CN109137482A - A kind of preparation method of air-permeable cool type finishing agent - Google Patents

A kind of preparation method of air-permeable cool type finishing agent Download PDF

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Publication number
CN109137482A
CN109137482A CN201810869967.1A CN201810869967A CN109137482A CN 109137482 A CN109137482 A CN 109137482A CN 201810869967 A CN201810869967 A CN 201810869967A CN 109137482 A CN109137482 A CN 109137482A
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calcium carbonate
essential oil
porous calcium
parts
artemisia annua
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李德喜
陈宗明
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Suzhou City Tianao Special Embroidery Co Ltd
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Suzhou City Tianao Special Embroidery Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing Of Micro-Capsules (AREA)

Abstract

The present invention provides a kind of preparation methods of air-permeable cool type finishing agent, comprising the following steps: S1. prepares modified artemisia annua essential oil Nano capsule；S2. porous calcium carbonate microballoon is prepared；S3. surface water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal are prepared；S4. the porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is prepared；S5. 30-50 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil is weighed by weight, 300-400 parts of deionized water, 50-80 parts of Sodium Polyacrylate, it is 40-70 parts of organic silicone oil, 8-15 parts of dodecyl sodium sulfate, then that Sodium Polyacrylate is soluble in water, the porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, supersonic oscillations, add organic silicone oil and dodecyl sodium sulfate stirs to get air-permeable cool type finishing agent.The cooling effect of finishing agent of the invention is good and washable lasting.

Description

A kind of preparation method of air-permeable cool type finishing agent
Technical field
The present invention relates to textile finshing agent fields, and in particular to a kind of preparation method of air-permeable cool type finishing agent.
Background technique
With the development of science and technology, the improvement of people's living standards, requirement of the people to quality of life is also higher and higher, it should The appearance of the fabric of a large amount of functional form, meets requirement of the people to quality of life.The body temperature of human normal is 37 DEG C or so, When environment temperature is higher than this temperature, the body of people just may feel that discomfort, if radiating not in time, it is existing to will appear heatstroke etc. As to influence the comfort of human body.The fabric for much just having excellent thermally conductive moisture-inhibiting function has been developed at present, still The function of fabric also determines the expensive of fabric, thus defines the range using crowd, is difficult in many people popular Get up, it is therefore desirable to it researches and develops a kind of cheap, is applicable in the fabric of the majority of consumers, and material treatment agent is as the fabric later period Arrangement equally can be fabric and have different functions.
Summary of the invention
Technical problems to be solved: the object of the present invention is to provide a kind of air-permeable cool type finishing agents, have simple whole Reason mode is obtained with corresponding function, while being suitble to promote and apply.
A kind of technical solution: preparation method of air-permeable cool type finishing agent, comprising the following steps:
S1. the Cetyltrimethylammonium bromide of 0.2-0.5g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then will 100m hexadecane, 8-15g ethyl orthosilicate and 3-5g artemisia annua essential oil, which are uniformly mixed, obtains mixed solution B, by mixed solution A and 5-15min is mixed in mixed solution B, and then ultrasonic shear 20-60min, shearing power 3000-5000W are again heated to 50 DEG C are stirred to react 12h with the speed of 400r/min, are eventually adding silane coupling A -174, and modified artemisia annua essential oil nanometer is made Capsule；
S2. by CaCl2Solution, SDS solution and Na2CO3Solution is that 1:2:1 is successively mixed by volume, wherein Ca2+And CO3 2- Molar ratio be 1:1, be collected by centrifugation precipitating, after washing and drying, sediment calcined into 80-120min at 320-400 DEG C, is obtained Porous calcium carbonate microballoon；
S3. the porous calcium carbonate microballoon prepared by step S2 is as in filter screen, the palm for being 8-12wt% by mass fraction Sour toluene solution pours into sieve, drains to solvent in sieve, then the porous calcium carbonate microballoon being filtered for multiple times in washing sieve, obtains To surface water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal；
S4. modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon 1:1-3 in mass ratio are added to absolute ethanol, are first stirred 20-45min is mixed, then ultrasonic shear 10-30min, ultrasonic power 1500-2500W obtains nanometre glue containing artemisia annua essential oil The porous calcium carbonate microballoon of capsule；
S5. 30-50 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil, deionization are weighed by weight 300-400 parts of water, 50-80 parts of Sodium Polyacrylate, 40-70 parts of organic silicone oil, 8-15 parts of dodecyl sodium sulfate, then by poly- third Olefin(e) acid sodium is soluble in water, and the porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, ultrasound Wave vibrates 60-80min, adds organic silicone oil and dodecyl sodium sulfate stirs to get the arrangement of air-permeable cool type Agent.
The utility model has the advantages that air-permeable cool type finishing agent of the invention, by addition artemisia annua essential oil, artemisia annua essential oil has good Cooling effect, it is compound by preparing modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon, the finishing agent of preparation it is refrigerant Effect is lasting, while porous calcium carbonate also has good air permeability effect.
Specific embodiment
Embodiment 1
A kind of preparation method of air-permeable cool type finishing agent, which comprises the following steps:
S1. the Cetyltrimethylammonium bromide of 0.2g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then by 100m Hexadecane, 15g ethyl orthosilicate and 3g artemisia annua essential oil are uniformly mixed and obtain mixed solution B, by mixed solution A and mixed solution 5min is mixed in B, and then ultrasonic shear 60min, shearing power 5000W, are again heated to 50 DEG C of speed with 400r/min Degree is stirred to react 12h, is eventually adding silane coupling A -174, and modified artemisia annua essential oil Nano capsule is made；
S2. by CaCl2Solution, SDS solution and Na2CO3Solution is that 1:2:1 is successively mixed by volume, wherein Ca2+And CO3 2- Molar ratio be 1:1, be collected by centrifugation precipitating, after washing and drying, sediment calcined into 120min at 320 DEG C, obtains porous carbon Sour calcium microballoon；
S3. the porous calcium carbonate microballoon prepared by step S2 is as in filter screen, the palmitinic acid first for being 8wt% by mass fraction Benzole soln pours into sieve, drains to solvent in sieve, then the porous calcium carbonate microballoon being filtered for multiple times in washing sieve, obtains table Face water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal；
S4. modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon 1:1 in mass ratio are added to absolute ethanol, are first stirred 20min, then ultrasonic shear 30min, ultrasonic power 1500W, obtain the porous carbonic acid of the Nano capsule containing artemisia annua essential oil Calcium microballoon；
S5. 50 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil, deionized water are weighed by weight 300 parts, 50 parts of Sodium Polyacrylate, 70 parts of organic silicone oil, 15 parts of dodecyl sodium sulfate, Sodium Polyacrylate is then dissolved in water In, the porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, supersonic oscillations 60min, It adds organic silicone oil and dodecyl sodium sulfate stirs to get air-permeable cool type finishing agent.
Embodiment 2
A kind of preparation method of air-permeable cool type finishing agent, which comprises the following steps:
S1. the Cetyltrimethylammonium bromide of 0.5g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then by 100m Hexadecane, 8g ethyl orthosilicate and 5g artemisia annua essential oil are uniformly mixed and obtain mixed solution B, by mixed solution A and mixed solution B 15min is mixed, then ultrasonic shear 20min, shearing power 3000W, are again heated to 50 DEG C of speed with 400r/min Degree is stirred to react 12h, is eventually adding silane coupling A -174, and modified artemisia annua essential oil Nano capsule is made；
S2. by CaCl2Solution, SDS solution and Na2CO3Solution is that 1:2:1 is successively mixed by volume, wherein Ca2+And CO3 2- Molar ratio be 1:1, be collected by centrifugation precipitating, after washing and drying, sediment calcined into 80min at 400 DEG C, obtains porous carbonic acid Calcium microballoon；
S3. the porous calcium carbonate microballoon prepared by step S2 is as in filter screen, the palmitinic acid for being 12wt% by mass fraction Toluene solution pours into sieve, drains to solvent in sieve, then the porous calcium carbonate microballoon being filtered for multiple times in washing sieve, obtains Surface water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal；
S4. modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon 1:3 in mass ratio are added to absolute ethanol, are first stirred 45min, then ultrasonic shear 10min, ultrasonic power 2500W, obtain the porous carbonic acid of the Nano capsule containing artemisia annua essential oil Calcium microballoon；
S5. 30 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil, deionized water are weighed by weight It is 400 parts, 80 parts of Sodium Polyacrylate, 40 parts of organic silicone oil, 8 parts of dodecyl sodium sulfate, then that Sodium Polyacrylate is soluble in water, The porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, supersonic oscillations 80min, then plus Enter organic silicone oil and dodecyl sodium sulfate stirs to get air-permeable cool type finishing agent.
Embodiment 3
A kind of preparation method of air-permeable cool type finishing agent, which comprises the following steps:
S1. the Cetyltrimethylammonium bromide of 0.3g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then by 100m Hexadecane, 10g ethyl orthosilicate and 5g artemisia annua essential oil are uniformly mixed and obtain mixed solution B, by mixed solution A and mixed solution 8min is mixed in B, and then ultrasonic shear 30min, shearing power 3500W, are again heated to 50 DEG C of speed with 400r/min Degree is stirred to react 12h, is eventually adding silane coupling A -174, and modified artemisia annua essential oil Nano capsule is made；
S2. by CaCl2Solution, SDS solution and Na2CO3Solution is that 1:2:1 is successively mixed by volume, wherein Ca2+And CO3 2- Molar ratio be 1:1, be collected by centrifugation precipitating, after washing and drying, sediment calcined into 110min at 370 DEG C, obtains porous carbon Sour calcium microballoon；
S3. the porous calcium carbonate microballoon prepared by step S2 is as in filter screen, the palmitinic acid first for being 9wt% by mass fraction Benzole soln pours into sieve, drains to solvent in sieve, then the porous calcium carbonate microballoon being filtered for multiple times in washing sieve, obtains table Face water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal；
S4. modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon 1:1 in mass ratio are added to absolute ethanol, are first stirred 40min, then ultrasonic shear 15min, ultrasonic power 1800W, obtain the porous carbonic acid of the Nano capsule containing artemisia annua essential oil Calcium microballoon；
S5. 35 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil, deionized water are weighed by weight It is 320 parts, 60 parts of Sodium Polyacrylate, 50 parts of organic silicone oil, 9 parts of dodecyl sodium sulfate, then that Sodium Polyacrylate is soluble in water, The porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, supersonic oscillations 65min, then plus Enter organic silicone oil and dodecyl sodium sulfate stirs to get air-permeable cool type finishing agent.
Embodiment 4
A kind of preparation method of air-permeable cool type finishing agent, which comprises the following steps:
S1. the Cetyltrimethylammonium bromide of 0.4g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then by 100m Hexadecane, 14g ethyl orthosilicate and 3g artemisia annua essential oil are uniformly mixed and obtain mixed solution B, by mixed solution A and mixed solution 12min is mixed in B, and then ultrasonic shear 50min, shearing power 4500W, are again heated to 50 DEG C of speed with 400r/min Degree is stirred to react 12h, is eventually adding silane coupling A -174, and modified artemisia annua essential oil Nano capsule is made；
S2. by CaCl2Solution, SDS solution and Na2CO3Solution is that 1:2:1 is successively mixed by volume, wherein Ca2+And CO3 2- Molar ratio be 1:1, be collected by centrifugation precipitating, after washing and drying, sediment calcined into 90min at 340 DEG C, obtains porous carbonic acid Calcium microballoon；
S3. the porous calcium carbonate microballoon prepared by step S2 is as in filter screen, the palmitinic acid for being 11wt% by mass fraction Toluene solution pours into sieve, drains to solvent in sieve, then the porous calcium carbonate microballoon being filtered for multiple times in washing sieve, obtains Surface water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal；
S4. modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon 1:3 in mass ratio are added to absolute ethanol, are first stirred 25min, then ultrasonic shear 25min, ultrasonic power 2200W, obtain the porous carbonic acid of the Nano capsule containing artemisia annua essential oil Calcium microballoon；
S5. 45 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil, deionized water are weighed by weight 380 parts, 70 parts of Sodium Polyacrylate, 60 parts of organic silicone oil, 14 parts of dodecyl sodium sulfate, Sodium Polyacrylate is then dissolved in water In, the porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, supersonic oscillations 75min, It adds organic silicone oil and dodecyl sodium sulfate stirs to get air-permeable cool type finishing agent.
Embodiment 5
A kind of preparation method of air-permeable cool type finishing agent, which comprises the following steps:
S1. the Cetyltrimethylammonium bromide of 0.3g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then by 100m Hexadecane, 10g ethyl orthosilicate and 5g artemisia annua essential oil are uniformly mixed and obtain mixed solution B, by mixed solution A and mixed solution 8min is mixed in B, and then ultrasonic shear 50min, shearing power 3500W, are again heated to 50 DEG C of speed with 400r/min Degree is stirred to react 12h, is eventually adding silane coupling A -174, and modified artemisia annua essential oil Nano capsule is made；
S2. by CaCl2Solution, SDS solution and Na2CO3Solution is that 1:2:1 is successively mixed by volume, wherein Ca2+And CO3 2- Molar ratio be 1:1, be collected by centrifugation precipitating, after washing and drying, sediment calcined into 100min at 360 DEG C, obtains porous carbon Sour calcium microballoon；
S3. the porous calcium carbonate microballoon prepared by step S2 is as in filter screen, the palmitinic acid for being 10wt% by mass fraction Toluene solution pours into sieve, drains to solvent in sieve, then the porous calcium carbonate microballoon being filtered for multiple times in washing sieve, obtains Surface water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal；
S4. modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon 1:1-3 in mass ratio are added to absolute ethanol, are first stirred 30min is mixed, then ultrasonic shear 20min, ultrasonic power 2000W obtains the porous carbon of the Nano capsule containing artemisia annua essential oil Sour calcium microballoon；
S5. 40 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil, deionized water are weighed by weight 350 parts, 65 parts of Sodium Polyacrylate, 55 parts of organic silicone oil, 12 parts of dodecyl sodium sulfate, Sodium Polyacrylate is then dissolved in water In, the porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, supersonic oscillations 70min, It adds organic silicone oil and dodecyl sodium sulfate stirs to get air-permeable cool type finishing agent.
Comparative example 1
A kind of preparation method of air-permeable cool type finishing agent, which comprises the following steps:
S1. the Cetyltrimethylammonium bromide of 0.5g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then by 100m Hexadecane, 8g ethyl orthosilicate and 5g artemisia annua essential oil are uniformly mixed and obtain mixed solution B, by mixed solution A and mixed solution B 15min is mixed, then ultrasonic shear 20min, shearing power 3000W, are again heated to 50 DEG C of speed with 400r/min Degree is stirred to react 12h, is eventually adding silane coupling A -174, and modified artemisia annua essential oil Nano capsule is made；
S2. above-mentioned 30 parts of gained artemisia annua essential oil Nano capsule are weighed by weight, 400 parts of deionized water, 80 parts of Sodium Polyacrylate, 40 parts of organic silicone oil, 8 parts of dodecyl sodium sulfate, then that Sodium Polyacrylate is soluble in water, artemisia annua essential oil Nano capsule is added In aqueous sodium polyacrylate, supersonic oscillations 80min, adds organic silicone oil and dodecyl sodium sulfate is sufficiently stirred It is even to get air-permeable cool type finishing agent.
Fabric after dressing, using air-permeable cool type finishing agent carry out the arrangement of absorbing fast-drying cool feeling, dosage 60g/l, Processing method is second dipping and rolling, and pick-up rate 70% dries 130 DEG C, drying time 60 seconds, bakes 170 DEG C, bake the time 60 Second.
There is contact coldness performance to skin using GB/T 35263-2017 test.
Contact coldness evaluation of estimate (W/ (cm210 DEG C)) Contact coldness evaluation of estimate (W/ (cm210 DEG C)) (after washing 20 times)
Embodiment 1 0.117 0.107
Embodiment 2 0.122 0.110
Embodiment 3 0.131 0.117
Embodiment 4 0.119 0.110
Embodiment 5 0.123 0.114
Comparative example 1 0.119 0.075
Unfinished blank fabric 0.065 0.063
。

Claims (1)

1. a kind of preparation method of air-permeable cool type finishing agent, which comprises the following steps:
S1. the Cetyltrimethylammonium bromide of 0.2-0.5g is dissolved in 100mL water and be uniformly mixed and obtain mixed solution A, then will 100m hexadecane, 8-15g ethyl orthosilicate and 3-5g artemisia annua essential oil, which are uniformly mixed, obtains mixed solution B, by mixed solution A and 5-15min is mixed in mixed solution B, and then ultrasonic shear 20-60min, shearing power 3000-5000W are again heated to 50 DEG C are stirred to react 12h with the speed of 400r/min, are eventually adding silane coupling A -174, and modified artemisia annua essential oil nanometer is made Capsule；
S2. by CaCl2Solution, SDS solution and Na2CO3Solution is that 1:2:1 is successively mixed by volume, wherein Ca2+And CO3 2-'s Molar ratio is 1:1, is collected by centrifugation precipitating, after washing and drying, sediment is calcined 80-120min at 320-400 DEG C, is obtained more Hole calcium carbonate microspheres；
S3. the porous calcium carbonate microballoon prepared by step S2 is as in filter screen, the palm for being 8-12wt% by mass fraction Sour toluene solution pours into sieve, drains to solvent in sieve, then the porous calcium carbonate microballoon being filtered for multiple times in washing sieve, obtains To surface water repellent, the hydrophilic porous calcium carbonate microballoon of cellular internal；
S4. modified artemisia annua essential oil Nano capsule and porous calcium carbonate microballoon 1:1-3 in mass ratio are added to absolute ethanol, are first stirred 20-45min is mixed, then ultrasonic shear 10-30min, ultrasonic power 1500-2500W obtains nanometre glue containing artemisia annua essential oil The porous calcium carbonate microballoon of capsule；
S5. 30-50 parts of the porous calcium carbonate microballoon of above-mentioned gained Nano capsule containing artemisia annua essential oil, deionization are weighed by weight 300-400 parts of water, 50-80 parts of Sodium Polyacrylate, 40-70 parts of organic silicone oil, 8-15 parts of dodecyl sodium sulfate, then by poly- third Olefin(e) acid sodium is soluble in water, and the porous calcium carbonate microballoon of the Nano capsule containing artemisia annua essential oil is added in aqueous sodium polyacrylate, ultrasound Wave vibrates 60-80min, adds organic silicone oil and dodecyl sodium sulfate stirs to get the arrangement of air-permeable cool type Agent.
CN201810869967.1A 2018-08-02 2018-08-02 A kind of preparation method of air-permeable cool type finishing agent Pending CN109137482A (en)

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CN111485431A (en) * 2019-01-27 2020-08-04 广州山木新材料科技有限公司 Dyeing and finishing process of hydrophobic cool fabric
CN114960012A (en) * 2022-05-31 2022-08-30 广东电网有限责任公司 Cool fabric, preparation method thereof and gloves

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Application publication date: 20190104