CN109136897A - 一种氮化金属锰磷化液配方及其处理方法 - Google Patents

一种氮化金属锰磷化液配方及其处理方法 Download PDF

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CN109136897A
CN109136897A CN201811179986.8A CN201811179986A CN109136897A CN 109136897 A CN109136897 A CN 109136897A CN 201811179986 A CN201811179986 A CN 201811179986A CN 109136897 A CN109136897 A CN 109136897A
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zinc
nitrate
water
dihydrogen phosphate
formula
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高飞
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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Abstract

针对上述存在的技术问题,而提供一种具有挥发性弱,人体不直接接触液体,实用性强,与防锈油相比成本更低,保护时效更长,即使长期库存在仓库内也不会对环境造成二次污染氮化金属锰磷化配方,其成分是由:马日夫盐、磷酸二氢锌、硝酸锌、亚硝酸钠、硝酸镍、柠檬酸钠、十二烷基硫酸钠、水组成,本发明配方按如下质量组份配成:马日夫盐15‑20 g/L、磷酸二氢锌5‑10 g/L、硝酸锌50‑60 g/L、亚硝酸钠0.6‑1.2 g/L、硝酸镍1.0‑1.5 g/L、柠檬酸钠0.8‑1.1 g/L、十二烷基硫酸钠0‑0.9 g/L、余量为水。

Description

一种氮化金属锰磷化液配方及其处理方法
技术领域:
本发明属于表面氧化处理技术领域。具体涉及一种氮化金属锰磷化配方及其处理方法。
背景技术:
许多氮化金属产品都是采用刷防锈油来对其进行表面保护,这些被保护的氮化金属产品对于生产厂家或经销商来说或多或少的都会有一些库存,加之不是每一件产品都能在很短的时间内销售出去,这样一来就会造成产品有加压现象,随着时间的推移,被刷上去的防锈油要么被挥发要么干结附着在其产品的表面,影响产品的使用效果,同时防锈油有极强的挥发性,对车间生产环境也有一定的破坏,同样也给库存仓库造成二次污染,不利于工人生产和保管,影响工人的身心健康。
因此,研究一种氮化金属锰磷化配方及其处理方法就有着十分必要的现实意义。
发明内容:
针对上述存在的技术问题,而提供一种氮化金属锰磷化配方及其处理方法,其具有挥发性弱,人体不直接接触液体,实用性强,与防锈油相比成本更低,保护时效更长,即使长期库存在仓库内也不会对环境造成二次污染。
为达到上述目的,本发明所述的一种氮化金属锰磷化液配方,其成分由:马日夫盐、磷酸二氢锌、硝酸锌、亚硝酸钠、硝酸镍、柠檬酸钠、十二烷基硫酸钠、水组成,本发明配方按如下质量组份配成:马日夫盐15 -20 g/L、磷酸二氢锌5-10 g/L、硝酸锌50-60 g/L、亚硝酸钠0.6-1.2 g/L、硝酸镍1.0-1.5 g/L、柠檬酸钠0.8-1.1 g/L、十二烷基硫酸钠0-0.9g/L、余量为水。
为达到上述目的,本发明所述的一种氮化金属锰磷化液配方,其特征在于,本发明配方按如下质量组份配成:马日夫盐15 g/L、磷酸二氢锌5L、硝酸锌50 g/L、亚硝酸钠0.6g/L、硝酸镍1.0 g/L、柠檬酸钠0.8 g/L、十二烷基硫酸钠0.1 g/L、余量为水。
为达到上述目的,本发明所述的一种氮化金属锰磷化液配方,其特征在于,本发明配方按如下质量组份配成:马日夫盐18 g/L、磷酸二氢锌8 g/L、硝酸锌55 g/L、亚硝酸钠0.8 g/L、硝酸镍1.2g/L、柠檬酸钠0.9g/L、十二烷基硫酸钠0.2g/L、余量为水。
为达到上述目的,本发明所述的一种氮化金属锰磷化配方,其特征在于,本发明配方按如下质量组份配成:马日夫盐20 g/L、磷酸二氢锌10 g/L、硝酸锌60 g/L、亚硝酸钠1.0g/L、硝酸镍1.5 g/L、柠檬酸钠1.0g/L、十二烷基硫酸钠0.3 g/L、余量为水。
为达到上述目的,本发明所述的一种氮化金属锰磷化液配方所采用的处理方法,其特征在于,将配方好的锰磷化液升温至95±3℃,将金属工件浸入其中浸泡30±5秒钟,工件在温为95±3℃的锰磷化液内上下震荡,震荡时不露出液面,时间结束后用热水清洗60±10秒钟,再冷水清洗30±10秒钟,冷水温度为常温,再浸入烘箱烘干。
具体实施方式:
本发明一种金属锰磷化配方及其处理方法优选的实施例一中,按如下重量百分比组成: 本发明配方按如下质量组份配成:马日夫盐15 g/L、磷酸二氢锌5L、硝酸锌50 g/L、亚硝酸钠0.6g/L、硝酸镍1.0 g/L、柠檬酸钠0.8 g/L、十二烷基硫酸钠0.1 g/L、余量为水。
本发明一种金属锰磷化配方及其处理方法优选的实施例二中,按如下质量组份配成:马日夫盐18 g/L、磷酸二氢锌8 g/L、硝酸锌55 g/L、亚硝酸钠0.8 g/L、硝酸镍1.2g/L、柠檬酸钠0.9g/L、十二烷基硫酸钠0.2g/L、余量为水。
本发明一种金属锰磷化配方及其处理方法优选的实施例三中,按如下质量组份配成:马日夫盐20 g/L、磷酸二氢锌10 g/L、硝酸锌60 g/L、亚硝酸钠1.0g/L、硝酸镍1.5 g/L、柠檬酸钠1.0g/L、十二烷基硫酸钠0.3 g/L、余量为水。
本发明所述的一种氮化金属锰磷化液配方所采用的处理方法是,将配方好的锰磷化液升温至95±3℃,将金属工件浸入其中浸泡30±5秒钟,工件在温为95±3℃的锰磷化液内上下震荡,震荡时不露出液面,时间结束后用热水清洗60±10秒钟,再冷水清洗30±10秒钟,冷水温度为常温,再浸入烘箱烘干。
针对上述存在的技术问题,而提供一种具有挥发性弱,人体不直接接触液体,实用性强,与防锈油相比成本更低,保护时效更长,即使长期库存在仓库内也不会对环境造成二次污染氮化金属锰磷化配方及其处理方法。
根据上述说明书的揭示和教导,本发明所属领域的技术人员还可以对上述实施方式重量百分比进行适当的变更和修改。因此,本发明并不局限于上面揭示和描述的具体实施方式,对本发明的一些修改和变更也应当落入本发明的权利要求的保护范围内。此外,尽管本说明书中使用了一些特定的术语,但这些术语只是为了方便说明,并不对本发明构成任何限制。

Claims (5)

1.一种氮化金属锰磷化液配方,其特征是由:马日夫盐、磷酸二氢锌、硝酸锌、亚硝酸钠、硝酸镍、柠檬酸钠、十二烷基硫酸钠、水组成,本发明配方按如下质量组份配成:马日夫盐15 -20 g/L、磷酸二氢锌5-10 g/L、硝酸锌50-60 g/L、亚硝酸钠0.6-1.2 g/L、硝酸镍1.0-1.5 g/L、柠檬酸钠0.8-1.1 g/L、十二烷基硫酸钠0-0.9 g/L、余量为水。
2.根据权利要求1所述的一种氮化金属锰磷化液配方,其特征在于,本发明配方按如下质量组份配成:马日夫盐15 g/L、磷酸二氢锌5L、硝酸锌50 g/L、亚硝酸钠0.6g/L、硝酸镍1.0 g/L、柠檬酸钠0.8 g/L、十二烷基硫酸钠0.1 g/L、余量为水。
3.根据权利要求1所述的一种氮化金属锰磷化液配方,其特征在于,本发明配方按如下质量组份配成:马日夫盐18 g/L、磷酸二氢锌8 g/L、硝酸锌55 g/L、亚硝酸钠0.8 g/L、硝酸镍1.2g/L、柠檬酸钠0.9g/L、十二烷基硫酸钠0.2g/L、余量为水。
4.根据权利要求1所述的一种氮化金属锰磷化配方,其特征在于,本发明配方按如下质量组份配成:马日夫盐20 g/L、磷酸二氢锌10 g/L、硝酸锌60 g/L、亚硝酸钠1.0g/L、硝酸镍1.5 g/L、柠檬酸钠1.0g/L、十二烷基硫酸钠0.3 g/L、余量为水。
5.根据权利要求1所述的一种氮化金属锰磷化液配方所采用的处理方法,其特征在于,将配方好的锰磷化液升温至95±3℃,将金属工件浸入其中浸泡30±5秒钟,工件在温为95±3℃的锰磷化液内上下震荡,震荡时不露出液面,时间结束后用热水清洗60±10秒钟,再冷水清洗30±10秒钟,冷水温度为常温,再浸入烘箱烘干。
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008146368A1 (ja) * 2007-05-30 2008-12-04 Shin-Etsu Chemical Co., Ltd. 高耐食性希土類永久磁石の製造方法及び使用方法
CN107419249A (zh) * 2017-05-12 2017-12-01 冯志海 一种钢铁无磷纳米陶化剂

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008146368A1 (ja) * 2007-05-30 2008-12-04 Shin-Etsu Chemical Co., Ltd. 高耐食性希土類永久磁石の製造方法及び使用方法
CN107419249A (zh) * 2017-05-12 2017-12-01 冯志海 一种钢铁无磷纳米陶化剂

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Application publication date: 20190104