CN109135352A - A kind of preparation method of nano anion slurry - Google Patents

A kind of preparation method of nano anion slurry Download PDF

Info

Publication number
CN109135352A
CN109135352A CN201810610639.XA CN201810610639A CN109135352A CN 109135352 A CN109135352 A CN 109135352A CN 201810610639 A CN201810610639 A CN 201810610639A CN 109135352 A CN109135352 A CN 109135352A
Authority
CN
China
Prior art keywords
parts
slurry
preparation
anion
solid solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810610639.XA
Other languages
Chinese (zh)
Inventor
陆嘉君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Cui Li Amperex Technology Ltd
Original Assignee
Taicang Cui Li Amperex Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Cui Li Amperex Technology Ltd filed Critical Taicang Cui Li Amperex Technology Ltd
Priority to CN201810610639.XA priority Critical patent/CN109135352A/en
Publication of CN109135352A publication Critical patent/CN109135352A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of preparation method of nano anion slurry, which is characterized in that formula is by following quality than content at being grouped as: deionized water: 100 parts；Tungsten bronze ferroelectric powder: 20~50 parts；Dispersing agent: 20~40 parts；Other auxiliary agents: 0~10 part；The tungsten bronze structure powder, partial size is less than 2 μm, including (Ca, Ba, Sr)3(La, Nd, Sm)3Ti5(Nb, Ta)5O30And its element doping solid solution, (Ca, Ba, Sr)4(La, Nd, Sm)2Ti4(Nb, Ta)6O30And its element doping solid solution, (Ca, Ba, Sr)5(La, Nd, Sm) Ti3(Nb, Ta)7O30And its one of element doping solid solution or combinations thereof；Production method is to sequentially add tungsten bronze ferroelectric nano particle, dispersing agent, other auxiliary agents in deionized water, obtains stable dispersion liquid slurry using 20~60min of revolving speed 8000~16000rpm homogenizer emulsifying homogeneous.The slurry is uniformly dispersed, anion generation efficiency is more traditional significantly improves by the product of anion functional component of tourmaline, for processing the function component of anion plastic thin slice after can be used for the compounding function component of functional paint, can also drying.

Description

A kind of preparation method of nano anion slurry
Technical field
The invention belongs to material chemistry technical fields, are related to a kind of preparation method of nano anion slurry.
Background technique
Medical field generally acknowledges that negative oxygen ion has human body and eliminates fatigue, activating cell, enhancing disease resistance and antiallergy energy The health-care effects such as power.Early stage generates anion using high-pressure electrostatic mode ionized air, but simultaneously can be with ozone, nitrogen oxides Concentration improves, and forms secondary pollution.Presently commercially available nano-negative ion powder and slurry generally use the tourmaline of micro/nano level As most important functional active components, anion luminous efficiency is limited, especially some because color, intensity etc. are required to electrical Stone additive amount has the coating strictly limited or polymer membrane material field, and actual anion generation efficiency further decreases.It is higher Powder occurs for the anion of effect and slurry is industry urgent problem to be solved.
Summary of the invention
In view of the shortcomings of the prior art, the purpose of the present invention is to provide a kind of preparation method of nano anion slurry, It is characterized in that, formula is by following quality than content at being grouped as: deionized water: 100 parts；Tungsten bronze ferroelectric powder: 10~ 50 parts；Dispersing agent: 20~40 parts；Other auxiliary agents: 0~10 part；The tungsten bronze structure powder, partial size is less than 2 μm, packet Include (Ca, Ba, Sr)3(La, Nd, Sm)3Ti5(Nb, Ta)5O30And its element doping solid solution, (Ca, Ba, Sr)4(La, Nd, Sm)2Ti4(Nb, Ta)6O30And its element doping solid solution, (Ca, Ba, Sr)5(La, Nd, Sm) Ti3(Nb, Ta)7O30And its element is mixed One of miscellaneous solid solution or combinations thereof；Production method be by tungsten bronze ferroelectric nano particle, dispersing agent, other auxiliary agents successively It is added in deionized water, stable dispersion liquid is obtained using 20~60min of revolving speed 8000~16000rpm homogenizer emulsifying homogeneous Slurry.
The tungsten bronze structure powder processing method includes ball milling, molten in sintering block-high speed planetary ball mill One of sol-gel synthesis.
The dispersing agent includes organic polyphosphate, arylate blocks polymer, propylene glycol block polyester, polyoxy third One of alkene polyoxyethylene copolymer or sodium polymethacrylate or combinations thereof.
Other described auxiliary agents include one of thickener, defoaming agent or combinations thereof.
The slurry is uniformly dispersed, anion generation efficiency is more traditional significant using tourmaline as the product of anion functional component It improves, for processing the function component of anion plastic thin slice after can be used for the compounding function component of functional paint, can also drying.
The contents of the present invention and feature have revealed that as above, however the present invention that describes of front only briefly or pertains only to this The specific part of invention, feature of the invention may be more than what content disclosed herein was related to.Therefore, protection model of the invention The revealed content of embodiment should be not limited to by enclosing, and should include the combination of all the elements embodied in different piece, with And it is various without departing substantially from replacement and modification of the invention, and covered by claims of the present invention.
Specific embodiment
Embodiment 1
A kind of preparation method of nano anion slurry, formula is by following quality than content at being grouped as:
Deionized water: 100 parts；
Ba3La3Ti5Ta5O30Powder: 30 parts；
Sodium polyphosphate: 40 parts；
Thickener sodium hydroxyethyl cellulose: 5 parts；
By the Ba that ball milling obtains in high speed planetary ball mill3La3Ti5Ta5O30Powder, sodium polyphosphate, thickener ethoxy Sodium cellulosate sequentially adds in deionized water, obtains stable dispersion using revolving speed 16000rpm homogenizer emulsifying homogeneous 20min Slurry material.Negative aeroion detector tests 8300/cm of anion generation concentration3。
Embodiment 2
A kind of preparation method of nano anion slurry, formula is by following quality than content at being grouped as:
Deionized water: 100 parts；
Sr4Nd2Ti4Nb6O30Powder: 50 parts；
Potassium polyphosphate: 40 parts；
The Sr that sol-gal process is synthesized4Nd2Ti4Nb6O30Powder, potassium polyphosphate sequentially add in deionized water, Stable dispersion liquid slurry is obtained using revolving speed 8000rpm homogenizer emulsifying homogeneous 20min.The test of negative aeroion detector is negative 11200/cm of ion generation concentration3。
Embodiment 3
A kind of preparation method of nano anion slurry, formula is by following quality than content at being grouped as:
Deionized water: 100 parts；
Ba5SmTi3Nb7O30Powder: 20 parts；
Sodium polyphosphate: 20 parts；
Thickener sodium hydroxyethyl cellulose: 10 parts；
By the Ba that ball milling obtains in high speed planetary ball mill5SmTi3Nb7O30Powder, sodium polyphosphate, thickener ethoxy Sodium cellulosate sequentially adds in deionized water, obtains stable dispersion using revolving speed 16000rpm homogenizer emulsifying homogeneous 20min Slurry material.Negative aeroion detector tests 6700/cm of anion generation concentration3。
Embodiment 4
A kind of preparation method of nano anion slurry, formula is by following quality than content at being grouped as:
Deionized water: 100 parts；
Sr3La3Ti5Nb5O30Powder: 30 parts；
Potassium polyphosphate: 30 parts；
Defoaming agent mineral oil: 3 parts；
The Sr that sol-gal process synthesis ball milling is obtained3La3Ti5Nb5O30Powder, potassium polyphosphate, defoaming agent mineral oil according to In secondary addition deionized water, stable dispersion liquid slurry is obtained using revolving speed 12000rpm homogenizer emulsifying homogeneous 60min.Air Anionic textiles instrument tests 7900/cm of anion generation concentration3。
Embodiment 5
A kind of preparation method of nano anion slurry, formula is by following quality than content at being grouped as:
Deionized water: 100 parts；
Sr4Nd2Ti4Ta6O30Powder: 10 parts；
Sodium polyphosphate: 20 parts；
By the Sr that ball milling obtains in high speed planetary ball mill4Nd2Ti4Ta6O30Powder, sodium polyphosphate sequentially add from In sub- water, stable dispersion liquid slurry is obtained using revolving speed 10000rpm homogenizer emulsifying homogeneous 30min.Negative aeroion detection Instrument tests 4600/cm of anion generation concentration3。
Embodiment 6
A kind of preparation method of nano anion slurry, formula is by following quality than content at being grouped as:
Deionized water: 100 parts；
CaBa4SmTi3Ta7O30Powder: 40 parts；
Potassium polyphosphate: 40 parts；
The CaBa that sol-gal process is synthesized4SmTi3Ta7O30Powder, potassium polyphosphate sodium sequentially add deionized water In, stable dispersion liquid slurry is obtained using revolving speed 10000rpm homogenizer emulsifying homogeneous 60min.Negative aeroion detector is surveyed Try 7900/cm of anion generation concentration3。

Claims (5)

1. a kind of preparation method of nano anion slurry, which is characterized in that formula is by following quality than content at being grouped as: Deionized water: 100 parts；Tungsten bronze ferroelectric powder: 10~50 parts；Dispersing agent: 20~40 parts；Other auxiliary agents: 0~10 part；Institute Tungsten bronze structure powder is stated, partial size is less than 2 μm, including (Ca, Ba, Sr)3(La, Nd, Sm)3Ti5(Nb, Ta)5O30And its Element doping solid solution, (Ca, Ba, Sr)4(La, Nd, Sm)2Ti4(Nb, Ta)6O30And its element doping solid solution, (Ca, Ba, Sr)5(La, Nd, Sm) Ti3(Nb, Ta)7O30And its one of element doping solid solution or combinations thereof；Production method is by tungsten blueness Copper ferroelectric nano particle, dispersing agent, other auxiliary agents sequentially add in deionized water, using revolving speed 8000~16000rpm homogeneous 20~60min of machine emulsifying homogeneous obtains stable dispersion liquid slurry.
2. a kind of preparation method of nano anion slurry according to claim 1, it is characterised in that: the tungsten bronze structure Ferroelectric powder processing method includes one of ball milling in sintering block-high speed planetary ball mill, sol-gal process synthesis.
3. a kind of preparation method of nano anion slurry according to claim 1, it is characterised in that: the dispersing agent includes Organic polyphosphate, arylate blocks polymer, propylene glycol block polyester, polyoxyethylene polyoxypropylene copolymer or poly- first One of base sodium acrylate or combinations thereof.
4. a kind of preparation method of nano anion slurry according to claim 1, it is characterised in that: other described auxiliary agent packets Include one of thickener, defoaming agent or combinations thereof.
5. nanometer prepared by a kind of preparation method of the nano anion slurry as described in Claims 1 to 4 any one is negative Ion slurry.
CN201810610639.XA 2018-06-07 2018-06-07 A kind of preparation method of nano anion slurry Withdrawn CN109135352A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810610639.XA CN109135352A (en) 2018-06-07 2018-06-07 A kind of preparation method of nano anion slurry

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810610639.XA CN109135352A (en) 2018-06-07 2018-06-07 A kind of preparation method of nano anion slurry

Publications (1)

Publication Number Publication Date
CN109135352A true CN109135352A (en) 2019-01-04

Family

ID=64801987

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810610639.XA Withdrawn CN109135352A (en) 2018-06-07 2018-06-07 A kind of preparation method of nano anion slurry

Country Status (1)

Country Link
CN (1) CN109135352A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111560198A (en) * 2020-04-17 2020-08-21 吴瑛 High-efficiency physical negative ion coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101249272A (en) * 2008-03-14 2008-08-27 南京师范大学 Nano composite negative ion material
CN105016728A (en) * 2014-04-23 2015-11-04 中国民航大学 Rear earth doped non-fullness tungsten bronze luminescence ferroelectric material and preparation method thereof
CN205145162U (en) * 2015-10-26 2016-04-13 郑安志 Dry -type dressing and goods thereof
CN107513293A (en) * 2017-08-10 2017-12-26 广州市黑本新材料科技有限公司 A kind of preparation method of caesium tungsten bronze modified powder and its slurry

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101249272A (en) * 2008-03-14 2008-08-27 南京师范大学 Nano composite negative ion material
CN105016728A (en) * 2014-04-23 2015-11-04 中国民航大学 Rear earth doped non-fullness tungsten bronze luminescence ferroelectric material and preparation method thereof
CN205145162U (en) * 2015-10-26 2016-04-13 郑安志 Dry -type dressing and goods thereof
CN107513293A (en) * 2017-08-10 2017-12-26 广州市黑本新材料科技有限公司 A kind of preparation method of caesium tungsten bronze modified powder and its slurry

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111560198A (en) * 2020-04-17 2020-08-21 吴瑛 High-efficiency physical negative ion coating and preparation method thereof

Similar Documents

Publication Publication Date Title
JP2018109030A (en) Cosmetic additive and cosmetic containing same
JP4073788B2 (en) Colloidal solution of metal nanoparticles, metal-polymer nanocomposite, and production method thereof
Liu et al. Nanoparticle morphology and film-forming behavior of polyacrylate/ZnO nanocomposite
CN105199587B (en) A kind of coating and preparation method thereof
TW201210947A (en) Sheet-shaped cerium oxide and petal-shaped cerium oxide powder which is aggregate of the sheet-shaped cerium oxide, process for production of the sheet-shaped cerium oxide and the petal-shaped cerium oxide powder, coated sheet-shaped cerium oxide and
Ding et al. Humic acid regulation of the environmental behavior and phytotoxicity of silver nanoparticles to Lemna minor
CN108676424A (en) A kind of water-soluble environment protective nano mill base and preparation method thereof
CN109135352A (en) A kind of preparation method of nano anion slurry
CN105601842A (en) Dispersing agent for dispersing micron-nano powder and preparation method and application thereof
CN109370344A (en) Zeolite negative ion paint
CN108559018A (en) Nano-scale water Narrow Molecular Weight Distribution acrylic acid copolymer ester and preparation method thereof
CN109796933A (en) It is a kind of efficiently to discharge tourmaline modified powder of anion and preparation method thereof
CN102581300A (en) Gold nano particle preparation method
JP2013036116A (en) Flaky silver particle of microscale and method for producing the same
CN105418841B (en) A kind of dispersant, its water-borne dispersions and its preparation and application for fluorescent whitening agent
CN104725934B (en) A kind of preparation method containing the cork paper water color ink carrying silver meerschaum anti-biotic material
Zhang et al. pH-responsive self-assembly of fluorophore-ended homopolymers
CN103992524A (en) Preparation method of fine dispersed nanometer rare earth/rubber ray radiation shield composite material
CN107619045A (en) A kind of method in situ for preparing small sized metallic oxide on graphene
CN109593400A (en) The application of nano-scale water Narrow Molecular Weight Distribution acrylic acid copolymer ester
TW201631114A (en) Water-dispersed aerogel and method of manufacturing the same
CN104409697B (en) Electric conduction MoS2 membrane and sodium ion battery prepared from electric conduction MoS2 membrane
CN105792796A (en) Water-based skin care agent
CN109276474A (en) A kind of preparation method of nano zine oxide/cationic polysaccharide hybrid nanomaterial
JP2022113918A (en) Nano platinum particle-containing resin fiber

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20190104

WW01 Invention patent application withdrawn after publication