CN109137592B - 一种透明纸基烟包材料及其制备方法 - Google Patents

一种透明纸基烟包材料及其制备方法 Download PDF

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CN109137592B
CN109137592B CN201810652506.9A CN201810652506A CN109137592B CN 109137592 B CN109137592 B CN 109137592B CN 201810652506 A CN201810652506 A CN 201810652506A CN 109137592 B CN109137592 B CN 109137592B
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cigarette packet
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CN109137592A (zh
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陈港
张俊奇
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Zhejiang Shangfeng Packaging New Material Co ltd
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South China University of Technology SCUT
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Abstract

本发明公开了一种透明纸基烟包材料及其制备方法，涉及卷烟包装技术领域。所述透明纸基烟包材料主要成分包括：植物微纳米纤维、施胶剂、交联剂、助留助滤剂、水分调节剂。所述透明纸基烟包材料的制备方法为：将植物纤维浆料处理得到植物微纳米纤维，通过单长网纸机或多长网纸机或多圆网纸机单层或多层抄造得到透明纸基烟包材料，所述透明纸基烟包材料定量为180‑250g/m2，应用于卷烟的外包装，具有透明度高，香气阻隔保存性好，美观，环境友好等优势。

Description

一种透明纸基烟包材料及其制备方法
技术领域
本发明涉及造纸技术领域，具体是一种透明纸基烟包材料及其制备方法。
背景技术
香烟包装是一种非常独特的包装产品，它不仅是一个品牌的象征，更是一种文化和精神的体现，为了彰显香烟品牌的与众不同，香烟包装正在经历着由普通加工品向艺术品的转变过程。
对卷制好的烟支进行包装，方能成为上市的香烟商品。香烟包装的作用：一是便于消费者识别和享用。有良好内在品质的香烟，靠美观高雅的包装，才能让消费者认可和喜欢，进而树立起品牌的形象，香烟成为社会交际的手段，也有赖于它具有美好的外观，香烟的外包装还是其产品档次与规格的标识。二是保护产品品质。卷烟的包装能够在一定期限内保存烟支的水分，在潮湿季节防止霉变，在干燥季节防止空松，还能保持香精不至挥发，维持香气值。三是便于商业部门运输、仓储和销售。
目前市场上常见的香烟包装材料为白卡纸、白纸板、铜版纸、箱纸板、真空镀铝纸、BOPP烟膜等材料，在卷烟透明包装应用方面，主要为石油产品制造的塑料膜材料，而且是局部应用，不易降解，对环保带来危害。
发明内容
针对现有技术的缺点和不足，本发明的首要目的在于提供一种透明纸基烟包材料及其制备方法，解决现有技术中透明包装材料的局限，所制备的透明纸基烟包材料应用于卷烟包装，香气保留性佳，美观高雅，环境友好。
本发明提供了一种透明纸基烟包材料，包括如下成分：植物微纳米纤维、施胶剂、交联剂、助留助滤剂、水分调节剂。
进一步的，所述透明纸基烟包材料中各成分按质量份数为：植物微纳米纤维100份，施胶剂0.05-2份，交联剂0.02-0.1份，助留助滤剂0.05-0.2份，水分调节剂0.05-0.1份。
进一步的，所述植物微纳米纤维为植物纤维浆料经处理后得到，所述处理方式为将植物纤维浆料加入到卤化物醇溶液中预处理，然后加入碱醇溶液加热高速搅拌反应，反应结束后洗涤，即得到植物微纳米纤维。
进一步的，所述施胶剂包括松香、烷基烯酮二聚体（AKD）、马来酸酐、烯基琥珀酸酐、改性淀粉、聚乙烯醇（PVA）、石蜡胶、硬脂酸胶、石油树脂、羧甲基纤维素、甲基纤维素、羟乙基纤维素、酚醛树脂、壳聚糖、苯丙胶乳、丙烯酸胶乳或丁苯胶乳中的一种或两种以上。
进一步的，所述交联剂包括异氰酸酯、醛类化合物、乙烯砜类化合物、硼酸、硼砂类化合物、金属离子类化合物或碳酸锆盐中的一种或两种以上。
进一步的，所述助留助滤剂包括聚合氯化铝、阳离子淀粉、两性淀粉、阳离子聚丙烯酰胺、微聚物（Micropolymer）、聚酰胺多胺环氧氯丙烷、膨润土中的一种或两种以上，一般是采取多元系统较为合适。
进一步的，所述水分调节剂为纤维素衍生物。
本发明还提供了一种透明纸基烟包材料的制备方法，包括以下步骤：
（1）植物微纳米纤维素制备，将植物纤维浆料加入到卤化物醇溶液中预处理，然后加入碱醇溶液加热高速搅拌反应，反应结束后洗涤，即得到植物微纳米纤维。
（2）上网浆料配制，将植物微纳米纤维100份，施胶剂0.05-2份，交联剂0.02-0.1份，助留助滤剂0.05-0.2份，水分调节剂0.05-0.1份混合均匀，配制成浆。
（3）通过单长网纸机或多长网纸机或多圆网纸机单层或多层抄造制备透明纸基烟包材料，所述抄造的单层定量为60-250g/m2，透明纸基烟包材料总定量为180-250 g/m2。
进一步的，步骤（1）中所述卤化物醇溶液中溶质为3-氯-2-羟丙基三甲基氯化铵，3-氯-2-羟基丙磺酸钠，一氯乙酸，二氯乙酸，三氯乙酸或氯乙酸钠中的一种或两种以上，溶剂为甲醇、乙醇或异丙醇中的一种或两种以上，卤化物醇溶液的质量浓度为5.0~10.0%；所述植物纤维浆料中绝干浆与卤化物的质量比为1:0.3~0.8；所述预处理采用高速搅拌，搅拌速度1500-3000r/min，搅拌时间为5-10min。
进一步的，步骤（1）中所述碱醇溶液中溶质为甲醇钠、乙醇钠、乙醇钾、乙醇胺、叔丁醇钠、季铵碱、氢氧化钾、氢氧化钠或氢氧化锂中的一种或两种以上，溶剂为甲醇、乙醇或异丙醇中的一种或两种以上，碱醇溶液的质量浓度为14%-30%；所述预处理浆料中卤化物与所述碱醇溶液中溶质的质量比为1:0.8-1.2；所述加热高速搅拌温度为40-80℃，搅拌速度为1500-3000r/min，搅拌时间为30-120min；所述浆料洗涤的次数为1-3次。
与现有技术相比，本发明具有如下优点和有益效果：
本发明所用原材料为植物纤维浆料，制备得到的透明纸基烟包材料透明度高，制成烟盒后，可透过烟盒看到烟支，半透明的朦胧感给卷烟包装带来新的灵感，美观高雅，同时透明纸基烟包材料结构紧密，香气保留性佳，环境友好。
具体实施方式
以下结合实例对本发明的具体实施作进一步说明，但本发明的实施和保护不限于此。
实施例1
透明纸基烟包材料定量180g/m2，成分组成：植物微纳米纤维100kg，施胶剂0.05kg，交联剂0.02kg，助留助滤剂0.06kg，水分调节剂0.06kg。
制备方法如下：
（a）植物微纳米纤维素制备，将植物纤维浆料110kg加入到质量浓度为5.0%的3-氯-2-羟丙基三甲基氯化铵-异丙醇溶液中，绝干植物纤维浆料与3-氯-2-羟丙基三甲基氯化铵的质量比为1：0.8，在1500r/min转速下高速搅拌5min，加入质量浓度20%的氢氧化钠/异丙醇溶液，3-氯-2-羟丙基三甲基氯化铵与氢氧化钠的质量比为1:1.2，加热至80℃，搅拌30min，搅拌速度为1500r/min，反应结束后洗涤3次，即得到植物微纳米纤维。
（b）上网浆料配制，将植物微纳米纤维100kg，施胶剂0.05kg，交联剂0.02kg，助留助滤剂0.06kg，水分调节剂0.06kg混合均匀，配制成浆。
（c）通过单长网纸机一次成形抄造制备透明纸基烟包材料，透明纸基烟包材料定量为180 g/m2。
上述实施例中所述施胶剂为烷基烯酮二聚体，交联剂为乙二醛，助留助滤剂为阳离子淀粉，水分调节剂为羧甲基纤维素。
实施例2
透明纸基烟包材料定量200g/m2，成分组成：植物微纳米纤维100kg，施胶剂0.5kg，交联剂0.08kg，助留助滤剂0.05kg，水分调节剂0.05kg。
制备方法如下：
（a）植物微纳米纤维素制备，将植物纤维浆料110kg加入到质量浓度为8.0%的3-氯-2-羟基丙磺酸钠-乙醇溶液中，绝干植物纤维浆料与3-氯-2-羟基丙磺酸钠的质量比为1：0.5，在2000r/min转速下高速搅拌8min，加入质量浓度30%的乙醇胺/乙醇溶液，3-氯-2-羟基丙磺酸钠与乙醇胺的质量比为1:1，加热至60℃，搅拌60min，搅拌速度为2000r/min，反应结束后洗涤1次，即得到植物微纳米纤维。
（b）上网浆料配制，将植物微纳米纤维100kg，施胶剂0.5kg，交联剂0.08kg，助留助滤剂0.05kg，水分调节剂0.05kg混合均匀，配制成浆。
（c）通过双长网纸机两次成形抄造制备透明纸基烟包材料，单层均为100g/m2，透明纸基烟包材料定量为200 g/m2。
上述实施例中所述施胶剂为改性淀粉，交联剂为硼酸，助留助滤剂为膨润土和微聚物，膨润土：微聚物比例为10:1，水分调节剂为羟乙基纤维素。
实施例3
透明纸基烟包材料定量250g/m2，成分组成：植物微纳米纤维100kg，施胶剂2kg，交联剂0.1kg，助留助滤剂0.2kg，水分调节剂0.1kg。
制备方法如下：
（a）植物微纳米纤维素制备，将植物纤维浆料110kg加入到质量浓度为10.0%的一氯乙酸-甲醇溶液中，绝干植物纤维浆料与一氯乙酸的质量比为1：0.3，在3000r/min转速下高速搅拌10min，加入质量浓度14%的乙醇钠/甲醇溶液，一氯乙酸与乙醇钠的质量比为1:0.8，加热至40℃，搅拌120min，搅拌速度为3000r/min，反应结束后洗涤2次，即得到植物微纳米纤维。
（b）上网浆料配制，植物微纳米纤维100kg，施胶剂2kg，交联剂0.1kg，助留助滤剂0.2kg，水分调节剂0.1kg混合均匀，配制成浆。
（c）通过四圆网纸机四次成形抄造制备透明纸基烟包材料，各层定量分别为60 g/m2,60 g/m2,60 g/m2,70g/m2，透明纸基烟包材料定量为250 g/m2。
上述实施例中所述施胶剂为松香，交联剂为碳酸锆铵，助留助滤剂为聚合氯化铝，水分调节剂为羧甲基纤维素。
根据实施例1-3所制备的透明纸基烟包材料性能如表1所示。
表1
定量 厚度 挺度 抗张强度（纵/横） 耐折度（纵/横） 氧气透过量 水蒸气透过量 透明度
单位 g/m<sup>2</sup> um mN.m kN/m 次 cm<sup>3</sup>/（m<sup>2</sup>·24h·0.1MPa） g/（m<sup>2</sup>·24h） %
实施例1制得产品 180 225 6.4/3.0 15.4/8.2 420/210 2000 6.3 80
实施例2制得产品 200 250 7.0/3.3 16.1/8.4 431/221 1890 6.1 78
实施例3制得产品 250 315 7.5/3.5 16.6/8.8 445/238 1600 5.4 75
上述实施例为本发明较佳的实施方式，但本发明的实施方式并不受上述实施例的限制,其它的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化，均应为等效的置换方式，都包含在本发明的保护范围之内。

Claims (8)

1.一种透明纸基烟包材料，其特征在于，所述透明纸基烟包材料包括如下成分：植物微纳米纤维、施胶剂、交联剂、助留助滤剂和水分调节剂；所述透明纸基烟包材料中各成分按质量份数为：植物微纳米纤维100份，施胶剂0.05-2份，交联剂0.02-0.1份，助留助滤剂0.05-0.2份，水分调节剂0.05-0.1份；所述植物微纳米纤维为植物纤维浆料经处理后得到，所述处理的方式为将植物纤维浆料加入到卤化物醇溶液中预处理，然后加入碱醇溶液加热高速搅拌反应，反应结束后洗涤。
2.根据权利要求1所述的一种透明纸基烟包材料，其特征在于所述施胶剂包括松香、烷基烯酮二聚体（AKD）、马来酸酐、烯基琥珀酸酐、改性淀粉、聚乙烯醇（PVA）、石蜡胶、硬脂酸胶、石油树脂、羧甲基纤维素、甲基纤维素、羟乙基纤维素、酚醛树脂、壳聚糖、苯丙胶乳、丙烯酸胶乳或丁苯胶乳中的一种或两种以上。
3.根据权利要求1所述的一种透明纸基烟包材料，其特征在于所述交联剂包括异氰酸酯、醛类化合物、乙烯砜类化合物、硼酸、硼砂类化合物、金属离子类化合物或碳酸锆盐中的一种或两种以上。
4.根据权利要求1所述的一种透明纸基烟包材料，其特征在于所述助留助滤剂包括聚合氯化铝、阳离子淀粉、两性淀粉、阳离子聚丙烯酰胺、微聚物（Micropolymer）、聚酰胺多胺环氧氯丙烷、膨润土中的一种或两种以上。
5.根据权利要求1所述的一种透明纸基烟包材料，其特征在于所述水分调节剂为纤维素衍生物。
6.一种制备权利要求 1~5任一项所述透明纸基烟包材料的制备方法，其特征在于包括以下步骤：
（1）植物微纳米纤维素制备：将植物纤维浆料加入到卤化物醇溶液中预处理，然后加入碱醇溶液加热高速搅拌反应，反应结束后洗涤，即得到植物微纳米纤维；
（2）上网浆料配制，按质量份计，将植物微纳米纤维100份，施胶剂0.05-2份，交联剂0.02-0.1份，助留助滤剂0.05-0.2份，水分调节剂0.05-0.1份混合均匀，配制成浆；
（3）通过单长网纸机或多长网纸机或多圆网纸机单层或多层抄造制备透明纸基烟包材料，所述抄造的单层定量为60-250g/m2，透明纸基烟包材料总定量为180-250 g/m2。
7.根据权利要求6所述的制备方法，其特征在于所述卤化物醇溶液中溶质为3-氯-2-羟丙基三甲基氯化铵，3-氯-2-羟基丙磺酸钠，一氯乙酸，二氯乙酸，三氯乙酸或氯乙酸钠中的一种或两种以上，溶剂为甲醇、乙醇或异丙醇中的一种或两种以上，卤化物醇溶液的质量浓度为5.0~10.0%；所述植物纤维浆料中绝干浆与卤化物的质量比为1:0.3~0.8；所述预处理采用高速搅拌，搅拌速度1500-3000r/min，搅拌时间为5-10min。
8.根据权利要求6所述的制备方法，其特征在于所述碱醇溶液中溶质为甲醇钠、乙醇钠、乙醇钾、乙醇胺、叔丁醇钠、季铵碱、氢氧化钾、氢氧化钠或氢氧化锂中的一种或两种以上，溶剂为甲醇、乙醇或异丙醇中的一种或两种以上，碱醇溶液的质量浓度为14%-30%；所述预处理浆料中卤化物与所述碱醇溶液中溶质的质量比为1:0.8-1.2；所述加热高速搅拌温度为40-80℃，搅拌速度为1500-3000r/min，搅拌时间为30-120min；所述浆料洗涤的次数为1-3次。
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