CN109130359A - A kind of novel flame-retardant composite fiber material - Google Patents

A kind of novel flame-retardant composite fiber material Download PDF

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Publication number
CN109130359A
CN109130359A CN201810837230.1A CN201810837230A CN109130359A CN 109130359 A CN109130359 A CN 109130359A CN 201810837230 A CN201810837230 A CN 201810837230A CN 109130359 A CN109130359 A CN 109130359A
Authority
CN
China
Prior art keywords
layer
retardant
fire
fabric
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810837230.1A
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Chinese (zh)
Inventor
王俊明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Ming Ye Chemical Fiber Co Ltd
Original Assignee
Taicang Ming Ye Chemical Fiber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Ming Ye Chemical Fiber Co Ltd filed Critical Taicang Ming Ye Chemical Fiber Co Ltd
Priority to CN201810837230.1A priority Critical patent/CN109130359A/en
Publication of CN109130359A publication Critical patent/CN109130359A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/02Layered products comprising a layer of natural or synthetic rubber with fibres or particles being present as additives in the layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0246Acrylic resin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14Mixture of at least two fibres made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing

Landscapes

  • Woven Fabrics (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of novel flame-retardant composite fiber materials, it include: fabric substrate layer (1), the fabric substrate layer (1) is using modification of aramid fiber and acid fiber by polylactic is blended is made, one layer of fire resistance fibre precoat (2) is arranged in area substrate layer (1) upper surface, fire resistance fibre precoat (2) upper surface is provided with fireprotection layer (3), the fabric substrate layer (1), fire resistance fibre precoat (2), fireprotection layer (3) is combined with each other by adhesive, the lower surface of the fabric substrate layer (1) is provided with protective layer (4), protective layer (4) lower surface is provided with thermal insulation layer.By the above-mentioned means, the present invention is fire resistance fibre fabric using surface layer, is had lasting flame retardant effect, inner layer is fireprotection layer, and heat-resisting quantity is good, can increase substantially the permanent flame retardant property of fabric lining using the structure design of optimization.

Description

A kind of novel flame-retardant composite fiber material
Technical field
The present invention relates to fabric fields, more particularly to a kind of novel flame-retardant composite fiber material.
Background technique
As the improvement of people's living standards, requirement of the modern to clothes is higher and higher, people remove when selecting clothes Outside selection color style, it is also contemplated that the functionality of clothes, such as this clothes be comfortable, it is heat-resisting, breathe freely etc., in the prior art Inflaming retarding fabric is had a single function using fabric lining, and when encountering kindling, inflaming retarding fabric is inflammable, and fire-retardant effect is not very good.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of novel flame-retardant composite fiber materials.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: it is multiple to provide a kind of novel flame-retardant Condensating fiber fabric characterized by comprising fabric substrate layer (1), the fabric substrate layer (1) using modification of aramid fiber and Acid fiber by polylactic is blended to be made, and one layer of fire resistance fibre precoat (2), the resistance is arranged in area substrate layer (1) upper surface The combustion fibrous face bed of material (2) upper surface is provided with fireprotection layer (3), and the fabric substrate layer (1), is prevented fire resistance fibre precoat (2) Fire bed (3) is combined with each other by adhesive, and the lower surface of the fabric substrate layer (1) is provided with protective layer (4), described Protective layer (4) lower surface is provided with thermal insulation layer.
In a preferred embodiment of the present invention, the fire resistance fibre precoat be using fire-retardant carbon fiber, long filament and Organic fire-retardant, according to the blended rear obtained fire resistance fibre fabric of the ratio of 3:2:1.
In a preferred embodiment of the present invention, the fireprotection layer includes the blended of flame-retardant acrylic fibre fiber and flame-retardant cotton fiber Fabric.
In a preferred embodiment of the present invention, the protective layer is polyphenylene sulfide and polyester fiber mixing composition.
In a preferred embodiment of the present invention, the thermal insulation layer is fire-retardant polytetrafluoroethylene fibre and solar heat protection rubber.
In a preferred embodiment of the present invention, the adhesive is chlorinated rubber.
The beneficial effects of the present invention are: a kind of structure design of the novel flame-retardant composite fiber material of the present invention using optimization, It is fire resistance fibre fabric using surface layer, there is lasting flame retardant effect, inner layer is fireprotection layer, and heat-resisting quantity is good, can be significantly Improve the permanent flame retardant property of fabric lining.
Detailed description of the invention
Fig. 1 is the schematic perspective view of one preferred embodiment of mobile phone of the present invention;
The components in the drawings are labeled as follows: 1. fabric substrate layers, 2. fire resistance fibre precoats, 3. fireprotection layers, 4. protection Layer, 5. thermal insulation layers.
Specific embodiment
The preferred embodiments of the present invention will be described in detail with reference to the accompanying drawing, so that advantages and features of the invention energy It is easier to be readily appreciated by one skilled in the art, so as to make a clearer definition of the protection scope of the present invention.
Referring to Fig. 1, the embodiment of the present invention includes:
A kind of novel flame-retardant composite fiber material, comprising: fabric substrate layer (1), the fabric substrate layer (1) use modifying aramid fiber Fiber and acid fiber by polylactic is blended is made, one layer of fire resistance fibre precoat (2) is arranged in area substrate layer (1) upper surface, Fire resistance fibre precoat (2) upper surface is provided with fireprotection layer (3), the fabric substrate layer (1), fire resistance fibre precoat (2), fireprotection layer (3) is combined with each other by adhesive, and the lower surface of the fabric substrate layer (1) is provided with protective layer (4), protective layer (4) lower surface is provided with thermal insulation layer.
It further illustrating, the fire resistance fibre precoat is to use fire-retardant carbon fiber, long filament and organic fire-retardant, according to Obtained fire resistance fibre fabric, fire retardant after the ratio of 3:2:1 is blended, assign the functional aid of combustible polymers flame retardancy, main If being directed to the Principle And Method of Flame Retardation Design of high molecular material;Fire retardant there are many type, by application method be divided into additive flame retardant and Reactive flame retardant.Additive flame retardant is added in polymer by mechanical mix techniques, and polymer is made to have anti-flammability , it is halogenated flame retardant (organic chloride and organic bromide) and non-that additive flame retardant, which mainly has organic fire-retardant, at present Halogen.Organic is using bromine system, phosphorus nitrogen system, nitrogen system and red phosphorus and compound as some fire retardants of representative, and this fire retardant is added to For mixed textile at fire resistance fibre fabric, heat resistance is strong in carbon fiber and long filament, high mechanical strength.
It further illustrates, the fireprotection layer includes the blended fabric of flame-retardant acrylic fibre fiber and flame-retardant cotton fiber;Acrylic fibers are poly- Dralon China trade name, it is external then be known as " Orlon ", " cashmere synthetic fibre ".Typically refer to the propylene with 85% or more Nitrile and second and Third monomer copolymer, through synthetic fibers made from wet spinning or dry spinning.Acrylonitrile content is 35% Fiber made from copolymer spinning between~85% is known as modified acrylic fibre, and the performance pole of polyacrylonitrile fibre is like sheep Hair, preferably, rebound degree can still keep 65% to elasticity when elongation 20%, fluffy curling and it is soft, warmth retention property is higher than wool by 15%, there is conjunction At the title of wool.22.1~48.5cN/dtex of intensity is 1~2.5 times higher than wool.Sun-proof function admirable, open-air exposure 1 year, Intensity only declines 20%, can be made into curtain, curtain, tarpaulin, gun cover etc..The acidproof, antioxidant of energy and common organic solvents, but it is resistance to Alkalinity is poor.190~230 DEG C of fiber softening temperature, sunlight resistance and against weather (occupy first) very well, and moisture absorption is poor.It is internal Close structure, wearability is poor, can improve these disadvantages by addition flame-retardant cotton fiber.
It further illustrates, the fireprotection layer includes the blended fabric of flame-retardant acrylic fibre fiber and flame-retardant cotton fiber.
Further illustrate, the protective layer is polyphenylene sulfide and polyester fiber mixing composition, polyphenylene sulfide chemical resistance It is good, stability can be enhanced by polyester fiber, there is high temperature resistant, fire retardant advantage.
It further explains, the adhesive is chlorinated rubber.
A kind of novel flame-retardant composite fiber material of the present invention is fire resistance fibre face using surface layer using the structure design of optimization Material has lasting flame retardant effect, and inner layer is fireprotection layer, and heat-resisting quantity is good, can increase substantially the permanent resistance of fabric lining Fire performance.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification and accompanying drawing content is applied directly or indirectly in other relevant skills Art field, is included within the scope of the present invention.

Claims (6)

1. a kind of novel flame-retardant composite fiber material characterized by comprising fabric substrate layer (1), the fabric substrate layer (1) using modification of aramid fiber and acid fiber by polylactic is blended is made, area substrate layer (1) upper surface be arranged one layer it is fire-retardant The fibrous face bed of material (2), fire resistance fibre precoat (2) upper surface are provided with fireprotection layer (3), the fabric substrate layer (1), Fire resistance fibre precoat (2), fireprotection layer (3) are combined with each other by adhesive, the lower surface of the fabric substrate layer (1) It is provided with protective layer (4), protective layer (4) lower surface is provided with thermal insulation layer.
2. novel flame-retardant composite fiber material according to claim 1, which is characterized in that the fire resistance fibre precoat It is using fire-retardant carbon fiber, long filament and organic fire-retardant, according to the blended rear obtained fire resistance fibre fabric of the ratio of 3:2:1.
3. novel flame-retardant composite fiber material according to claim 1, which is characterized in that the fireprotection layer includes fire-retardant nitrile The blended fabric of synthetic fibre fiber and flame-retardant cotton fiber.
4. novel flame-retardant composite fiber material according to claim 1, which is characterized in that the protective layer is polyphenylene sulfide Resin and polyester fiber mixing composition.
5. novel flame-retardant composite fiber material according to claim 1, which is characterized in that the thermal insulation layer is fire-retardant poly- four Vinyl fluoride fiber and solar heat protection rubber.
6. novel flame-retardant composite fiber material according to claim 1, which is characterized in that the adhesive is chlorination rubber Glue.
CN201810837230.1A 2018-07-26 2018-07-26 A kind of novel flame-retardant composite fiber material Pending CN109130359A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810837230.1A CN109130359A (en) 2018-07-26 2018-07-26 A kind of novel flame-retardant composite fiber material

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Application Number Priority Date Filing Date Title
CN201810837230.1A CN109130359A (en) 2018-07-26 2018-07-26 A kind of novel flame-retardant composite fiber material

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CN109130359A true CN109130359A (en) 2019-01-04

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110936689A (en) * 2019-12-10 2020-03-31 龙泉服饰(南通)有限公司 Artificial fiber fabric with fireproof function

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102429336A (en) * 2011-09-30 2012-05-02 常熟市众望经纬编织造有限公司 Wear-resisting and inflaming retarding shell fabric
CN103556351A (en) * 2013-10-17 2014-02-05 苏州威尔德工贸有限公司 Flame-retardant fabric
CN205648991U (en) * 2016-05-23 2016-10-19 绍兴文理学院 Anti -flaming fabrics

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102429336A (en) * 2011-09-30 2012-05-02 常熟市众望经纬编织造有限公司 Wear-resisting and inflaming retarding shell fabric
CN103556351A (en) * 2013-10-17 2014-02-05 苏州威尔德工贸有限公司 Flame-retardant fabric
CN205648991U (en) * 2016-05-23 2016-10-19 绍兴文理学院 Anti -flaming fabrics

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110936689A (en) * 2019-12-10 2020-03-31 龙泉服饰(南通)有限公司 Artificial fiber fabric with fireproof function

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