiple resins Withe parallelly distribute on, lower section is resin filter layer again for reduced diameter portion below collection vessel, for filtering below collection vessel The collector of layer, insulating layer should include a suction filtration pump interface, suction filter pump with the collector avris of filter layer, insulating layer Interface connects suction filter pump, should take mouth comprising a collection liquid with the collector lower section of filter layer, insulating layer.
2. the collection device of acid mist in stationary source atmosphere as described in claim 1, which is characterized in that the collector Oral area has card slot, and card slot can place resin filter layer.
3. the collection device of acid mist in stationary source atmosphere as described in claim 1, which is characterized in that the collector Bottom wall is inclined surface, and inclined surface slope aspect collection liquid takes mouth.
4. the collection device of acid mist in stationary source atmosphere as described in claim 1, which is characterized in that the collection liquid takes Mouth and suction filtration pump interface respectively contain valve.
5. the collection device of acid mist in stationary source atmosphere as described in claim 1, which is characterized in that the collection vessel Oral area with collector docking is reduced diameter portion.
6. the collection device of acid mist in stationary source atmosphere as described in claim 1, which is characterized in that the collector There is one layer of heat preservation material in outside.
7. the collection device of acid mist in stationary source atmosphere as described in claim 1, which is characterized in that the droplet is collected Disk is the plastic disc of acquisition, has aperture resin withe on disk, having an aperture on disk is that can install biography Sensor, the sensor are liquid level sensor, the adherent cabling of the wall of liquid level sensor, liquid level sensor communication connection alarm dress It sets.
8. the collection device of acid mist in stationary source atmosphere as described in claim 1, which is characterized in that the resin filtering Layer can filter out organic substance.
9. the collection method of acid mist in stationary source atmosphere, which is characterized in that utilize any collection of claim 1-8 Device comprises the following steps that mist is the tiny droplet swum in low latitude, is suspended in subaerial aerosol;Collection starts, Filter pump startup;Mist during doing Brownian movement, collide with advanced withe, and droplet is captured by irregular movement, with More and more droplets aggregations, gravity and under the action of, be deposited in discoid first time filter device i.e. droplet and collect and justify On disk, by this aperture, droplet continues to flow down, and by filter layer, is finally collected into collector;During entire collection, such as The acid solution that fruit is collected into is more than that then sensor can warn liquid level, avoids collection liquid from excessively overflowing and causes secondary pollution.
CN201710504988.9A 2017-06-28 2017-06-28 Device and method for collecting acid mist in atmosphere of fixed pollution source Active CN109141973B (en)

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