CN109130565A - A kind of magnetic rolls pattern printed matter surely - Google Patents

A kind of magnetic rolls pattern printed matter surely Download PDF

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Publication number
CN109130565A
CN109130565A CN201810897259.9A CN201810897259A CN109130565A CN 109130565 A CN109130565 A CN 109130565A CN 201810897259 A CN201810897259 A CN 201810897259A CN 109130565 A CN109130565 A CN 109130565A
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CN
China
Prior art keywords
magnetic
layer
radium
light beam
printed matter
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Granted
Application number
CN201810897259.9A
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Chinese (zh)
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CN109130565B (en
Inventor
徐军
欧立国
杨建江
黄沫
李新建
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Changde Jinpeng Printing Co Ltd
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Changde Jinpeng Printing Co Ltd
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Priority to CN201810897259.9A priority Critical patent/CN109130565B/en
Publication of CN109130565A publication Critical patent/CN109130565A/en
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Publication of CN109130565B publication Critical patent/CN109130565B/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
    • B44F1/10—Changing, amusing, or secret pictures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/14—Multicolour printing
    • B41M1/18—Printing one ink over another
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/22—Metallic printing; Printing with powdered inks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/06—Veined printings; Fluorescent printings; Stereoscopic images; Imitated patterns, e.g. tissues, textiles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14—Security printing
    • B41M3/148—Transitory images, i.e. images only visible from certain viewing angles

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Vascular Medicine (AREA)
  • Printing Methods (AREA)
  • Laminated Bodies (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Credit Cards Or The Like (AREA)

Abstract

The invention discloses a kind of magnetic to roll pattern printed matter, including radium-shine light beam paper, and the magnetic paint layer successively printed from inside to outside on the radium-shine light beam paper, plain net flower bottom, pattern level middle tone layer surely.Wherein: radium-shine light beam paper is as printing element；Magnetic paint layer is that magnetic powder is printed on printing element by magnetic orientation printing technology into magnetic paint layer；Lead to the background color layer of version printing carried out by plain net flower bottom using blue ink；Pattern level middle tone layer is the floral designs layer of blue ink print in use, and floral designs region has a performance of middle tone level, background area vacates, not ink.Realize stereoscopic effect and the anti-fake function of magnetic recording information.

Description

A kind of magnetic rolls pattern printed matter surely
Technical field
The present invention relates to printed matter technical field, especially a kind of magnetic rolls pattern printed matter surely.
Background technique
Printed matter has become part indispensable in modern society, is widely used in newspaper, magazine, packaging etc. and respectively leads Domain.Especially have for the printed matter of product packaging and be extremely widely applied, such printed matter is common in the using face of paper wood On be printed with one layer of ink layer so that paper wood has the effect of advertisement, mark.And with the improvement of living standards and, people couple The quality requirements of printed matter for product packaging also greatly improve, for this purpose, the printing technology in package introduces magnetic Property anti-counterfeiting printing technology, i.e., magnetic orientation is carried out to the magnetic pigment flakes of magnetic optically internal ink using magnetic orientation device, generated The particular optical pattern artificially designed.This technical application needs specific printing equipment to realize, such as: application number: 201210276242.4 a kind of entitled magnetic printing equipment.It is also desirable to which specific magnetic optically ink cooperation comes in fact It is existing, such as: application number: 201310439920.9, entitled a kind of infrared pigment of sheet-like magnetic and preparation method thereof, the two technology knot After conjunction, the infrared pigment of sheet-like magnetic generates such as " roller ball " effect, but this single effect by determining magnetic after printing.
Summary of the invention
In view of this, it is an object of the invention to propose that a kind of decorative effect magnetic outstanding rolls pattern printed matter surely.
One of to achieve the purpose of the present invention, a kind of magnetic is provided and rolls pattern printed matter, including radium-shine light beam paper surely, and Magnetic paint layer, plain net flower bottom and the pattern level middle tone layer successively printed from inside to outside on the radium-shine light beam paper； Wherein:
The radium-shine light beam paper is as printing element；
The magnetic paint layer is that magnetic powder is printed on printing element by magnetic orientation printing technology into magnetic paint Layer；
Lead to the background color layer of version printing carried out by the plain net flower bottom using blue ink；
The pattern level middle tone layer is the floral designs layer of blue ink print in use, and floral designs region has The performance of middle tone level, contrast range are 35%-65%, background area vacates, not ink；
The equivalent grain size of the magnetic paint layer is 1~100 μm, with a thickness of 0.1~10 μm, the color of the blue ink Allotment ratio are as follows: blue: red=4-6:1-3；The mixing color ratio of blue ink in the pattern level middle tone layer are as follows: blue: red =4-6:3-5；
The plain net flower bottom, pattern level middle tone layer are printed using offset printing or gravure mode.
Further, the magnetic powder is four oxygen that surface coats one layer of aluminum oxide by chemical liquid deposition Change three iron powders.
The aluminum oxide realizes coated ferriferrous oxide powder by the following method:
By AlCl3It is placed under stationary temperature and pH value condition, hydrolysis generates aluminium hydroxide uniform deposition in sheet-like magnetic On powder surface, drying is then filtered.
Further, the aluminum oxide realizes coated ferriferrous oxide powder by the following method:
(1) ferroso-ferric oxide powder is taken, ammonium fluoride aqueous solution is added, stirring is warming up to 50 DEG C, is put into suction filtration after handling 0.5h Slot, filtering and washing fluorinion concentration into filtrate are less than 50ppm, obtain pretreated ferroso-ferric oxide powder；
(2) resulting ferroso-ferric oxide powder, deionized water will be pre-processed, stirring is warming up to 80 DEG C, and adjusting pH value is 7.0, It is uniformly added into AlCl3 solution, and is adjusted with NaOH solution maintain pH stable simultaneously, insulated and stirred 2h, then takes out after having fed Filter, is first washed with deionized, then cleaned with ethyl alcohol, then dries at 100 DEG C.
Further, the radium-shine light beam paper is band, twill or radial radium-shine light beam paper.
Another object to realize the present invention provides the printing process that a kind of magnetic rolls pattern printed matter surely, including following Step:
Use radium-shine light beam paper as printing element, magnetic powder is printed on printing element by magnetic orientation printing technology At magnetic paint layer；
The plain net flower bottom for using blue ink to lead to version printing as background color layer on the magnetic bisque；The blue ink Mixing color ratio are as follows: it is blue: red=4-6:1-3；
Pattern level middle tone of the blue ink print as floral designs layer in the plain net is spent on bottom, used Layer, wherein floral designs region is showed using middle tone level, contrast range is 35%-65%, and background area vacates, not Ink；The mixing color ratio of the middle blue ink are as follows: blue: red=4-6:3-5.
Compared with prior art, the beneficial effects of the present invention are by successively using magnetic paint layer on printing element Magnetic orientation printing technology is realized, can reach
Magnetic orientation printing technology and conventional printing techniques, wherein stereo progressiveness ball caused by magnetic orientation printing technology because Observer visual angle is different, and in printed matter position " rolling " can occur for sphere, and with " quiet at the planar graph of traditional printing printing Therefore only " state relatively moves between ball and planar graph, feeling figure " floating " ultimately forms on sphere A kind of visual effect of the big depth of field of dynamic, to achieve the effect that common printed picture and text cannot be when.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
Fig. 1 is common printed effect diagram.
Fig. 2 is common printed effect diagram.
Fig. 3 is the effect diagram that specific embodiment of the invention printed matter is observed from different perspectives.
Specific embodiment
With reference to the accompanying drawings and examples, the present invention is specifically described.It will be appreciated that following description In, the terms such as "upper", "lower", "inner", "outside" are only used for indicating the direction referring to indicated by attached drawing.
The printed matter gesture X-Y scheme that common printing technology prints, it is as shown in Figure 1, Figure 2, shown.With printing technology Raising of the raising and people of development to the quality requirements of the printed matter for product packaging, three-dimensional, anti-fake requirement are being printed On be suggested.The present invention proposes that a kind of magnetic rolls pattern printed matter, including radium-shine light beam paper surely, and in the radium-shine light beam paper On the magnetic paint layer that successively prints from inside to outside, plain net flower bottom, pattern level middle tone layer；Wherein:
Radium-shine light beam paper is as printing element.Band, twill or radial radium-shine light beam paper can be selected in radium-shine light beam paper, excellent It is selected as the radium-shine light beam paper of band；Magnetic paint layer is that magnetic powder is printed on printing element by magnetic orientation printing technology into magnetism Coat of colo(u)r；The background color layer for being led to version printing carried out by plain net flower bottom using blue ink, is showed, rank using milder middle tone level Tune range is 35%-65%, the region other than floral designs be background area vacate, not ink.This layer is in overall dynamics matter The saturation degree that enhancing decorative pattern is played in sense effect, pulls open the space length of decorative pattern and background, generates stereoscopic effect；In pattern level Between adjust the layer to be the floral designs layer of blue ink print in use, floral designs region has the performance of middle tone level, background area Vacate, not ink.The radium-shine light beam film of PET on the radium-shine light beam paper surface as printing element " can go here and there with angle change It is dynamic ", the whole floral designs after can making printing are rich in dynamic.
Magnetic powder in preceding solution is surface by the four of chemical liquid deposition one layer of aluminum oxide of cladding Fe 3 O powder.The principle of this method is by AlCl by the following method3It is placed under stationary temperature and pH value condition, hydrolysis life At aluminium hydroxide uniform deposition on sheet-like magnetic powder surface, then filtering drying can be obtained one layer of aluminum oxide of cladding Sheet-like magnetic powder, is implemented as follows:
(1) ferroso-ferric oxide powder is taken, ammonium fluoride aqueous solution is added, stirring is warming up to 50 DEG C, is put into suction filtration after handling 0.5h Slot, filtering and washing fluorinion concentration into filtrate are less than 50ppm, obtain pretreated ferroso-ferric oxide powder.The step makes four oxygen Change three iron powder roughing in surface and activation, effectively improve specific surface area and surface-active, makes the clad of next step aluminum oxide It is fine and close, stable.
(2) resulting ferroso-ferric oxide powder, deionized water will be pre-processed, stirring is warming up to 80 DEG C, and adjusting pH value is 7.0, It is uniformly added into AlCl3Solution, and adjusted with NaOH solution maintain pH stable simultaneously, insulated and stirred 2h, then takes out after having fed Filter, is first washed with deionized, then cleaned with ethyl alcohol, then dries at 100 DEG C.
The equivalent grain size of magnetic paint layer is 1~100 μm, with a thickness of 0.1~10 μm.When thickness selects above range, magnetic Property coat of colo(u)r can preferably be suitble to ink print.
Plain net spends bottom, pattern level middle tone layer to print using offset printing or gravure mode.Magnetic paint layer is fixed by magnetic To printing.Fig. 3 is the product printed out using the technical program, the effect seen from different perspectives.Sphere can be regarded with observer In printed matter position " rolling " occurs for angle variation, relatively moves between ball and planar graph, feels figure " floating " in sphere On, and ultimately form a kind of visual effect of big depth of field of dynamic, thus achieve the effect that common printed picture and text cannot when, Simultaneously also with the function of magnetic anti-counterfeit.
The present invention also provides the printing processes that a kind of magnetic rolls pattern printed matter surely, comprising the following steps:
Use radium-shine light beam paper as printing element, magnetic powder is printed on printing element by magnetic orientation printing technology At magnetic paint layer；
The plain net flower bottom for using blue ink to lead to version printing as background color layer on magnetic bisque；The color tune of the blue ink With ratio are as follows: blue: red=4-6:1-3；
On plain net flower bottom, use in pattern level middle tone layer of the blue ink print as floral designs layer, wherein it is colored Line area of the pattern is showed using middle tone level, and contrast range is 35%-65%, background area vacates, not ink；In described The mixing color ratio of blue ink are as follows: blue: red=4-6:3-5.
It should be understood by those ordinary skilled in the art that: the discussion of any of the above embodiment is exemplary only, not It is intended to imply that the scope of the present disclosure (including claim) is limited to these examples；Under thinking of the invention, above embodiments Or can also be combined between the technical characteristic in different embodiments, step can be realized with random order, and be existed such as Many other variations of the upper different aspect of the invention, for simplicity, they are not provided in details.Therefore, it is all Within the spirit and principles in the present invention, any omission, modification, equivalent replacement, improvement for being made etc. be should be included in of the invention Within protection scope.

Claims (5)

1. a kind of magnetic rolls pattern printed matter surely, which is characterized in that including radium-shine light beam paper, and on the radium-shine light beam paper Magnetic paint layer, plain net flower bottom and the pattern level middle tone layer successively printed from inside to outside；Wherein:
The radium-shine light beam paper is as printing element；
The magnetic paint layer is that magnetic powder is printed on printing element by magnetic orientation printing technology into magnetic paint layer；
The plain net flower bottom is the background color layer for leading to version printing using blue ink；
The pattern level middle tone layer is the floral designs layer of blue ink print in use, and floral designs region has centre Adjust level performance, contrast range is 35%-65%, background area vacates, not ink；
The equivalent grain size of the magnetic paint layer is 1~100 μm, with a thickness of 0.1~10 μm, the mixing color of the blue ink Ratio are as follows: blue: red=4-6:1-3；The mixing color ratio of blue ink in the pattern level middle tone layer are as follows: blue: red=4- 6:3-5；
The plain net flower bottom, pattern level middle tone layer are printed using offset printing or gravure mode.
2. magnetic according to claim 1 rolls pattern printed matter surely, which is characterized in that the magnetic powder passes through for surface Chemical liquid deposition coats the ferroso-ferric oxide powder of one layer of aluminum oxide.
3. magnetic according to claim 2 rolls pattern printed matter surely, which is characterized in that the aluminum oxide is by such as Lower method realizes coated ferriferrous oxide powder:
By AlCl3It is placed under stationary temperature and pH value condition, hydrolysis generates aluminium hydroxide uniform deposition on sheet-like magnetic powder surface On, then filter drying.
4. magnetic according to claim 2 rolls pattern printed matter surely, which is characterized in that the aluminum oxide is by such as Lower method realizes coated ferriferrous oxide powder:
(1) ferroso-ferric oxide powder is taken, ammonium fluoride aqueous solution is added, stirring is warming up to 50 DEG C, is put into suction filtration tank after handling 0.5h, takes out Filter washing fluorinion concentration into filtrate is less than 50ppm, obtains pretreated ferroso-ferric oxide powder；
(2) resulting ferroso-ferric oxide powder, deionized water will be pre-processed, stirring is warming up to 80 DEG C, and adjusting pH value is 7.0, uniformly AlCl3 solution is added, and is adjusted with NaOH solution maintain pH stable simultaneously, insulated and stirred 2h, then filters after having fed, first It is washed with deionized, then is cleaned with ethyl alcohol, then dried at 100 DEG C.
5. magnetic according to claim 1 rolls pattern printed matter surely, which is characterized in that the radium-shine light beam paper be band, Twill or radial radium-shine light beam paper.
CN201810897259.9A 2015-12-11 2015-12-11 Magnetic fixed rolling pattern printed matter Active CN109130565B (en)

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